Experiment 6 Data

Temperature: 30 C
Time, t (s) Conductivity, (mS/cm)

15 16.12
315 1.51
615 0.9
915 0.68
1215 0.57
1515 0.51
1815 0.46
2115 0.43
2415 0.41
2715 0.39
3015 0.37
3315 0.36
3615 0.35
Temperature: 30 C
15 16.12
315 1.51
615 0.9
915 0.68
1215 0.57
1515 0.51
1815 0.46
2115 0.43
2415 0.41
2715 0.39
3015 0.37
3315 0.36
3615 0.35
0.6410235732
39.997
1000
Temperature: 40 C
15 9.81
315 0.84
615 0.53
915 0.43
1215 0.37
1515 0.34
1815 0.32
2115 0.3
2415 0.29
2715 0.28
3015 0.27
3315 0.27
3615 0.26
emperature: 30 C Temperature: 40 C
Concentration 10E5, CA (mol/L) Conductivity, (mS/cm)
((((B19*0.6411023573)/1000))/39.997)*10 9.81
2.4203 0.84
1.4426 0.53
1.0900 0.43
0.9136 0.37
0.8175 0.34
0.7373 0.32
0.6892 0.3
0.6572 0.29
0.6251 0.28
0.5931 0.27
0.5770 0.265
0.5610 0.26
Temperature: 50 C
15 5.85
315 0.51
615 0.35
915 0.3
1215 0.27
1515 0.25
1815 0.24
2115 0.23
2415 0.23
2715 0.22
3015 0.22
3315 0.22
3615 0.21
Temperature: 40 C Temperature: 50 C
Concentration 10E5, CA (mol/L) Conductivity, (mS/cm)
15.7242 5.85
1.3464 0.51
0.8495 0.35
0.6892 0.3
0.5931 0.27
0.5450 0.25
0.5129 0.24
0.4809 0.23
0.4648 0.225
0.4488 0.22
0.4328 0.2133
0.4248 0.2167
0.4167 0.21
Temperature: 50 C
Concentration 10E5, CA (mol/L)
9.3768
0.8175
0.5610
0.4809
0.4328
0.4007
0.3847
0.3687
0.3606
0.3526
0.3419
0.3473
0.3366
Temperature: 30 C
15 16.12
315 1.51
615 0.9
915 0.68
1215 0.57
1515 0.51
1815 0.46
2115 0.43
2415 0.41
2715 0.39
3015 0.37
3315 0.36
3615 0.35
Time (s) Conductivity, (mS/cm)

15 16.12
315 1.51
615 0.9
915 0.68
1215 0.57
1515 0.51
1815 0.46
2115 0.43
2415 0.41
2715 0.39
3015 0.37
3315 0.36
3615 0.35

15 9.81
315 0.84
615 0.53
915 0.43
1215 0.37
1515 0.34
1815 0.32
2115 0.3
2415 0.29
2715 0.28
3015 0.27
3315 0.27
3615 0.26

15 5.85
315 0.51
615 0.35
915 0.3
1215 0.27
1515 0.25
1815 0.24
2115 0.23
2415 0.23
2715 0.22
3015 0.22
3315 0.22
3615 0.21
Concentration 10E5, Ca (mol/L) Conductivity, (mS/cm)
25.8384 9.81
2.4203 0.84
1.4426 0.53
1.0900 0.43
0.9136 0.37
0.8175 0.34
0.7373 0.32
0.6892 0.3
0.6572 0.29
0.6251 0.28
0.5931 0.27
0.5770 0.27
0.5610 0.26
Results for 30C
Concentration of NaOH 10E5, Ca(mol/L) Conversion, X (%)
25.8384 0.9871
2.4203 0.9988
1.4426 0.9993
1.0900 0.9995
0.9136 0.9995
0.8175 0.9996
0.7373 0.9996
0.6892 0.9997
0.6572 0.9997
0.6251 0.9997
0.5931 0.9997
0.5770 0.9997
0.5610 0.9997
Results for 40C
15.7242 0.9921
1.3464 0.9993
0.8495 0.9996
0.6892 0.9997
0.5931 0.9997
0.5450 0.9997
0.5129 0.9997
0.4809 0.9998
0.4648 0.9998
0.4488 0.9998
0.4328 0.9998
0.4248 0.9998
0.4167 0.9998
Results for 50C
9.3768 0.9953
0.8175 0.9996
0.5610 0.9997
0.4809 0.9998
0.4328 0.9998
0.4007 0.9998
0.3847 0.9998
0.3687 0.9998
0.3606 0.9998
0.3526 0.9998
0.3473 0.9998
0.3419 0.9998
0.3366 0.9998
2.0000
1.8000 f(x) = 0.000388314x + 0.5262789196
1.6000 R = 0.9320834491
1.4000
1.2000
1.0000
1/Ca
0.8000
0.6000
0.4000
0.2000
0.0000
0 500 1000 1500 2000 2500 3000 3500 4000
Time (s)
Concentration 10E5, Ca (mol/L) Conductivity, (mS/cm)
15.7242146289 5.85
1.3464159315 0.51
0.8495243377 0.35
0.6892367269 0.3
0.5930641603 0.27
0.544977877 0.25
0.5129203549 0.24
0.4808628327 0.23
0.4648340716 0.23
0.4488053105 0.22
0.4327765494 0.22
0.4327765494 0.22
0.4167477883 0.21
0C
(-dCa/dt) ln (-dCa/dt)
131.6107758 4.8798
0.0780601 -2.5503
0.0032592 -5.7263
0.0011754 -6.7461
0.0005877 -7.4393
0.0003206 -8.0454
0.0002671 -8.2277
0.0001603 -8.7385
0.0001069 -9.1440
0.0001069 -9.1440
0.0001069 -9.1440
0.0000534 -9.8372
0.0000534 -9.8372
0C
132.2851 4.8850
0.0479260 -3.0381
0.0016563 -6.4032
0.0005343 -7.5346
0.0003206 -8.0454
0.0001603 -8.7385
0.0001069 -9.1440
0.0001069 -9.1440
0.0000534 -9.8372
0.0000534 -9.8372
0.0000534 -9.8372
0.0000267 -10.5303
0.0000267 -10.5303
0C
132.7082 4.8882
0.0285312 -3.5568
0.0008549 -7.0646
0.0002671 -8.2277
0.0001603 -8.7385
0.0001069 -9.1440
0.0000534 -9.8372
0.0000534 -9.8372
0.0000267 -10.5303
0.0000267 -10.5303
0.0000176 -10.9458
0.0000182 -10.9160
0.0000176 -10.9458
3.0000
2.5000 f(x) = 0.0004501938x + 0.9791131598

R = 0.8909075192
2.0000
1.5000
1/Ca
1.0000
0.5000
0.0000
0 3500 4000 0 500 1000 1500 2000 2500 3000
Time (s)
Temperature: 50 C
Concentration 10E5, Ca (mol/L)
9.3768252374
0.8174668156
0.5610066381
0.4808628327
0.4327765494 2000
0.4007190272 0.9998
0.3846902661 f(x) = 1.96342982577
0.9996 R = 0.6282280357
0.3686615051
0.3686615051 0.9994
0.352632744
0.9992
0.352632744
0.352632744 0.9990
Conversion, X (%)
0.3366039829
0.9988
ln (Ca) 1/Ca 0.9986

3.2519 0.0387 0.9984
0.8839 0.4132
0.9982
0.3664 0.6932
0 500 1000 1500
Tim
0.0861 0.9175
-0.0903 1.0945
-0.2015 1.2233
-0.3047 1.3563
-0.3722 1.4509
-0.4198 1.5217
-0.4698 1.5997
0.9999
-0.5225 1.6862
0.9998 f(x) = 9.8124787
-0.5499 1.7330 R = 0.63095308
-0.5780 1.7825 0.9997
0.9996
ln (Ca) 1/Ca
0.9995
2.7552 0.0636
0.2974 0.7427 Conversion, 0.9994
X (%)
-0.1631 1.1771 0.9993
-0.3722 1.4509 0.9992
-0.5225 1.6862
0.9991
-0.6070 1.8349
-0.6676 1.9496 0.9990
-0.7322 2.0796 0 500 1000 150
T
-0.7661 2.1513
-0.8012 2.2281
-0.8375 2.3107
-0.8562 2.3543
-0.8753 2.3995
0.9999
ln (Ca) 1/Ca 0.9999 f(x) = 1.5267675160
2.2382 0.1066 R = 0.6330542522
0.9998
-0.2015 1.2233
0.9998
-0.5780 1.7825
-0.7322 2.0796 0.9997
-0.8375 2.3107 Conversion, X (%)
0.9997
-0.9145 2.4955
0.9996
-0.9553 2.5995
-0.9979 2.7125 0.9996
-1.0199 2.7728 0.9995
-1.0423 2.8358 0.9995
-1.0574 2.8790 0 2 4 Ti
-1.0733 2.9249
-1.0888 2.9709
00
00 f(x) = 0.0004501938x + 0.9791131598

R = 0.8909075192
00
00
00
00
00
0 500 1000 1500 2000 2500 3000 3500 4000
Time (s)
f(x) = 1.96342982577491E-007x + 0.9991506877
R = 0.6282280357
500 1000 1500

Time2000
(s) 2500 3000 3500 4000
8 f(x) = 9.81247874393694E-008x + 0.9995069795

R = 0.630953086
7
5
)
4
0
0 500 1000 1500
Time2000
(s) 2500 3000 3500 4000
f(x) = 1.52676751609207E-005x + 0.9996847058
R = 0.6330542522
%)
0 2 4 6 (s) 8 10 12 14
Time
3.5000
3.0000 f(x) = 0.0004507106x + 1.5799304426

R = 0.8349333624
2.5000
2.0000
1/Ca 1.5000
1.0000
0.5000
0.0000
0 500 1000 1500 2000 2500 3000 3500 4000
Time (s)
00 4000
Results for 30C
15 16.12
315 1.51
615 0.9
915 0.68
1215 0.57
1515 0.51
1815 0.46
2115 0.43
2415 0.41
2715 0.39
3015 0.37
3315 0.36
3615 0.35
Results for 40C
15 9.81
315 0.84
615 0.53
915 0.43
1215 0.37
1515 0.34
1815 0.32
2115 0.3
2415 0.29
2715 0.28
3015 0.27
3315 0.27
3615 0.26
Results for 50C
15 5.85
315 0.51
615 0.35
915 0.3
1215 0.27
1515 0.25
1815 0.24
2115 0.23
2415 0.23
2715 0.22
3015 0.22
3315 0.22
3615 0.21
2
1.8 f(x) = 0.000388314x + 0.5262789196
1.6 R = 0.9320834491
1.4
1.2
1
Conversion, X (%)
0.8
0.6
0.4
0.2
0
0 500 1000 1500 2000 2500 3000 3500 4000
Time (s)
25.8383628764 0.9870808186
2.4203429245 0.9063275434
1.4425884981 0.4039735099
1.0899557541 0.2444444444
0.9136393821 0.1617647059
0.8174668156 0.1052631579
0.7373230101 0.0980392157
0.6892367269 0.0652173913
0.6571792047 0.0465116279
0.6251216825 0.0487804878
0.5930641603 0.0512820513
0.5770353992 0.027027027
0.5610066381 0.0277777778

15.7242146289 0.9921378927
1.3464159315 0.9143730887
0.8495243377 0.369047619
0.6892367269 0.1886792453
0.5930641603 0.1395348837
0.544977877 0.0810810811
0.5129203549 0.0588235294
0.4808628327 0.0625
0.4648340716 0.0333333333
0.4488053105 0.0344827586
0.4327765494 0.0357142857
0.4247621689 0.0185185185
0.4167477883 0.0188679245

9.3768252374 0.9953115874
0.8174668156 0.9128205128
0.5610066381 0.3137254902
0.4808628327 0.1428571429
0.4327765494 0.1
0.4007190272 0.0740740741
0.3846902661 0.04
0.3686615051 0.0416666667
0.3606471245 0.0217391304
0.352632744 0.0222222222
0.3473432528 0.015
0.341893474 0.0156898939
0.3366039829 0.0154711674
0388314x + 0.5262789196
0834491
0 1500 2000 2500 3000 3500 4000
Time (s)
(-dCa/dt) ln (-dCa/dt) ln (Ca) 1/Ca
131.610775808 4.8798488986 3.2518603207 0.0387021424
0.0780600665 -2.5502766652 0.8839092345 0.4131645933
0.0032591814 -5.7262792128 0.366439068 0.6931983732
0.0011754425 -6.7461106236 0.0861371028 0.9174684351
0.0005877212 -7.4392578042 -0.0903193345 1.0945237471
0.0003205752 -8.0453936078 -0.2015449696 1.2232912468 Concentration of Na
0.000267146 -8.2277151646 -0.3047292058 1.3562576866
0.0001602876 -8.7385407883 -0.3721704866 1.4508803159
0.0001068584 -9.1440058964 -0.4197985356 1.5216549655
0.0001068584 -9.1440058964 -0.4698089562 1.5996885535
0.0001068584 -9.1440058964 -0.5224526897 1.686158205
5.342920E-005 -9.837153077 -0.5498516639 1.7329959329
5.342920E-005 -9.837153077 -0.5780225408 1.7825101024

132.285052358 4.8849590818 2.7552018572 0.063596181
0.0479259957 -3.0380972149 0.2974461965 0.7427125427
0.0016563053 -6.4031658725 -0.1630786888 1.1771293129
0.000534292 -7.534567984 -0.3721704866 1.4508803159
0.0003205752 -8.0453936078 -0.5224526897 1.686158205
0.0001602876 -8.7385407883 -0.6070100777 1.8349368701
Concentration of Na
0.0001068584 -9.1440058964 -0.6676346995 1.9496204245
0.0001068584 -9.1440058964 -0.7321732207 2.0795951195
5.342920E-005 -9.837153077 -0.7660747723 2.151305296
5.342920E-005 -9.837153077 -0.8011660922 2.228137628
5.342920E-005 -9.837153077 -0.8375337363 2.3106612439
2.671460E-005 -10.5303002576 -0.8562258693 2.3542586258
2.671460E-005 -10.5303002576 -0.8752740643 2.3995328302

132.708211651 4.8881528207 2.2382412449 0.1066459036
0.0285311947 -3.556757238 -0.2015449696 1.2232912468
0.0008548673 -7.0645643548 -0.5780225408 1.7825101024
0.000267146 -8.2277151646 -0.7321732207 2.0795951195
0.0001602876 -8.7385407883 -0.8375337363 2.3106612439
0.0001068584 -9.1440058964 -0.9144947775 2.4955141434 Concentration of NaO
5.342920E-005 -9.837153077 -0.955316772 2.5994938994
5.342920E-005 -9.837153077 -0.9978763864 2.7125153732
2.671460E-005 -10.5303002576 -1.0198552931 2.7727934927
2.671460E-005 -10.5303002576 -1.042328149 2.8358115266
1.763164E-005 -10.9458157015 -1.0574417868 2.8789964737
1.816593E-005 -10.9159627384 -1.0732560699 2.9248876505
1.763164E-005 -10.9458157015 -1.0888481646 2.9708501707
Concentration of N
3
2.5
6 2
f(x) =43.8819985862x - 7.2224029439
1.5
Concentration of NaOH 10E5, Ca(mol/L)
R = 0.9880542739
2
1
0
-1 -0.5 00.5 0.5 1 1.5 2 2.5 3 3.5
-2
ln (-dCa/dt) 0
-4
0 1000 2000 3000 4000
-6
Time (s)
-8
-10
1.6
-12
1.4 ln (Ca)
1.2
1
0.8 6
f(x) =0.6
4.2695418246x - 6.1557072012
4
R = 0.9745606302
0.4 2
0.2
0
-1.5 -1 -0.50 0 0.5 1 1.5 2 2.5 3
-2
ln (-dCa/dt) 0 1000 2000 3000 4000
-4
Time (s)
-6
-8
-10
0.9
-12
0.8
0.7 ln (Ca)
0.6
0.5
Concentration of NaOH 10E5, Ca(mol/L) 0.4 6
f(x) =0.3
4.8061467264x - 5.0526918244
4
R = 0.2
0.9579630077
2
0.1
0 0
-1.5 -1 -0.5
0 0 0.5 1 1.5 2 2.5
-2 1000 2000 3000 4000
ln (-dCa/dt)
-4 Time (s)
-6
-8
-10
0 0
-1.5 -1 -0.5
0 0 0.5 1 1.5 2 2.5
-2 1000 2000 3000 4000
ln (-dCa/dt)
-4 Time (s)
-6
-8
3
-10
2.5 -12
2 ln (Ca)
1.5
1
0.5
0
0 1000 2000 3000 4000
Time (s)
3 3.5
2.5 3
2 2.5
2 2.5
k T T(K)
0.0005 30 303.15
0.1351 40 313.15
0.0005 50 323.15
1/T ln(k)
0.003299 -7.600902
0.003193 -2.00174 0
0.003095 -7.600902 0.00305 0.0031 0.00315
-1
-2
-3
ln(k) -4
-5
-6 f(x) = - 583
-7
-8
0
0.00305 0.0031 0.00315 0.0032 0.00325 0.0033 0.00335
-1
-2
-3
-4
-5
-6 f(x) = - 583.6648354787x - 3.8693959147

-7
-8
1/T
Temperature (C) Reaction order () Rate constant (k)
30 3.882 7.3005 E-04
40 4.2695 2.1214 E-04
50 4.8061 6.3921 E-03
Parameters
Activation energy (J/mol) 4852.8236
Arrhenius constant 0.0209

Experiment 6 Data

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Experiment 6 Data

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Temperature: 30 C

Time, t (s) Conductivity, (mS/cm)

Time (s) Conductivity, (mS/cm)

Time (s) Conductivity, (mS/cm)

Time (s) Conductivity, (mS/cm)

2.5000 f(x) = 0.0004501938x + 0.9791131598

ln (Ca) 1/Ca 0.9986

00 f(x) = 0.0004501938x + 0.9791131598

500 1000 1500

8 f(x) = 9.81247874393694E-008x + 0.9995069795

3.0000 f(x) = 0.0004507106x + 1.5799304426

Concentration of NaOH 10E5, Ca(mol/L) Conversion, X (%)

Concentration of NaOH 10E5, Ca(mol/L) Conversion, X (%)

0 1500 2000 2500 3000 3500 4000

(-dCa/dt) ln (-dCa/dt) ln (Ca) 1/Ca

(-dCa/dt) ln (-dCa/dt) ln (Ca) 1/Ca

-6 f(x) = - 583.6648354787x - 3.8693959147

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