Jee Advanced Paper 2 With Solutions PDF

JEE(Advanced) 2016 Final Exam/Paper-2/Code-9
JEE(Advanced) 2016 TEST PAPER WITH SOLUTIONS
PHYSICS
(HELD ON SUNDAY 22nd MAY, 2016)
PART-I : PHYSICS
SECTION1 : (Maximum Marks : 18)
This section contains SIX questions.
Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is correct.
For each question, darken the bubble corresponding to the correct option in the ORS.
For each question, marks will be awarded in one of the following categories :
Full Marks : +3 If only the bubble corresponding to the correct option is darkened.
Zero Marks : 0 If none of the bubbles is darkened.
Negative Marks : 1 In all other cases.
1. The electrostatic energy of Z protons uniformly distributed throughout a spherical nucleus of radius R is
3 Z(Z 1)e 2
given by E 5 4 R
0
The measured masses of the neutron, 11 H , 157 N and 15

8 O
are 1.008665 u, 1.007825 u, 15.000109 u and
15.003065 u respectively. Given that the radii of both the 157 N and 158 O nuclei are same, 1u = 931.5 MeV/c2
e2
(c is the speed of light) and (4 ) = 1.44 MeV fm. Assuming that the difference between the binding

0
energies of 157 N and 15

8 O
is purely due to the electrostatic energy, the radius of either of the nuclei is
(1fm = 1015m)
(A) 2.85 fm (B) 3.03 fm (C) 3.42 fm (D) 3.80 fm

Ans. (C)
Sol. Electrostatic energy = BEN BEO
= [7M H 8M n M N ] [8M H 7M n MO ] C2
= [MH + Mn + MO MN]C2
= [1.007825 + 1.008665 + 15.003065 15.000109] 931.5
= + 3.5359 MeV
3 1.44 8 7 3 1.44 7 6
E 3.5359
5 R 5 R
3 1.44 14
R 3.42fm
5 3.5359
CODE-9 JEE(Advanced) 2016 Final Exam/Paper-2/Held on Sunday 22nd May, 2016

1/45
2. The ends Q and R of two thin wires, PQ and RS, are soldered (joined) together. Initially each of
PHYSICS
the wires has a length of 1m at 10C. Now the end P is maintained at 10C, while the end S is heated
and maintained at 400C. The system is thermally insulated from its surroundings. If the thermal
conductivity of wire PQ is twice that of the wire RS and the coefficient of linear thermal expansion
of PQ is 1.2 105 K1, the change in length of the wire PQ is
(A) 0.78 mm (B) 0.90 mm (C) 1.56 mm (D) 2.34 mm
Ans. (A)
P Q,R S
10C 2K K 400C
Sol. T
1m 1m
Heat flow from P to Q
dQ 2KA(T 10)

dt 1
Heat flow from Q to S
dQ KA(400 T)

dt 1
At steady state heat flow is same in whole combination

2KA(T 10)
= KA(400-T)
1
2T 20 = 400T
3T = 420

T = 140
140
P Q,R S
10C K 400C
dx
x Junction
Temp of junction is 140C

Temp at a distance x from end P
is Tx = (130x + 10)
Change in length dx is dy
dy = dx(Tx 10)
y 1
dy dx(130x 10 10)
0 0
2/45 JEE(Advanced) 2016 Final Exam/Paper-2/Held on Sunday 22nd May, 2016

CODE-9
1
x 2
PHYSICS

y 130
2 0
y = 1.2 105 65
5
y = 78.0 10 m = 0.78 mm
3. An accident in a nuclear laboratory resulted in deposition of a certain amount of radioactive material
of half-life 18 days inside the laboratory. Tests revealed that the radiation was 64 times more than
the permissible level required for safe operation of the laboratory. What is the minimum number of
days after which the laboratory can be considered safe for use?
(A) 64 (B) 90 (C) 108 (D) 120
Ans. (C)
Sol. Let the permissible level have activity of Apermissible
Thus, initially
A0 = 64 Apermissible [Given]

Let number of days required be t.
A0
A permissible
2t / t1/ 2
64A permissible
A permissible

2 t /18
t = 108 days
4. There are two vernier calipers both of which have 1 cm divided into 10 equal divisions on the main
scale. The Vernier scale of one of the calipers (C1) has 10 equal divisions that correspond to 9 main
scale divisions. The Vernier scale of the other caliper (C2) has 10 equal divisions that correspond to

11 main scale divisions. The readings of the two calipers are shown in the figure. The measured values
(in cm) by calipers C1 and C2 respectively, are
2 3 4
C1
5
0 10
2 3 4
C2
0 5
10
(A) 2.87 and 2.86 (B) 2.87 and 2.87 (C) 2.87 and 2.83 (D) 2.85 and 2.82

3/45
Ans. (C)
PHYSICS
Sol. For caliper C1

10 VSD = 9MSD
LC = 1MSD 1VSD
LC = 0.01 cm
Measured value = Main scale reading + vernier scale reading
= (2.8 + 7 0.01) cm
= 2.87 cm
For Caliper C2
10 VSD = 11 MSD
LC = 0.01 cm
Measured value = {2.8 + (107) 0.01}cm
= 2.83 cm
5.

A gas is enclosed in a cylinder with a movable frictionless piston. Its initial thermodynamic state at
1
pressure Pi = 105 Pa and volume Vi = 103 m3 changes to a final state at Pf 10 Pa and Vf
5
32
3 3 3 5
= 8 10 m in an adiabatic quasi-static process, such that P V = constant. Consider another
thermodynamic process that brings the system from the same initial state to the same final state in two

steps: an isobaric expansion at Pi followed by an isochoric (isovolumetric) process at volumes Vf. The
amount of heat supplied to the system in the two step process is approximately
(A) 112 J (B) 294 J (C) 588 J (D) 813 J
Ans. (C)
Sol. In adiabatic process

3 5
P V = constant
5/3
PV = constant
5 3 5
CV R and CP R
3 2 2
In another process
P(Pa)
A B
105
5
1/320 C
3
3 V(m )
10 8103

CODE-9
Q = nCPT + nCVT
PHYSICS
5 3
= nR(TB TA ) nR(TC TB )
2 2
5 3
Q (PB VB PA VA ) (PC VC PBVB )
2 2
Putting values
Q = 587.5 J 588J
6. A small object is placed 50 cm to the left of thin convex lens of focal length 30 cm. A convex spherical
mirror of radius of curvature 100 cm is placed to the right of the lens at a distance of 50 cm. The mirror
is tilted such that the axis of the mirror is at an angle = 30 to the axis of the lens, as shown in the figure.
If the origin of the coordinate system is taken to be at the centre of the lens, the coordinates (in cm) of
the point (x, y) at which the image is formed are :
f=30cm

||||||
|||||
||
||||
||
| |||
(50,0) (0,0) x
| ||||||||
||||||||| |
R=
1
00
50cm
c m

(50+503, 50)

125 25
(A) (25,25 3) (B) 3 , (C) (50 25 3,25) (D) (0, 0)
3
Ans. (A)

I2
50

43

r
503

43
////
/////
/
/ /
///
I1
//
30 25
////
Sol.
///
O 30
/////////////
50 25

3 2
2

5/45
50 30
PHYSICS
For lens V 75
50 30
25 3
50 50 3
V 2
For mirror 25 3 4 3
50
2
50 3

v h2 4 3 25
m h2
u h1 25 3 2

2
50
h2

4 3
The x coordinate of the images = 50 v cos 30 + h2 cos 60 25
The y coordinate of the images = v sin 30 + h2 sin 60 25 3
This section contains EIGHT questions.

Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these
four option(s) is (are) correct.
For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS.

Full Marks : +4 If only the bubble(s) corresponding to all the correct option(s) is (are) darkened.
Partial Marks : +1 For darkening a bubble corresponding to each correct option, Provided NO
incorrect option is darkened.
for example, if (A), (C) and (D) are all the correct options for a question, darkening all these three
will result in +4 marks; darkening only (A) and (D) will result in +2 marks; and darkening (A) and
(B) will result in 2 marks, as a wrong option is also darkened.
7. While conducting the Young's double slit experiment, a student replaced the two slits with a large
opaque plate in the x-y plane containing two small holes that act as two coherent point sources
(S1, S2) emitting light of wavelength 600 nm. The student mistakenly placed the screen parallel to
the x-z plane (for z > 0) at a distance D = 3m from the mid-point of S1S2, as shown schematically
in the figure. The distance between the sources d = 0.6003 mm. The origin O is at the intersection
of the screen and the line joining S1S2. Which of the following is (are) true of the intensity pattern
on the screen ?

CODE-9
PHYSICS
Screen
z
O
S1 S2 y
d x
D
(A) Hyperbolic bright and dark bands with foci symmetrically placed about O in the x-direction
(B) Semi circular bright and dark bands centered at point O
(C) The region very close to the point O will be dark
(D) Straight bright and dark bands parallel to the x-axis
Ans. (B, C)

Sol.
d
O
S1 S2

Path difference at point O = d = .6003 mm = 600300 nm
2001
= 600nm 1000
2 2

minima form at point O

Line S1S2 and screen are to each other so fringe pattern is circular (semi-circular because only half
of screen is available)
8. In an experiment to determine the acceleration due to gravity g, the formula used for the time period
7 R r
of a periodic motion is T 2 . The values of R and r are measured to be (60 1) mm
5g
and (10 1) mm, respectively. In five successive measurements, the time period is found to be
0.52 s, 0.56 s, 0.57s, 0.54 s and 0.59 s. The least count of the watch used for the measurement of
time period is 0.01 s. Which of the following statement(s) is(are) true ?
(A) The error in the measurement of r is 10%
(B) The error in the measurement of T is 3.57 %
(C) The error in the measurement of T is 2%
(D) The error in the determined value of g is 11%
7/45
Ans. (A, B, D)
PHYSICS
Sol. T Absolute error

1 0.52 0.04
2 0.56 00
3 0.57 0.01
4 0.54 0.02
5 0.59 0.03
Tavg 0.556
0.56
.04 00 .01 .02 .03

Avg. absolute error = .02
5
T .02
100% = 100% 3.57% (B)
T .56
r 1
100% = 100 10% (A)
r 10
g R r T
also
g Rr T

g 11
100% 100% + 2(3.57)%
g 50
11% (D)

9. A rigid wire loop of square shape having side of length L and resistance R is moving along the
x-axis with a constant velocity v0 in the plane of the paper. At t = 0, the right edge of the loop enters
a region of length 3L where there is a uniform magnetic field B0 into the plane of the paper, as shown
in the figure. For sufficiently large v0, the loop eventually crosses the region. Let x be the location
of the right edge of the loop. Let v(x), I(x) and F(x) represent the velocity of the loop, current in the
loop, and force on the loop, respectively, as a function of x. Counter-clockwise current is taken as
positive.
R
L
v0
x
0 L 2L 3L 4L

CODE-9
Which of the following schematic plot(s) is(are) correct ? (Ignore gravity)
PHYSICS
F(x)
I(x)
x
0 L 2L 3L 4L
(A) (B)
x
0 L 2L 3L 4L
I(x)
v(x)
v0
3L 4L
x
0 L 2L
(C) (D)

x
0 L 2L 3L 4L
Ans. (C, D)

Sol. R
x
When loop was entering (x < L)

= BLx
d dx
e= BL
dt dt
e BLV
e BLV
i= ACW
R R
B2 L2 V
F = iB (Left direction) = (in left direction)
R

9/45
F B2 L2 V dV
PHYSICS
a = aV
m mR dx
V x
dV B2 L2 V B2 L2
V dV dx
dx mR V0
mR 0
B2 L2
V = V0 x (straight line of negative slope for x < L)
mR
BL
I V (I vs x will also be straight line of negative slope for x < L)
R
L x 3L
d
dt
0

e=0i=0
F=0

x > 4L
v

e = Bv
Force also will be in left direction.
BLV B2L2V dV
i= (clockwise) a = V
R mR dx
x V
B2 L2 V B2 L2 f
F=
R
L mR dx V dV
i
B2L2
x L = Vf Vi
mR
B2 L2
Vf = Vi x L (straight line of negative slope)
mR
BLV
I= (Clockwise) (straight line of negative slope)
R
CODE-9
10. Light of wavelength ph falls on a cathode plate inside a vacuum tube as shown in the figure. The
PHYSICS
work function of the cathode surface is and the anode is a wire mesh of conducting material kept
at a distance d from the cathode. A potential difference V is maintained between the electrodes. If
the minimum de Broglie wavelength of the electrons passing through the anode is e, which of the
following statement(s) is(are) true ?
Light
Electrons
V
+
(A) For large potential difference (V >> /e), e is approximately halved if V is made four times

(B) e increases at the same rate as ph for ph < hc/
(C) e is approximately halved, if d is doubled
(D) e decreases with increase in and ph
Ans. (A)
hc
Sol. Kmax =

Ph
kinetic energy of e reaching the anode will be
hc
K = eV

Ph
Now
h h
e
2mK hc
2m eV
Ph
If eV >>
h
e
hc
2m eV
Ph
If Vf = 4Vi
(e)f e i
2

11/45
11. Two thin circular discs of mass m and 4m, having radii of a and 2a, respectively, are rigidly fixed
PHYSICS
by a massless, right rod of length 24a throught their center. This assembly is laid on a firm and
flat surface, and set rolling without slipping on the surface so that the angular speed about the axis

of the rod is . The angular momentum of the entire assembly about the point 'O' is L (see the figure).
Which of the following statement(s) is(are) true ?
z 4m

m
2a
a
O
(A) The magnitude of angular momentum of the assembly about its center of mass is 17ma2/2

(B) The magnitude of the z-component of L is 55 ma2
(C) The magnitude of angular momentum of center of mass of the assembly about the point O is 81 ma2
(D) The center of mass of the assembly rotates about the z-axis with an angular speed of /5
Ans. (A,D)

5mVCr

Sol. PC r

x
IC 90

1 1 2 17ma 2
LC = IC = ma 2 + 4m 2a =
2 2 2
m a 4m 2a 9a
VC
5m 5
m 4m 2 9
r
5m 5
5m 9a 9
L of cm =
5 5
2 24
= 81 ma
5

CODE-9
24
PHYSICS
Lz = 81 ma2 cos IC sin
5
24 24 17ma 2
= 81 ma2
5 5 10
ma 2 81 24 17

5 5 2
1134
m a 2
50
'x = r
r
' sin
x 5
12. Consider two identical galvanometers and two identical resistors with resistance R. If the internal resistance
of the galvanometers RC < R/2, which of the following statement(s) about any one of the galvanometers
is(are) true ?
(A) The maximum voltage range is obtained when all the components are connected in series
(B) The maximum voltage range is obtained when the two resistors and one galvanometer are connected

in series, and the second galvanometer is connected in parallel to the first galvanometer
(C) The maximum current range is obtained when all the components are connected in parallel
(D) The maximum current range is obtained when the two galvanometers are connected in series and
the combination is connected in parallel with both the resistors.

Ans. (B,C)
R R
G G
Sol.
E
Range = ig(2RC + 2R)
G
G
R R
Range = 2ig Req

13/45
RC
PHYSICS

= 2ig 2R
2
= ig (4R + RC)
R
RC
2
2RC < R Range in 1 < 3igR
Range in 2 > 4igR
So (B)
G
i
R
RC
Range = 2ig + 2ig
R
R
2i g 1 C

ig
G G
2R
ig C
R

2R
ig C
R
RC
Range = ig + 4ig
R
1 2R C
2i g
2 R
1 R R
2i g C C
2 R R
So (C)

CODE-9
13. In the circuit shown below, the key is pressed at time t = 0. Which of the following statement(s) is(are)
PHYSICS
true?
40F 25k

V
+
A 50k 20F
+
Key 5V
(A) The voltmeter displays 5V as soon as the key is pressed, and displays +5V after a long time
(B) The voltmeter will display 0 V at time t = ln 2 seconds
(C) The current in the ammeter becomes 1/e of the initial value after 1 second
(D) The current in the ammeter becomes zero after a long time
Ans. (A,B,C,D)

Sol. (A) At t = 0, capacitor acts as short-circuit
At t , capacitor acts as open circuit & no current flows through voltmeter.
V
+

x
2C R
x
V
y y
(B) 2R C
V t / 2CR
q x 2CV 1 e t / 2CR x e
R
V t / 2CR
q y CV 1 e t / 2CR y e
2R
15/45
qx
PHYSICS
V y2R
2C
= V 1 2e t / 2CR 0
(C) = 1 sec
So by i = i0et/ current at t = 1 sec is = i0/e
(D) After long time no current flows since both capacitor & voltmeter does not allow.
14. A block with mass M is connected by a massless spring with stiffness constant k to a rigid wall and
moves without friction on a horizontal surface. The block oscillates with small amplitude A about an
equilibrium position x0. Consider two cases : (i) when the block is at x0; and (ii) when the block is
at x = x0 + A. In both the cases, a particle with mass m (<M) is softly placed on the block after which
they stick to each other. Which of the following statement(s) is(are) true about the motion after the
mass m is placed on the mass M?

(A) The amplitude of oscillation in the first case changes by a factor of
M
mM
, whereas in the
second case it remains unchanged

(B) The final time period of oscillation in both the cases is same
(C) The total energy decreases in both the cases

(D) The instantaneous speed at x0 of the combined masses decreases in both the cases.
Ans. (A,B,D)
M Mm
Sol. Ti 2 , Tf 2
K K

case (i) :
M (A) = (M + m)V
Velocity decreases at equilibrium position.
By energy conservation
M
Af Ai
Mm
case (ii) :
No energy loss, amplitude remains same
At equilibrium (x0) velocity = A.
In both cases decreases so velocity decreases in both cases

CODE-9
PHYSICS
This section contains TWO paragraphs.
Based on each paragraph, there are TWO questions.
Each question has FOUR options (A), (B), (C) and (D) ONLY ONE of these four options is correct.
Full Marks : +3 If only the bubble corresponding to the correct answer is darkened.
Zero Marks : 0 In all other cases.
PARAGRAPH 1
A frame of reference that is accelerated with respect to an inertial frame of reference is called a non-
inertial frame of reference. A coordinate system fixed on a circular disc rotating about a fixed axis
with a constant angular velocity is an example of a non-inertial frame of reference. The relationship

between the force Frot experienced by a particle of mass m moving on the rotating disc and the force

Fin experienced by the particle in an inertial frame of reference is

Frot Fin 2m rot m r ,

where rot is the velocity of the particle in the rotating frame of reference and r is the position vector
of the particle with respect to the centre of the disc.
Now consider a smooth slot along a diameter of a disc of radius R rotating counter-clockwise with

a constant angular speed about its vertical axis through its center. We assign a coordinate system
with the origin at the centre of the disc, the x-axis along the slot, the y-axis perpendicular to the slot
and the z-axis along the rotation axis
k . A small block of mass m is gently placed in the slot
at r R / 2 i at t = 0 and is constrained to move only along the slot.

m
R/2
15. The distance r of the block at time t is :
R 2 t R R R t
(A) e e 2 t (B) cos 2t (C) cos t (D) e e t
4 2 2 4
Ans. (D)

17/45
PHYSICS
vdv
Sol. Force on block along slot = m2r = ma = m
dr
v r
2
vdv
0
rdr
R/2
v 2 2 2 R 2 2 R 2 dr
r v r
2 2 4 4 dt
r t
dr
dt
R /4 2 R2 0
r
4

r r2
R2

R /2
R2 R2

n 4 n 4 4 t
R R

2 2

R 2 R t
2
r r e
4 2
R 2 R 2 2 t 2 R
r2 e r 2r et

4 4 2
R 2 2 t R 2
e
r 4 4 R et e t
t
Re 4
16. The net reaction of the disc on the block is :
(A) m2 R cos tj mgk (B) m2 R sin tj mgk
1 1
(C) m2 R e t e t j mgk (D) m2 R e 2 t e2 t j mgk
2 2
Ans. (C)

CODE-9
PHYSICS
N1
N2
Sol.
2m(V'rot ) mg

N1 mgk

N 2 2m V 'rot j
R t t
2m e e j
4
1
m2 R et e t j

2

Total reaction on block = N1 N 2
1
m2 R e t et j mgk
2

PARAGRAPH 2
Consider an evacuated cylindrical chamber of height h having rigid conducting plates at the ends and an
insulating curved surface as shown in the figure. A number of spherical balls made of a light weight and
soft material and coated with a conducting material are placed on the bottom plate. The balls have a radius
r <<h. Now a high voltage source (HV) is connected across the conducting plates such that the bottom

plate is at +V0 and the top plate at V0. Due to their conducting surface, the balls will get charged, will
become equipotential with the plate and are repelled by it. The balls will eventually collide with the top
plate, where the coefficient of restitution can be taken to be zero due to the soft nature of the material
of the balls. The electric field in the chamber can be considered to be that of a parallel plate capacitor.
Assume that there are no collision between the balls and the interaction between them is negligible. (Ignore
gravity)

HV
+

19/45
17. Which of the following statements is correct ?

PHYSICS
(A) The balls will bounce back to the bottom plate carrying the opposite charge they went up with
(B) the balls will execute simple harmonic motion between the two plates
(C) The balls will bounce back to the bottom plate carrying the same charge they went up with
(D) The balls will stick to the top plate and remain there
Ans. (A)
Sol. Balls placed on +ve plate become positive charge and move upward due to electric field.
These balls on colliding with negative plate become negatively charged and move opposite to the direction
of electric field.
18. The average current in the steady state registered by the ammeter in the circuit will be :
1/2 2
(A) Proportional to V0 (B) Proportional to V0
(C) Proportional to the potential V0 (D) Zero
Ans. (B)
Sol. E
+q
h E
q
1
h at 2 [as u = 0]
2

2hm 2m
= time time
qE qV
V0
E
h

charge q qV0
<current> =
time 2mh 2
q V0
< I > V02

CODE-9
CHEMISTRY
PART - II : CHEMISTRY
19. The correct order of acidity for the following compounds is :
CO2H CO2H CO2H CO2H

HO OH OH
OH
OH
I II III IV

(A) I > II > III > IV (B) III > I > II > IV (C) III > IV > II > I (D) I > III > IV > II
Ans. (A)
COOH COOH COOH COOH
HO OH OH
Sol.
> > >

OH
orthoeffect orthoeffect I OH
+R

O O
H C H
COOH
HO OH O O
+
+ H
Most stable due to chelation of two

OH group with COO group
O O

COOH C H
OH O
+
+H
Stable due to chelation of one

OH group with COO group
21/45
O O

CHEMISTRY
COOH C
+
+H
OH OH
I
O OH O O

C C
+
+H
OH OH
+R / +M
20. The geometries of the ammonia complexes of Ni2+ , Pt2+ and Zn2+ , respectively , are :
(A) octahedral, square planar and tetrahederal
(B) square planar, octahederal and tetrahederal
(C) tetrahederal, square planar and octahederal

(D) octahederal , tetrahederal and square planar
Ans. (A)
Sol. Metal ion Complex with NH3 Geometry
2+ 2+
Ni [Ni(NH3)6] Octahedral
Pt2+ [Pt(NH3)4]2+ Square planar
2+ 2+

Zn [Zn(NH3)4] Tetrahedral
So, option (A) is correct.
21. For the following electrochemical cell at 298K,
Pt(s) | H2(g, 1bar) | H+ (aq, 1M) || M4+(aq.), M2+(aq.) | Pt(s)
[M 2 (aq.)]

Ecell = 0.092 V when 10 x

[M 4 (aq.)]
RT
Given : E 0M 4
/ M 2
= 0.151V ; 2.303 0.059
F
Thevalue of x is -
(A) 2 (B) 1 (C) 1 (D) 2
Ans. (D)
Sol. At anode : H2(g) 2H+ (aq) + 2e
4+ 2+
At cathode : M (aq) + 2e M (aq)
Net cell reaction : H2(g) + M4+ (aq) 2H+ (aq) + M2+ (aq)
2
0.059 H M 2
Now, Ecell = E
M 4 / M 2
E
H / H2
n
.log 4
PH 2 . M

CODE-9
CHEMISTRY
0.059 12 M 2
or, 0.092 = (0.151 0) 2 .log 1 M 4

M 2
10 2 x=2
M 4
22. The major product of the following reaction sequence is :

O
(i) HCHO (excess) / NaOH, heat

+
(ii) HCHO / H (catalytic amount)
O O O O OH
(A) (B)
HO
O O O OH
(C) (D)
OH
Ans. (A)

OH OH
O O OH
O CH2 O CH2
HCH / NaOH HCH / NaOH
Sol. H + HCOO
[Cross aldol reaction] [Cross cannizaro
reaction]

OH
OH O O
CH2 O
+
HCH / H
Acetal formation
23. In the following reaction sequence in aqueous soluiton, the species X, Y and Z respectively, are -
2 Ag+ Ag+ With time

S2O 3 X Y Z
clear white black
solution precipitate precipitate
3 5
(A) [Ag(S2O3)2] , Ag2S2O3, Ag2S (B) [Ag(S2O3)3] , Ag2SO3, Ag2S
3 3
(C) [Ag(SO3)2] , Ag2S2O3, Ag (D) [Ag(SO3)3] , Ag2SO4, Ag
Ans. (A)

23/45
CHEMISTRY
+ +
2 Ag 3 Ag
Sol. S2O3 [Ag(S2O3)2] Ag2S2O3
(X) Y
clear solution white precipitate
with time
Ag2S
Z
black precipitate
3
So, X, Y and Z are [Ag(S2O3)2] , Ag2S2O3 and Ag2S respectively.
24. The qualitative sketches I , II and III given below show the variation of surface tension with molar
concentration of three different aqueous solutions of KCl, CH3OH and CH3(CH2)11OSO3 Na+ at room
temperature. The correct assignment of the sketches is -
I II III
surface tension
surface tension
surface tension

concentration concentration concentration
(A) I : KCl II : CH3OH III : CH3(CH2)11OSO3 Na+

(B) I : CH3(CH2)11OSO3 Na+ II : CH3OH III : KCl

(C) I : KCl II : CH3(CH2)11OSO3 Na+ III : CH3OH
(D) I : CH3OH II : KCl III : CH3(CH2)11OSO3 Na+
Ans. (D)

Sol. Water has large surface tension due to very strong interaction. Generally adding organic derivatives
to water decreases its surface tension due to hydrophobic interaction.
In case III, hydrophobic interaction is stronger than case I causing surface tension to decrease more
rapidly.
Due to K+Cl (inorganic electrolyte) intermolecular forces increases, surface tension increases.

CODE-9
CHEMISTRY
25.

For 'invert sugar', the correct statement(s) is (are)
(Given : specific rotations of (+)-sucrose, (+)-maltose, L-()-glucose and L-(+)-fructose in aqueous solution
are + 66, +140, 52 and + 92, respectively)
(A) 'invert sugar' is prepared by acid catalyzed hydrolysis of maltose
(B) 'invert sugar' is an equimolar mixture of D-(+) glucose and D-()-fructose

(C) specific rotation of 'invert surgar' is 20
(D) on reaction with Br2 water, 'invert sugar' forms saccharic acid as one of the products
Ans. (B,C)
Sol. Invert sugar is equailmolar mixture of D-glucose and D-fructose which is obtained by hydrolysis of
sucrose

52 (92 )
Specific rotation of mixture is half of sum of sp. rotation of both components = 20
2
H OH O H
+
OH H H HO H3O
HO O CH2OH D-glucose (sp. rotation +52) + D-fructose (sp. rotation 92)
H OH OH H
Sucrose sp. rotation + 66
CHO COOH
H OH H OH
HO H Br2, H2O HO H
H OH H OH
H OH H OH
CH2OH CH2OH
D-glucose D-gluconic acid (not saccharic acid)
Br2, H2O
D-fructose No reaction
25/45
26. Among the following reaction(s) which gives (give) tert-butyl benzene as the major product is(are)
CHEMISTRY
Br
Cl
(A) (B)
NaOC2H5 AlCl3
OH
(C) (D)
H 2SO 4 BF3.OEt2
Ans. (B,C,D)
2 E
Sol. + NaOC2H5 mechanism
Br
3 alkyl bromide
+ No reaction
+ AlCl3 +
1,2 shift
of H

+
Cl +
AlCl4 tert-butyl benzene

+
H +
(H2SO4)
tert-butyl
benzene

+ 1,2 shift
: :
OH + F3BOEt2 + of H +
(D) O BF3
+
H HOBF3 tert-butyl
benzene
27. Extraction of copper from copper pyrite (CuFeS2) involves

(A) crushing followed by concentration of the ore by froth-flotation
(B) removal of iron as slag
(C) self-reduction step to produce 'blister copper' follwoing evolution of SO2
(D) refining of 'blister copper' by carbon reduction
Ans. (A,B,C)

CODE-9
CHEMISTRY
Sol. Copper pyrite [CuFeS2]
Crushing into fine powder
Concentrated by froth floatation process
Roasting take place in reverberatory furnace

2CuFeS2 + O2 Cu S + 2FeS + SO
2 2
(air)
FeS + O2 FeO + SO2
Iron is removed as slag of FeSiO3
Smelting
FeO + SiO (flux) FeSiO ()(slag)
2 3
Copper matte (Cu2S + FeS)

Self reduction occurs in Bessemer converter
Self reduction 2Cu2S + 3O2 2Cu2S + 2SO2 (
Cu2S + 2Cu2O 6Cu + SO2 (
(Blister copper)
Refining of blister copper is done by poling followed by

electrorefining but not by carbon reduction method.
28. The CORRECT statement(s) for cubic close packed (ccp) three dimensional structure is (are)

(A) The number of the nearest neighbours of an atom present in the topmost layer is 12
(B) The efficiency of atom packing is 74%
(C) The number of octahedral and tetrahedral voids per atom are 1 and 2, respectively
(D) The unit cell edge length is 2 2 times the radius of the atom

Ans. (B,C,D)
Sol. CCP is ABC ABC ..... type packing
(A) In topmost layer, each atom is in contact with 6 atoms in same layer and 3 atoms below
this layer.
4 3
4 r
3
(B) Packing fraction = 3 = (0.74)
4r

2
(C) Each FCC unit has effective no of atoms = 4

Octahedral void = 4
Tetrahedral void = 8
(D) 4r = a 2

27/45
CHEMISTRY
29. Reagent(s) which can be used to bring about the following transformation is(are)
O O O O
C O C
H OH
COOH O COOH O
(A) LiAlH4 in (C2H5)2O (B) BH3 in THF

(C) NaBH4 in C2H5OH (D) Raney Ni / H2 in THF
Ans. (C)
O O O O
Sol. C O C
H OH
O NaBH4 O
CO2H in EtOH CO2H
LiAlH4 in (C2H5)2O ; BH3 in (THF) ; Raney Ni (H2) either can reduce all functional group or can
reduce some of the functional group of the compound given above in reactant side.

But NaBH4 is example of selective reducing agent. It can not reduce CO (ester group) , COH
O O
(carboxylic acid group) , (epoxide group) , but reduces CH=O (aldehyde group)
O

into CH2OH (1 alcohol)

30. Mixture(s) showing positive deviation from Raoult's law at 35C is (are)
(A) carbon tetrachloride + methanol (B) carbon disulphide + acetone
(C) benzene + toluene (D) phenol + aniline
Ans. (A, B)
Sol. (A) H-bonding of methanol breaks when CCl4 is added so bonds become weaker, resulting positive
deviation.
(B) Mixing of polar and non-polar liquids will produce a solution of weaker interaction, resulting positive
deviation
(C) Ideal solution
(D) ve deviation because stronger H-bond is formed.

CODE-9
31. The nitrogen containing compound produced in the reaction of HNO3 with P4O10
CHEMISTRY
(A) can also be prepared by reaction of P4 and HNO3
(B) is diamagnetic
(C) contains one N-N bond
(D) reacts with Na metal producing a brown gas
Ans. (B,D)
dehydration of HNO3
Sol. P4O10 + 4HNO3 4(HPO3) + 2N2O5
(required product)
(A) P4 + 20 HNO3 4H3PO4 + 20NO2+ 4H2O
(B) N2O5 is diamagnetic in nature
O O
(C) N2O5 N N
O O O
N2O5 contains one NON bond not NN bond.

(D) Na + N2O5 NaNO3 + NO2
(Brown gas)
32. According to Molecular Orbital Theory,
(A) C22 is expected to be diamagnetic
(B) O22+ is expected to have a longer bond length than O2
(C) N2+ and N2 have the same bond order

(D) He2+ has the same energy as two isolated He atoms
Ans. (A,C)
Sol (A) The molecular orbital energy configuration of C22 is
1s2 , 1s
*2 2
, 2s , *2 2 2 2
2s , 2p x 2 p y , 2p z
2
In the MO of C2 there is no unpaired electron hence it is diamagnatic

2+ 2+
(B) Bond order of O2 is 3 and O2 is 2 therefore bond length of O2 is greater than O2
+
(C) The molecular orbital energy configuration of N2 is
1s2 , 1s
*2 2
, 2s , *2 2 2 1
2s , 2p x 2 p y , 2p z
1
Bond order of N2+ 9 4
2
= 2.5
The molecular orbital energy configuration of N2 is
*
1s2 , 1s
*2
, 22s , *2 2 2 2 *1
2s , 2p x 2p y , 2p z , 2p 2p
x y
1
Bond order of N2 10 5
2
= 2.5
+
(D) He2 has less energy as compare to two isolated He atoms

29/45

CHEMISTRY

PARAGRAPH 1
Thermal decomposition of gaseous X2 to gaseous X at 298 K takes place according to the following
equation :
2X(g)
X2(g)
The standard reaction Gibbs energy, rG, of this reaction is positive. At the start of the reaction, there
is one mole of X2 and no X. As the reaction proceeds, the number of moles of X formed is given

by . Thus, equilibrium is the number of moles of X formed at equilibrium. The reaction is carried out
at a constant total pressure of 2 bar. Consider the gases to behave ideally.
1 1
(Given : R = 0.083 L bar K mol )
33. The equilibrium constant KP for this reaction at 298 K, in terms of equilibrium , is
2
8equilibrium 82equilibrium 42equilibrium 42equilibrium

(A) 2 (B) 4 2 (C) 2 (D) 4 2

equilibrium equilibrium equilibrium equilibrium
Ans. (B)
Sol. 2X(g)
X2(g)

eq. eq.
1
2
2
eq.
PT
1 eq
PX2 2
KP =
PX2 eq.
1 2
PT
1 eq
2
2eq. 2 2eq
KP = 2
PT
eq.
1 1 eq.
4 4
2
8eq.
= 2
4 eq.

CODE-9
34. The INCORRECT statement among the following , for this reaction, is
CHEMISTRY
(A) Decrease in the total pressure will result in formation of more moles of gaseous X
(B) At the start of the reaction, dissociation of gaseous X2 takes place spontaneously
(C) equilibrium = 0.7
(D) KC < 1
Ans. (C)
n x2 PT
Sol. (A) On decreasing PT Q Q will be less than Kp reaction will move in forward direction
n x2 n T
0
(B) At the start of the reaction G = G + RT ln Q
t = 0 , Q = 0 rxnG = ve (spontaneous)
(C) if eq = 0.7
8 0.49 3.92
Kp =
4 0.49 3.51
Kp > 1
Since it is given that
0
G > 0 Kp < 1
This is incorrect
(D) Kp = KC (RT)ng

KP
KC =
(R 298)1
KC < 1
PARAGRAPH 2
Treatment of compound O with KMnO4 / H+ gave P, which on heating with ammonia gave Q. The

compound Q on treatment with Br2 / NaOH produced R. On strong heating, Q gave S, which on
further treatmenet with ethyl 2-bromopropanoate in the presence of KOH following by acidification,
gave a compound T.
(O)
35. The compound R is :
O O O
NH2
Br NHBr
(A) (B) (C) (D) NBr
Br NHBr
NH2
O O O
Ans. (A)

31/45
36. The compound T is :
CHEMISTRY
(A) Glycine (B) Alanine (C) Valine (D) Serine

Ans. (B)
Sol.
Solution Q.35 & 36.
HOOC COOH H2NOC
+ NH2
H KMnO4 NH3 Br2
NaOH NH2
(O) (P) (Q) (R)
O CH3 O
(i) KOH
N CH C OEt NH
(ii) CH3CHCOEt
O O O
Br O
(S)
+
H3O
CH3
COOH
+ H2N CH COOH
COOH (T)
Phthalic acid Alanine
Q to R is Hoffmann's bromamide degradation reaction

S to T is Gabriel's phthalimide sysnthesis


CODE-9
MATHEMATICS
PART - III : MATHEMATICS

1 0 0
37. Let P 4 1 0 and I be the identity matrix of order 3. If Q = [qij] is a matrix such that
16 4 1

50 q 31 q 32
P Q = I, then equals
q 21
(A) 52 (B) 103 (C) 201 (D) 205
Ans. (B)

1 0 0 1 0 0
4 1 0 1 0
Sol. P = P2 = 8
16 4 1 16 32 8 1
1 0 0

12 1 0
so, P3 = (from the symmetry)
16 32 48 12 1

1 0 0

P50 = 200 1 0
16.50.51
200 1
2
50 16.50.51
As, P Q = I q31 =
2
q32 = 200 and q21 = 200
q 31 q 32 16.50.51
q 21 = + 1 = 102 + 1 = 103
2.200

33/45
MATHEMATICS
38.
2

Area of the region (x, y) : y | x 3 |, 5y x 9 15 is equal to -
1 4 3 5
(A) (B) (C) (D)
6 3 2 3
Ans. (C)
y
A(4,1) D(1,2)
A1 A2
O C(1,0) x
Sol. B(4,0)
(3,0)
Clearly required area = area (trapezium ABCD) (A1 + A2) .....(i)

1 15
area (trapezium ABCD) 1 2 5
3
2 2
A1 x 3 dx
4
2

3

1
1/ 2 16
and A 2 x 3 dx
3
3
15 2 16 3
From equation (1), we get required area
2 3 3 2

13
1
39. The value of (k 1) k
is equal to
k 1
sin sin
4 6 4 6
(A) 3 3 (B) 2(3 3) (C) 2( 3 1) (D) 2(2 3)

Ans. (C)
Sol. We have,
k
sin
13 k 1
6 4 6 4 13
2. k
cot k 1 cot
k 2
6 4

6 4
k 1
sin k 1 .sin k 1
4 6 4 6
13 2 1 cot 5 2 1 2 3 2 3 1
2 cot cot
4 6 4 12

CODE-9
MATHEMATICS
40. Let bi > 1 for i = 1, 2, ....., 101. Suppose logeb1, logeb2,.....,logeb101 are in Arithmetic Progression (A.P.)
with the common difference loge2. Suppose a1, a2,......, a101 are in A.P. such that a1 = b1 and
a51 = b51. If t = b1 + b2 + ..... + b51 and s = a1 + a2 + .... + a51 then
(A) s > t and a101 > b101 (B) s > t and a101 < b101
(C) s < t and a101 > b101 (D) s < t and a101 < b101
Ans. (B)
Sol. If logeb1, logeb2......logeb101 AP ; D = loge2
b1 b2 b3....b101 GP ; r = 2
b1,2b1, 22b1,........., 2100b1...... GP
a1 a2 a3 .......a101 ..... AP
Given, a1 = b1 & a51 = b51
a1 + 50D = 250b1

a1 + 50D = 250a1 (As b1 = a1)
51
Now, t = b1(251 1) ; s 2a1 50D
2

51
t a1 .251 a1 t < a1.251 ....(i) ; s a1 a1 50D
2
51
s a1 250 a1
2

51a1 51 50
s .2 a1
2 2
s > a1.251 ....(ii)

clearly s > t (from equation (i) and (ii))
Also a101 = a1 + 100D ; b101 = b1.2100
250 a1 a1
a
101 a 1 100 ; b101 = 2100a1 ....(iii)
50
a101 = a1 + 251a1 2a1 a101 = 251a1 a1 a101 < 251a1 ....(iv)

clearly b101 > a101 (from equation (iii) and (iv))

35/45
MATHEMATICS

2
x 2 cos x
41. The value of 1 ex dx is equal to

2

2 2 2 2
(A) 2 (B) 2 (C) e2 (D) e2
4 4
Ans. (A)
/2
x 2 cos x /2
1 1 2
Sol. Let I = x
dx = 1 e x
x cos x dx
/2 1 e 0 1 e x
/2 /2
/ 2
= x 2 cos x dx = x 2 sin x 2 x .sin x dx
0
0 0
(I) (II) (I) (II)
/2
2 / 2 2 2
= 2 x.cos x 0 1.cos x = 2[0 + 1] = 2
4 0 4 4
42. Let P be the image of the point (3, 1, 7) with respect to the plane x y + z = 3. Then the equation

x y z
of the plane passing through P and containing the straight line is
1 2 1
(A) x + y 3z = 0 (B) 3x + z = 0
(C) x 4y + 7z = 0 (D) 2x y = 0

Ans. (C)
x 3 y 1 z 7
Sol. Line AP : A(3,1,7)
1 1 1
F(3 + , 1 , + 7) lies in the plane F
xy+z=3
3 + (1 ) + + 7 = 3
3 = 6 = 2
P
F(1,3,5) P
P(1,5,3)
O
i+
2j+
k
x0 y0 z0
so required plane is 1 2 1 0
1 5 3
x 4y + 7z = 0
CODE-9
MATHEMATICS

3 3
43. Let a, b and : be defined by (x) = acos(|x x|) + b|x|sin(|x + x|). Then is -
(A) differentiable at x = 0 if a = 0 and b = 1
(B) differentiable at x = 1 if a = 1 and b = 0

(C) NOT differentiable at x = 0 if a = 1 and b = 0

(D) NOT differentiable at x = 1 if a = 1 and b = 1
Ans. (A,B)
3 3 3
Sol. If x x > 0 cos|x x| = cos(x x)
x3 x < 0 cos|x3 x| = cos(x3 x)

Similarly b|x|sin|x3 + x| = bxsin(x3 + x) for all x R

3 3
(x) = acos(x x) + bxsin(x + x)
which is composition and sum of differentiable functions
therefore always continuous and differentiable.
x/n
n n
n n (x n) x ..... x
2 n
44. Let (x) lim , for all x > 0. Then
n 2
n n2
n!(x 2 n 2 ) x 2 ..... x 2 2
4 n

1 1 2 '(3) '(2)
(A) (1) (B) (C) '(2) < 0 (D)
2 3 3 (3) (2)
Ans. (B,C)

37/45
MATHEMATICS
n 1
x
x r 1 r/n 1
Sol. n(x) lim n n
n n 2 1 n
2
x r / n
r 1 (r / n) r 1
r
x 1
1 n n
x lim n
n n
r 1
r
2
x 1
n
1
1 tx
x n 2 2
dt put tx = z
0 1 t x
x
1 z
n(x) n 2
dz
0 1 z

'(x)
(x)
1 x
n 2
1 x
+
sign scheme of '(x) also '(1) = 0
1
1 1 2
(1), , '(2) 0
2 3 3

'(3) '(2) 4 3
Also n n
(3) (2) 10 5
4 '(3) '(2)
n 0
6 (3) (2)

45. Let : (0, ) and g : be twice differentiable function such that '' and g'' ar continuous
(x)g(x)
functions on . Suppose '(2) = g(2) = 0, ''(2) 0 and g'(2) 0. If lim 1 , then
x 2 '(x)g'(x)
(A) has a local minimum at x = 2 (B) has a local maximum at x = 2

(C) ''(2) > (2) (D) (x) ''(x) = 0 for at least one x
Ans. (A,D)
Sol. Using L'Hpital's Rule
'(x)g(x) (x)g '(x)
lim 1
x 2 ''(x)g '(x) '(x)g ''(x)
(2)g'(2)
1 '(2) (2) 0
''(2)g '(2)
option (D) is right and option (C) is wrong
also '(2) = 0 and ''(2) > 0 x = 2 is local minima.

CODE-9
MATHEMATICS
1
46.
2
Let u u1i u 2 j u 3 k be a unit vector in and w (i j 2k) . Given that there exists a vector
6
3
v in such that u v 1 and w.(u
v) 1 . Which of the following statement(s) is(are) correct?

(A) There is exactly one choice for such v

(B) There are infinitely many choice for such v
(C) If u lies in the xy-plane then | u1 | | u 2 |
(D) If u lies in the xz-plane then 2 | u1 | | u 3 |

Ans. (B,C)
|| u v | cos 1 0
Sol. | w

also | v | sin 1
P
u v w

there may be infinite vectors v OP
1
such that P is always 1 unit dist. from u

i j O
k u

For option (C) : u v u1 u2 0
v1 v2 v3
(u 2 v 3 )i (u1v3 )j (u1v 2 u 2 v1 )k
w

1 1
u 2 v3 , u1v 3 |u1| = |u2|
6 6
i j k

for option (D) : u v u1 0 u3
v1 v 2 v3

(v 2 u 3 )i (u1v 3 u 3 v1 )j (u1v 2 )k
w
1 2
v 2 u 3 , u1v 2
6 6
2|u3| = |u1| So (D) is wrong
47. Let P be the point on the parabola y2 = 4x which is at the shortest distance from the center S of the
circle x2 + y2 4x 16y + 64 = 0. Let Q be the point on the circle dividing the line segment SP
internally. Then-
(A) SP 2 5
(B) SQ : QP 5 1 : 2
(C) the x-intercept of the normal to the parabola at P is 6
1
(D) the slope of the tangent to the circle at Q is
2
Ans. (A,C,D)

39/45
MATHEMATICS
S
Q
P
Sol..
2
y = 4x
point P lies on normal to parabola passing through centre of circle
y + tx = 2t + t3 .......(i)
3
8 + 2t = 2t + t
t=2
P(4, 4)

SP (4 2) 2 (4 8)2
SP = 2 5
SQ = 2
PQ = 2 5 2
SQ 1 5 1

QP 5 1 4
To find x intercept
put y = 0 in (i)
x = 2 + t2
x=6

Slope of common normal = t = 2

1
Slope of tangent =
2
48. Let a,b and a + b 0. Suppose S z : z

2 2
1
a ibt
, t , t 0 , where i 1 .
If z = x + iy and z S, then (x,y) lies on

1 1
(A) the circle with radius and centre , 0 for a > 0, b 0
2a 2a
1 1
(B) the circle with radius and centre , 0 for a < 0, b 0
2a 2a
(C) the x-axis for a 0, b = 0
(D) the y-axis for a = 0, b 0
Ans. (A,C,D)

CODE-9
MATHEMATICS
1
Sol.. x iy
a ibt
a ibt
x iy 2
a b2 t 2
Let a 0 & b 0
a
x .......(1)
a b2 t 2
2
bt
y 2 .......(2)
a b2 t 2
y bt ay
t
x a bx
put in (1)
2 2
2 2 a y
x a b . 2 2 a
b x
2 2 2
a (x + y ) = ax

1
x2 y2 x 0
a
2
1 2 1
x y 2
2a 4a
option (A) is correct

for a 0, b = 0
1
x iy
a
1
x , y 0 z lies on x-axis option (C) is correct
a
for a = 0, b 0

1
x iy
ibt
1
y i, x 0
bt
z lies on y-axis. option (D) is correct
49. Let a,,m . Consider the system of linear equations
ax + 2y =
3x 2y =
Which of the following statement(s) is(are) correct ?
(A) If a = 3, then the system has infinitely many solutions for all values of and
(B) If a 3, then the system has a unique solution for all values of and
(C) If + = 0, then the system has infinitely many solutions for a = 3
(D) If 0, then the system has no solution for a = 3
Ans. (B,C,D)

41/45
Sol. ax + 2y =
MATHEMATICS
3x 2y =
for a = 3 above lies will be parallel or coincident
parallel for 0 and coincident if = 0
and if a 3 lies are intersecting unique solution.
1 1
Let : , 2 and g : , 2 be function defined by (x) = [x 3] and
2
50.
2 2
g(x) = |x| (x) + |4x 7| (x), where [y] denotes the greatest integer less than or equal to y
for y . Then
1
(A) is discontinuous exactly at three points in , 2
2
1
(B) is discontinuous exactly at four points in , 2
2
1
(C) g is NOT differentiable exactly at four points in , 2
2
(D) g is NOT differentiable exactly at five points in 1 , 2

2
Ans. (B,C)

Sol. (x) = [x2 ] 3

g(x) = (|x| + |4x 7|)([x2 ] 3)
1
is discontinuous at x 1, 2, 3, 2 in , 2
2

and |x| + |4x 7| 0 at x 1, 2, 3, 2
1
g(x) is discontinuous at x 1, 2, 3 in , 2
2
In (0 , 0 + )
g(x) = (|x| + |4x 7|). (3)
'g' is non derivable at x = 0.
7 7
In ,
4 4
g(x) = 0 as (x) = 0
7
Derivable at x
4
7
'g' is non-derivable at 0,1, 2,
4

CODE-9
MATHEMATICS
PARAGRAPH 1
Football teams T1 and T2 have to play two games against each other. It is assumed that the outcomes
of the two games are independent. The probabilities of T1 winning, drawing and losing a game against
1 1 1
T2 are , and , respectively. Each team gets 3 points for a win, 1 point for a draw and 0 point
2 6 3
for a loss in a game. Let X and Y denote the total points scored by teams T1 and T2, respectively,

after two games
51. P(X > Y) is-
1 5 1 7
(A) (B) (C) (D)
4 12 2 12

Ans. (B)
Sol.. P(X > Y) = P(T1 win) P(T1 win) + P(T1 win) P(match draw) + P(match draw).P(T1 win)

1 1 1 1 1 1 5
= + + =
2 2 2 6 6 2 12
52. P(X = Y) is-
11 1 13 1
(A) (B) (C) (D)
36 3 36 2
Ans. (C)
Sol. P(X = Y) = P(match draw) P(match Draw) + P(T1 win) P(T2 win) + P(T2 win) P(T1 win)
1 1 1 1 1 13
= + + =
6 6 2 3 3 2 36

43/45
MATHEMATICS
PARAGRAPH 2
x 2 y2
Let F1(x1, 0) and F2(x2, 0) for x1 < 0 and x2 > 0, be the foci of the ellipse 1 . Suppose a
9 8
parabola having vertex at the origin and focus at F2 intersects the ellipse at point M in the first quadrant
and at point N in the fourth quadrant.
53. The orthocentre of the triangle F1MN is-
9 2 9 2
(A) , 0 (B) , 0 (C) , 0 (D) , 6
10 3 10 3
Ans. (A)
6)
/2,
M(3
Sol.
F1 F2
(1,0) (1,0)
N(3
/2 ,
6)
Orthocentre lies on x-axis
5 3
Equation of altitude through M : y 6 x

2 6 2
Equation of altitude through F1 : y = 0
9
solving, we get orthocentre , 0
10
If the tangents to the ellipse at M and N meet at R and the normal to the parabola at M meets the

54.
x-axis at Q, then the ratio of area of the triangle MQR to area of the quadrilateral MF1NF2 is-
(A) 3 : 4 (B) 4 : 5 (C) 5 : 8 (D) 2 : 3
Ans. (C)
6)
/2,
M(3
Sol. x
F1 R
(1,0) (6,0)
N(3
/2,
6)
6 3
Normal to parabola at M : y 6 x
2.1 2

CODE-9
MATHEMATICS
7
Solving it with y = 0, we get Q , 0
2
3
x.
Tangent to ellipse at M : 2 y( 6) 1
9 8
Solving it with y = 0, we get R (6, 0)
1 7 5 6
Area of triangle MQR = . 6 . 6
2 2 4
1
Area of quadrilateral MF1NF2 2. . 1 1 . 6 2 6
2
Required ratio = 5 : 8

45/45

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JEE(Advanced) 2016 Final Exam/Paper-2/Code-9

JEE(Advanced) 2016 TEST PAPER WITH SOLUTIONS

The measured masses of the neutron, 11 H , 157 N and 15

energies of 157 N and 15

CODE-9 JEE(Advanced) 2016 Final Exam/Paper-2/Held on Sunday 22nd May, 2016

Heat flow from P to Q

At steady state heat flow is same in whole combination

Temp of junction is 140C

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CODE-9 JEE(Advanced) 2016 Final Exam/Paper-2/Held on Sunday 22nd May, 2016

Sol. For caliper C1

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6/45 JEE(Advanced) 2016 Final Exam/Paper-2/Held on Sunday 22nd May, 2016

Path difference at point O = d = .6003 mm = 600300 nm

minima form at point O

Sol. T Absolute error

.04 00 .01 .02 .03

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When loop was entering (x < L)

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kinetic energy of e reaching the anode will be

CODE-9 JEE(Advanced) 2016 Final Exam/Paper-2/Held on Sunday 22nd May, 2016

12/45 JEE(Advanced) 2016 Final Exam/Paper-2/Held on Sunday 22nd May, 2016

Range = ig(2RC + 2R)

Range = 2ig Req

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14/45 JEE(Advanced) 2016 Final Exam/Paper-2/Held on Sunday 22nd May, 2016

At t , capacitor acts as open circuit & no current flows through voltmeter.

second case it remains unchanged

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15. The distance r of the block at time t is :

CODE-9 JEE(Advanced) 2016 Final Exam/Paper-2/Held on Sunday 22nd May, 2016

16. The net reaction of the disc on the block is :

(A) m2 R cos tj mgk (B) m2 R sin tj mgk

18/45 JEE(Advanced) 2016 Final Exam/Paper-2/Held on Sunday 22nd May, 2016

CODE-9 JEE(Advanced) 2016 Final Exam/Paper-2/Held on Sunday 22nd May, 2016

17. Which of the following statements is correct ?

20/45 JEE(Advanced) 2016 Final Exam/Paper-2/Held on Sunday 22nd May, 2016

JEE(Advanced) 2016 TEST PAPER WITH SOLUTIONS

CO2H CO2H CO2H CO2H

Stable due to chelation of one

Ecell = 0.092 V when 10 x

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22. The major product of the following reaction sequence is :

(i) HCHO (excess) / NaOH, heat

2 Ag+ Ag+ With time

CODE-9 JEE(Advanced) 2016 Final Exam/Paper-2/Held on Sunday 22nd May, 2016

(B) I : CH3(CH2)11OSO3 Na+ II : CH3OH III : KCl

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27. Extraction of copper from copper pyrite (CuFeS2) involves

26/45 JEE(Advanced) 2016 Final Exam/Paper-2/Held on Sunday 22nd May, 2016

Roasting take place in reverberatory furnace

Copper matte (Cu2S + FeS)

Refining of blister copper is done by poling followed by

(C) Each FCC unit has effective no of atoms = 4

CODE-9 JEE(Advanced) 2016 Final Exam/Paper-2/Held on Sunday 22nd May, 2016

(A) LiAlH4 in (C2H5)2O (B) BH3 in THF

into CH2OH (1 alcohol)

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SECTION3 : (Maximum Marks : 12)

This section contains TWO paragraphs.