1240 nm V
min
V
atoms in a state of energy En is given by a
Boltzmann distribution expression
67. An electron in chromium moves 70. All atoms have the same size, to an
from the n = 2 state to the n = 1 state order of magnitude. (a) To show this,
without emitting a photon. Instead, the estimate the diameters for aluminum (with
excess energy is transferred to an outer molar mass 27.0 g/mol and density 2.70
electron (one in the n = 4 state), which is g/cm3) and uranium (molar mass 238
then ejected by the atom. (This is called an g/mol and density 18.9 g/cm3). (b) What do
Auger [pronounced ohjay] process, and the results imply about the wave functions
the ejected electron is referred to as an for inner-shell electrons as we progress to
Auger electron.) Use the Bohr theory to find higher and higher atomic mass atoms?
the kinetic energy of the Auger electron. (Suggestion: The molar volume is
approximately D3NA, where D is the atomic
68. In interstellar space, atomic diameter and NA is Avogadros number.)
hydrogen produces the sharp spectral line
called the 21-cm radiation, which 71. In the technique known as electron
astronomers find most helpful in detecting spin resonance (ESR), a sample containing
clouds of hydrogen between stars. This unpaired electrons is placed in a magnetic
radiation is useful because it is the only field. Consider the simplest situation, in
signal cold hydrogen emits and because which only one electron is present and
interstellar dust that obscures visible light is therefore only two energy states are
transparent to these radio waves. The possible, corresponding to ms = . In ESR,
radiation is not generated by an electron the absorption of a photon causes the
transition between energy states electrons spin magnetic moment to flip
characterized by different values of n. from the lower energy state to the higher
Instead, in the ground state (n = 1), the energy state. According to Section 29.3, the
electron and proton spins may be parallel or change in energy is 2BB. (The lower energy
antiparallel, with a resultant slight state corresponds to the case where the z
difference in these energy states. (a) Which component of the magnetic moment spin is
condition has the higher energy? (b) More aligned with the magnetic field, and the
precisely, the line has wavelength 21.11 cm. higher energy state is the case where the z
What is the energy difference between the component of spin is aligned opposite to the
field.) What is the photon frequency traveling in opposite directions. An atom in
required to excite an ESR transition in a the ground state immediately absorbs a
0.350-T magnetic field? photon. Total system momentum is
conserved in the absorption process. After a
72. Show that the wave function for an lifetime on the order of 108 s, the excited
electron in the 2s state in hydrogen atom radiates by spontaneous emission. It
has an equal probability of emitting a
1 1
3/ 2
r r / 2 a0 photon in any direction. Thus, the average
2s r 2 e
4 2 a 0 a 0 recoil of the atom is zero over many
absorption and emission cycles. (a) Estimate
the average deceleration of the atomic
satisfies the spherically symmetric
beam. (b) What is the order of magnitude of
Schrdinger equation given in Problem 21.
the distance over which the atoms in the
beam will be brought to a halt?
73. Review problem. Steven Chu,
Claude Cohen-Tannoudji, and William
74. Find the average (expectation) value
Phillips received the 1997 Nobel Prize in
of 1/r in the 1s state of hydrogen. It is given
physics for the development of methods to
by
cool and trap atoms with laser light. One
part of their work was with a beam of
1 / r dV P r 1 / r 4
2
atoms (mass ~1025 kg) that move at a speed 1/ r
0
on the order of 1 km/s, similar to the speed
all space