Competence in pH measurement

Sensors, assemblies and transmitters

for all applications
Solutions for liquid analysis
Over 30 years' experience in analysis
measuring technology makes the globally
present Endress+Hauser Group a strong
partner. Endress+Hauser pH measuring
systems can be found everywhere where
the customer requires reliable measured
values, a high degree of availability and
long operating times. With the production
of 250,000 process electrodes per year,
the company has achieved the top
position in the world market. The quality
of the electrodes and solutions is among
the highest customers can actually use.
Ongoing expansion of its research and
development capacity in the past number
Research and development pay
With the new Ceragel and Tophit sensors,
Endress+Hauser is presenting sensor types
whose capabilities can hardly be beaten.
The CPS71 sensor is the only sensor on
the market with an innovative double
chamber and double gel reference system
with a classic design, i.e. 120 mm length
and 12 mm shaft glass diameter. New
gel compositions ensure a high level of
protection against contamination and
a wide measuring range of 0 to 14 pH.
Longer operating times are automatically
guaranteed here. Progress could also be
made in glass research. The new B glass
introduced a membrane glass to meet
the present-day and future demands
2
of years has further improved the
performance and high quality of the
products and the company has been able
to offer new technologies to the user.
Consequently, not only was the non-
glass pH sensor made available to process
measurement but the fully automated
measuring point with a very good cost/
performance ratio was also launched on product quality for the customer as well
the market. By mastering all the technically as rapid turnaround times and outstanding
difficult production stages in conjunction delivery reliability with regard to all
with a high degree of automation in almost standard products or individual products
all production areas, Endress+Hauser has tailor-made for special applications.
achieved a very good range of manufacture. Solutions are offered for almost every
This results in very high and consistent relevant branch.
of the processes. At Endress+Hauser, This ensures a safe connection to IP 68
there are just two membrane glasses which is TV certified up to 16 bar at
to cover all applications. The objective three-fold safety.
behind the new development was to
improve upon the sensor operating times Thus, in all areas of the economy,
of conventional pH/redox sensors and the dependable pH sensors from
thus reduce operating costs for the user. Endress+Hauser help to protect man and
By making ISFET technology available the environment and guarantee the quality
in the CPS441/471/491 sensor family of high-quality products.
for on-line pH measurement, new fields
of application have been opened in the
areas of biotechnology, the pharmaceutical
industry, the food industry and
environmental technology. All sensors from
Endress+Hauser are approved to ATEX/FM
and equipped with TOP 68 or Memosens.
Modular measuring point concept
The ambitious implementation of the
modular measuring point concept in
all assemblies of a pH measuring point
allows the customer to instrument from
a high-quality low-cost version right
up to a complete high-tech application
all from the one shop. If developing
a manual measuring point right up to a
fully automatic pH solution, the user finds
the ideal solution for every requirement.
Well planned and thought-out modular
concepts give the customer the opportunity
of introducing the optimum sensor into
the process. There is a great range of
assemblies to choose from with so many
different process connections for all possible
installation positions and various materials
from PVC to stainless steel right up to
Hastelloy.
With the retractable assemblies, the
customer is always integrating a sensor
with the standard length of 120 mm into
the application. All sensor types fit into
the same assemblies. As a result, it is easy
to convert to another sensor type even in
difficult applications.
The modularity element continues in the
transmitter concept. Here too, models
range from the new powerful Liquiline in
two-wire technology to the pH transmitter
"Liquisys" (most sales worldwide) right
up to the top-class device "Mycom". Each
device line is characterised by its simple
and uniform operation. The unique Parawin
software tool for the Mycom transmitter
allows users to configure the entire pH
measurement off line at their own PC.
Service means more than just maintenance
Perfectly functioning measurement requires
thorough planning. The right choice of
sensor leads to an optimum operating
time of the pH sensor. Today, engineers at
Endress+Hauser assist the customer from
planning the pH measuring point right
up to commissioning and maintenance
The configuration is then transferred to the
transmitter locally by means of an easy-to-
use data block and measurement can start.
This makes any adjustment for complex
processes absolute child's play.
It goes without saying that downloadable
software as well as HART and PROFIBUS
are available for all transmitter families and
offer the highest possible degree of variation
for differing applications.
on site. Together with the customer, the
applications are observed in detail and
the various measuring point modules
are recommended. The media in which
measurement takes place, the pressure
and the temperature are important factors
for the correct specification of the pH
measurement. All moving parts of the
retractable assemblies must be serviced
regularly to ensure the high degree of
availability of the system. If the customer
so desires, maintenance concepts and
training programmes are worked out for the
operating staff. Endress+Hauser accepts the
entire responsibility for the pH measuring
point.
3
pH measurement in the chemical industry
Assemblies
Optimum installation solutions with
retractable assembly technology or
permanent installations
The pH sensors can be optimally
integrated into the processes with the aid
of Endress+Hauser assembly technology.
Almost any process connection can be
made. Many special materials are available
on request.
Dipfit CPA140
Cleanfit CPA475
Unifit CPA442
4
pH measurement is one of the most
important online analysis methods in
the chemical industry. The monitoring,
accuracy and maintenance of the pH value
in the production plants is a guarantee
for optimised product yields. As a result,
the pH value is also especially suited as a
measured variable to control and regulate
chemical processes. As a limit variable it is
Flow assemblies
Flowfit CPA240
Bypass measurement
Installation of up to three electrodes
Spray cleaning possible
Cost-effective and high degree of sensor
availability
Dipfit CPA140 immersion assemblies
Installation in open basins and high
containers
Sensor holder with bayonet lock prevents
the cable from twisting
during installation
Use in enamelled or rubberised
containers
Wide range of materials allows diverse
use
Installation of up to three electrodes
possible
Cleanfit CPA471
Cleanfit CPA450
Flowfit CPA240
used to trigger alarms, protect material
and the environment against damage and to
guarantee a high degree of product quality.
Large demands are made on electrodes in
modern industrial processes. By selecting
the right electrode and with the long
operating times of Endress+Hauser sensors,
the user can easily reduce the operating
costs of a plant.
Unifit CPA442 installation assemblies
Simple permanent installation
Integrated protection guard protects
against electrode breakage
Low-cost pipe and boiler mounting
Retractable assemblies for high
demands Cleanfit CPA450/471
Highest degree of safety for man and
process thanks to ball valve or patented
O-ring sealing concept as process seal
Simple and easy to operate
High degree of sensor availability
Sensor change and check during the
running process
Integrated rinse chamber allows
contamination-free work and cleans the
sensor optimally
Large choice of special materials and
sealing concepts
Integrated scraper ring possible
All assemblies can be easily converted
from gel-filled to liquid-filled sensors
Transmitters Mycom S CPM153

Mycom S CPM153 transmitter Liquiline M CM42 transmitter

Monitoring functions for electrode slope,
zero point, membrane glass impedance
and diaphragm resistance
Newly developed process check system
Logbook functions for calibrations, pH
value, alarms and operating commands
Optimum diagnosis module
Two independent measuring channels for
redundancy and differential measurement
Configuration with software module
Parawin at PC workplace.
Can be easily expanded to fully automatic
measuring point
NAMUR contacts
Optimised alarm and controller functions
Two freely configurable current outputs
The fully automatic system solutions with
Topcal S are described on Page 10.
Two-wire transmitter with large, high-
contrast display and red alarm LED
Plastic housing with handy keys, IP 67
Flexible module concept, fast
replacement or extension even in
hazardous applications
Menu navigation and configuration via
navigator, intuitive operation thanks to
plain text messages and online help
Second current output
Monitoring function for electrode
slope, zero point, sensor check system
for impedance of glass membrane and
diaphragm
FOUNDATION FIELBUS, PROFIBUS and
HART fieldbus protocols
Liquiline M CM42

Sensors
New sensor technologies
open up new applications
All relevant sensors from Endress+Hauser
are approved to ATEX/FM and equipped
with TOP 68 or Memosens. This ensures a
safe connection to IP 68; the plug-in heads
are TV certified up to 16 bar.
Orbisint CPS11
Dirt-repellent teflon ring diaphragm
High chemical stability thanks to
advanced gel developments
Reliable measurement results in event of
extreme pH values (pH 0 14)
Can be used with high pressures
Ceraliquid CPS41
Rapid response time and highest level of
precision
High degree of protection against
contamination thanks to
liquid electrolyte refilling
Can be used with external reference
Ideal for media with low
conductivity
Electrolyte flow can be increased if there
is a risk of diaphragm blockage
Orbipore CPS91
Open aperture allows use in precipitation
reactions, emulsions and suspensions
Rapid response time and high level of
precision
Standard sensor for chemical element
production
Can be used with high pressures
Use is recommended in pigment
manufacturing and in the production of
colourants
Tophit sensors CPS441/CPS491
New applications are opened up with the
new non-glass ISFET sensors
(ion-sensitive fieldeffect transistor). The
ISFET sensors in the Tophit line can
even be installed overhead. They are
characterised by their extremely stable
PEEK shaft and can be used in media with
high organic solvent parts.
Low-maintenance
Liquid electrolyte refilling
(CPS441)
High sensor stability leads to extended
calibration intervals
Ideal for low medium conductivity
Rapid response time even at low
temperatures (up to -15 C)
Open aperture allows use in precipitation
reactions, emulsions and suspensions
(CPS491)
Suitable for media with a low proportion
of water

Orbisint Ceraliquid Orbipore Tophit Tophit

CPS11D CPS41D CPS91D CPS441 CPS491

5
pH measurement in food/pharmaceuticals
Very high demands are made on
a measuring point in the food and
pharmaceutical industries with regard to
hygiene and cleanability. Endress+Hauser
offers a wide range of special pH sensors
for this purpose which are characterised
by optimum cleanability, a high number
of CIP and SIP cycles and the possibility
of autoclaving. In addition, special pH
sensors have a certified biocompatibility to
ISO standard which guarantees that only
biologically safe materials are in direct
contact with the medium. As an additional
Assemblies
Cleanfit CPA475
and CPA465 retractable assemblies
Automation especially of
hygienic processes possible
In-line steam sterilisability according to
EHEDG test procedure
Unifit CPA442
Cleanfit CPA475/465
Cleanfit CPA475/465
6
product safety element, Endress+Hauser is
the only supplier to equip its sensors with
biologically safe, completely acrylamide-free
gel. Various safety measures (to prevent
against contamination) are combined in a
sensor to achieve especially long electrode
operating times in contaminated conditions
in particular (for example, in processes with
amino acid compounds containing sulphur).
The CPS71 and CPS471 sensors are
equipped with a bridge electrolyte which
makes the way longer for toxic substances.
They also have a double chamber reference
Leak check of process seal
3A-approval with materials in conformity
with the FDA
Fully automatic calibration and cleaning
possible with Topcal S CPC300
Thermal decoupling of process
connection from pneumatic drive with
Cleanfit CPA465
Electrolyte vessel
which protects the reference system from
the electrode poisons. Typical processes
such as active agent synthesis, product
treatment and fermentation can be
monitored more easily since the CPS471
and CPS441 sensors can be installed in an
overhead position. In the pharmaceutical
and foodstuff industries, major demands are
made on the hygiene of the pH measuring
points. The EHEDG certified CPA442
assembly meets these demands and thus
guarantees the safety and quality of the
products.
Unifit CPA442 installation assembly
Permanent installation assembly
with patented moulded seal for glass
electrodes and non-glass ISFET sensors
EHEDG certified online cleanability
Electropolished surface
Available for all important process
connections
Cleanfit CPA475/465
Unifit CPA442

Liquisys M CPM223
Transmitters
Liquisys M CPM223/253
transmitter
Simple to operate: clear menu structure
with plain language in 6 languages makes
configuration easier
Large two-line display allows
simultaneous display of measured value
and temperature
Ultra simple two-point calibration via the
CAL key
Sensor check system for pH glass
Live check of the sensor
Sensors
Ceraliquid CPS41
with electrolyte vessel CPY7
pH combination electrode with KCl liquid
electrolyte for special applications with
high requirements, especially in the case
of rapidly changing media
Sterilisable
Tophit CPS441
Non-glass and break-proof
pH sensor (material in contact with
medium FDA listed);
Material in contact with medium
biocompatible
Horizontal mounting and overhead
installation possible
Sterilisable, autoclavable,
cleanability according to EHEDG
test procedure
Liquisys M CPM253
Liquiline M CM42
Mycom S CPM153 transmitter
The ideal supplement for standard glass
electrodes and ISFET pH sensors with
clear text operation
High safety and certainty of
measurement thanks to integrated
monitoring functions
Logbook functions of operation,
calibration and error messages
Documentation of complete measuring
point possible with optional off-line
Parawin tool
Can be retrofitted to fully automatic
calibration and cleaning system
Topcal S CPC300
Ceraliquid CPS71
CIP/steam-sterilisable/autoclavable glass
sensor for sterile
pH measurement
Certified biocompatibility of all
materials in contact with medium
Especially low-maintenance thanks to
double chamber reference with
integrated bridge electrolyte
Reference gel free from acrylamide and
polyacrylamide
Ceraliquid Tophit
CPS41D CPS441
Mycom S CPM153
Liquiline M CM42 transmitter
Two-wire transmitter with large, high-
contrast display and red alarm LED
Stainless steel housing with membrane
keypad, hygienic design, IP 67
Flexible module concept, fast
replacement or extension even in
hazardous applications
Menu navigation and configuration via
navigator, intuitive operation thanks to
plain text messages and online help
Second current output
Monitoring function for electrode
slope, zero point, sensor check system
for impedance of glass membrane and
diaphragm
FOUNDATION FIELBUS, PROFIBUS and
HART fieldbus protocols
Tophit CPS471
Non-glass and break-proof
pH sensor (materials in contact with
medium FDA listed);
Wetted ports biocompatible
Horizontal mounting and
overhead installation possible
Sterilisable, autoclavable
cleanability according to EHEDG
test procedure
Especially low-maintenance
Reference gel free from acrylamide and
polyacrylamide
Ceragel Tophit
CPS71D CPS471
7
pH measurement in water/wastewater

The treatment of drinking water or

wastewater always involves monitoring
regulated processes. As a result, the
pH value is one of the most important
measured variables in all stages of the
process as both a value determining the
quality of the water and as a controlled
variable which has a direct effect on the
economic efficiency of the plant.

Assemblies
Cleanfit CPA473 retractable assembly
Automation even for difficult processes
Various immersion depths
(tank/pipe installation)
Sealing water to screen off the rinse
chamber
Optionally with scraper seal
Fully automatic calibration and cleaning
in conjunction with Topcal S CPC 300
Cleanfit CPA450 retractable assembly
Reliable separation of process with
stainless steel ball valve
Use of standard gel electrodes with or
without integrated Pt 100 with length
120 mm
Variable immersion depth up to
700 mm
Integrated rinse and calibration
connections
Dipfit CYA611 immersion assembly
3 possible ways of securing unit:
Wall mounting, suspension bracket,
pendulum mounting
Simple sensor mounting via G1 and
NPT 34" thread
Flowfit CPA250 flow assembly
Installation locations for maximum three
sensors Pg 13.5 (pH, redox, temperature,
cleaning)
Easy access to the electrodes in the flow
area thanks to screw-off sealing cap; as
a result, calibration or cleaning can take
place without the need to remove the
sensor.
Dipfit CPA111 immersion assembly
Flexible adjustment of immersion depth
thanks to adjustable flange; additionally
with bayonet lock thus easy to install and
detach the assembly.
Simple installation and removal of
electrode holder using bayonet securing
technology.
Three electrode installation locations for
pH/redox and temperature sensor or
cleaning in a standard length of 120 mm.
Chemoclean CPR31
spray cleaning system
The spray cleaning unit can be
retrofitted any time without the
need to convert the assembly.

Chemoclean CPR31
CYH101

Cleanfit CPA473

Dipfit CYA611

Dipfit CPA111
Cleanfit CPA450

Flowfit CPA250

8
Transmitters
Liquisys M CPM223/253
transmitter
Simple to operate: clear menu structure
with plain language in 6 languages makes
configuration easier
Large two-line display allows
simultaneous display of measured value
and temperature
Simple two-point calibration by means of
Cal key
Safe to operate: overvoltage protection
(high-voltage protector) to
EN 61000-4-5
Directly accessible manual control of
contacts
Calibration plausibility check
Customised alarm configuration for fault-
signalling contact and error current
Automatic start of cleaning following
alarm or limit value overshoot
Sensor check system for pH glass and
reference
Live sensor check
Special neutralisation regulator
Liquisys M CPM253 Liquisys M CPM223

Sensors
Orbisint CPS11
We recommend the Orbisint CPS11 sensor
with ring-shaped PTFE diaphragm and fixed
electrolyte for all standard applications. The
CPS12 is the standard redox electrode with
the CPS11 reference system.
Ceraliquid CPS41
The Ceraliquid CPS41 sensor with refillable
liquid electrolyte is used in applications
where there is a high risk of the diaphragm
blocking or where a high level of accuracy
is required.
Orbipac CPF81
Orbipore CPS91
pH combination electrodes with
The open aperture allows the use of the
"integrated" assembly as simplest
electrode in media with a high solids
mechanical adaptation in pipelines
content, in suspensions/emulsions as well
or immersion assemblies
as in precipitation reactions where the
Double chamber reference with
diaphragm would otherwise block in a short
KNO3 electrolyte bridge
time.
Optionally available with flat membrane
and integrated potential matching

Orbisint Ceraliquid Orbipore Orbipac

CPS11D CPS41D CPS91D CPF81

9
System solutions for pH measuring technology
Fully automatic measuring, calibration, sterilisation
and cleaning with Endress+Hauser.
Continuous maintenance of the sensor
guarantees a high degree of accuracy
and the highest degree of availability of
a pH measuring point. This comprises
both the cleaning and calibration of the
sensor as well as the monitoring of the
entire measuring point. However, this
leads to high operating and maintenance
costs. This makes a significant difference
Topcal S
The fully automated Topcal S system
for greater demands provides reliable
measurement results with a minimum
amount of maintenance particularly in
aggressive and highly contaminated media
as often occur in chemical processes. With
Topcal S, you can clean and calibrate
fully automatically outside the process.
Maintenance work is reduced to changing
the electrodes and buffer as well as the
cleaning solution.
10
especially in applications with high
requirements, such as in the chemical,
food and pharmaceutical industry or
with measuring points with aggressive
process conditions. Endress+Hauser offers
automatic pH measuring points to reduce
the running costs and maintenance costs
to a minimum. Thanks to the various
degrees of automation, a suitable automatic
Topclean S
Topclean S, the alternative, in which
automatic cleaning and manual
calibration outside the process suffice.
With Topclean S, you have the option of
automatically rinsing and cleaning the
electrodes outside the process. With an
additional valve, sterilisation can also
optionally take place. The programming,
safety functions and the data handling are
the same as for Topcal S.
measuring system can be found for each
process: from the simple application in
the area of wastewater to processes in
the chemical industry right up to very
demanding applications with regard to
accuracy and measuring safety and certainty
in the pharmaceutical industry.
Chemoclean
Chemoclean used in conjunction with
a Liquisys M or Mycom S as the control
unit ensures optimum cleaning of the
electrode directly in the process, as is
mostly sufficient in the wastewater sector.
By selecting a Mycom as the control unit,
you also have the extensive options of
off-line configuration at the PC as well as
the function of documenting the entire
measuring point by means of the Parawin
tool.
CYC300 cabinet for Topcal S
or Topclean S
Reliable protection of Topcal S or
Topclean S against environmental
conditions (dirt, water jets); also suitable
for use in the field under extreme
weathering conditions thanks to
integrated heater
Stainless steel or plastic version
meets requirements of both the food/
pharmaceutical sector and the chemical
industry
Maintenance friendly thanks to
retractable buffer box, a central unit for
all electrical connections, easy access to
wear parts
Operating panel for rapidly starting the
calibration and cleaning programmes
integrated in Topcal S simply at the press
of a button
Operating panel can be detached and
installed separately
Additional measured value recording
thanks to optional measured value
recorder (e.g. Memograph S)
Low-maintenance and cost-effective measurement
with Endress+Hauser.
Topcal S CPC300 Topclean S CPC30 Chemoclean

Fully automatic Fully automatic pH measuring

pH measuring pH measuring point with auto-
point with inte- point with inte- matic cleaning
grated control grated control system

Calibration Sterilisation Cleaning

Sterilisation Cleaning Rinsing
Cleaning Rinsin
Rinsing

pH transmitters

Mycom S CPM153
pH/redox transmitter
with controller and
limit functions for Ex and
non-Ex areas

Mycom S Liquisys M
CPM153 CPM223/253

pH assemblies

Retractable Cleanfit Cleanfit Immersion

assemblies CPA473 CPA475 assemblies
Cleanfit Process retrac- Sterilisable Dipfit CPA111
Compact pH assemblies table assembly retractable Dipfit CPA140
in various materials with ball valve assembly for
for all process connections shut-off the highest Flow
hygienic assemblies
requirements Flowfit CPA250
Flowfit CPA240

Spray cleaning
systems
Chemoclean CPR3
Chemoclean CPR30
Chemoclean CPR31

Zubehr

CPR40 CYR10 Toolkit

rinse block injector Parawin
For 1 or 2 Cleaning injector For off-line configuration
additional valves for Chemoclean of Topcal S/Topclean S
(sterilisation) system with at the PC
valves for motive
water and For Chemoclean in
cleaning agents conjunction with
Mycom S

11
pH sensors with Memosens technology
Measuring the pH value makes great
demands not only on the pH-sensitive
glass but also on the transmission of the
measured value from the sensor to the
transmitter. Low currents and very high
sensor internal resistances require a high-
impedance connection to the transmitter.
12
Moisture in the connection can change
the measured value and may even result
in measurement failure. The Memosens
technology revolutionises the safety of data
transfer by digitalising the measured value
in the sensor and transferring it to the
transmitter without a contacting, and thus
moisture-sensitive, connection. The jump in
technology to a new generation of sensors
has additional advantages and eliminates
general limitations of the technology in
place to date.
Memosens makes the pH electrode
a digital sensor with integrated data
storage
pH sensors with Memosens technology
save the current calibration data and
other information which can be used for
look-ahead maintenance, such as hours
of operation, maximum and minimum
pH values and maximum and minimum
temperature.
When the sensor is mounted, the
calibration data are automatically
transferred to the transmitter and used
to calculate the current pH value.
The result:
Measuring point maintenance is no
longer based on individual issues
identified but rather all relevant sensor
data are used.
The current application of the sensors
can be made to depend on the previous
history.
pH sensors with Memosens technology
are the first pH sensors to allow
calibration/adjustment away from the
measuring point in the measuring lab.

The result:
The availability of the measuring point is
dramatically increased by the quick and
easy replacement of precalibrated sensors.
Measuring point down-time is reduced to
the time between detecting and replacing
the sensor.
The calibration/adjustment itself
takes place under optimum external
conditions in the measuring lab.

Standard sensor Sensor with Memosens

Calibration on site Calibration in the measuring lab

sensor sensor
removal removal
sensor
installation

Calibration /
adjustment
Saving sensor data
QS documentation
Optimum
sensor lab conditions
installation

Measuring point maintenance Measurement

An unestablished connection between
the sensor and transmitter is actively
displayed the first really definite
connection
Digital measured value transmission
automatically results in an error message
if the signal flow is interrupted. And
this regardless of whether the sensor or
measuring cable is no longer working
properly. The result:
The availability of the measuring point is
dramatically increased and ensured
Automatic sensor detection allows for
unproblematic sensor replacement
The first non-contact measured value
transmission from the pH sensor to the
transmitter
pH sensors with integrated Memosens
technology transmit the measured value
contactlessly from the plug-in head of the
electrode to the cable coupling.
The result:
Principally free from corrosion of the
connection
A coupling system that can even be
connected under water
Free from leaks and measured value
distortion from moisture
EMC safety through galvanic
decoupling of medium from transmitter
Highly integrated electronics in the sensor
convert the analog signal of the pH sensor
to digital information which is then
transferred via the cable coupling to the
transmitter contactlessly and free from
interference potential. The result:
No more need to ask about
"symmetrically high-resistance" or
"unsymmetrical" or an impedance
converter.

Inductive signal transmission

Inductive energy transmission

13
pH glass electrodes

The method of pH measurement using glass This voltage is then measured relative to Internal buffer H+
electrodes is a potentiometric measurement a reference element. Nowadays, the most pH 7 H+
H+
method. Since glass is basically an modern pH glasses display high selectivity Cl-
H+
electric insulator, amplifiers for the pH (low cross-sensitivity to ions other than
measurement must have an extremely high H+) over a wide temperature range. H+
H+ +
input impedance. The measuring effect is A pH sensor achieves the outstanding H Cl-
based on a pH-sensitive glass membrane performance of the linear measurement of e +
ra n + H Cl-
H+ b
m H
whose surface reacts to the acid content a material component over a concentration e
sm
Glas H+ Medium
of the solution with a specific voltage. range of 14 (!) exponents. H +

Voltage occurrence with

pH measurement with glass electrodes

Glass electrodes Recommended General Diaphragm/ Version Special

area of application reference characteristics/
application features

Orbisint Standard applications Long-term monitoring, PTFE diaphragm, Ex, all shaft lengths with Very robust,
in process and the processes with little Double gel reference temperature sensor, Heavy-duty version / high
CPS11
environment change Memosens, pressure,
Advanced Gel integrated
Technology potential matching,
flat membrane,

Ceraliquid Special Rapidly changing Ceramic diaphragm, Ex, all shaft lengths with Greatest accuracy,
applications composition of media, Liquid lead temperature sensor Can be subject to pressure
CPS41
with high requirements highly clogging media, to prevent clogging,
with regard to low conductivities Gel-free,
accuracy, refillable
speed electrolyte,
3A

Ceragel Hygiene and Pharmaceuticals, Ceramic diaphragm, Ex, all shaft lengths with Overhead installation,
sterile applications biotechnology, Double chamber and temperature sensor, CIP/SIP and
CPS71
fermenters, double gel reference Memosens, autoclavable,
contaminating Advanced Gel with high
media, Technology accuracy,
overhead installation Free from acrylamide and
polyacrylamide,
3A,
biocompatible

Orbipore Process applications Media with high Open aperture, Ex, all shaft lengths with Rapid response,
contamination: Double gel reference temperature sensor, new, stabilised gel
CPS91
emulsions, Memosens, insensitive to contamination
suspensions, Advanced Gel
precipitation reactions Technology

14
Non-glass pH sensors
H+ Gate
Apart from using a glass membrane, the pH here. "Chemistry and electrical measure- H+
value can also be measured using an ion- ment are kept totally separate. As a result, H+
selective field-effect transistor (ISFET). It is, the sensor material does not change and
in effect, a simple transistor with a source the need for recalibration is by no means
and drain that are separated from the as frequent as with glass electrodes. Since Source Drain
gate by means of an isolator. As with the there is no source layer, ISFETs are also
glass membrane, hydrogen ions from the suitable for pH measurement in media with Semicon-
medium can accumulate on the gate. The a low proportion of water. Modern ISFET ductor
The current between the
resulting positive charge on the outer side materials are highly selective and follow element source and drain of the
of the gate is "mirrored" on the inner side the Nernst law in closer tolerance limits semiconductor element
where a negative charge occurs. This makes than glass. The sensor's extreme robustness depends on the charge at
the gate and thus directly
the semiconductor channel conductive. The comes from embedding the chip in a stable on the pH value.
"field effect" results from the extent of the and unbreakable PEEK body.
conductivity: the higher the pH value of the
liquid, the more H+ ions accumulate on the
gate and the more current can measurably
flow between the source and drain. In
contrast to the glass electrode, there is no
ion flow between the fluid and the sensor

Non-glass Recommended General Diaphragm/ Version Special

sensors area of application application reference characteristics/
features
Tophit Special applications Low temperatures, Ceramic diaphragm, Ex, all shaft lengths with Overhead installation, rapid
with high requirements Rapidly changing Liquid lead temperature sensor response at
CPS441
with regard to composition of media, low temperatures,
accuracy and speed, highly clogging media, lower amount of
non-glass low conductivities maintenance required than
break-proof with glass,
3A

Tophit Hygiene and sterile Low temperatures, Ceramic diaphragm, Ex, all shaft lengths with Overhead installation,
applications, pharmaceuticals, double chamber reference, temperature sensor, SIP, autoclavable,
CPS471
non-glass, biotechnology, double gel Advanced Gel rapid response, low
break-proof contaminating media Technology temperatures, lower
amount of maintenance
required than with glass,
free from acrylamide and
polyacrylamide,
3A,
biocompatible

Tophit Process applications, non- Low temperatures, Open aperture, Ex, all shaft lengths with Overhead installation, rapid
glass, emulsions, double gel reference temperature sensor, response at
CPS491
break-proof suspensions, Advanced Gel low temperatures,
organic solvents Technology stabilised gel
insensitive to contamination
lower amount of
maintenance required than
with glass

15
Overview of pH assemblies
Assemblies, whether used as immersion
assemblies, flow assemblies or retractable
assemblies, are the most important
connecting element between the sensor
and the process. Endress+Hauser is offering
100%-suitable solutions with regard to the
design and material, to pressure resistance and
comfort with the assemblies described and is
thus the only manufacturer who can equip all
measuring points safely and flexibly.

Immersion assemblies Flow assemblies Permanent installation assemblies

Dipfit Dipfit Dipfit Flowfit Flowfit Unifit

CYA611 CPA111 CPA140 CPA240 CPA250 CPA442
Application Water, wastewater Water, wastewater, Process Process Water Process, food,
process pharmaceuticals
Description Simple assembly 3 electrode installation 3 electrode installation 3 electrode installation 3 electrode installation 120 mm electrode
locations, 120 mm locations, 120 mm locations, locations, with and without
electrode, electrode, 120 mm electrode 120 mm electrode protection guard
bayonet technology bayonet technology

Area of use Open tank, Open tank, Closed tank Piping, Piping, Open and
open channel open channel bypass bypass closed tank,
closed tank piping

Process Suspended assembly Suspended assembly, Pressurised flange Pressurised flange Thread G 1 DN20, DN25 thread adapter
connection lap joint flange DN80/PN16, DN25/PN16, flange DN25 nut, TriClamp,
DN100, pressurised ANSI 3" lbs 150 ANSI 1" lbs 150 Varivent, APV,
flange DN100/PN4 JIS 10K80A JIS 10K25A dairy fitting DN50,
adjustable flange Neumo BioControl
DN100

Material PCV - U PP PVDF PVDF PP Stainless steel 1.4435

stainless steel 1.4404 stainless steel 1.4404 (AISI 316L)
(AISI 316L) (AISI 316L)
Max. pressure Unpressurised 4 bar 6 or 10 bar 8 or 10 bar 6 bar 10 bar
Max. temperature 60 C 80 C 120 or 150 C 120 or 150 C 80 C 140 C
Immersion depth 1430 mm 500 . . . 3000 mm 500 . . . 2500 mm 10 . . . 86 mm
(as of process special lengths special lengths
connection) on request on request
Sensor connection G1/NPT 3/4 3x Pg 13.5 3x Pg 13.5 3x Pg 13.5 3x Pg 13.5 Pg 13.5
thread
Certificates 3.1.B EN 10204 3.1.B EN 10204 3A, EHEDG ("in line
steam sterilisability +
cleanability")
3.1.B EN 10204
Associated cleaning External spray cleaning Integrated spray Integrated spray Spray cleaning Spray cleaning
systems cleaning CPR 31, cleaning CPR 31 connection G 1/2 connection with CPR 3
external spray cleaning
CPR 30

16
Retractable assemblies

Cleanfit Probfit Cleanfit Cleanfit Cleanfit Cleanfit Cleanfit

CPA450 CPA465 CPA471 CPA472 CPA473 CPA474 CPA475
Water, wastewater, Food, process, Water, wastewater, Water, wastewater, Water, wastewater, Water, wastewater, Food, process,
process pharmaceuticals process process process process pharmaceuticals
Manual, Manual or pneumatic, Manual or pneumatic, Manual or pneumatic, Manual or pneumatic, Manual or pneumatic, Manual or pneumatic,
120 mm electrode can be fully automated can be fully automated can be fully automated can be fully automated can be fully automated can be fully automated
with CPC30/300 with CPC30/300 with CPC30/300 with CPC30/300 with CPC30/300 with CPC30/300

Open and Open and Open and Open and Open and Open and Open and
closed tank, closed tank, closed tank, closed tank, closed tank, closed tank, closed tank,
piping piping piping piping piping piping piping
(min DN 80) (min DN 80) (min DN 80) (min DN 80) (min DN 80) (min DN 80)

Thread G 1 1/4, DN25 thread adapter DN25 thread adapter Thread G 1 1/4 Thread G 1 1/4, Flange DN50/PN16, DN 25 thread adapter
thread NPT 1 1/4", nut, TriClamp, nut, TriClamp, external, flange DN50/PN16, flange ANSI 2 / nut, TriClamp,
flange DN32 PN16, Varivent, APV, dairy Varivent, APV, thread NPT 1" flange 150 lbs Varivent, APV, dairy
flange ANSI 1 1/4" fitting DN50, flange dairy fitting DN50 external, ANSI 2" / 150 lbs fitting DN50, flange
DN50/PN10, flange flange DN50/PN10, flange
ANSI 2 / 150 lbs DN50 / ANSI 2", ANSI 2 / 150 lbs
dairy fitting DN50

Stainless steel 1.4404 Stainless steel 1.4435 Stainless steel 1.4404 PP, PVDF, PEEK Stainless steel 1.4404 PP, PVDF, PEEK Stainless steel 1.4435
(AISI 316L) (AISI 316L) (AISI 316L) (AISI 316L) (AISI 316L)
Hastelloy C4, titanium
4 (overpressure 20)bar 10 bar 4/6 or 10 bar 4/6 bar 4/6 or 10 bar 4/6 or 10 bar 4/6 or 10 bar
130 C 140 C 80 or 140 C 60 or 80 C 80 or 140 C 80 or 130 C 80 or 140 C
Up to 700 mm 47 . . . 120 mm 66 . . . 208 mm 66 . . . 215 mm 61 . . . 235 mm 71 . . . 207 mm 48 . . . 102 mm

Pg 13.5 Pg 13.5 Pg 13.5 Pg 13.5 Pg 13.5 Pg 13.5 Pg 13.5

3.1.B EN 10204 3A, "in line steam 3.1.B EN 10204 3.1.B EN 10204 3A, "in line steam
sterilisability" acc. to sterilisability" acc. to
EHEDG test procedure EHEDG test procedure
3.1.B EN 10204 3.1.B EN 10204
Rinse chamber Integrated rinse Integrated rinse Integrated rinse Integrated rinse Integrated rinse Integrated rinse
connection G 1/4 chamber (Z-shape) chamber with chamber with chamber with chamber with chamber (Z-shape)
with connection connection connection connection connection with connection
G 1/4 and G 1/2" G 1/4 or NPT 1/4" G 1/4 or NPT 1/4" G 1/4 or NPT 1/4" G 1/4 or NPT 1/4" G 1/4 or NPT 1/4"

17
Electrodes Technical data

Quality and performance in the area of
sensor technology are the deciding factors.
In no other component of a measuring
point is so much development competence
and time invested than here. The range of
manufacture, modularity with regard to
the design technology and a high degree of
automation guarantee the user absolutely
reliable quality, certainty and safety. At its
locations in Waldheim (Saxony, Germany)
and Los Angeles (USA), Endress+Hauser
has the most modern pH electrode
production worldwide. Computer-aided
inspection units monitor the technical
production quality during the production.

Orbisint Orbisint Ceragel Tophit Ceragel

CPS11/CPS11D CPS12/CPS12D CPS71/CPS71D CPS471 CPS72/CPS72D
Material Glass Glass Glass PEEK, EPDM Glass
Parameter pH ORP/redox pH pH ORP/redox
Meas. range 0-14 -1500 bis 1500 mV 0-14 0-14 -1500 bis 1500 mV
Temperature 0-135 (-5-80) C -15-135 C 0-135 (-15-80) C -15-135 C -15-135 C
Temperature Pt100, Pt1000 / integrated Pt100, Pt1000 / integrated Pt1000
sensor
Minimum 50 S/cm 50 S/cm 10 S/cm 10 S/cm 10 S/cm
conductivity
Pressure up to 6 bar/16 bar 6 bar 13 bar 10 bar 13 bar
Diaphragm PTFE PTFE Ceramic Ceramic Ceramic
Reference Gel Gel Gel Gel Gel
Lengths [mm] 120/225/360/425 120/225/360/425 120/225/360/425 120/225/360/425 120/225/360/425
Cable CPK9 / CYK10 CPK9 / CPK10 CPK9 / CPK10 CPK12 CPK9 / CPK10
Certifikates ATEX, FM ATEX, FM ATEX, FM, 3A, ATEX, FM, ATEX, FM
biocompatible 3A, biocompatible

18
 CPS11 CPS71 CPS91 Tophit CPF81

The wide range of applications does not
necessarily mean that there must be a
wide range of different sensor types.
Endress+Hauser offers the following
four basic types which cover the entire
application range:
Sensors with teflon diaphragm and gel Sensors with open aperture with gel
reference reference as well as
Sensors with ceramic diaphragm and gel Sensors with ceramic diaphragm and
reference liquid reference

Ceraliquid Tophit Ceraliquid Orbipore Tophit

CPS41/CPS41D CPS441 CPS42/CPS42D CPS91/CPS91D CPS491
Glass PEEK, EPDM Glass Glass PEEK, perfluorelastomer
pH pH ORP/redox pH pH
0-14 0-14 -1500 bis 1500 mV 0-14 0-14
0-130 (-15-80) C -15-135 C -15-130 C 0-110 C -15-110 C
Pt100 Pt1000 Pt100, Pt1000 Pt1000

0,1 S/cm 0,1 S/cm 0,1 S/cm 500 S/cm 500 S/cm

8 bar 10 bar 8 bar 13 bar 10 bar

Ceramic Ceramic Ceramic open open
liquid liquid liquid solid gel solid gel
120/225/360/425 120/225/360/425 120/225/360/425 120/225/360/425 120/225/360/425
CPK9 / CPK10 CPK12 CPK9 / CPK10 CPK9 / CPK10 CPK12
ATEX, FM, 3A ATEX, FM, 3A ATEX, FM ATEX, FM ATEX, FM

19
DIN Koax-Kupplung (GSA) TOP68-Kupplung (ESA) Memosens-Kupplung

To ensure the safe transmission of measured
values for contacting plug-in systems,
double-screened measuring cables are
required to prevent against electromagnetic
interfering impulses.
A distinction is made between simple cables
where only the pH value is transmitted
right up to multi-pin cables which also
allow temperature measured value
transmission (TOP68).
With Memosens technology, the sensor
data are digitalised directly in the sensor
and transmitted with a standard bus cable
of low impedance (CYK10).

Orbipac Orbipac Purisys

CPF81 CPF82 CPF201
PPS / Glass PPS / Glass SS316 L / Glass Material
pH ORP/redox pH Parameter
0-11 (0-14) -1500 bis 1500 mV 0-14 Measuring range
0-80 (0-110) C 0-110 C 0-75 C Temperature
Pt100 Pt100 Pt100, Pt1000 Temperature
sensor
50 S/cm 50 S/cm 0,05 - 100 S/cm Minimum
conductivity
3,5 bar (110 C) 3,5 bar (110 C) 3,5 bar Pressure up to
PTFE PTFE PTFE Diaphragm
Gel Gel Gel Reference
12,5/23/58,5 12,5/23/58,5 Lengths [mm]
fixed cable / CPK9 fixed cable / CPK9 CPK9 Cable
Certificates

20
Applications for pH sensors

CPS11 CPS41 CPS71 CPS91 CPF81 CPF201 CPS441 CPS471 CPS491

Chemical industry
Chemical production monitoring
Chrome detoxification
Colourants
Metal finishing and mining
Petrochemicals
Refineries
Power plants
Boiler feedwater
Paper industry
Non-aqueous media
Resin production
Starch
Gelatine
Pharmaceutical industry
Biotechnology
Blood plasma fractioning
Fermenters
Pharmaceutical-chemical production
Food and beverages
Beverages
Brewing water
Cheese production
Dairy, milk and yoghurt processing
Drinking water
Fish farming
Sauces/ketchup
Yeast propagation
Marmalade
Puree
Drinks bottling
Sugar
Water treatment
Gas scrubbers
Boiler feedwater
Cooling water
Ultrapure water (semiconductor)
Neutralisation
Drinking water
Municipal wastewater
Industrial wastewater
Wastewater treatment
Tannery
Detoxification
Flue gas cleaning
Wastewater, galvanic
Heavy metal precipitation
Sludge draining
Ground sanitation

21
Additional documentation
Technical information

Transmitter

TI 194C Liquisys M CPM223/253

TI 233C Mycom S CPM153
TI 381C Liquiline M CM42

Assemblies

TI 112C Dipfit W CPA111

TI 179C Flowfit P CPA240
TI 041C Flowfit W CPA250
TI 306C Unifit H CPA442
TI 183C Cleanfit W CPA450
TI 146C Probfit H CPA465
TI 217C Cleanfit P CPA471
TI 223C Cleanfit P CPA472
TI 344C Cleanfit P CPA473
TI 345C Cleanfit P CPA474
TI 240C Cleanfit H CPA475
TI 166C Dipfit W CYA611

Sensors

TI 028C Orbisint CPS11

TI 079C Ceraliquid CPS41
TI 245C Ceragel CPS71
TI 191C Orbipac CPF81
TI 375C Orbipore CPS91
TI 266C Purisys CPF201
TI 352C Tophit CPS441
TI 282C Tophit CPS471
TI 377C Tophit CPS491

Cleaning and calibration systems

TI 235C Topclean S CPC30

TI 236C Topcal S CPC300
TI 046C Chemoclean CYR10
BA 201C Chemoclean CPR31
TI 342C Chemoclean CPR40

Further information is available under: www.analysis.endress.com

03.05/MSC
Instruments International

Endress+Hauser GmbH+Co. KG
Instruments International
P.O. Box 2222
79574 Weil am Rhein
Germany
Tel. +49 7621 975 02
Fax +49 7621 975 345
http://www.endress.com
info@ii.endress.com

FA 007C/07/en/03.05
51515969
DT/INDD 2.0