CHEMISTRY
MAC
2016
2 jam
CHEMISTRY
Kertas 1 & 2
2 jam 30 minit
5. Rajah yang mengiringi soalan tidak dilukiskan mengikut skala kecuali dinyatakan
C neon gas
Gas neon
D Water
Air
2 The figure below shows the symbols for lithium atom and oxygen atom.
Rajah di bawah menunjukkan simbol bagi atom litium dan atom oksigen.
7 16
Li O
3 8
Which of the following shows the right chemical formula for the compound that formed between
lithium and oxygen elements?
Antara berikut yang manakah formula kimia yang betul bagi sebatian yang terbentuk antara
unsur litium dan oksigen?
A LiO
B LiO2
C Li2O
D Li2O2
3 Which of the following statements are correct for element in group 1 when they move down the
group in the periodic table?
Antara pernyataan berikut yang manakah benar bagi unsur kumpulan 1 apabila menuruni
kumpulan dalam Jadual Berkala Unsur?
2
Bilangan elektron valens bertambah
Bulb
mentol
Carbon Rode
Rod karbon
Substance A
bahan A
B Ammonium solution
larutan ammonia
C Molten naphthalene
naftalena lebur
D Ethanol
etanol
3
6 Figure below show s the set- up of apparatus for the experiment to determine the chemical
properties of sulphuric acid.
Rajah menunjukkan susunan radas bagi mengkaji sifat kimia asid sulfurik
Dilute
Sulphuric
acid Zinc carbonate
asid sulfurik Zink karbonat
cair
Which of the following are the results from the above reaction?
Antara berikut yang manakah merupakan hasil tindakbalas di atas?
A polimer
Polymer
B monomer
mononer
C polimonomer
Polymonomer
D makromolekul
Macromolecule
8 Which of the following statements are correct when chemical reaction occur?
Antara pernyataan berikut yang manakah benar apabila suatu tindak balas kimia berlaku?
4
B Time of reaction are proportional with concentration reaction substances
Masa tindak balas berkadar terus dengan kepekatan bahan tindak balas
A Butane
Butana
B But-2-ene
But-2-ena
C Butan-2-ol
Butan-2-ol
D Butanoic acid
Asid butanoik
10 Table below shows the number of neutron, proton and electrons for P,Q,R and S particles.
Jadual menunjukkan bilangan neutron, proton dan elektron bagi zarah P,Q,R dan S.
CH4
Which of the following statements are true for one mole methane gas?
Antara pernyataan berikut yang manakah benar bagi satu mol gas metana?
Use the information Relative Atomic Mass C = 12, H = 1, Avogadro constants =
6.0 1023 mol- 1, 1 mol gas= 24.0 dm3 at room condition.
Gunakan maklumat jisim atom relatif C = 12, H = 1, pemalar Avogadro = 6.0 10 23 mol-1,
1 mol gas menempati 24.0 dm3 pada suhu dan tekanan bilik.
5
A Has mass 12g
Mempunyai jisim 12 g
J
Which of the following electron arrangements are true for ion in J element
Antara susunan elektron berikut yang manakah benar bagi ion unsur J?
A 2.4
B 2.5
C 2.6
D 2.8
13 Table below shows nucleon number and number of neutron for K, L, M and N elements
Jadual di bawah menunjukkan nombor nukleon dan bilangan neutron bagi unsur K, L, M dan N
14 Figure below shows the set-up of apparatus to purifying metal from electrolysis process.
Gambar rajah menunjukkan susunan radas untuk menulenkan logam melalui proses elektrolisis.
X Y
Substances
Z
Bahan Z
6
Between Z electhrode and Y electhrode and substances Z which are suitable to purify copper
metal?
Antara elektrod X, elektrod Y dan bahan Z berikut yang manakah sesuai digunakan untuk
menulenkan logam kuprum?
15 Figure below shows volume and concentration of potassium hydroxide solution and propanoic
acid
Rajah menunjukkan isipadu dan kepekatan bagi larutan kalium hidroksida dan asid propanoik
3
50cm3
50cm potassium
ethanoic hydroxide
acid
0.1moldm-3
17 Table below shows proton number and nucleon number for several elements
Jadual di bawah menunjukkan nombor proton dan nombor nukleon bagi beberapa unsur.
8
Carbon 6 12
Karbon
Nitrogen 7 14
Nitrogen
Magnesium 12 24
Magnesium
A The mass of one carbon atom and the mass of two lithium atom are same
Jisim satu atom karbon dan jisim dua atom litium adalah sama
C One atom magnesium is four times heavier than one atom lithium
Satu atom magnesium adalah empat kali lebih berat daripada satu atom litium
D total mass of one atom carbon and mass of one atom magnesium equalto six
Jumlah jisim satu atom karbon dan jisim satu atom magnesium sama dengan enam
18 Table below shows mass for element X and oxygen with empirical formula that formed.
Jadual menunjukkan jisim bagi unsur X dan oksigen serta formula empirik yang terhasil.
Element X O
Unsur
Mass (g) 2.3 0.8
Jisim (g)
Empirical formula X2O
Formula empirik
A 23
B 24
C 39
D 40
19 Which of the following shows number of proton and electron for ion in group 2 element in
Periodic Table?
Antara berikut yang manakah menunjukkan bilangan proton dan elektron bagi suatu ion unsur
kumpulan 2 dalam Jadual Berkala Unsur?
Which of the following couple of elements that form compound at higher melting point?
Antara pasangan unsur berikut, yang manakah membentuk sebatian dengan takat lebur yang tinggi?
A P and S
P dan S
B Q and R
Q dan R
C Q and S
Q dan S
D P and Q
P dan Q
21 Figure below shows the set-up of apparatus for electrolysis process copper(II) sulphate solution
using carbon electrode.
Rajah di bawah menunjukkan susunan radas bagi proses elektrolisis larutan kuprum(II) sulfat
menggunakan elektrod-elektrod karbon.
Carbon
electrod
e Copper(II) sulphate
Elektrod solution
karbon Larutan kuprum(II)
The reaction that occur at anode is:
10
Tindak balas yang berlaku di anod ialah
C C(s) C 4+(aq) + 4e
22 Figure below shows the set-up of apparatus for dilution process of sodium hydroxide solution
Gambar rajah menunjukkan susunan radas bagi proses pencairan larutan natrium
hidroksida
180 cm3
distilled water
added 20 cm3 sodium hydroxide
air suling solution 1.0 mol dm-3
ditambah
What is the concentration of sodium hydroxide now?
Berapakah kepekatan larutan natrium hidroksida yang baru?
23
Mg(s) + 2 HCl(aq) MgCl2(aq) +
H2(g)
Mg(p)+ 2 HCl(ak) MgCl2(ak) +
Based on the equation reaction above, which of the following changing in quantity that could be
observe to determine the rate of reaction?
Berdasarkan persamaan tindak balas di atas, perubahan kuantiti yang manakah dapat
diperhatikan untuk menentukan kadar tindak balas?
11
D Reducing concentration of hydrochloric acid
Pengurangan kepekatan asid hidroklorik
A 1,1 dibromopropane
1,1 dibromopropana
B 1,2 dibromopropane
1,2 dibromopropana
C 1,2 dibromopropene
1,2 dibromopropena
D 2,3 dibromopropane
2,3 dibromopropana
A Zn + Cl ZnCl
B Cu + Cl2 CuCl2
C Ag + Cl2 AgCl2
D Al + Cl2 AlCl2
A U,V,W
B U,W,V
C V,U,W
D W,U,V
Copper rode
Zinc rod kuprum
rode
Copper (II) sulphate
Zinc nitrate solution
solution Larutan kuprum(II)
Larutan zink nitrat
nitrat
What is the readings of voltmeter if zinc rode replaced with aluminium and zinc sulphate solution
are replaced with aluminium nitrate solutions
Apakah bacaan voltmeter jika rod zink diganti dengan aluminium dan larutan zink sulfat diganti
dengan larutan aluminium nitrat.
A 0V
B 1.10 V
What is the type of bonding that forms when element M combines with oxygen element?
Use the information number of proton O = 16
Apakah jenis ikatan yang terbentuk apabila unsur M berpadu dengan unsur oksigen?
Gunakan maklumat nombor proton O = 16.
A ionic bonding
Ikatan ion
Particles
zarah
State I state II
14
B II dan IV only
II dan IV sahaja
D I, II dan IV only
I, II dan IV sahaja
A 35
B 46
C 79
D 81
What is the mass of oxygen produced if 12.25 g potassium chlorate decomposed completely by
the heat?
Relative atomic mass given: K = 39, Cl = 35.5 and O = 16
Berapakah jisim oksigen terhasil jika 12.25 g kalium klorat terurai sempurna oleh haba?
Diberi jisim atom relatif K = 39, Cl = 35.5 dan O = 16
A 1.20 g
B 2.40 g
C 4.80 g
D 18.38 g
32 The diagram below shows the position of elements V,W,X,Y and Z in the Periodic Table of
element.
Rajah di bawah menunjukkan kedudukan unsur V, W, X, Y dan Z dalam Jadual Berkala Unsur.
1 18
2 13 14 15 16 17
15
V W X
Y 3 4 5 6 7 8 9 10 11 12 Z
33 Element P and Q combine to form a compound that has the following properties.
Unsur P dan Q berpadu membentuk satu sebatian yang mempunyai sifat seperti berikut :
P Q
A 2.2 2.5
B 2.3 2.6
C 2.4 2.7
D 2.5 2.8
34 The table below shows the results of experiment for three chemical cells with the different pairs of
metals.
16
Jadual di bawah menunjukkan keputusan eksperimen bagi tiga sel kimia dengan pasangan logam
yang berbeza.
What is the voltan of the chemical cell which built from the pair of magnesium and silver?
Berapakan nilai voltan bagi sel kimia yang dibina daripada pasangan logam magnesium dan
argentum?
A 0.30 V
B 0.65 V
C 1.30 V
D 2.40 V
35 Which of the following substances has the highest percentage of nitrate ions ?
Antara bahan berikut yang manakah mempunyai peratus ion nitrat yang paling tinggi? .
Relative atomic mass given: H=1, N=14, O=16, Mg=24, K=39, Ca=40
Diberi jisim atom relatif : H=1, N=14, O=16, Mg=24, K=39, Ca=40
A Magnesium nitrate
Magnesium nitrat
B Ammonium nitrate
Ammonium nitrat
C Calcium nitrate
Kalsium nitrat
D Potassium nitrate
Kalium nitrat
36 The following table shows the total of volume of hydrogen gas collected from the reactions
between zinc powdwer with hydrochloric acid 2.0 mol dm -3 .
17
Jadual berikut menunjukkan jumlah isipadu gas hidrogen yang dikumpul daripada tindak balas
antara serbuk zink dengan asid hidroklorik 2.0 mol dm-3
Time/min 0 1 1 2 2 3 3 4
Masa/min
Volume H2/cm3 0 15.0 25.0 32.0 36.0 38.0 39.0 39.0 39.0
Isipadu H2/cm3
A 9.75 cm3/min
B 11.14 cm3/min
C 13.0 cm3/min
D 30.0 cm3/min
37 The following equation represents the reaction between magnesium and dilute of sulphuric acid.
Persamaan berikut mewakili tindak balas antara magnesium dan asid sulfurik cair .
If 4.8 g magnesium reacts with 1.0 mol of sulphuric acid , what is the number of moles gas X
produced ?
Relative atomic mass given Mg =24
Jika 4.8 g magnesium bertindak balas dengan 1.0 mol asid sulfurik, berapakah bilangan mol
gas X yang terhasil?
Diberi jisim atom relatif Mg = 24
A 0.1
B 0.2
C 1.0
D 2.0
38 Figure below shows the set-up of apparatus for double decomposition reaction
Gambar rajah menunjukkan susunan radas bagi tindakbalas penguraian ganda dua
A I and II only
I dan II sahaja
CH3 H
CC
H C2H5 n
H H H H
A H C C = C C H
19
H H
H H H H H
B H C C = C C C H
H H H
H H H H H
C H C C C C = C H
H H H
H H H H H
D H C = C C C C H
H H H
40 Decomposition by heat of lead(II) nitrate can be represented by the following chemical equation,
Persamaan kimia berikut menunjukkan penguraian haba plumbum(II) nitrat
What is the mass of oxygen gas given off when 33.1 g of lead(II) nitrate decompose completely?
Relative atomic mass O = 16, N = 14 and Pb = 207
Berapakah jisim oksigen yang dibebaskan apabila 33.1 g pepejal plumbum(II) nitrat terurai
sempurna?
Gunakan maklumat Jisim atom relatif O = 16, N = 14 dan Pb = 207
A 1.6 g
B 3.2 g
C 16.0 g
D 32.0 g
41 The graph below shows the relationship of the volume of carbon dioxide gas and the time taken
for chemical reaction between hydrochloric acid and a carbonate salt at room temperature and
pressure.
Rajah menunjukkan graf isi padu gas karbon dioksida melawan masa bagi satu tindak balas
kimia antara marmar dengan asid hidroklorik yang dilakukan pada suhu dan tekanan bilik.
Volume
gas CO2 / cm
180
Isipadu
3
Gas CO2/cm 20
20
0 30 60 Time / s
Masa/s
Berapakah jisim maksimum gas karbon dioksida yang terkumpul dalam tindak balas itu?
Gunakan maklumat jisim atom relatif : C = 12 , O = 16 , 1 mol menempati ruangan 24 dm
pada keadaan bilik
A 0.147 g
B 0.220 g
C 146.7 g
D 220.0 g
H H H
| | |
H C C = C
| |
H Cl
21
What is the structural formula of its polymer?
Apakah formula struktur polimernya?
A
CH3 H
| |
-----C C -----
| |
H Cl n
B
H H H
| | |
----- C C C ------
| | |
H H Cl n
C CH3 H
| |
---- C = C -----
| |
H Cl n
D CH3 H H
| | |
------- C C C -----
| | |
H H Cl n
43 Diagram shows the set-up of apparatus for the titration of sodium hydroxide solution with sulphuric
acid.
Rajah menunjukkan susunan radas bagi titratan larutan natrium hidroksida dengan asid sulfurik.
22
Sulphuric
acid
Asid sulfurik
0.05 mol dm-
20 cm3 of
3 sodium hydroxide
solution
0.1 mol dm-3 and
phenolphthalein as an indicator
20 cm3 larutan natrium
hidroksida 0.1 mol dm-3 dan
fenoltalein sebagai penunjuk
What is the volume of sulphuric acid needed at the end point of the titration in Figure ?
Berapakah isipadu asid sulfurik yang diperlukan pada takat akhir titratan dalam rajah ?
A 10.00 cm3
20.00 cm3
B
30.00 cm3
C
40.00 cm3
D
44 Table shows the voltage reading chemical cells using different electrode
pairs dipped into copper(II) sulphate solution.
Jadual menunjukkan nilai voltan bagi sel kimia menggunakan pasangan
logam yang berlainan yang dicelupkan ke dalam larutan kuprum(II) sulfat.
Metal electode
Cell Elektrod logam Voltage reading(V)
sel Negative terminal Positive terminal Bacaan Voltan (V)
Terminal negatif Terminal positif
I W Z 2.7
II W Y 2.3
III X Z 1.5
IV X Y
A 0.4 V
23
B 1.1 V
C 1.2 V
D 1.6 V
W + X Y + Z
Energy
Tenaga
E3
E2 W+X
E1 Y+Z
E0
Progress of
reaction
Kemajuan
tindak balas
A E2 - E1
B E3 - E1
C E3 - E2
D E3 - E0
24
STRUKTUR (Jawab Semua Soalan)
BAHAGIAN A
Copper(II) oxide
Combustion tubeKuprum(II) oksida
Tiub pembakaran Hydrogen flame
Hydrogen gas
Gas hidrogen Nyalaan hidrogen
Dilute hydrochloric acid
Asid hidroklorik cair
Asbestos paper
Heat Kertas asbestos
Panaskan
Result :
Keputusan :
......
...........................................
[1 mark]
(c) How to ensure that the combustion tube has been totally filled with
hydrogen gas?
Bagaimana untuk memastikan bahawa tiub pembakaran telah
dipenuhi dengan gas hidrogen?
.
....
.................................................................................................................
..........................
[2 marks]
(d) Based on the above results,
Berdasarkan keputusan di atas,
(i) Calculate the mass of copper and the mass of oxygen that have
reacted.
Hitungkan jisim kuprum dan jisim oksigen yang bertindak balas.
[1 mark]
[1 mark]
(iii) Determine the empirical formula of copper (II) oxide.
Tentukan formula empirik kuprum (II) oksida.
26
...............
.............................
[1 mark]
(iv) Write the chemical equation for the reaction in the experiment.
Tulis persamaan kimia bagi tindak balas dalam eksperimen
tersebut.
.....
.......................................
[1 mark]
.
....
[2 marks]
Element
Sodium Magnesium Aluminium Chlorine Argon
Unsur
Proton number
11 12 13 17 18
Nombor proton
TABLE / JADUAL 2
Based on Table 2, answer the following questions :
Berdasarkan Jadual 2, jawab soalan-soalan berikut :
...
[1 mark]
(b) Chlorine is in the group 17 in the Periodic Table. What is another name
for group 17?
Klorin terletak dalam Kumpulan 17 dalam Jadual Berkala. Apakah
nama lain bagi kumpulan 17?
[1 mark]
(c) Write the electron arrangement of aluminium atom.
27
Tuliskan susunan elektron bagi atom aluminium.
[1 mark]
(d) (i) Arrange the element in Table 2 according to their atomic sizes in
descending order.
Susunkan unsur dalam Jadual 2 mengikut susunan menurun saiz
atom.
.
[1 mark]
(ii) Explain your answer in (d) (i).
Terangkan jawapan anda di (d) (i).
....
[2 marks]
(e) When sodium is burnt in chlorine, sodium chloride is formed.
Apabila natrium dibakar dalam klorin, natrium klorida terbentuk.
.
[1 mark]
.
[2 marks]
(iii) State one physical property of sodium chloride.
Nyatakan satu sifat fizik bagi natrium klorida.
.
[1 mark]
3 Diagram 3Zinc
shows the/ set-up of apparatus of a chemical cell.
plate
Rajah 3 menunjukkan susunan radas sebuah selCopper
kimia. plate /
Kepingan zink Kepingan kuprum
Zinc sulphate solution / Porous pot /
Larutan zink sulfat Pasu berliang
Copper(II) sulphate solution /
Larutan kuprum(II) sulfat
28/ RAJAH 3
DIAGRAM
(a) What is the function of the porous pot?
Apakah fungsi pasu berliang?
.................................................................................................................
........................
[1 mark]
(b) What is the energy change that occurs in the cell?
Apakah perubahan tenaga yang berlaku dalam sel itu?
...............
..........................................
[1 mark]
(c) State which metal plate acts as the
Nyatakan kepingan yang mana bertindak sebagai
negative terminal :
terminal negatif :
............................
........................................
positive terminal :
terminal positif :
............................
........................................
[1 mark]
...............
..........................................
[2 marks]
(f) Draw arrows indicating the flow of electrons in Diagram 3.
Lukis anak panah yang menunjukkan pergerakan elektron pada Rajah
3.
[1 mark]
(g) Describe how to increase the cell voltage.
Huraikan bagaimana anda dapat meningkatkan voltan sel di atas.
....................................
.....................
...............
..........................................
[2 marks]
4 Table 5 shows the result obtained from an experiment to determine the rate of
reaction between magnesium ribbon with excess hydrochloric acid solution. The
volume of gas released during the reaction was recorded every 30 second.
Jadual 5 di bawah menunjukkan keputusan yang diperolehi daripada satu
eksperimen untuk menentukan kadar tindak balas antara pita magnesium
dengan larutan asid hidroklorik berlebihan. Isipadu gas yang dibebaskan semasa
tindak balas dicatat setiap 30 saat.
Time / 0 3 6 90 12 15 18 21 24 27 30 33 36
second 0 0 0 0 0 0 0 0 0 0 0
Masa/ saat
Experiment
1
Eksperimen 0 1 3 42 54 66 75 84 90 96 99 99 99
I 5 0
Total of gas
volume
Jumlah
Isipadu gas /
cm3
TABLE / JADUAL 5
(a) (i) Write the chemical equation for the reaction.
Tuliskan persamaan tindak balas yang terlibat.
.
............................................
.................
30
[1 mark]
(ii) Draw a graph volume of gas against time on the graph paper.
Lukiskan graf isipadu gas melawan masa pada kertas graf.
[3 marks]
31
(iii) Based on the graph in (b), determine the average of rate of reaction.
Berpandukan graf di (b) tentukan kadar tindak balas purata bagi
tindak balas tersebut.
[2 marks]
(b) A student was carried out two experiments to determine the factor that
affect the rate of reaction between hydrochloric acid with magnesium.
Table 6 shows the result.
Seorang pelajar telah menjalankan dua eksperimen untuk menentukan
faktor yang mempengaruhi kadar tindak balas antara asid hidrokorik
dengan magnesium. Jadual 6 di bawah menunjukkan keputusan yang
diperolehi.
Excess
Experiment hydrochloric
Eksperimen acid + 2 g of
II magnesium
powder
Asid
20
hidroklorik
berlebihan
+ 2 g serbuk
magnesium
TABLE / JADUAL 6
(i) Referring to collision theory, explain why there is difference in result in
experiment I and Experiment II.
Merujuk kepada teori perlanggaran, terangkan mengapa terdapat
perbezaan keputusan dalam Eksperimen I dan Eksperimen II.
.................................................................................................................
.............................
32
.................................................................................................................
.............................
.................................................................................................................
.............................
[3 marks]
.................................................................................................................
..........................
[1 mark]
Ethene
etena
Combustion
pembakaran
Q Bromoethane
UV Bromoetana
P + H2O
Ethane Br2
etana
DIAGRAM / RAJAH 6
.
[1 mark]
(ii) Write the general formula of the homologous series that you
have stated in (a) (i).
Tuliskan formula am bagi siri homolog yang anda nyatakan di
(a) (i).
.
[1 mark]
33
(i) Name substance P.
Namakan bahan P.
.
[1 mark]
[2 marks]
...
[1 mark]
(d) Ethane react with bromine gas in the presence of UV light to produce
bromoethane.
Etana bertindak balas dengan gas bromin dalam kehadiran sinar UV
menghasilkan bromoetana.
.
[1 mark]
.
[1 mark]
(e)
Ethane do not has isomers
Butane has two isomers
Etana tidak mempunyai isomer
Butana mempunyai dua isomer
34
[2 marks]
35