Examinefs
Use
Section A
* r1l
..') ....r11
[Total: 5]
(a) Put ticks (/) in the boxes to show whether the following statements about the compound
are true or false.
true false
It is a saturated hydrocarbon. l,/"
It could be ammonia, NH.. L/
It is a halogen compound. \r/
It is an ionic compound. V t3l
(b) Draw a similar diagram to show the arrangement of electrons in a molecule of carbon
dioxide, COr.
You only need to show outer shell electrons.
X - eU. cl''a
v - e,ur'l.r;,"_
"l(
a) L'
j
l2l
[Total: 5]
(a) One way of making hydrogen for fuel is by the electrolysis of water.
(i) Write a single equation, with state symbols, to show the products of
the electrolysis
of water.
/! ::-j.,y,.Qr**r....k,..i,r{bt.&..chttl.c*,..{.4*vt:r{....(ttn...k*..y,r.,sd...,
:*il."j?E ...1!K:..(l.y!E*..cQ.(1.t,(v.,.!.kc.vt:.<{....fttn....1k*..1:?g:.4. U.f .
*_1
6
v
For
Examinefs
4 The table shows some information about the homologous series
of a class of organic Use
compounds called acyl chlorides.
HHH
butanoyl chloride caHTcoc/
I I L.,.o
H-C-C __ C-C'a
lll'cr
HH H
(a) (i)
(ii) you can tell that these molecules are from the
(iii)
(b) Ethanoyl chloride reacts with ethanol in the following reaction. Use
[Total: 9]
enthalpy change
name of number of
of combustion in
alkane carbon atoms
kJ / mol
A L,Tt
"-tf8 ct
1:tiTt: ghril
I
l1J
(b) What general trend in the enthalpy changes of combustion is shown by the data rn the
table?
(c) Sor" cars use diesel fuel while some use petrol.
Petrol and diesel are produced from fractions of crude oil.
Diesel boils at a higher temperature than petrol.
(Aril, Luft
lcu,;er i'' P :t
t'WlwL,lf W
WrWr r'r''lL* 'n
+L t'r)vnl 1-'thii'
fue*-Lr
X
r- tu-Xkr
b rr i> ;,6,atJ-i{
+il- la*r o,Jl*4
[Total: 1 1]
(a) What are the essential conditions for making ammonia from nitrogen and hydrogen?
l2l
(b) The ammonia is used to make ammonium phosphate and ammonium nitrate.
(i) Ammonium phosphate contains ammonium ions, NHo*, and phosphate ions,
Poo*'
What is the formula for ammonium phosphate?
( Nrtl t?flv i,l
(ii) Ammonium nitrate has the formula NH.NO..
Calculate the percentage by mass of nitrogen in ammonium nitrate.
,! hfr.,,i(^ =ffi,o_*i
rfi
/ylrii /ia)
i ) ) -35.q,/' '2
(c) Phosphate ions, POot-, are present in the waste water from the factory.
One way of treating the water to remove these phosphate ions is by adding colci;n-l
ions.
The calcium ions react with the phosphate ions to form a precipitate.
Write an equation, with state symbols, to show the reaction between calcium ions ano
phosphate ions.
l- r
+' ['e,-
f;y1e."-.L,ff
'
....!t,::,!:,'t*:...l.,{,.r.'rg...frn:1..+i...,:).,.:t::.o',.|...ri.i:!,.?.
v
12
Section B
The last question is in the form of an either/or and only one of the alternatives should be attempted.
V
crushed waste gas A
magnesite
dilute sulfuric
acid
A dilute magnesium
sulfate solution
process B : heating
concentrated
liquid waste tnagnesiurn
sulfate solutron
\ptocess D magnestum
solid /1
T hydroxide
suspension
magnesium \ ,""ctant c
hydroxide
reaction E
pure waste
magnesium water
oxide vapour
" t. /
(a) (i) Give the name of the main gas in waste gas A. (rr-/t-'"'' r[i*"" r tLf-"-
(ii) Name reactant C. jr rh i/:y\ b1,^l,rr,,,lt'-
tl
(iii) What method should be used to 'separate out the solid magnesium hydroxide in
process D?
f ith't,t r v7
(iv) write an equation for reaction E.
N:1{-r:t,11} . *__) Ni,1 {, .*. H, c,
l4l
.'l 71
('' ;
. Yl^x tt1,.s>
\l fnt,l
fur rtc =i" lij('" 3 "h,,nn _,
! ('l i
4t 7 'f c I I lYft cc3
(() /n +& ,l; .: q,
fr,ld-:
'l-
';/{: t3='t;'
+"e*: U{Ulf: |.lr,il^*
(!
. tb,.'- " f,i,
+
.'
' of
^c
fl(^u'l
w[*;;;
It '
5rt4e
: ffin,#V
----------=- 0 fu+''-lltzen)^trz
,
SLL,^ffin'
7,t"V-V \ .'
'-rto
fty(,'r;*tr",'"f
(t
;l,olrlot-
,;:;,'*,"". -t-'i-':: *'ot- = ttu,1*' +
rtr )cl I (hlo,.o'tL
_J i(,,r,^,..qli)tr,i,r:l
J.{ufia/r l'ilr<{f 1,-\,ri;1t C h1. . ,.[,-
J 5r {.,fi.,L
H-C-C:C.
I ,.H
ll'H
HH
(a) Name the polymer formed when this molecule polymerises and draw the structure of the
repeating unit of the polymer. l2l
(b) A sample of the polymer was analysed and found to have an average relative molecular mass
of 1 0500.
How many carbon atoms are present in an average chain? t3l
(c) Separate samples of the monomer and the polymer are each shaken with bromine w'ater.
What would you expect to see in each case? t1l
(d) The diagram shows a section of another polymer with a similar structure.
fTotal: 8]
(n) r "hi,[r*i, rx )
t l-l
tyt
ltr
+ c*(
litthz
t t4
EITHER
burning hydrogen
hydrogen ------+
metal oxide
The table shows the appearance of each metal oxide when cold.
Use the results to work out the empirical formula of the copper oxide
used in experiment 2.
(A
) i .- t. vis,W { hl,,"rr? ruLC*0 wsr^.kn
7*n4**f t3l
z -* il- rtr
k"0
t'h l
,,n.ldt
Lypo,-,,*,,,.y
)clba; y"J+"*
I