Emissions of many air pollutants have been shown to have variety of negative
effects on public health and the natural environment. Emissions that are principal
pollutants of concern include:
NOx - Generated when nitrogen in the air reacts with oxygen at the high
temperature and pressure inside the engine. NO x is a precursor to smog and acid
rain. NOx is the sum of NO and NO2.[1] NO2 is extremely reactive. NOx production
is increased when an engine runs at its most efficient (i.e. hottest) operating
point, so there tends to be a natural tradeoff between efficiency and control of
NOx emissions.
Hidrokarbon (HC) - Satu kelas bahan api dibakar atau sebahagiannya dibakar,
hidrokarbon toksin. Hidrokarbon adalah penyumbang utama kepada kabut, yang
boleh menjadi masalah utama di kawasan bandar. Pendedahan yang berpanjangan
kepada hidrokarbon menyumbang kepada asma, penyakit hati, penyakit paru-paru,
dan kanser. Peraturan-peraturan berkenaan hidrokarbon berbeza mengikut jenis
enjin dan bidang kuasa; dalam beberapa kes, "hidrokarbon bukan metana" dikawal
selia, manakala dalam kes lain, "jumlah hidrokarbon" dikawal selia. Teknologi untuk
satu permohonan (mencari hidrokarbon standard bukan metana) mungkin tidak
sesuai untuk digunakan dalam satu aplikasi yang perlu memenuhi jumlah standard
hidrokarbon. Metana tidak secara langsung toksik, tetapi adalah lebih sukar untuk
memecahkan dalam penukar bermangkin, jadi dalam kesan yang "bukan metana-
hidrokarbon" peraturan boleh dianggap lebih mudah untuk memenuhi. Sejak metana
adalah gas rumah hijau, faedah yang semakin meningkat dalam bagaimana untuk
menghapuskan pelepasan itu. pelepasan HC boleh datang bukan sahaja dari
mencari-cari alasan enjin kenderaan juga secara langsung dari tangki bahan api dan
garis-garis, 24 jam sehari, walaupun enjin dimatikan; sistem yang kompleks garis
bolong bahan api dan kanister arang bertujuan untuk mengumpul dan mengandungi
wap bahan api dan laluan mereka sama ada kembali ke tangki bahan api atau,
selepas enjin dimulakan dan panas, ke dalam pengambilan udara untuk dibakar
dalam enjin.
Bahan Zarah - Jelaga atau asap terdiri daripada zarah dalam pelbagai saiz
mikrometer: perkara Zarah menyebabkan kesan-kesan kesihatan yang negatif,
termasuk tetapi tidak terhad kepada penyakit pernafasan dan kanser. Sangat
perkara zarah halus telah dikaitkan dengan penyakit kardiovaskular.
Sulfur oksida (SOx) - Satu istilah umum untuk oksida sulfur, yang berpunca
daripada penggunaan kenderaan motor pembakaran bahan api yang mengandungi
sulfur. Mengurangkan tahap sulfur bahan api mengurangkan tahap oksida Sulfur
dipancarkan dari tailpipe itu.
History[edit]
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Throughout the 1950s and 1960s, various federal, state and local governments in
the United States conducted studies into the numerous sources of air pollution.
These studies ultimately attributed a significant portion of air pollution to the
automobile, and concluded air pollution is not bounded by local political boundaries.
At that time, such minimal emission control regulations as existed in the U.S. were
promulgated at the municipal or, occasionally, the state level. The ineffective local
regulations were gradually supplanted by more comprehensive state and federal
regulations. By 1967 the State of California created the California Air Resources
Board, and in 1970, the federal United States Environmental Protection
Agency (EPA) was established. Both agencies, as well as other state agencies, now
create and enforce emission regulations for automobiles in the United States. Similar
agencies and regulations were contemporaneously developed and implemented
in Canada, Western Europe, Australia, and Japan.
The first effort at controlling pollution from automobiles was the PCV (positive
crankcase ventilation) system. This draws crankcase fumes heavy in unburned
hydrocarbons a precursor to photochemical smog into the engine's intake tract
so they are burned rather than released unburned from the crankcase into the
atmosphere. Positive crankcase ventilation was first installed on a widespread basis
by law on all new 1961-model cars first sold in California. The following year, New
York required it. By 1964, most new cars sold in the U.S. were so equipped, and
PCV quickly became standard equipment on all vehicles worldwide. [2]
The first legislated exhaust (tailpipe) emission standards were promulgated by the
State of California for 1966 model year for cars sold in that state, followed by the
United States as a whole in model year 1968. Also in 1966, the first emission test
cycle was enacted in the State of California measuring tailpipe emissions in PPM
(parts per million). The standards were progressively tightened year by year, as
mandated by the EPA.
By the 1974 model year, the emission standards had tightened such that the de-
tuning techniques used to meet them were seriously reducing engine efficiency and
thus increasing fuel usage. The new emission standards for 1975 model year, as
well as the increase in fuel usage, forced the invention of the catalytic converter for
after-treatment of the exhaust gas. This was not possible with
existing leaded gasoline, because the lead residue contaminated the platinum
catalyst. In 1972, General Motors proposed to the American Petroleum Institute the
elimination of leaded fuels for 1975 and later model year cars. [citation needed] The
production and distribution of unleaded fuel was a major challenge, but it was
completed successfully in time for the 1975 model year cars. All modern cars are
now equipped with catalytic converters and leaded fuel is nearly impossible to buy in
most First World countries.
Regulatory agencies[edit]
The agencies charged with regulating exhaust emissions vary from jurisdiction to
jurisdiction, even in the same country. For example, in the United States, overall
responsibility belongs to the EPA, but due to special requirements of the State of
California, emissions in California are regulated by the Air Resources Board. In
Texas, the Texas Railroad Commission is responsible for regulating emissions
from LPG-fueled rich burn engines (but not gasoline-fueled rich burn engines).
North America[edit]
Emissions control[edit]
Engine efficiency has been steadily improved with improved engine design, more
precise ignition timing and electronic ignition, more precise fuel metering,
and computerized engine management.
Advances in engine and vehicle technology continually reduce the toxicity of exhaust
leaving the engine, but these alone have generally been proved insufficient to meet
emissions goals. Therefore, technologies to detoxify the exhaust are an essential
part of emissions control.
Air injection[edit]
Main article: Secondary air injection
One of the first-developed exhaust emission control systems is secondary air
injection. Originally, this system was used to inject air into the engine's exhaust ports
to provide oxygen so unburned and partially burned hydrocarbons in the exhaust
would finish burning. Air injection is now used to support the catalytic converter's
oxidation reaction, and to reduce emissions when an engine is started from cold.
After a cold start, an engine needs an air-fuel mixture richer than what it needs
at operating temperature, and the catalytic converter does not function efficiently
until it has reached its own operating temperature. The air injected upstream of the
converter supports combustion in the exhaust headpipe, which speeds catalyst
warmup and reduces the amount of unburned hydrocarbon emitted from the tailpipe.
Exhaust gas recirculation[edit]
Main article: Exhaust gas recirculation
In the United States and Canada, many engines in 1973 and newer vehicles (1972
and newer in California) have a system that routes a metered amount of exhaust into
the intake tract under particular operating conditions. Exhaust neither burns nor
supports combustion, so it dilutes the air/fuel charge to reduce peak combustion
chamber temperatures. This, in turn, reduces the formation of NOx.
Catalytic converter[edit]
Main article: Catalytic converter
The catalytic converter is a device placed in the exhaust pipe, which converts
hydrocarbons, carbon monoxide, and NOx into less harmful gases by using a
combination of platinum, palladium and rhodium as catalysts.
There are two types of catalytic converter, a two-way and a three-way converter.
Two-way converters were common until the 1980s, when three-way converters
replaced them on most automobile engines. See the catalytic converter article for
further details.
Kecekapan enjin telah semakin bertambah baik dengan reka bentuk yang lebih baik
enjin, pemasaan pencucuhan yang lebih tepat dan pencucuhan elektronik, bahan api
pemeteran lebih tepat, dan pengurusan enjin berkomputer.
Kemajuan dalam teknologi enjin dan kenderaan terus mengurangkan ketoksikan
ekzos meninggalkan enjin, tetapi ini sahaja secara amnya telah terbukti tidak
mencukupi untuk memenuhi matlamat pelepasan. Oleh itu, teknologi untuk
menyahtoksik ekzos adalah bahagian yang penting dalam kawalan pelepasan.
suntikan udara [sunting]
Rencana utama: suntikan udara Menengah
Salah satu sistem kawalan pelepasan ekzos pertama dibangunkan adalah suntikan
udara sekunder. Pada asalnya, sistem ini digunakan untuk menyuntik udara ke
dalam pelabuhan ekzos enjin untuk menyediakan oksigen supaya hidrokarbon yang
tidak terbakar dan sebahagiannya dibakar dalam ekzos akan menyelesaikan
terbakar. suntikan udara kini digunakan untuk menyokong tindak balas
pengoksidaan penukar bermangkin, dan untuk mengurangkan pelepasan apabila
enjin dimulakan dari sejuk. Selepas permulaan yang sejuk, enjin yang memerlukan
campuran udara-bahan api lebih kaya daripada apa yang diperlukan pada suhu
operasi, dan penukar bermangkin tidak berfungsi dengan cekap sehingga ia
mencapai suhu operasi sendiri. Udara yang disuntik hulu penukar menyokong
pembakaran dalam headpipe ekzos, yang mempercepatkan pemangkin warmup dan
mengurangkan jumlah hidrokarbon yang tidak terbakar dipancarkan dari tailpipe itu.
Exhaust gas edaran semula [sunting]
Rencana utama: Exhaust edaran semula gas
Di Amerika Syarikat dan Kanada, banyak enjin pada tahun 1973 dan baru kenderaan
(1972 dan baru di California) mempunyai satu sistem yang laluan sejumlah bermeter
ekzos ke dalam saluran pengambilan di bawah keadaan operasi tertentu. Exhaust
tidak terbakar dan tidak menyokong pembakaran, jadi ia mencairkan caj udara /
bahan api untuk mengurangkan puncak suhu kebuk pembakaran. Ini seterusnya,
mengurangkan pembentukan NOx.
Penukar bermangkin [sunting]
Rencana utama: Penukar bermangkin
Penukar bermangkin adalah alat yang diletakkan di dalam paip ekzos, yang
menukarkan hidrokarbon, karbon monoksida, dan NOx ke dalam gas kurang
berbahaya dengan menggunakan gabungan platinum, palladium dan rhodium
sebagai pemangkin.
Terdapat dua jenis penukar pemangkin, dua hala dan tiga hala penukar. penukar dua
hala adalah biasa sehingga tahun 1980-an, apabila penukar tiga hala menggantikan
mereka pada enjin kereta yang paling. Lihat artikel penukar pemangkin untuk
maklumat lanjut.
Evaporative emissions control[edit]
"EVAP" redirects here. EVAP may also refer to Evaporation.
Evaporative emissions are the result of gasoline vapors escaping from the vehicle's
fuel system. Since 1971, all U.S. vehicles have had fully sealed fuel systems that do
not vent directly to the atmosphere; mandates for systems of this type appeared
contemporaneously in other jurisdictions. In a typical system, vapors from the fuel
tank and carburetor bowl vent (on carbureted vehicles) are ducted to canisters
containing activated carbon. The vapors are adsorbed within the canister, and during
certain engine operational modes fresh air is drawn through the canister, pulling the
vapor into the engine, where it burns.
emisi meruap adalah hasil daripada wap petrol melarikan diri dari sistem bahan
api kenderaan. Sejak tahun 1971, semua kenderaan AS mempunyai sistem
bahan api berturap yang tidak melepaskan terus ke atmosfera; mandat untuk
sistem jenis ini muncul contemporaneously dalam bidang kuasa lain. Dalam
sistem biasa, wap dari mangkuk tangki bahan api dan karburetor melepaskan
(atas kenderaan carbureted) sedang disalurkan ke kanister mengandungi karbon
diaktifkan. Wap terjerap dalam bejana, dan semasa mod operasi enjin tertentu
udara segar diambil melalui bejana, menarik wap ke dalam enjin, di mana ia
membakar.
keputusan ujian pelepasan dari kenderaan individu dalam banyak kes disusun
untuk menilai prestasi pelepasan dari pelbagai kelas kenderaan, keberkesanan
program ujian dan pelbagai peraturan yang berkaitan pelepasan-lain (seperti
perubahan untuk menjana rumusan) dan model kesan pelepasan auto ke atas
kesihatan awam dan alam sekitar. Sebagai contoh, Kumpulan Kerja Alam Sekitar
digunakan California ASM data pelepasan untuk mewujudkan "Index Asma Auto"
bahawa model kadar kenderaan mengikut pelepasan hidrokarbon dan nitrogen
oksida, peningkatan kimia untuk kabut fotokimia.