KIM3204
WHAT CAN YOU LEARN FROM A
STRUCTURAL IDENTIFICATION OF
MOLECULAR FORMULA ?
CHEMICAL COMPOUNDS
CH3CH2CH3 C3H8
CH3CH2CH2CH3 C4H10
CH3CH2CH2CH2CH3 C5H12
Adding a degree of unsaturation decreases the
CH3 CH3 number of H atoms by two.
CH3 CH CH C CH3 C9H20
CH3 CH3
branched compounds
also follow the formula
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C5H12 = ( CnH2n+2 )
Correct the formula for heteroatoms
C5H8
Subtract the actual formula of your compound
H4 Two Unsaturations
Index = 4/2 = 2
double bond and
ring in this example
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C-H C-NH2
+1 +N,+H Index = 6/2 = 3 two double bonds and
ring in this example
rings in a molecule
one ring and the INDEX C6H14
equivalent of three
Benzene double bonds gives -C6H8
an index of 4
H6 Index = 6/2 = 3
HYDROGENATION
If index = 4, or more, Pd
C6H8 + 2 H2 C6H12
expect a benzene ring
Hydrogenation shows only two double bonds.
Therefore, there must also be a ring.
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H3C CH3
CH3
CH2CH3