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3 For

Examinefs
Use
Section A

Answer all the questions in this section in the spaces provided.


The total mark for this section is 50.

The table shows some information about substances A to D.

substance melting point boiling point Does it conduct Does it conduct


l"c /"c electricity when it is electricity when
a solid? molten?
A -95 69 no no
B 1251 1970 no yes
c 1240 2100 yes yes
D 1 650 2230 no no

(a) Which substance is most likely to be a metal?

* r1l

(b) Which substance is a liquid at room temperature?


A
l:) .... t1 l
(c) Which substance is most likely to be silicon dioxide (sand)?

..') ....r11

(d) (i) What type of bonding is present in substance B?

1' i t,. .. .br,;,


.....,:.L ;r.....
".,.,. rl.i.,:,
/.1 . .... tl]
(ii) Explain your answer.

[Total: 5]

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4 For
Examinels
Use
The diagram shows how the outer shell electrons are arranged in a compound.

(a) Put ticks (/) in the boxes to show whether the following statements about the compound
are true or false.

true false
It is a saturated hydrocarbon. l,/"
It could be ammonia, NH.. L/
It is a halogen compound. \r/
It is an ionic compound. V t3l

(b) Draw a similar diagram to show the arrangement of electrons in a molecule of carbon
dioxide, COr.
You only need to show outer shell electrons.

X - eU. cl''a
v - e,ur'l.r;,"_
"l(
a) L'
j

l2l
[Total: 5]

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5 For
Examinels
Hydrogen is a fuel that may be used on a large scale in the future for cars. Use

(a) One way of making hydrogen for fuel is by the electrolysis of water.

(i) Write a single equation, with state symbols, to show the products of
the electrolysis
of water.

; flr( il;?),!* t--.--. irt ,t : {, ({;t


(ii) The electrolysis is an endothermic process.
Use ideas about bond breaking and bond making to explain why this reaction
is
endothermic.

(b) Hydrogen-powered cars use the hydrogen fuel to produce electricity


to run the car.
How is the electricity generated in the car?

\fihltil rc*,:h *: illt t:ry'f* rf: .p.*$*,...rdr:f*,:......:.[hi,...c*i.e,l*r...urr.$. !s7,.:!>

.d*:,+:h:l;1.rir....i.ri{:rd.r. ...t;;::i,.tt:.(2...1:gri::+ ..t:lt!.r.c!;,.*.r...h:!i(.,...*!i+,.ti:,t".i*.rl:,.vr:ir*.:.t...


121
! f g( c4t t ;,rir uuln;,- t, I fnCur" .(t<..fr,-\
(c) Ethanol can also be used as a car fuel. j |
ln some countries it is produced from the sugars in sugar cane.

(i) Name the process used to produce ethanol from sugar.


.'.?

...{.<r.n.q.nb${.{t:. ... . t1l


(ii) An environmentalist claims that ethanol as a fuel is 'carbon neutral'because using
it does not add to the amount of carbon dioxide in the atmosphere.
Explain why this is true.

/! ::-j.,y,.Qr**r....k,..i,r{bt.&..chttl.c*,..{.4*vt:r{....(ttn...k*..y,r.,sd...,
:*il."j?E ...1!K:..(l.y!E*..cQ.(1.t,(v.,.!.kc.vt:.<{....fttn....1k*..1:?g:.4. U.f .

*_1

oj rc'rh;,,,t thtn,rQ ,{,tl fu_ u*vl ,nl,


[Total: 10]
Xw ,v"4,,'nl ,l (I; enlk& i4 *J ti.,i^b-+4>A 'l
L{h,,n,l it dr"l1u,{ hn'lw'1r'tli,t,, '1 cc:'
q"l'T't*'4
T
,tr ,"V.1 6,(r(-'A"*"r!

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6
v
For
Examinefs
4 The table shows some information about the homologous series
of a class of organic Use
compounds called acyl chlorides.

name condensed formula displayed formula

ethanoyl chloride cH3coc/ H-C


| ,,o
H
|-C:'cr
hFt
ii
C;
cilsrc( LI.C- --C //
f 'dfo"o1l thlcr ic{a t
lr
C
-al
l,t H

HHH
butanoyl chloride caHTcoc/
I I L.,.o
H-C-C __ C-C'a
lll'cr
HH H

(a) (i)

(ii) you can tell that these molecules are from the

(iii)

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v
7 For
Examiner's

(b) Ethanoyl chloride reacts with ethanol in the following reaction. Use

CH3COCI + C2H'OH + CH3COOCTH' + HC/


compound X

(i) What is the name of compound X?

e-\h.fr .r.....\.. L)n.o.ef s ; ....


..t:.':i:.JY.(*.1.S..,
l... .eil.: ..... .. t1]

(ii) Ethanoic acid also reacts with ethanol.


Write an equation for the reaction of ethanoic acid with ethanol.

('ytlg c 1,y + c t'lr(r: n# '-*) tt t.t { r' i-- t'li'ts T 4 uO

difference.....L,.rrr.....p.r:.i.+.w* ....h{.J....r,-.tr,k ...-Jtk..".tl!*r...nr;:r.fu.t-!.t:e..11v.P...


ll
... .... t2l

[Total: 9]

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v
8 For
Examinefs
Use
The table shows information about some alkanes.

enthalpy change
name of number of
of combustion in
alkane carbon atoms
kJ / mol

A L,Tt

"-tf8 ct

(a) Predict the enthalpy change of combustion of butane in kJ/mol.

1:tiTt: ghril
I
l1J

(b) What general trend in the enthalpy changes of combustion is shown by the data rn the
table?

A .l.h.u..itr+mlx {..q....tu,rk.r.;...:;t.(.t:y(:iLt..i*....ill*.. .*k::*./...e.!,Iy,lf ,1.,

.(lur .!:.. -', .(.r.t::!::ttk.1.:1... .ir.rer,,x.-:610.f tri*t*lfX '1:

(c) Sor" cars use diesel fuel while some use petrol.
Petrol and diesel are produced from fractions of crude oil.
Diesel boils at a higher temperature than petrol.

(Aril, Luft
lcu,;er i'' P :t
t'WlwL,lf W
WrWr r'r''lL* 'n
+L t'r)vnl 1-'thii'
fue*-Lr
X
r- tu-Xkr
b rr i> ;,6,atJ-i{
+il- la*r o,Jl*4

@ UCLES & MOE 2OO9 5072lOztOtNt09


For
Examiner's
Use

[Total: 1 1]

O UCLES & MOE 2OO9 5072t02totNt09


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=
v
10 For
Examinefs
Use
A fertiliser factory uses ammonia to make fertilisers.

(a) What are the essential conditions for making ammonia from nitrogen and hydrogen?

l2l

(b) The ammonia is used to make ammonium phosphate and ammonium nitrate.

(i) Ammonium phosphate contains ammonium ions, NHo*, and phosphate ions,
Poo*'
What is the formula for ammonium phosphate?
( Nrtl t?flv i,l
(ii) Ammonium nitrate has the formula NH.NO..
Calculate the percentage by mass of nitrogen in ammonium nitrate.

,! hfr.,,i(^ =ffi,o_*i
rfi

/ylrii /ia)
i ) ) -35.q,/' '2

(c) Phosphate ions, POot-, are present in the waste water from the factory.
One way of treating the water to remove these phosphate ions is by adding colci;n-l
ions.
The calcium ions react with the phosphate ions to form a precipitate.

Write an equation, with state symbols, to show the reaction between calcium ions ano
phosphate ions.

j C,rf. ,ry, *'ff ct* (tt,r> ---) (',i+lftr^*), ( s )


L

l- r

(d) The waste water also contains nitrate ions.


Explain why nitrate ions cannot be removed by precipitation reactions.

+' ['e,-
f;y1e."-.L,ff
'

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J
11 For
Examine/s
(e) The bags of ammonium nitrate fertiliser have the following warning printed on them. Use

Do not add fertiliser to soil that


has been recently treated with
any lime-containing product.

The main lime-containing product used on farms is calcium hydroxide.

(i) Why is calcium hydroxide added to soils?


<
...{.q....(#r::YK....(.r.*.i.2 4v:CV
....'..., i,r s',[.>
ff.....:.... ......t11
(ii) Why is it important not to add ammonium compounds to soils that have
been
treated with calcium hydroxide?
4
....'.N.r,....9rl:1"...*i::.f. ,*...i,:..-:..1r;...{).(!n1,.t!....:j.t::...fry....t!(,(.,i(.fi....4...!.ti:;.!::!.1......

....!t,::,!:,'t*:...l.,{,.r.'rg...frn:1..+i...,:).,.:t::.o',.|...ri.i:!,.?.

ig bu:;:.titr,,,'"u- ( Jtk_ ; (,rll,r.* ,lrri"r, r-d/(! ,,,ff,,,0,i1r,.1


f | -t 't ]
tTotal: 10]

@ UCLES & MOE 2OO9 5072t02totNt09


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v
12

Section B

Answer all three questions from this section.

The last question is in the form of an either/or and only one of the alternatives should be attempted.

87 Magnesium oxide, Mgo, is used to make many medicines.


It is made from magnesite mineral by the process shown in the flow chart.
Magnesite contains 75% magnesium carbonate, MgCO..

V
crushed waste gas A
magnesite

dilute sulfuric
acid
A dilute magnesium
sulfate solution

process B : heating

concentrated
liquid waste tnagnesiurn
sulfate solutron

\ptocess D magnestum

solid /1
T hydroxide
suspension

magnesium \ ,""ctant c
hydroxide

reaction E

pure waste
magnesium water
oxide vapour

" t. /
(a) (i) Give the name of the main gas in waste gas A. (rr-/t-'"'' r[i*"" r tLf-"-
(ii) Name reactant C. jr rh i/:y\ b1,^l,rr,,,lt'-
tl
(iii) What method should be used to 'separate out the solid magnesium hydroxide in
process D?
f ith't,t r v7
(iv) write an equation for reaction E.
N:1{-r:t,11} . *__) Ni,1 {, .*. H, c,
l4l
.'l 71

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U
13
(b) mass of masnesium oxide that can be produced
::fi:XfJf;rnaximum from 280 tonnes of
l4l
(c) the solution in process B, 400dm3 of dirute
fff"i;Jfating sorution has a concentration of

After process B, the concentrated solution


has a concentration of 560g/dm3.
what is the vorume of the concentrated sorution? pl
(d) Magnesium chloride is used to make many
medicines.
It can be made by reacting solid magnesium
oxide wiirr a dilute acid.
Draw a flow chart' similar to the one above,
to show how
/vY to produce il
rlJ PrvLruu., a L;oncenlrateo
concentrated solution
of magnesium chloride from magnesium oxide.
el
[Total: 12]
(L) .. -r.
Yt1Lt-' f"l rt C, .r ( (ri
/! J

lir t,ly(I'1,7( t.^', : t y


N, lj',' l'l,r('
4
= +.'
:. t

('' ;
. Yl^x tt1,.s>
\l fnt,l
fur rtc =i" lij('" 3 "h,,nn _,

! ('l i
4t 7 'f c I I lYft cc3
(() /n +& ,l; .: q,
fr,ld-:
'l-

';/{: t3='t;'
+"e*: U{Ulf: |.lr,il^*
(!
. tb,.'- " f,i,
+
.'
' of
^c
fl(^u'l
w[*;;;
It '
5rt4e

: ffin,#V
----------=- 0 fu+''-lltzen)^trz
,

i,,iiJ I ,.'.-; (* a"i


s (:c'fa'J tl/t';"e-
Y'; x +t
Jd) vtLarv")"Y**:#
lL

SLL,^ffin'
7,t"V-V \ .'
'-rto
fty(,'r;*tr",'"f
(t
;l,olrlot-
,;:;,'*,"". -t-'i-':: *'ot- = ttu,1*' +
rtr )cl I (hlo,.o'tL
_J i(,,r,^,..qli)tr,i,r:l
J.{ufia/r l'ilr<{f 1,-\,ri;1t C h1. . ,.[,-
J 5r {.,fi.,L

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5072t02/O/N/09
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\
14

BB The diagram shows a monomer that can undergo addition poiymerisation.

H-C-C:C.
I ,.H
ll'H
HH
(a) Name the polymer formed when this molecule polymerises and draw the structure of the
repeating unit of the polymer. l2l

(b) A sample of the polymer was analysed and found to have an average relative molecular mass
of 1 0500.
How many carbon atoms are present in an average chain? t3l

(c) Separate samples of the monomer and the polymer are each shaken with bromine w'ater.
What would you expect to see in each case? t1l

(d) The diagram shows a section of another polymer with a similar structure.

c2H5 H QzHs u QrHu H


l--lllll
c-c-c-c-
tlllll
-cHHHHHH
Draw the structure of the monomer from which it forms. Name this monomer. 12)

fTotal: 8]
(n) r "hi,[r*i, rx )

t l-l
tyt

ltr
+ c*(
litthz
t t4

( l,) ffiri ,ryn'y:t't'< = (;tlt' : 4L


Mi t'\n:;(<{"'tLt', = ry; : Jl-c:
frvpcr*;
fu'" (i ("tLt) , r'hu''.- Y,'zk'lL = )fr'X -j
YI
! ' :.,7Tr#
,, 1,'
(*'-- f\
,l ;'-<' w /-
v
15

EITHER

Bg Experiments are set up to investigate the reduction of three


metal oxides by hydrogen.

burning hydrogen
hydrogen ------+

metal oxide

The table shows the appearance of each metal oxide when cold.

experiment metal oxide colour when cold


1 calcium oxide white
2 copper oxide red
3 lead oxide yellow

(a) what would you expect to see happen in each experiment?


t3l
(b) ln which tube would you expect to see the fastest reaction?
l1l
(c) (i) Write an equation for the reaction that happens between lead
oxide, pbg, and hydrogen.
t1l
(ii) Explain, in terms of oxidation state, why lead is said to be reduced
in the reaction . tzl
(d) The following table shows the mass change in experiment
2.

mass of copper oxide at start I O.lZg


mass of copper at end 0.64 g

Use the results to work out the empirical formula of the copper oxide
used in experiment 2.
(A
) i .- t. vis,W { hl,,"rr? ruLC*0 wsr^.kn
7*n4**f t3l

) - G<o&)sh- f,,.',,.. lrcr( , ,'tn,y,^ti, e i ,-ur^lu,- [Total: 10]

3 t)re11 ,.,(_" / elnl;wh , \ ,-,rfu,

z -* il- rtr
k"0
t'h l
,,n.ldt
Lypo,-,,*,,,.y
)clba; y"J+"*
I

(d)l i 'flr61 -+ l-t* I'L r ,/r"C


tL
-? tq i"t
( it ) 4b i, ,Tl;{, S rzclus rl &5 ,fr s':4ir/3.1t, ,u Sbnl,, &, ,ern-tn"
't Pl" C
J*'n
i, C i,l qb Ltt r r A;:|.*erl /t:) Ct 67,;a$tht:,r .frl< t^t.<-(1')?<, f *,,'n'
r

il ,ol tl>- h 'r I r:t Fl>Q


{al t4rrnln jli- + M*ltr "$ "
n 7 abb {'t\J
(1't , {f
,or{nt--a/,
''
-?l
t^fr'-r(ai'l Funr,^lr, f
o ucLES & MoE
I
.;,f
<--
o'1, sorzl'z/otNtos -l [Turn over
o''-t , ----
o"n':,',-
q-1raLll1,7.) 'lof'r1tn" -v{ y'r, n{ny'{1 ''n;V_,vtt, *
un1)",u",;
+, /tqs i'
{' u n"Jt ' i''r ( 1? 6002 rov\l I ssrcn o
\<
,4 ,rifr',tyorf1zto6 ['T:n
C rq'o!'l)
-.)-trtovt) 1" 1'r'[u7t!)t:lr hOnrt' -4 ftp'4a:ot-hC Jnzlatt
/ py'+[u
Wr+uflvrt t*litl
-ttovt r''stti t?4 :v'a'-y}'lp t*li|
{) v v? -:^ro,vr'Ntry
,qng r,fu4,a--^PlxlFrsv('?u1"toyq7 ( t
)
Zffi
T'.i cil -nf t) .'f,, -Y,,,51 ,
0;'U
.* ) 7 /, (lr
frh1,]0Q )e ur. ,"tt \ h I : .,
7Fx-it 1
x(.' ,ruf,(r., t,r,tnl6
lor :1e1ol
tel epoleJluacuoc ojotu sol.uocoq uollnlos oql uotlM srs{;otlcolo or.ll lo s}cnpord eq1 ojp leLlM
'polejluecuoc
ojolu seruooeq ucllnlos oUt 'oLull oulos Jol 6uruun.l uoaq seq sls^;or1ce;e etlt Jallv (c)
lll asrurol uo6Axo etucS't uoqm srurol ue6orp{q lo ounlo^ lBqM
'uotlDeor eq1 6uunp opoqlec et{}
le po}colloc sl ue6orp{g (tt)
'(d't'.t) elnsseld pLtP olnletaduel u;ool
le eup vz sl se6 {ue lo olor.u ouo }o ounlo^ aql
-
tel 'ue6Axo
;o lo sseu oql er'rncr'c
'opoue oql le slcolloc ueo^xo erucg't 'uollceor aq1 6uung (l) (q)
lo er.ucg't
tt] .Outuoseel
rno{ ule;dx3
euotlceol uotlcnpal e Jo uotleptxo ue uotlcpal stql sl (tt)
lzl 'ua6{xo stulol leqt uol}ceoJ oq} ro} 's;oqurAs olels Ll}rM 'uorlenba-;;eq
e o}rrM (r)
'apoue orll le surol ua6{xg (e)
aprJolr.lc
unrpos snoenbe
olnllp fuan
opoqlec unulleld opoue unurle;d
ue6orpAq
'oplrolqc untpos snoenbe olnl!p fuen esA;o.r1cele ol
lno potJJpc st lueuuedxa uV 6g
uo
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