0.

035
Fe+3 (10 ml)

0.03

f(x) = 0.0281005604 exp( -0.0021630433 x )

x/R = 0.9609646926
0.025
t

0.02

0.015

0.01

0.005

0
0 50 100 150 200 250 300 350 400 450 500

Time (t) (secs)

x(ml) x/t t(sec)
1.1 0.02973 37
1.6 0.024615 65
2.2 0.02268 97
2.6 0.021311 122
3 0.018987 158
3.4 0.018085 188
3.6 0.016216 222
3.9 0.015415 253
4.3 0.014381 299
4.6 0.013372 344
4.8 0.012214 393
5.2 0.011135 467
 Fe+3 (20 ml)
0.07

0.06
f(x) = 0.0593154265 exp( -0.0028031744 x )
R = 0.945781923

0.05

0.04

0.03

0.02

0.01

0
0 50 100 150 200 250 300 350 400

Time (t) (secs)

x x/t t
1.7 0.062963 27
2.7 0.05625 48
4 0.044944 89
4.8 0.039669 121
5.3 0.036806 144
5.8 0.034524 168
6.2 0.033155 187
6.6 0.031731 208
6.9 0.03 230
7.4 0.028244 262
7.8 0.026351 296
8.2 0.025231 325
8.5 0.023876 356
 Fe+3 (30 ml)
0.12

0.1

f(x) = 0.0918400065 exp( -0.0025374221 x )

R = 0.9410818743
0.08

0.06

0.04

0.02

0
0 50 100 150 200 250 300 350 400 450 500

Time (t) (secs)

x t x/t
3.5 35 0.1
5.2 62 0.083871
6.7 92 0.072826
7.5 113 0.066372
8.4 140 0.06
9.6 183 0.052459
10.6 215 0.049302
11.4 247 0.046154
12 277 0.043321
12.6 310 0.040645
13.2 343 0.038484
14.1 389 0.036247
14.9 442 0.03371
 Fe+3 (40 ml)
0.16

0.14

f(x) = 0.1274859443 exp( -0.003016121 x )

0.12
R = 0.9558932118

0.1

0.08

0.06

0.04

0.02

0
0 50 100 150 200 250 300 350 400

Time (t) (sec)

x t x/t
4.3 32 0.134375
7.2 69 0.104348
8.8 94 0.093617
10.2 124 0.082258
11.5 151 0.076159
13 196 0.066327
13.8 220 0.062727
14.4 240 0.06
15 263 0.057034
15.6 284 0.05493
16.2 314 0.051592
16.9 344 0.049128
 I - ( 10 mL)
0.009

0.008 f(x) = 0.0081455621 exp( -0.0013245891 x )

R = 0.8065369639

0.007

0.006

0.005
x/t
Exponential (x/t)
0.004

0.003

0.002

0.001

0
0 50 100 150 200 250 300 350 400

Time (t)(secs)
x t x/t
0.3 43 0.006977
0.7 84 0.008333
0.9 137 0.006569
1.2 187 0.006417
1.5 260 0.005769
1.8 360 0.005
 I - ( 20 mL)

0.04

0.035
f(x) = 0.0353978267 exp( -0.0030669231 x )
R = 0.9768795852

0.03

0.025

0.02
x/t
0.015

0.01

0.005

0
0 50 100 150 200 250 300 350

Time (t) (sec)

x t x/t
1 30 0.033333
1.5 47 0.031915
2 69 0.028986
2.3 85 0.027059
2.8 114 0.024561
3.1 143 0.021678
3.4 175 0.019429
3.8 213 0.01784
4.2 251 0.016733
4.5 287 0.015679
 I - ( 30 mL)

0.08
f(x) = 0.0797323223 exp( -0.0042551052 x )
R = 0.9829254469
0.07

0.06

0.05

X/t
0.04

0.03
Time (t) (secs)

0.02

0.01

0
0 50 100 150 200 250 300
x t x/t
2.1 29 0.072414
3.9 60 0.065
4.6 82 0.056098
5.2 107 0.048598
5.7 129 0.044186
6.1 152 0.040132
6.5 177 0.036723
6.9 205 0.033659
7.3 241 0.03029
 I - ( 40 mL)
0.12

f(x) = 0.1113907858 exp( -0.004129179 x )

R = 0.9601777024
0.1

0.08

0.06
X/t

0.04

0.02

0
0 50 100 150 200 250 300 350 400

Time(t)(secs)
x t x/t
5 47 0.106383
6 67 0.089552
6.7 87 0.077011
7.2 105 0.068571
7.9 135 0.058519
8.6 173 0.049711
9.1 205 0.04439
9.6 250 0.0384
10 295 0.033898
10.4 340 0.030588
 fe x/t fe' c
10 0.017 0.17 0.001545 0.02 -2.810944 -1.69897
20 0.017 0.34 0.002833 0.056 -2.547702 -1.251812
30 0.017 0.51 0.003923 0.087 -2.406373 -1.060481
40 0.017 0.68 0.004857 0.12 -2.313619 -0.920819
 Log(X/t) vs Log[I- conc at constant Fe(NO3)3]

0
-2.7 -2.6 -2.5 -2.4 -2.3 -2.2 -2.1

-0.5

Log(x/t)
-1
f(x) = 2.2516503477x + 3.8678787553
R = 0.994898988

Log[I- conc at constant Fe(NO3)3] -1.5

-2

-2.5
 fe' c
10 0.025 0.25 0.002273 -2.643453 0.008
20 0.025 0.5 0.004167 -2.380211 0.033
30 0.025 0.75 0.005769 -2.238882 0.074
40 0.025 1 0.007143 -2.146128 0.099
fe'' c''
-2.643453 -2.09691
-2.380211 -1.481486
-2.238882 -1.130768
-2.146128 -1.004365