produced from the reaction of covalent molecules like HCl with water.
H3O+ (aq) + Cl (aq) HCl (g) + H2O (l) Some bases are ionic
compounds that dissolve in water or react with it to produce aqueous
hydroxide
NaOH (s) Na+ (aq) + OH (aq) BaO (s) + H2O (l) Ba2+ (aq) + 2OH
(aq) Other bases such as ammonia, NH3, and related amines produce
hydroxide ions when dissolved in water
NH4+ (aq) + OH (aq) NH3 (g) + H2O (l) Acids and bases are classified
as either strong or weak. Strong acids or bases are those that are
completely or almost completely ionized in dilute aqueous solution. We
can easily calculate the
Equation 1.
H3O+ (aq) + OH (aq) H2O (l) + H2O (l) In this reaction one molecule
of water acts as a Bronsted-Lowry acid (a proton donor) while the other
and OH are exactly the same. For every water molecule that
dissociates, one hydronium and one
If we represent the acid form of the indicator as H:In, and the base form
of the indicator as :In, we can
write its reaction with a base :B or acid H:B as the following reversible
equation.
H:In (aq) + :B (aq) :In (aq) + H:B (aq) Acid form of indicator Base
Base form of
Indicator
Methyl violet
Congo red
Litmus
Phenolphthalein
change
0 2.0
3.0 5.0
5.0 8.2
8.3 10.0
Blue
Red
Colorless
Yellow Violet
Red
Blue
Red/pink
Red Hydrolysis
Weak acids are poorly ionized in aqueous solution; that is, they are poor
proton donors or BronstedLowry acids. Conversely, the bases formed
when weak acids dissociate (their conjugate bases) have
acid than H2CO3. Table II lists some common acids and bases in order
of their relative acid and base strengths. This table
will aid you in your interpretation of the observations you will make in
the hydrolysis experiments. Table II. Relative strengths of acids and their
conjugate bases Strongest Weakest Acid
H2SO4
HCl
H3O+
HSO4
H3PO4
HC2H3O2
H2CO3
H2PO4
NH4+
H2O
HCO3
HSO4
Cl
H2O
SO42
H2PO4
C2H3O2
HCO3
HPO42
NH3
OH
CO32
system.
HCO3 (aq) + H+ (l) H2O (aq) + H2CO3 (aq) Acid or base added to the
system is removed by reacting with one component of the buffer system,
beginning of lab)
1. You will work with 0.10 M acetic acid and 17 M acetic acid in this
experiment. What is the
equations for reactions of acid, base, and salt hydrolysis not used as
examples in the
acetate. Calculate the pH that you expect for this buffer. Write the
chemical equation for the
5. To the solution from #4, you add 0.50 mL of 0.10 M HCl. Calculate
the new pH of the buffer
solution. Write the chemical equations for the reaction and the
equilibrium. Show your work
6. To the solution from #4, you add 0.50 mL of 0.10 M NaOH. Calculate
the new pH of the buffer
solution. Write the chemical equation for the equilibrium. Show your
work using an ICE table.
not submit the tables with your pre-lab questions, as you will record
your data in the tables
during lab.
Procedure
photo I.D. in order to check out a Lab Quest unit and box containing the
cables, a conductivity probe,
and a pH probe. The lab Quest and other equipment is available from the
prep room. Your I.D. will be
returned when the Lab Quest unit and other equipment is returned to the
prep room at the end of the
lab session.
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