Update: 2016/2/19
The most common fuel that is used for power generation currently is a
chemical compound that contains carbon, hydrogen, and oxygen only,
and is called the hydrocarbon fuel.
Fuel is burned with sufficient amount of air such that all the carbon in the
fuel oxides to carbon dioxide, and all the hydrogen in the fuel oxides to
water. Besides, neither fuel nor oxygen remains.
Composition of air:
N2: 78.08%
O2: 20.95%
Argon: 0.93%
CO2: 0.03%
Others: 0.01%
Water vapor: variable
Average molecular weight: 28.97 kg/kmole
It is noted that the average molecular weight of the simplified air is 28.84
kg/kmole. However, the actual value of 28.97 kg/kmole is still used in
the calculation of combustion for accuracy.
The combustion formulas of several fuels with air for industry usage are
as following.
Methane:
CH4 + 2(O2 + 3.76N2) CO2 + 2H2O + 7.52N2
CombustionEngineeringMEDeptNCHU 1
Propane:
C3H8 + 5(O2 + 3.76N2) 3CO2 + 4H2O + 18.8N2
Benzene:
C6H6 + 7.5(O2 + 3.76N2) 6CO2 + 3H2O + 28.2N2
Coal:
C + O2 + 3.76N2 CO2 + 3.76N2
Hydrogen:
H2 + 0.5(O2 + 3.76N2) H2O + 1.88N2
In general, we have
If oxygen is contained in the fuel, the amount of air required to oxide the
fuel is reduced due to the presence of oxygen in the air fuel mixture.
Methanol:
CH3OH + 1.5(O2 + 3.76N2) CO2 + 2H2O + 5.64N2
Ethanol:
C2H5OH + 3(O2 + 3.76N2) 2CO2 + 3H2O + 11.28N2
In general, we have
m y m m y
Cn H m O y ( n )(O2 3.76 N 2 ) CO2 H 2O 3.76( n ) N 2
4 2 2 4 2
CombustionEngineeringMEDeptNCHU 2
In general, gasoline and diesel fuels are represented as CH1.85
Stoichiometric combustion:
The air fuel ratio for complete combustion is called stoichiometric air fuel
ratio.
Lean combustion:
If the amount of air is more than that required for complete combustion,
there will be excess air after combustion. This is call lean combustion.
In a lean combustion, the air fuel ratio is greater than the stoichiometric
air fuel ratio.
Rich combustion
If the amount of air is less than that required for complete combustion,
part of the fuel would not be fully oxidized such that either there will be
excess fuel left after combustion or there will be incomplete combustion
products, such as carbon monoxide or unburned hydrocarbon.
In a rich combustion, the air fuel ratio is less than the stoichiometric air
fuel ratio.
CombustionEngineeringMEDeptNCHU 3
A/F < (A/F)st
A/ F
1 lean combustion
1 stoichiometric combustion
1 rich combustion
Fuel air ratiothe reciprocal of air fuel ratio, usually used by Diesel
engine and gas turbine engine people.
100%
% of theoretical air =
% of excess air =
1 100%
CombustionEngineeringMEDeptNCHU 4
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ExampleMethane is burned with dry air. The molar analysis of the
products on a dry basis is CO2 9.7%CO 0.5%O2 2.95%and N2
86.85%Determine the air fuel ratio, the equivalence ratio, the
percentage of theoretical air, and the percentage of excess air.
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ExampleE50 is a bio fuel which is blended 50% (in volume) of ethanol
with 50% of gasoline. Suppose that the density of gasoline is 750 kg/m3,
and that of ethanol is 800 kg/m3, and gasoline can be expressed as CH1.85,
calculate the stoichiometric air fuel ratio o E50.
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Assignment 2.1
M85 is a bio fuel that was promoted about twenty years ago. It contains
85% (in volume) of methanol and 15% of gasoline. The density of
methanol is 790 g/L, and that of gasoline is 750 g/L. Suppose gasoline
can be expressed as CH1.85, calculate the stoichiometric air fuel ratio of
M85.
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Assignment 2.2
Coal is burned with dry air with the feeding rate of 10 tons/hr. The
molar analysis of the products of combustion on a dry basis is CO2 10%.
Determine the flow rate of air.
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Assignment 2.3
Hydrogen is burned with dry air with the feeding rate of 10 m3/min.
The molar analysis of the products of combustion on a dry basis is O2
10%. Determine the flow rate of air.
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CombustionEngineeringMEDeptNCHU 5
Lambda sensors produces a voltage signal that recognises the amount of
unburned oxygen in the exhaust. An oxygen sensor is essentially a
battery that generates its own voltage. When hot (at least 250.), the
zirconium dioxide element in the sensor's tip produces a voltage that
varies according to the amount of oxygen in the exhaust compared to
the ambient oxygen level in the outside air. The greater the difference,
the higher the sensor's output voltage.
Sensor output ranges from 0.2 Volts (lean) to 0.8 Volts (rich). A
stoichiometric fuel mixture gives an average reading of around 0.45
Volts.
CombustionEngineeringMEDeptNCHU 6
(2.2). Energy balance in a reacting system
In an open system,
m f ma m p
Q m f h f m a ha m p h p W
e.g.: gas turbine engine, steam boiler.
m f ma mp
CombustionEngineeringMEDeptNCHU 7
(2.2.2). Enthalpy of formation
C + O2 CO2
Since the process does not produce any output work, the energy equation
of an open system gives the relationship between the enthalpy of products
and that of reactants.
Q m r hr m p hp
Q h h h
C O2 CO2
T
h h h h c p dT
o
f
o
f
T0
Q h f ,C h f ,O2 h f ,CO2
393520 h f ,C h f ,O2 h f ,CO2
h of ,C 0
h of ,O2 0
CombustionEngineeringMEDeptNCHU 8
Elements: O, H, S, H, Cu, C
Compound: CO2, H2O, CuO, SO2, CH4
CombustionEngineeringMEDeptNCHU 9
Thermochemical Properties of selected substances at 298 K and 1 atm
CombustionEngineeringMEDeptNCHU 10
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ExampleStoichiometric mixture of carbon monoxide and oxygen are at
298 K and 100 kPa. Find the heat release of the reaction if the products
are (1). at 298 K, (2). at 1000K.
1
CO O2 CO2
2
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ExampleMethane at 25is mixed with air at 600K in the combustor of
a gas turbine engine. The gas temperature at the inlet of turbine should
be confined to 1200K. Determine the air fuel ratio. (69.53)
25Methane
1200K products
600K air
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ExampleA mixture of liquid methanol and air is fed to the inlet of an
adiabatic fuel reformer to produce hydrogen. The inlet mixture is at 25,
and the outlet gas is at 600K. Determine the air fuel ratio.
(partial oxidation reforming process)
CH3OH + x(O2 + 3.76N2) CO2 + 2H2 + (x-0.5)O2 + 3.76xN2
(Ans: x=3.017, A/F = 13.0)
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ExampleIn an electrolysis reaction, water is decomposed into hydrogen
and oxygen. Calculate the required power if 100 L/min of hydrogen is
produced. (19.23 kW)
CombustionEngineeringMEDeptNCHU 11
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Assignment 2.4
Hydrogen is produced in a steam reformer in which methanol is reacted
with steam as the following equation.
CH3OH + H2O CO2 + 3H2
Determine the heat transfer required to produce one mole of hydrogen if
both the reactants and the products are kept at 25.
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Assignment 2.5
Hydrogen is produced in a partial oxidation reformer in which methanol
is reacted with air as the following equation.
CH3OH +0.5 (O2+3.76N2) CO2 +2H2 +1.88N2
Determine the heat transfer required to produce one mole of hydrogen if
both the reactants and the products are kept at 25.
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Assignment 2.6
Hydrogen is produced in an autothermal reformer in which methanol is
reacted with air and steam to form carbon dioxide and hydrogen as the
following equation.
CH3OH +x(O2+3.76N2) +yH2O Products( CO2 , H2 , N2)
This reaction may occur in an adiabatic way in which neither heat input
nor heat output is required. Determine the yield rate of hydrogen if 1
L/min of methanol is fed into the reformer.
(1). Assume that both the reactants and the products are kept at 25.
(2). The products are at 300K while the reactants are at 25.
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Assignment 2.7
Hydrogen is produced with the electrolysis of liquid water. Determine the
electric current required to produce hydrogen with the rate of 1 L/min at
100 kPa and 25 if the applied voltage is 110 volts. The efficiency of
electrolysis is assumed to be 75%.
H2O 0.5O2 + H2
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CombustionEngineeringMEDeptNCHU 12
(2.2.3). Heating value
Continuous flows of air and fuel are feeding into an adiabatic burner
and the hot exhaust gas is cooled by water coiled around the exhaust pipe.
The flow rate and the temperature difference of water are measured to
calculate the thermal energy released by the combustion products.
fuel
air exhaust
Q HR HP
CombustionEngineeringMEDeptNCHU 13
m y m m y
Cn H m O y ( n )(O2 3.76 N 2 ) CO2 H 2O 3.76( n ) N 2
4 2 2 4 2
m y m y
H R hF ( n )hO2 ( n )3.76hN 2
4 2 4 2
m m y
H P hCO2 hH 2O (n )3.76hN 2
2 4 2
hF h f , F
hO2 hN 2 0
hCO2 h f ,CO2
hH 2O h f , H 2O
m
Q H P H R h f ,CO2 h f , H 2O h f , F
2
Lower heating value (LHV): the heating value of a fuel in which that the
water vapor in the product remains in the form of vapor at 25.
h f , H 2O = -241818 kJ/kmole
Higher heating value (HHV): the heating value of a fuel in which that the
water vapor in the product is condensed to liquid water at 25.
h f , H 2O = -285830 kJ/kmole
HHV is greater than LHV. The difference between LHV and HHV is the
latent heat of water at 25.
The enthalpy of formation of any fuel can be obtained if the heating value
is already known.
m
h f , F h f ,CO2 h f , H 2O Q
2
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ExampleDetermine the lower heating value and the higher heating
value of ethylene.
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ExampleDetermine the lower heating value and the higher heating
value of hydrogen.
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ExampleIf the higher heating value of gasoline is 42000 kJ/kg, and the
H/C ratio is 1.85, determine the equivalent enthalpy of formation of
CombustionEngineeringMEDeptNCHU 14
gasoline.
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ExampleDmethyl ether (DME, CH 3OCH 3 ) is considered to be an
alternative fuel to replace fossil diesel. The lower heating value of DME
is 28900 kJ/kg. Determine the enthalpy of formation of DME.
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Assignment 2.8
DME is produced by catalytic dehydration of methanol with the
following reaction.
2CH 3OH CH 3OCH 3 H 2O
Is this an endothermic reaction or exothermic reaction? Find the heat that
should be added or removed from the reaction if both the reactants and
products are at 25 and 100 kPa.
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Assignment 2.9
Another way to produce is to synthesize DME directly from hydrogen
and carbon monoxide with the following reaction.
3CO 3H 2 CH 3OCH 3 CO2
Is this an endothermic reaction or exothermic reaction? Find the heat that
should be added or removed from the reaction if both the reactants and
products are at 25 and 100 kPa.
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Assignment 2.10
The averaged molecular weight of a jet fuel is 126 kg/kmole. The
hydrogen to carbon ratio is 1.85:1. If the lower heating value of the fuel
is 10280 kcal/kg, calculate the equivalent enthalpy of formation of the jet
fuel.
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Assignment 2.11
A turbojet engine runs on the fuel mentioned above. The temperature
and the pressure of the inlet air are 0 and 90 kPa. Jet fuel is injected
into the combustion chamber at 25. The pressure ratio of the
compressor is 10. The efficiency of compressor is 0.85. Find the air fuel
ratio of the mixture if the temperature at the outlet of combustor is
confined to 1200K. Assume that air is an ideal gas.
CombustionEngineeringMEDeptNCHU 15
CH1.85 X (O2 3.76 N 2 ) CO2 0.925 H 2O ( X 1.4625)O2 3.76 XN 2
h f ,CH1.85 ( X hO2 3.76hN 2 )T2
h f ,CO2 hCO2 0.925( h f , H 2O hH 2O ) ( X 1.4625) hO2 3.76 X hN 2
T3
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HHV= 0.3491C+1.1783H+0.1005S0.1034O0.0151N0.0211A
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ExampleThe lower heating value of DME is 28900 kJ/kg. Determine
the LHV of DME with the Channiwala & Parikh correlation.
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CombustionEngineeringMEDeptNCHU 16
(2.2.4). Energy content of air fuel mixture
m l m m l
Cn H mOl (n )(O2 3.76 N 2 ) nCO2 H 2O 3.76(n ) N 2
4 2 2 4 2
m l
(n ) 4.76 28.97
( A / F ) st 4 2
12n m 16l
The amount of heat that can be released expressed in terms of much fuel
contained inside cylinder and the heating value of fuel Q f .
ma
QH m f Q f Qf
A/ F
If the fuel is of liquid form like gasoline of methanol, the volume is filled
with air only because liquid fuel would occupy negligible fraction of
volume only.
PV
ma m D
RaTm
P V Qf
QH m D
RaTm A / F
CombustionEngineeringMEDeptNCHU 17
m l
PmVD Q f ( n )4.76
QH 4 2
RaTm A / F 1 ( n m l )4.76
4 2
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Example Fuel is burned with stoichiometric air in an internal
combustion engine. The engine displacement volume is 1 L. The
temperature of mixture is 300K and the pressure is 100 kPa. Find the
energy that can be released in the combustion process.
(1). Hydrogen. (2). Methane. (3). Liquid gasoline. (4). Liquid methanol.
PV nRuT
PV
n = 4.00910-5 kmole
RuT
H 2 0.5(O2 3.76 N 2 ) H 2O 1.88 N 2
Heating value of hydrogen is 241942 kJ/kmole
n -5
nH 2 nxH 2 = 1.18610 kmole
1 0.5 4.76
E nH 2 QH 2 =1.18610-5 kmole241942 kJ/kmole= 2.87 kJ
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CombustionEngineeringMEDeptNCHU 18
(2.3). Fuels
(2.3.1). Wood
Type C H O HHV(kJ/kg)
Cedar() 48.8 6.37 44.46 19540
Cypress() 54.98 6.54 38.08 22960
Fir() 52.3 6.3 40.5 21050
Hemlock() 50.4 5.8 41.4 20050
Pine() 59.0 7.19 32.68 26330
Redwood() 53.5 5.9 40.3 21030
Ash() 49.73 6.93 43.04 20750
Beech() 51.64 6.26 41.45 20380
Birch() 49.77 6.49 43.45 20120
Elm() 50.35 6.57 42.34 20490
Hickory() 49.67 6.49 43.11 20170
Maple() 50.64 6.02 41.74 19960
Oak() 48.78 6.09 44.98 19030
Poplar() 51.64 6.26 41.45 20750
SourceE.L. Keating, "Applied Combustion", Marcel Dekker, 1992.
Reference:
K. W. Ragland, D. J. Aerts, & A. J. Baker, Properties of Wood for
Combustion Analysis, Bioresource Technology 37 (1991) 161-168
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Example Determine the equivalent enthalpy of formation of cedar.
CombustionEngineeringMEDeptNCHU 19
C 48.8%, 48.8/12= 4.067
H 6.37%, 6.37/1 = 6.37
O 44.46%, 44.46/16=2.779
4.067+ 6.37/4-2.779/2 =4.27
48.8+6.37+44.46=99.63
4.067(-390509) +3.185(-285830)-hf=(-19540)99.63
hf= -3941.5 kJ/kg
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Example Dry cedar log is burned in a fireplace. Determine the amount
of excess air if the burned temperature is 700 K.
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Q=20000(1-x)-2400x=(20000-22400x) kJ/kg
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Assignment 2.12
Cedar log is burned in a fireplace, determine the amount of excess air if
the burned temperature is 700 K and the moisture content is 30%.
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CombustionEngineeringMEDeptNCHU 20
Table 1 Proximate and ultimate analysis of CJ
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Example Determine the LHV of CJ-Raw with the Channiwala & Parikh
correlation.
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(2.3.2). Coal
CombustionEngineeringMEDeptNCHU 21
matter of coal is determined by heating the coal sample to 900C for 7
minutes in a cylindrical silica crucible in a muffle furnace.
Ash content of coal is the non-combustible residue left after coal is burnt.
It represents the bulk mineral matter after carbon, oxygen, sulfur and
water (including from clays) has been driven off during combustion.
The fixed carbon content of the coal is the carbon found in the material
which is left after volatile materials are driven off. This differs from the
ultimate carbon content of the coal because some carbon is lost in
hydrocarbons with the volatiles. Fixed carbon is used as an estimate of
the amount of coke that will be yielded from a sample of coal.
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Example An Illinois coal that has the following ultimate analysis:
81.3% C; 5.3% H; 9.8% O; 1.7% N; 1.9% S. Find the stoiciometric air
fuel ratio of the Illinois coal.
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Heating value
CombustionEngineeringMEDeptNCHU 22
where C is the mass percent of carbon, H is the mass percent of hydrogen,
O is the mass percent of oxygen, and S is the mass percent of sulfur in the
coal. With these constants, Q is given in kilojoules per kilogram.
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Example An Illinois coal that has the following ultimate analysis:
81.3% C; 5.3% H; 9.8% O; 1.7% N; 1.9% S. Find the heating value of
the Illinois coal.
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(2.3.3)Hydrocarbon fuels
Alkane()
An alkane is a saturated hydrocarbon. Alkanes consist only of hydrogen
and carbon atoms, all bonds are single bonds, and the carbon atoms are
not joined in cyclic structures but instead form an open chain. They have
the general chemical formula CnH2n+2.
The members of the series (in terms of number of carbon atoms) are
named as follows:
Alkane Formula Boiling Melting Density [gcm3]
point [C] point [C] (at 20 C)
Methane CH4 -162 -182 gas
Ethane C2H6 -89 -183 gas
Propane C3H8 -42 -188 gas
CombustionEngineeringMEDeptNCHU 23
Butane C4H10 0 -138 gas
Pentane C5H12 36 -130 0.626 (liquid)
Hexane C6H14 69 -95 0.659 (liquid)
Heptane C7H16 98 -91 0.684 (liquid)
Octane C8H18 126 -57 0.703 (liquid)
Nonane C9H20 151 -54 0.718 (liquid)
Decane C10H22 174 -30 0.730 (liquid)
Undecane C11H24 196 -26 0.740 (liquid)
Dodecane C12H26 216 -10 0.749 (liquid)
Hexadecane C16H34 287 18 0.773
Icosane C20H42 343 37 solid
Triacontane C30H62 450 66 solid
Tetracontane C40H82 525 82 solid
Pentacontane C50H102 575 91 solid
Hexacontane C60H122 625 100 solid
Alkene()
An alkene is an unsaturated hydrocarbon containing at least one carbon
carbon double bond. They have the general chemical formula CnH2n.
CombustionEngineeringMEDeptNCHU 24
Fuel Property Comparison for Ethanol, Gasoline and No. 2 Diesel
CombustionEngineeringMEDeptNCHU 25
typically low-energy wood (producer) gas (~5.6 MJ/m), the gases can be
mixed with air or pure oxygen for complete combustion and the heat
produced transferred to a boiler for energy distribution.
CombustionEngineeringMEDeptNCHU 26
(2.3.6). Comparisons of the heating value of fuels
CombustionEngineeringMEDeptNCHU 27
(2.4). Adiabatic flame temperature
Q 0 W 0
m F hF m a ha m p hp H R H p
T
hF h 0
f ,F hF h 0
f ,F c pF dT
T0
T
hO2 h 0
f ,O2 hO2 c pO2 dT
T0
T
hN 2 h 0
f , N2 hN 2 c pN 2 dT
T0
CombustionEngineeringMEDeptNCHU 28
C2 H 2 2.5(O2 3.76 N 2 ) 2CO2 H 2O 9.4 N 2
(3). Carbon monoxide flame
CO 0.5(O2 3.76 N 2 ) CO2 1.88 N 2
(4). Coke oven gas: CO 7.0%H2 58.0%CO2 2.5%CH4 25.0%O2
0.5%, and N2 7.0%.
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CombustionEngineeringMEDeptNCHU 29
(2.4.2). Constant volume adiabatic flame temperature
mF u F maua m pu p U R U p
T
u h RT h c p dT RT
0
f
T0
nb RTb
Pb
V
Pb nb Tb
P0 n0 T0
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Example Hydrogen is mixed with air at an equivalence ratio of 1.0 in a
constant volume chamber at 25and 100 kPa. Determine the adiabatic
flame temperature and the final pressure.
H 2 0.5(O2 3.76 N 2 ) H 2O 1.88 N 2
u H 2 0.5uO2 1.88u N 2 u H 2O 1.88u N 2
hH 2 0.5hO2 3.76hN 2 3.38 RT1 h f , H 2O hH 2O 1.88hN 2 2.88 RTb
Pb 2.88 Tb
100 3.38 298
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Assignment 2.15
An internal combustion engine runs on the fuel of propane with an
equivalence ratio of 0.9. The temperature and the pressure at the
end of compression stroke are 500 and 2.6 MPa. If a constant
volume combustion process occurs in the cylinder, find the
temperature and the pressure after combustion.
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CombustionEngineeringMEDeptNCHU 30
(2.5). STANJAN
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Example Methane is burned with stoichiometric air at 25and 100 kPa
in a constant pressure process.
CH 4 2(O2 3.76 N 2 ) CO2 2 H 2O 7.52 N 2
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Example Methane is burned with 25% excess air at 25and 100 kPa in
a constant volume process.
CH 4 2.5(O2 3.76 N 2 ) CO2 2 H 2O 0.5O2 9.4 N 2
-----------------------------------------------------------------------------------------
Example Methane is burned in a gas turbine engine with an
equivalence ratio of 0.4. The pressure ratio of the engine is 10.0. Find
the specific work of the engine and the thermal efficiency.
wc h2 h1 = kJ/kg, wt h3 h4 = kJ/kg,
wnet wt wc = kJ/kg, work output per kg of mixture.
A / F = 43.09
mf 1
=0.0227, mass of fuel per kg of mixture.
m 1 A/ F
Q f = 50009 kJ/kg, heating value of methane.
qH m f Q f = 1135.2 kJ/kg, heat of combustion per kg of mixture.
wnet
= , thermal efficiency.
qH
P
2 = 10, pressure ratio.
P1
1
Brayton 1 k 1 = 0.6019, theoretical efficiency of Brayton cycle.
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CombustionEngineeringMEDeptNCHU 31
Example Methane is burned with stoichiometric air at 25and 100 kPa
in an Otto engine. The compression ratio of the engine is 10.0.
wc u2 u1 , we u3 u4 , wnet we wc
w V
W wnet V Tq 2 , Tq net , engine torque
2
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Assignment 2.16
A jet engine runs on the fuel of propane with an equivalence ratio of
0.3. The pressure ratio is 9.0. The compressor efficiency is 85%,
and the turbine efficiency is 90%. Find the thrust of the engine.
CombustionEngineeringMEDeptNCHU 32
h3 h4
h4 s h3
t
3 4s , isentropic expansion, h and s are specified
Since STANJAN does not have the function of specified h and s, iteration
process is required to find the final pressure.
4 5 , isentropic expansion, P is specified and s the same as last run
V2
h4 h5
2
engine thrust: F mV
m 2( h4 h5 )
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Assignment 2.17
An internal combustion engine runs on the fuel of propane with an
equivalence ratio of 0.9. The compression process is assumed to be
isentropic and the compression ratio is 9.0. The temperature and
the pressure before the compression stroke are 40 and 90 kPa. If
a constant volume combustion process occurs in the cylinder, find
the IMEP of the engine.
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CombustionEngineeringMEDeptNCHU 33
(2.6). Applications of combustion calculation
Water has been distilled out with a filter ahead of the inlet of
analyzer to avoid the problem of clogging and corrosion.
[CO ] [CO2 ] [ HC ]
[CO ]
a
[CO ] [CO2 ] [ HC ]
CombustionEngineeringMEDeptNCHU 34
[CO2 ]
b
[CO ] [CO2 ] [ HC ]
[ HC ]
c
[CO ] [CO2 ] [ HC ]
[O2 ]
x
[CO ] [CO2 ] [ HC ]
2 n
z (1 ) ( a 2b 2 x )
4
1 1 2 n
y ( n cn) z ( n cn) (1 ) (a 2b 2 x)
2 2 4
3.76 n
w (1 )
4
1 2 n 3.76 n
a b c x (n cn) (1 ) (a 2b 2 x) (1 )
2 4 4
n n 1.76 n
2a 3b c(1 ) 3 x (1 )
2 2 4
n
1 2[CO ] 3[CO2 ] (1 )[ HC ] 3[O2 ] n 1.76 n
2 (1 )
[CO ] [CO2 ] [ HC ] 2 4
n n
1.76 n 1 2(1 )[CO ] (3 )[CO2 ] [ HC ] 3[O2 ]
(1 ) 2 2
4 [CO ] [CO2 ] [ HC ]
1 1 1 n n
1 3 O2 (2 ) CO (3 ) CO2 HC
1.76(1 n ) CO CO2 HC 2 2
4
( A / F ) st
A/ F
( A / F ) st
A/ F
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Example Find the air fuel ratio of the following measured data.
CombustionEngineeringMEDeptNCHU 35
CO(%) HC(ppm) CO2(%) O2
1.02 1408 13.02 2.27
0.61 1232 12.44 2.99
1.40 1028 12.4 2.42
1.06 978 11.5 2.00
The oxygen concentration in normal air is about 21%. The oxygen rich
combustion is to increase the concentration of oxygen artificially to
enhance combustion. The flame temperature could be raised due to the
less content of dilute gas.
1 n n 1 n X n
CH n (1 )(O2 XN 2 ) CO2 H 2O ( 1)(1 )O2 (1 ) N 2
4 2 4 4
1
y : the molar fraction of oxygen
1 X
1
X 1
y
The amount of oxygen required for oxygen rich combustion:
CombustionEngineeringMEDeptNCHU 36
CH 4 2(O2 XN 2 ) CO2 2 H 2O 2 XN 2
For one mole of methane, if oxygen rich air is used as the oxidizer, the
amount of pure oxygen that has to be mixed with normal air is
y
n 2 z 7.52 2
1 y
For example, 40% oxygen rich air is used, 3.013 kmole of pure oxygen is
required for 1 kmole of methane.
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Example Find the products of methane mixed with oxygen rich air and
the associated adiabatic flame temperature.
(1). y 30%
(2). y 40%
(3). y 80%
-----------------------------------------------------------------------------------------
1 n n 1 n X n
CH n (1 )(O2 XN 2 ) CO2 H 2O ( 1)(1 )O2 (1 ) N 2
4 2 4 4
n
h f , F QHV h f ,CO2 h f , H 2O
2
n
h f , F h f ,CO2 h f , H 2O QHV
2
n n 1 n X n
h f , F h f ,CO2 hCO2 h f , H 2O hH 2O ( 1)(1 ) hO2 (1 ) hN 2
2 2 4 4
n 1 n X n
QHV hCO2 hH 2O ( 1)(1 ) hO2 (1 ) hN 2
2 4 4
If the products are cooled to the room temperature, then the heat of
combustion would be the same no matter how much excess air is.
n
QHV hCO2 hH 2O
2
CombustionEngineeringMEDeptNCHU 37
Heat of load: QL mc
p (Tb TL )
Heat of waste: Qe mc
p (TL Ta )
QL
Required flow rate: m
c p (Tb TL )
TL Ta
Qe QL
Tb TL
Since both TL and QL are fixed values, the higher the value of Tb is, the
lower the waste heat would be. The advantage of rich oxygen
combustion is that the burned gas temperature could be higher than that
of normal air.
-----------------------------------------------------------------------------------------
Example In a steam boiler, coal is fired with 150% excess air. The flue
gas temperature is 200. Find the saving of fuel if 50% oxygen rich air
is used instead of normal air.
-----------------------------------------------------------------------------------------
Assignment 2.19
In a foundry, molten iron is kept warm with stoichiometric propane flame.
Find the saving of fuel if 40% oxygen rich air is used instead of normal
air. The melting point of iron is 1536.
-----------------------------------------------------------------------------------------
Assignment 2.20
An internal combustion engine runs on the fuel of propane with an
equivalence ratio of 0.9. The compression process is assumed to be
isentropic and the compression ratio is 9.0. The temperature and
the pressure before the compression stroke are 40 and 90 kPa. If
40% oxygen rich air is used instead of normal air, find the IMEP of the
engine.
CombustionEngineeringMEDeptNCHU 38
In vehicle racing, nitrous oxide (often referred to as just "nitrous") allows
the engine to burn more fuel by providing more oxygen than air alone,
resulting in a more powerful combustion.
1
N 2O N 2 O2
2
The gas itself is not flammable at a low pressure/temperature, but it
delivers more oxygen than atmospheric air by breaking down at elevated
temperatures. Therefore, it is often mixed with another fuel that is easier
to deflagrate.
CombustionEngineeringMEDeptNCHU 39
structure of the engine is not properly reinforced, the engine may be
severely damaged or destroyed during this kind of operation.
1.85 1.85
CH1.85 (1 )(O2 2 N 2 ) CO2 H 2O 2.925 N 2
4 2
CombustionEngineeringMEDeptNCHU 40
Cost of oxygen production
CombustionEngineeringMEDeptNCHU 41
(2.7). Chemical Equilibrium
( dS )isolated 0
In a closed system, the system exchanges energy with its environment via
heat transfer and work. If an amount of heat Q is transferred from
system to its environment, the entropy change associated with the transfer
of heat is
Q
dS , or TdS Q
T
Q dU PdV
Combing the inequality of entropy and the first law results the following
equation.
CombustionEngineeringMEDeptNCHU 42
would reach the maximum value at the equilibrium state for a system in
which H and P are kept constant.
dA PdV SdT 0
The inequality implies that ( dA)T ,V 0 , which means that the Helmholtz
function would reach the minimum value at the equilibrium state for a
system in which T and V are kept constant.
dG VdP SdT 0
-----------------------------------------------------------------------------------------
Example: Calculate the Gibbs function of saturated water and that of
saturated vapor at 100.
g f h f Ts s f = 419.04-373.141.3069 = -68.617
g g hg Ts sg = 2676.1-373.147.3549 = -68.307
The error is caused by the uncertainty of the measured data.
g g g f ( hg Ts sg ) (h f Ts s f ) h fg Ts s fg 0
Note: When two phases are in equilibrium, their Gibbs functions are the
same.
-----------------------------------------------------------------------------------------
CombustionEngineeringMEDeptNCHU 43
(2.7.2). Properties of Gibbs Function
For a system in which T and P are kept constant, any spontaneous process
would cause a decrease of the Gibbs function, and the Gibbs function
would reach the minimum value at the equilibrium state. As a result, the
criterion for the equilibrium state of a system in which T and P are kept
constant is that ( dG )T , P 0 .
dG VdP SdT
G G (T , P )
G G
dG dT dP
T P P T
G G
S V
T P P T
G
Since S 0 , we may conclude that 0 . That is, G
T P
decreases when T is raised at constant pressure.
G
Since V 0 , we may conclude that 0 . That is, G
P T
increases when P is raised at constant temperature.
CombustionEngineeringMEDeptNCHU 44
Temperature dependence of Gibbs function
G H G GH
S
T T P T
G G H
T P T T
G 1 G G 1 H
T T T T T T T
P P
Gibbs-Helmholtz Equation
G H
T T T 2
P
G g
V , v
P T P T
RT
For ideal gas, v
P
g RT
P T P
P
RT P
g
P0
P
dP RT ln
P0
P
g g 0 RT ln
P0
g g 0 v( P P0 )
CombustionEngineeringMEDeptNCHU 45
-----------------------------------------------------------------------------------------
Example: Steam is compressed from a state of 200 and 1.5 bars to
another state of 10 bars adiabatically, calculate the change of the Gibbs
function.
G G (T , P, n1 , n2 , , nr )
G G G
dG
T P ,n
dT
P T ,n
dP n dni
i T , P ,n j
G
Define i chemical potential of component i
i T , P ,n j
n
dG SdT VdP i dni
i
k the effect of the mole number of component j
k T , P ,n j i T , P ,n j
n n
on the Gibbs function of the component i.
CombustionEngineeringMEDeptNCHU 46
Why does the mole number of component j affect the Gibbs function of
the component i ?
For a system in which T and P are kept constant, the variations of Gibbs
function in terms of the variations in the mole fractions of each
component is
dG i dni , dg i dxi
Eulers Theorem
f f ( z1 , z2 , , zr )
f is homogeneous of degree m if
f ( z1 , z2 , , zr ) m f ( z1 , z2 , , zr )
f
then mf ( z1 , z2 , , zr ) zi
zi z j
H H (T , P, n1 , n2 , , nr )
H TS i ni
G H TS i ni
When ni 1 , G g
CombustionEngineeringMEDeptNCHU 47
Gibbs function of formation
The Gibbs function of each component at the reference state will not
be the same.
g h Ts
C O2 CO2
g C hC TsC
g O2 hO2 TsO2
CombustionEngineeringMEDeptNCHU 48
Gibbs function of formation is the change of Gibbs function when a
compound is formed from its elements.
It is noted that the Gibbs function of formation does not equal to the
enthalpy of formation minus the product of temperature and entropy.
g f ,C h f ,C T0 sC
-----------------------------------------------------------------------------------------
Example: Calculate the Gibbs function of formation H2O at 298K and 1
bar.
g H 2O g H 2 0.5 g O2 ( hH 2O TsH 2O ) ( hH 2 TsH 2 ) 0.5( hO2 TsO2 )
CombustionEngineeringMEDeptNCHU 49
g 0f g 0f ,0 ( h h0 ) (Ts T0 s0 )
-----------------------------------------------------------------------------------------
Example: Calculate the Gibbs function of formation H2O at 1000K and
1 bar.
-----------------------------------------------------------------------------------------
Assignment 2.22
Calculate the Gibbs function of formation of the following component
and find out its value in Table A.1 ~ A.12 in the text book.
(1). H2O at 1000K and 1 bar.
(2). H2 at 1000K and 1 bar.
-----------------------------------------------------------------------------------------
Example: Methane is burned with stiochiometric amount of air.
Assume the reaction is complete, and the products are at 1000 K and 1
bar. Calculate the Gibbs function of the products.
CombustionEngineeringMEDeptNCHU 50
PN 2
g N 2 g N0 2 RT ln = 0 + 8.3141000 ln(0.715) = -2789
P0
1
g i xi ( g CO2 2 g H 2O 7.52 g N 2 ) -80741 kJ/kmole
10.52
-----------------------------------------------------------------------------------------
Assignment 2.23
Methane is burned with stiochiometric amount of air, and the products are
at 1000 K and 1 bar. Assume the reaction is not complete, as shown
below.
CH4 + 2(O2 + 3.76 N2 ) (1-X)CO2 + XCOX/2 O2 + 2 H2O + 7.52 N2
Calculate the Gibbs function of the products for different values of X, and
plot the results of calculations in terms of X values.
X=0.05, 0.01, 0.001, 0.0001, 0
-----------------------------------------------------------------------------------------
CombustionEngineeringMEDeptNCHU 51
(2.8). Equilibrium constant
A A B B CC D D
AdA B dB C dC D dD 0
dA A d dB B d dC C d dD D d
A Ad B B d C C d D D d 0
A A B B C C D D 0
g A A g B B g C C g D D 0
P
g A g 0A (T ) RuT ln A
P0
P P
g A0 RuT ln A A g B0 RuT ln B B
P0 P0
P P
g C0 RuT ln C C g D0 RuT ln D D 0
P0 P0
CombustionEngineeringMEDeptNCHU 52
C D
PC PD
C gC D g D A g A B g B RuT ln 0 A 0 B
0 0 0 0 P P
PA PB
P0 P0
G -3
K p1 exp 1.30310
RuT
-----------------------------------------------------------------------------------------
Example: Calculate the equilibrium constant of the reaction at
temperature of 2000 K and pressure of 10 bars.
1
H 2 O2 H 2O
2
CombustionEngineeringMEDeptNCHU 53
1 0
G2 g H0 2O g O2 g H0 2 -135643 (0) = -135643 kJ/kmole
2
G
K p2 exp 3489.47
u
R T
-----------------------------------------------------------------------------------------
Example: Calculate the equilibrium constant of the reaction at
temperature of 2000 K and pressure of 10 bars.
H 2 CO2 H 2O CO
1 1
G g H0 2O g CO
0
g CO
0
g H0 2 ( g O0 2 g CO
0
g CO
0
) ( g H0 2O g O0 2 g H0 2 )
2
2 2
2
G G1 G1
G1 G2 G1 G2
G
K p exp e
RuT
e RuT
e RuT
K p1 K p 2
RuT
K p 4.547
-----------------------------------------------------------------------------------------
Assignment 2.24
Calculate the equilibrium constant of the reaction at temperature of 2000
K and pressure of 10 bars.
N 2 O2 2 NO
-----------------------------------------------------------------------------------------
-----------------------------------------------------------------------------------------
Example: Calculate the equilibrium constant of the reaction at
temperature of 2000 K and pressure of 10 bars.
H 2 CO2 H 2O CO
-----------------------------------------------------------------------------------------
CombustionEngineeringMEDeptNCHU 54
If a reaction is expressed as N multiple of another reaction, the
equilibrium constant of this equation is the Nth order of that of the other
equation.
-----------------------------------------------------------------------------------------
Example: Calculate the equilibrium constant of the reaction at
temperature of 2000 K and pressure of 10 bars.
2CO2 2CO +O2
-----------------------------------------------------------------------------------------
CombustionEngineeringMEDeptNCHU 55
Equilibrium constants of come commonly used reactions
T B
log K p A ln( ) C DT ET 2
1000 T
1
1: H2 H
2
1
2: O2 O
2
1 1
3: H 2 O2 OH
2 2
1 1
4: N 2 O2 NO
2 2
1
5: H 2 O2 H 2O
2
1
6: CO O2 CO2
2
A B C D E
1 0.432168e+00 -0.112464e+05 0.267269e+01 -0.745744e-04 0.242484e-08
-----------------------------------------------------------------------------------------
Example: Calculate the equilibrium constant of the reaction at
temperature of 2000 K and pressure of 10 bars.
H 2 CO2 H 2O CO
-----------------------------------------------------------------------------------------
Assignment 2.25
Calculate the equilibrium constant of the following reaction at
temperature in the range of 1000~3000K.
H 2 CO2 H 2O CO
-----------------------------------------------------------------------------------------
CombustionEngineeringMEDeptNCHU 56
(2.9). Equilibrium calculations
PV nRuT
ni P P P P
[Ci ] i i xi
V RuT P RuT RuT
-----------------------------------------------------------------------------------------
Example: Carbon monoxide reacts with excess oxygen at temperature of
2000 K and pressure of 10 bars. Calculate the CO remaining in the
exhaust.
CO +O2 aCO2 bCO cO2
Balance in C atoms: a b 1 , b 1 a
a
Balance in O atoms: 2a b 2c 3 , c 1
2
a a
a b c 11 2
2 2
1
CO2 CO + O2
2
a a 2a
xCO2
abc 2 a 4a
2
b 1 a 2 2a
xCO
abc 2 a 4a
2
CombustionEngineeringMEDeptNCHU 57
a
1
xO2
c
2 2a
abc 2 a 4a
2
2 2a
PCO P
4a
2a
PCO2 P
4a
2a
PO2 P
4a
0.5
(2 2a )(2 a )0.5 P
K P =1.30310-3
2a (4 a ) 0.5 P0
1 a 2 a
= 4.1210-4
a 4a
a= 0.9994
CO +O2 0.9994CO2 0.0006CO 0.5003O2
-----------------------------------------------------------------------------------------
Example: Hydrogen is produced from steam and carbon monoxide in a
water shift reaction. It is known that steam and carbon monoxide are
mixed with the mole ratio of 1:1 at 800 K and 1 atm, calculate the mole
fraction of hydrogen at the outlet.
H 2O CO H 2 CO2
1 1 0 0
1-y 1-y y y
1111
xCO2 xH 2 P y y
K p =4.2435
xCO xH 2O P0 (1 y )(1 y )
y=0.319
xH 2 16%
1 m
Cn H m ( n )(O2 3.76 N 2 )
4
CO2 , CO, H 2O, H 2 , O2 , N 2 , OH , O, H , N , NO,.........
CombustionEngineeringMEDeptNCHU 58
For a lean combustion, CO2, H2O, and O2 are abundant in the products of
reaction, dissociation reactions do not affect the concentrations of these
components. As a result, it is reasonable to obtain the concentrations of
CO2, H2O, and O2 directly from atom balance.
-----------------------------------------------------------------------------------------
Example: A gas turbine engine runs on natural gas with an equivalence
ratio of 0.3. The inlet air is at 25 and 101.3 kPa. Fuel is injected into
the combustion chamber at 25. The pressure ratio of the compressor
is 10. The efficiency of compressor is 0.85. Assume that NO is in
equilibrium. Find the molar fraction of NO and CO at the exit of
combustor. Assume that air is an ideal gas.
1 1
N 2 O2 NO
2 2
1
CO2 CO + O2
2
-----------------------------------------------------------------------------------------
However, for rich and stoichiometric mixtures, O2 and H2 are rare in the
products of reaction, dissociation reactions play an important role to
determine the concentrations of these components.
-----------------------------------------------------------------------------------------
Example: Methane is burned with stiochiometric amount of air.
Assume the products are at 2000 K and 10 bar. Calculate the mole
fraction of each component assuming that the products contain CO, CO2,
H2O, H2, O2, and N2 only.
Carbon balance: a + b = 1
Hydrogen balance: 2c + 2d = 4
Oxygen balance: 2a + b + c + 2e =4
Nitrogen balance: f = 7.52
There are six unknowns in the reaction equation. However, there are
only four balance equations. We need two more equations. These two
equations should be derived from the equilibrium between components.
We propose the following equations.
1
CO2 CO O2
2
CombustionEngineeringMEDeptNCHU 59
1
H 2O H 2 O2
2
0.5 0.5 0.5
xCO xO2 P b e P
K p1
xCO2 P0 a P0
0.5 0.5
xH 2 xO0.52 P d eP
K p2
xH 2O P0 c P0
CH 4 2(O2 3.76 N 2 )
aCO2 bCO cH 2O dH 2 eO2 fN 2 gOH hO iH jN kNO
Carbon balance: a + b = 1
Hydrogen balance: 2c + 2d +g + I = 4
Oxygen balance: 2a + b + c + 2e + g + h + k =4
Nitrogen balance: 2f + j + k = 15.04
CombustionEngineeringMEDeptNCHU 60
There are eleven unknowns in the reaction equation. However, there are
only four balance equations. We need seven more equations. These
seven equations should be derived from the equilibrium between
components.
We propose the following equations.
1
CO2 CO O2
2
1
H 2O H 2 O2
2
O2 2O
H 2 2H
N2 2N
H 2 O2 2OH
N 2 O2 2 NO
0.5 0.5
xCO xO0.52 P b e P
K p1
xCO2 P0 a P0
0.5 0.5
xH 2 xO0.52 P d eP
K p2
xH 2O P0 c P0
xO2 P h 2 P
K p3
xO2 P0 e P0
xH2 P i2 P
K p4
xH 2 P0 d P0
xN2 P j2 P
K p5
xN 2 P0 f P0
2
xOH g2
K p6
xO2 xH 2 de
2
xNO k2
K p7
xO2 xN 2 fe
abcd e f g hi jk
CombustionEngineeringMEDeptNCHU 61
-----------------------------------------------------------------------------------------
Example: Methane is burned with stiochiometric amount of air
adiabatically in a constant pressure combustor. Assume the reactants
are at 298 K and 10 bar. Calculate the mole fraction of each component
assuming that the products contain CO, CO2, H2O, H2, O2, H, O, OH, NO,
N, and N2.
CH 4 2(O2 3.76 N 2 )
aCO2 bCO cH 2O dH 2 eO2 fN 2 gOH hO iH jN kNO
There are twelve unknowns in the reaction equation. Besides the mole
fractions that are not known, the temperature is also unknown. We need
eight more equations. These seven equations should be derived from the
equilibrium between components. The last equation is derived from the
conservation of energy before and after combustion.
HR=HP
-----------------------------------------------------------------------------------------
Example: Methane is burned with stiochiometric amount of air in a
constant volume combustor. Assume the reactants are at 298 K and 1 bar.
Calculate the mole fraction of each component assuming that the products
contain CO, CO2, H2O, H2, O2, H, O, OH, NO, N, and N2.
CH 4 2(O2 3.76 N 2 )
aCO2 bCO cH 2O dH 2 eO2 fN 2 gOH hO iH jN kNO
There are thirteen unknowns in the reaction equation. Besides the mole
fractions that are not known, the temperature and the pressure are also
unknown. We need nine more equations. These seven equations
should be derived from the equilibrium between components. One
equation is derived from the conservation of energy before and after
CombustionEngineeringMEDeptNCHU 62
combustion, and the other equation is derived form the state equation of
ideal gas.
UR=UP
uCH 4 2(uO2 3.76u N 2 ) a uCO2 b uCO c u H 2O d u H 2 e uO2
f u N 2 g uOH h uO i u H j u N k u NO
ni RT
P
V
The mole fractions to be determined are functions of temperature and
pressure. However, temperature should be solvable only when all the
mole fractions are already known. As a result, temperature and pressure
should be guessed before calculations proceed. The energy equation is
used to check if the guessed temperature is correct or not, and the ideal
gas equation is used to check if the pressure is correct or not.
-----------------------------------------------------------------------------------------
(2.9.3). STANJAN
-----------------------------------------------------------------------------------------
Example: Methane is burned with air at 2000K and 10 bar. If the
combustion products contain CO, CO2, O2, H2, H2O, HO, H, O, NO,
N, and N2, find the equilibrium concentrations of products at
equilibrium ratio of 1.0.
-----------------------------------------------------------------------------------------
Example: Mixtures of methane and air at 300K and 100 kPa are
burned in a constant pressure process. If the combustion products
contain CO, CO2, O2, H2, H2O, HO, H, O, NO, N, and N2, find the
equilibrium concentrations of products at equilibrium ratio of 1.0.
-----------------------------------------------------------------------------------------
Example: Mixtures of methane and air at 300K and 100 kPa are
burned in a constant volume process. If the combustion products
contain CO, CO2, O2, H2, H2O, HO, H, O, NO, N, and N2, find the
equilibrium concentrations of products at equilibrium ratio of 1.0.
-----------------------------------------------------------------------------------------
Example: An Otto engine runs with stoichiometric methane mixture.
The volume of the cylinder is 1L, and the compression ratio is 10. The
initial temperature and pressure inside cylinder are 300 K and 1 atm
CombustionEngineeringMEDeptNCHU 63
respectively. Calculate the work output, assuming that the products
contain CO, CO2, H2O, H2, O2, H, O, OH, NO, N, and N2.
-----------------------------------------------------------------------------------------
ANo dissociation
2 2 2
CH 4 (O2 3.76 N 2 ) CO2 2 H 2O ( 2)O2 3.76 N 2 , 1
2 2
CH 4 (O2 3.76 N 2 ) aCO2 bCO 2 H 2O 3.76 N 2 , 1
BWeak dissociation
2
CH 4 (O2 3.76 N 2 ) aCO2 bCO cH 2O dH 2 eO2 fN 2
CStrong dissociation
2
CH 4 (O2 3.76 N 2 )
aCO2 bCO cH 2O dH 2 eO2 fN 2 gOH hO iH jN kNO
A B C
0.8
0.9
1.0
1.1
1.2
-----------------------------------------------------------------------------------------
Assignment 2.27
Propane is burned with air at 2000K and 10 bar. If the combustion
products contain CO, CO2, O2, H2, H2O, HO, H, O, NO, N, and N2,
find the equilibrium concentrations of products at equilibrium ratios
from 0.7 to 1.3 with an increment of 0.1. The calculations may be
conducted with STANJAN. Plot the results of calculations.
-----------------------------------------------------------------------------------------
Assignment 2.28
CombustionEngineeringMEDeptNCHU 64
Mixtures of propane and air at 300K and 100 kPa are burned in a
constant pressure process. If the combustion products contain CO,
CO2, O2, H2, H2O, HO, H, O, NO, N, and N2, find the adiabatic
flame temperature and the equilibrium concentrations of products at
equilibrium ratios from 0.7 to 1.3 with an increment of 0.1. The
calculations may be conducted with STANJAN. Plot the results of
calculations.
-----------------------------------------------------------------------------------------
Assignment 2.29
Mixtures of propane and air at 300K and 100 kPa are burned in a
constant volume process. If the combustion products contain CO,
CO2, O2, H2, H2O, HO, H, O, NO, N, and N2, find the adiabatic
flame temperature, the final pressure, and the equilibrium
concentrations of products at equilibrium ratios from 0.7 to 1.3 with
an increment of 0.1. The calculations may be conducted with
STANJAN. Plot the results of calculations.
-----------------------------------------------------------------------------------------
Assignment 2.30
A gas turbine engine runs with mixtures of propane and air. The
equivalence ratio is 0.4. The inlet air is at 300 K and 1 bar. The pressure
ratio is 10.0. Fuel is injected into the combustion chamber at 300 K and
10 bars. Calculate the work output. Assume that the products contain CO,
CO2, H2O, H2, O2, H, O, OH, NO, N, and N2.
-----------------------------------------------------------------------------------------
Assignment 2.31
An Otto engine runs with stoichiometric mixtures of propane and air.
The inlet condition is 300K and 100 kPa. The compression ratio is
11. If the combustion products contain CO, CO2, O2, H2, H2O, HO,
H, O, NO, N, and N2, find the equilibrium concentrations of
products during the expansion stroke. The calculations may be
conducted with STANJAN. Plot the results of calculations.
-----------------------------------------------------------------------------------------
CombustionEngineeringMEDeptNCHU 65
(2.10). Applications of equilibrium calculations
a
, [CO2 ] b , [ HC ] 1 c
[CO ]
abc x yw
H 2 CO2 H 2O CO
[ H 2 ][CO2 ]
K
[ H 2O ][CO ]
CombustionEngineeringMEDeptNCHU 66
1 1 1
n CO CO2 HC
4.76(1 )
4
n 1 n 3 kn CO CO CO2
1 ( ) CO CO2 HC
4 2 4 4 CO2 k CO
1 n 1 1 n [CO ] [CO2 ]
x (1 ) ([CO ] 2[CO2 ] )
4 2 [CO ] [CO2 ] [ HC ] 2 [CO ] K 1
[CO2 ]
x
[O2 ]
( A / F ) st
A/ F
-----------------------------------------------------------------------------------------
Example The measured emission data of a motorcycle at idling are
shown as the following.
CombustionEngineeringMEDeptNCHU 67
1.82 3330 8.34 4.91
4.40 5010 5.82 5.52
4.51 6900 3.9 6.84
3.90 5660 5.1 6.56
3.17 4140 3.44 9.18
-----------------------------------------------------------------------------------------
CombustionEngineeringMEDeptNCHU 68