1

NAMA : . TINGKATAN : ..

SMK RAJA PERMAISURI BAINUN

PEPERIKSAAN AWAL TAHUN

TINGKATAN 5
4541/3
KIMIA
Kertas 3
Mac
1 jam Satu jam tiga puluh minit

JANGAN BUKA KERTAS SOALAN INI SEHINGGA DIBERITAHU

Untuk Kegunaan Pemeriksa

1. Tuliskan nama dan tingkatan pada ruang Soalan Markah Markah
yang disediakan. Penuh Diperoleh
2. Kertas soalan ini adalah dalam dwibahasa.
1 21
3. Soalan dalam bahasa Inggeris mendahului
soalan yang sepadan dalam bahasa Melayu.
2 12
4. Calon dibenarkan menjawab keseluruhan
atau sebahagian soalan sama ada dalam
2 17
bahasa Inggeris atau bahasa Melayu.
JUMLAH 50

Disediakan oleh : Disemak oleh :

. .
(PN UMI KALSUM BT AMRI) (PN SITI NORASIKIN BT
Ketua Panitia Kimia MUHYADDIN)
Guru Kimia
Disediakan oleh : Disemak oleh :
. .
Disahkan oleh :
(PN UMI KALSUM BT AMRI) (PN SITI NORASIKIN BT
.
Ketua Panitia Kimia MUHYADDIN)
(PN KASMA MANIS BT
Guru Kimia
ABDULLAH)
Ketua Bidang
Disediakan olehSains
: dan Matematik
Disahkan oleh
oleh :: Disemak oleh :
Disahkan
. .
. .
(PN UMI KALSUM BT (PN AMRI)
KASMA
(PN KASMA MANIS BTNORASIKIN BT MUHYADDIN)
MANIS BT
(PN ABDULLAH)
SITI
Ketua Panitia KimiaKetua Bidang Sains dan Matematik Guru Kimia
ABDULLAH)
Ketua Bidang Sains dan Matematik
 2

___________________________________________________________________________
ARAHAN : JAWAB SEMUA SOALAN.

1. Diagram 1.1 and 1.2 shows the initial and final burette readings for two
experiments. The aim of the experiments is to determine the concentration of
acid .
Rajah 1.1 dan 1.2 menunjukkan bacaan awal dan bacaan akhir buret bagi dua
eksperimen .Tujuan eksperimen ialah untuk menentukan kepekatan asid.

Experiment I
Eksperimen I

Titration of sulphuric acid of unknown concentration with 20 cm 3 of sodium

hydroxide solution 1.0 mol dm-3 using phenolftalein as indicator.
Pentitratan asid sulfurik yang tidak diketahui kepekatannya dengan 20 cm 3
larutan natrium hidroksida 1.0 mol dm-3 menggunakan penunjuk fenolftalein.

15 25

16 26

Diagram 1.1
Rajah 1.1

Initial burette reading: ........................................... cm3

Bacaan awal buret:

Final burette reading: ............................................ cm3

Bacaan akhir buret:

Volume of acid used: ........................................... cm3

Isipadu asid yang digunakan:

Experiment II
Eksperimen II

Titration of hydrochloric acid of same concentration as in Experiment I with

20 cm3 of sodium hydroxide solution 1.0 mol dm-3 using phenolftalein as
indicator.
Pentitratan asid hidroklorik yang kepekatan yang sama dalam Eksperimen I
dengan 20 cm3 larutan natrium hidroksida 1.0 mol dm-3 menggunakan penunjuk
 3

fenolftalein.

X1 Y1

X2 Y2

Diagram 1.2
Rajah 1.2

Initial burette reading:

Bacaan awal buret: . .......................................... cm3

Final burette reading:

Bacaan akhir buret: ............................................ cm3

Volume of acid used:

Isipadu asid yang digunakan: ........................................... cm3

(a) Write the initial, final burette reading and the volume of acid used for both
experiments in the spaces provided.
Tulis bacaan awal,akhir dan isipadu asid yang digunakan untuk kedua-dua
eksperimen dalam ruang yang disediakan.
[3 marks]

(b) Construct a table that consists of the initial, final burette reading and the volume
of acid for both experiments.
Bina satu jadual yang mengandungi bacaan awal, bacaan akhir buret dan
isipadu asid dalam kedua-dua eksperimen.
 4

[3 marks]
(c) The equation shows the reaction between sulphuric acid and sodium hydroxide
solution.
Persamaan menunjukkan tindak balas antara asid sulfurik dengan larutan
natrium hidroksida.

H2SO4 + 2 NaOH Na2SO4 + 2 H2O

Determine the concentration of sulphuric acid used in Experiment 1.

Tentukan kepekatan asid sulfurik yang digunakan dalam eksperimen I.

[3 marks]

(d)(i) Based on the volume and concentration of sulphuric acid in Experiment I, predict
the volume of hydrochloric acid used to neutralise 20 cm3 1.0 mol dm-3 sodium
hydroxide solution in Experiment II.
Berdasarkan isipadu dan kepekatan asid sulfurik dalam Eksperimen I, ramalkan
isipadu asid hidroklorik yang diperlukan untuk meneutralkan 20 cm3 1.0 mol dm-3
larutan natrium hidroksida.

[3 marks]

Explain the answer in 1(e)(i)

(ii) Terangkan jawapan dalam 1(e)(i)

....................................................................................................................................

....................................................................................................................................
[3 marks]
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(e) The addition of acid to the sodium hydroxide solution in the experiment is
stopped when the end point of titration is achieved. Give the operational
definition for the end point of titration.
Penambahan asid kepada larutan natrium hidroksida dalam eksperimen
dihentikan apabila takat akhir pentitratan telah tercapai. Beri definisi secara
operasi bagi takat akhir pentitratan.

....................................................................................................................................

....................................................................................................................................

....................................................................................................................................

[3 marks]

(f)
Hydrochloric acid, HCl Sulphuric acid, H2SO4
Asid hidroklorik, HCl Asid sulfurik, H2SO4

Phosphoric acid , H3PO4 Carbonic acid, H2CO3

Asid fosforik, H3PO4 Asid karbonik, H2CO3

Nitric acid, HNO3 Methanoic acid, HCOOH

Asid nitrik, HNO3 Asid metanoik, HCOOH

Classify the acids given into strong acid and weak acid.
Kelaskan asid-asid yang diberi kepada asid kuat dan asid lemah.
Strong acid Weak acid
Asid kuat Asid lemah

[3 marks]
 6

2 Diagram 1 shows the apparatus set-up for three sets of an experiment to compare the
reactivity of halogens towards hot iron wool.
Rajah 1 menunjukkan tiga set susunan radas bagi suatu eksperimen untuk
membandingkan kereaktifan halogen terhadap wul besi panas.

Set-up of apparatus Observation

Susunan radas Pemerhatian
Set I
Set I Soda lime Iron wool glows brightly
Iron wool
Wul besi Kapur soda
Wul besi membara dengan
Bromine gas
terang
Gas bromin

Heat
Panaskan

Set II
Set II
Soda lime .......................................................
Iron wool
Wul besi Kapur soda
.......................................................
Chlorine gas
Gas klorin

Heat
Panaskan

Set III
Set III Iron wool Soda lime
Wul besi Kapur soda
Iodine gas
Gas iodin

Heat
Panaskan

Diagram 1
Rajah 1

(a) State the observations in the space provided in Diagram 1.

Nyatakan pemerhatian dalam ruang disediakan dalam Rajah 1.
 7

[3 marks]
[3 markah]
(b) Based on the observations in three sets of the experiment, state an inference.
Berdasarkan pemerhatian dalam ketiga-tiga set eksperimen itu, nyatakan satu inferens.

[3 marks]
[3 markah]
(c) For this experiment, state :
Bagi eksperimen ini, nyatakan:
(i) the manipulated variable.
pemboleh ubah yang dimanipulasikan.
.............
(ii) the responding variable.
pemboleh ubah yang bergerak balas.
....
(iii) the fixed variable.
pemboleh ubah yang dimalarkan.
....
[3 marks]
[3 markah]
(d) State the hypothesis for the experiment.
Nyatakan hipotesis bagi eksperimen ini.

........

........

[3 marks]
[3 markah]
 8

Sodium thiosulphate solution react with sulphuric acid to produce sodium

sulphate,sulphur, sulphur dioxide and water according to the chemical equation
below.

Larutan natrium tiosulfat bertindak balas dengan asid sulfurik untuk menghasilkan
natrium sulfat, sulfur, sulfur dioksida dan air mengikut persamaan kimia di bawah.

Na2S2O3 + H2SO4 Na2SO4 + S + SO2 + H2O

Plan a laboratory experiment to investigate the effect of temperature on the rate of

reaction by using the chemical reaction.
Rancang satu eksperimen makmal untuk mengkaji kesan suhu ke atas kadar tindak
balas dengan menggunakan tindak balas kimia tersebut.

Your planning should include the following aspects :

Perancangan anda hendaklah mengandungi aspek-aspek berikut:

(a) Statement of the problem

Pernyataan masalah

(b) All the variables

Semua pembolehubah

(c) Statement of the hypothesis

Pernyataan hipotesis

(d) List of substances and apparatus

Senarai bahan dan radas

(e) Procedure of the experiment

Prosedur eksperimen

(f) Tabulation of data

Penjadualan data

[ 17 marks ]
 9

END OF QUESTION PAPER

KERTAS SOALAN TAMAT
SKEMA PEMARKAHAN KERTAS 3

Question Answers Score

number

1(a) Able to write all the readings are correct with two decimal place accurately 3

Experiment I Experiment II

Initial burette 15.45 X1.45

reading(cm3)

Final burette 25.45 Y1.45

reading(cm3)

Volume of acid(cm3) 10.00 Y1.45- X1.45

Able to write only four readings with two decimal places correctly// all the 2
readings are correct with one decimal place
(Hanya empat bacaan dengan dua tempat perpuluhan adalah betul //semua
bacaan betul dengan satu tempat perpuluhan)

Only two readings with two decimal places are correct/ all the readings are 1
correct with no decimal places.
(Hanya dua bacaan dengan dua tempat perpuluhan adalah betul / semua
bacaan betul tanpa tempat perpuluhan)

No response or wrong response (Tiada respons atau respons salah) 0

Question Answers Score

number

Able to constuct a table that contains the following information:

1(b) 3
(Dapat membina jadual yang mengandungi maklumat berikut):
1. Heading in the table: Experiment, Initial reading, final reading and volume of acid.
2. Transfer all readings from (a)(i) correctly.
(Pemindahan semua bacaan daripada (a)(i) dengan betul).
3. With unit(at heading)
(Berunit(pada tajuk)).
Sample answer:

Experiment Initial reading/ Final reading/ Volume of acid/

cm3 cm3 cm3

I 15.45 25.45 10.00

II X1.45 Y1.45 Y1.45- X1.45

Able to constuct a table that contains the following information:

2
(Dapat membina jadual yang mengandungi maklumat berikut):
 10

1. Heading in the table: Experiment, Initial reading,final/reading and volume of acid.

(Tajuk dalam jadual: Eksperimen, bacaan awal,bacaan akhir dan isipadu asid )
2. Transfer all readings from (a)(i) correctly.
(Pemindahan semua bacaan suhu daripada (a)(i) dengan betul).
3. Without unit.
(tanpa unit).

sample answer:

Experiment Initial reading Final reading Volume of acid

I
15.45 25.45 10.00
II
X1.45 Y1.45 Y1.45- X1.45

Note: jika pemindahan suhu cacat satu//ada satu bacaan tak betul: kekal skor 2

Able to construct a table that contains the following information:

1
(Dapat membina jadual yang mengandungi maklumat berikut):
1. suitable headings.
(tajuk sesuai)
2. 2 columns
(2 lajur)
No response or wrong response (Tiada respons atau respons salah) 0

Question Answers Score

number

Able to show the step to calculate the concentration of sulphuric acid accurately
1(c) 3
Sample answer:
From the equation, MAVA = 1
MBVB 2

MA = MBVB = 1.0 x 20 = 1 mol dm-3 //

VA 10 x2
1. Mol NaOH = 1 x2/1000 = 0.002

2. Nisbah NaOH : H2SO4

2 : 1
3. M H2SO4 = 0.001 x 1000 //1 mol dm-3

Able to state the step to calculate the concentration of sulphuric acid correctly.
2
Sample answer:
MA = MBVB = 1.0 x 20 = 2.0 mol dm-3
 11

VA 10
Able to give an idea on the concentration of sulphuric acid.
1
Sample answer:
[ 1- 2] mol dm-3 // no calculation is shown
No response or wrong response (Tiada respons atau respons salah) 0

Question Answers Score

number

1(d) (i) Able to predict the volume of hydrochloric acid used to neutralise 20cm 3 1.0 3
mol dm-3 sodium hydroxide .
Double the volume of acid compared to experiment I// 20cm3
Dua kali ganda isipadu asid berbanding eksperimen I//20 cm3
Able to predict a change on the volume of asid less accuartely
2
Menyatakan satu isipadu dalam julat 11 hg 19 cm3
Able to give an idea of predicting a volume of asid
1
The volume of acid changed
Isipadu asid berubah //lebih dari 10 cm3

No response or wrong response (Tiada respons atau respons salah) 0

Question Answers Score

number

1(d) (ii) Able to state the reason in (e)(i) 3

Sample answer:
1. Hydrochloric acid is monoprotic acid while sulphuric acid is diprotic acid.
2.At the same volume and concentration of both acids, hydrochloric acid
contains half the number of mole of H+ as in sulphuric acid.//
1 mole of sulphuric acid ionises to two mole of H+, whereas 1 mole of
hydrochloric acid ionises to one mole of H+.

Able to state any one point from the answer in score 3. 2

Able to state an idea of the reason.
1
Sample answer:
Hydrochloric acid/suphuric acid is strong acid
No response or wrong response (Tiada respons atau respons salah) 0
 12

Question Answers Score

number

Able to state the meaning of the end point correctly

1(e) 3
What to observe: pink solution change to colourless
What to do: acid added to react exactly with alkali
Sample answer:
A point at which pink colour of in the solution turns colourless when acid is
added to react exactly with alkali.
Able to state the meaning of end point less accurately
2
Sample answer:
1. The point at which pink colour of in the solution turns colourless when
acid is added to alkali.
//Pink colour of the solution turns colourless// acid is added to alkali.
Able to give an idea for meaning of end point
1
Sample answer:
The colour of the solution changes (Warna larutan berubah)

No response or wrong response (Tiada respons atau respons salah) 0

Question Answers Score

number

1(f) Strong acid Weak acid 3

Asid kuat Asid lemah
Hydrochloric acid, HCl Phosphoric acid , H3PO4
Sulphuric acid, H2SO4 Carbonic acid, H2CO3
Nitric acid, HNO3 Methanoic acid, HCOOH
 13

Question Rubric Score

Able to state all observations correctly

Sample answer:

Experiment Observation
3
2(a) II Iron wool glows brighter/(burns brightly)
III Iron wool glows dimly

Able to state any one observation correctly

2
Able to state any relavant observation
1
Sample answer:
Iron wool glows

Question Rubric Score

Able to state inference correctly

Sample answer: 3
Reaction between iron wool with chlorine is most reactive followed by
2(b) bromine and iodine
Able to state inference
2
Sample answer:

Chlorine is most reactive follow by bromine and iodine

Have an idea to state inference
1
Sample answer:

Reaction occurred.
Question Rubric Score
Able to state All variables correctly

Sample answer :
Manipulated variable : Chlorine, bromine and iodine//types of
halogens 3
2(c) Responding variable : Reactivity of halogen towards hot iron /
brightness
of glow
Constant variable : Iron wool
Able to state any two variables correctly 2
Able to state any one variable correctly 1

Question Rubric Score

 14

Able to give a hypothesis correctly

Sample answers :
Going down Group 17, the reactivity of halogen with iron wool 3
decreases //
2(d) Going down Group 17, the brightness of glow decreases.
Able to give a hypothesis

Sample answers :
The reactivity of halogen with iron wool decreases when going down 2
Group 17//
Chlorine is the most reactive halogen when reacts with iron wool.
Able to state an idea of the hypothesis
1
Sample answer :
Different halogen, different reactivity.
.
Experiment 1: Na2S2O3 + H2SO4 Na2SO4 + S + SO2 + H2O

Question No. Rubric Score

3 (i) Able to give the statement of the problem accurately.
Response is in question form.

Sample answer:

Does the temperature of sodium thiosulphate solution affect

the rate of reaction? //
3
How does the temperature of sodium thiosulphate solution
affect the rate of reaction? //

How does the high / low temperature of sodium thiosulphate

solution affect the rate of reaction?

Able to give the statement of the problem less accurately.

Response in question form.

Sample answer:

Does the increase / decrease in temperature 2

increase/decrease the rate of reaction? //

How does the increase/decrease in temperature affect the

rate of reaction?

Able to give an idea of statement of the problem. 1

Sample answer:

Does temperature affect the rate of reaction?

The increase/decrease in temperature will increase

/decrease the rate of reaction. //
 15

The higher / lower in temperature will increase /decrease the

rate of reaction. //

To investigate the effect of temperature to the rate of

reaction.

Question No. Rubric Score

3(ii) Able to state the three variables correctly

Sample answer:

Manipulated variable:
Temperature of sodium thiosulphate solution
3
Rate of reaction // Time taken for mark X to become
invisible /disappear

Constant variable:
Volume and concentration of sodium thiosulphate/ sulphuric
acid / size of conical flask

Able to state any two variables correctly 2

Able to state any one variables correctly 1

Question No. Rubric Score

3 (iii) Able to state the relationship correctly between the
manipulated variable and the responding variable with
direction.

Sample answer:
The higher/lower the temperature of sodium thiosulphate
solution, the higher/lower the rate of reaction. //

The higher/lower the temperature of sodium thiosulphate

solution, the shorter/longer the time taken for mark X to
3
disappear from sight/view //

The increase/decrease in temperature of sodium

thiosulphate solution will increase/decrease the rate of
reaction. //

When the temperature of sodium thiosulphate solution

increase /decrease, the rate of reaction will
increase/decrease.

Able to state the relationship between the manipulated 2

variable and the responding variable with direction.
 16

Sample answer:
The higher/lower the temperature, the higher/lower the rate
of reaction. //

The higher/lower the temperature, the shorter/longer the

time taken for mark X to disappear //

The increases/decreases in temperature will increase

/decrease the rate of reaction. //

Able to state the idea of hypothesis.

Sample answer;
1
Different temperature, different reactivity. //
Temperature changes, the time taken is different.

Question No. Rubric Score

5 (iv) Able to give complete list of materials and apparatus

Sample answer:

Materials:
Sodium thiosulphate solution, sulphuric acid.
3
Apparatus:
Conical flask, ,bunsen burner, measuring cylinder (10 ml),
measuring cylinder (50 ml), stop-watch, filter /white
/cardboard paper.

Able to give complete list of materials and four apparatus as

following.

Answer:

Materials:
2
Sodium thiosulphate solution, sulphuric acid.

Apparatus :
Conical flask, thermometer, bunsen burner, filter / white
/cardboard paper.

Able to give at least one substances and at least one

apparatus. 1

Question No. Rubric Score

 17

5 (v) Able to list all the steps correctly

Sample Answer:

1. X mark is drawn on a piece of white/filter/ cardboard

paper.
2. 50 cm3 of sodium thiosuphate solution [(0.01-1.0)
mol dm-3] is measured with a (50 cm3 ) measuring
cylinder and is poured into a conical flask.
3. The solution is slowly heated until 30 oC.
4. 5 cm3 of hydrochloric acid [(0.1- 2.0) mol dm-3] is
measured with a (10 cm3) measuring cylinder and is 3
added to the conical flask. A stop-watch is started
immediately.
5. The conical flask is swirled and is placed on a
white/filter/cardboard paper with a mark X.
6. The X mark is observed vertically from the top
through the solution.
7. The stop-watch is stopped immediately when the X
mark cannot be seen. Time is recorded.
8. The experiment is repeated by using the sodium
thiosuphate solution at 40 oC, 50 oC, 60 oC and 70 oC
respectively.
Able to list down steps 2, 4, 5, 7, 8 2
Able to give an idea to step 4. 1

Question No. Rubric Score

5 (vi) Able to tabulate the data with following aspects
1. Correct titles with units
2. Complete list of temperatures

Sample answer:
Temperature(oC) Time (s)
30 2
40
50
60
70

Able to contruct a table.

1. At least 1 titles correct without units

2. Incomplete list of tempereatures

Sample answer:
1

Temperature

30
18