Are easily inhaled and carried into the lower regions of the lung
where they can cause fibrotic lung disease ((Asbestosis)- is a
chronic lung disease in which there is scar-like tissue formed in
the lungs (pulmonary fibrosis). This fibrosis decreases the
elasticity of the lungs, making breathing more difficult. Shortness
of breath is the most common symptom. In most cases, a
common physical sign is "crackles" - sounds that can be heard
through a stethoscope. Also known as "rales", they are usually
detected near the end of a full inspiration.) and changes in the
lining of the chest cavity (pleura).
These diseases can lead to reduced respiratory function and
death. Long-term inhalation of asbestos fibres also increases the
risk of lung cancer and ((mesothelioma)- mesothelioma is an
aggressive, usually fatal cancer arising from the mesothelial cells
that form the lining of the pleural (lung), peritoneal (abdominal)
and pericardial (heart) cavities. For mesothelioma, the latency is
generally 30-40 years, with the longer periods seen where there
had been lower levels of asbestos exposure. Workers with a
heavy exposure probably swallow asbestos fibres (when fibres
are cleared from the airways in mucous and then swallowed),
which may contribute to the development of mesothelioma of the
lining of the abdominal cavity (peritoneum)).
Enlargement of the heart can also occur as an indirect effect
from the increased resistance of blood flow through the lungs.
Cement workers
Chrysotile
Chrysotile is an extremely hazardous material.
Clinical and epidemiologic studies have established incontrovertibly that
chrysotile causes cancer of the lung, malignant mesothelioma of the pleura
and peritoneum, cancer of the larynx and certain gastrointestinal cancers.
Chrysotile also causes asbestosis, a progressive fibrous disease of the lungs.
Risk of these diseases increases with cumulative lifetime exposure to
chrysotile and rises also with increasing time interval (latency) since first
exposure.
Comparative analyses have established that chrysotile is 2 to 4 times less
potent than crocidolite asbestos in its ability to cause malignant
mesothelioma, but of equal potency of causation of lung cancer.
The International Agency for Research on Cancer of the World Health
Organization has declared chrysotile asbestos a proven human carcinogen.
Sales of chrysotile asbestos have virtually ended in Western Europe and
North America, because of widespread recognition of its health hazards.
However, asbestos sales remain strong in Japan, across Asia and in
developing nations worldwide.
The claim has been made that chrysotile asbestos can be used "safely" under
"certain conditions" in those nations.
That claim is not accurate. The Collegium Ramazzini, an international learned
society in environmental and occupational medicine, has called for an
immediate worldwide ban on all sales and uses of all forms of asbestos,
including chrysotile.
The rationale for this ban is threefold: (1) that safer substitute materials are
readily available, (2) that "controlled" use of asbestos is not possible, and (3)
that the health risks of asbestos are not acceptable in either the industrialized
or the newly industrializing nations.
It is a soft, fibrous silicate mineral in the serpentine
subgroup of phyllosilicates; as such, it is distinct from other asbestiform
minerals in the amphibole group. Its idealized chemical
formula is Mg3(Si2O5)(OH)4. The material has physical properties which
[4]
Pulp
Workers in the pulp and paper industry are exposed to different substances,
such as hydrogen sulfide and other reduced sulfur compounds, chlorine,
chlorine dioxide, sulfur dioxide, terpenes, and paper dust.
The exposure level depends on the process, i.e., sulfite, sulfate, groundwood,
bleachery, or paper production. Hitherto, exposures have been poorly
described and more studies are certainly needed.
Workers with repeated exposure peaks to chlorine, e.g., bleachery workers,
seem to have an impaired lung function and an increased prevalence of
respiratory symptoms.
Exposure to high levels of paper dust, (> 5 mg/m3) causes impaired lung
function.
Therefore, exposure to respiratory irritants is an important, and probably
overlooked, occupational risk among certain groups of pulp and paper
workers.
Some studies indicate that sulfate workers with high exposure to reduced
sulfur compounds have an increased mortality due to ischemic heart disease.
However, before any definite conclusions can be drawn, the impact of
important confounders, such as shift-work and smoking habits have to be
further evaluated.
Pulp and paper mills stand as a salient example of chemical facilities that can
implement readily available safer alternatives to eliminate or reduce
unnecessary risks to workers and local communities in the event of an
accidental or deliberate chemical release.
Chlorine and chlorine dioxide are used as bleaching agents in many pulp and
paper-making processes. The dominant industry processes are the elemental
chlorine (EC) process, which relies on chlorine gas, or the elemental chlorine-
free (ECF) process, which uses chlorine dioxide, a gas with hazards similar to
chlorine.
In the event of an accidental or deliberate release, chlorine and chlorine
dioxide present serious hazards.
Chlorine, used as a chemical weapon, is highly toxic and corrosive. It irritates
the mucous membranes of the nose, throat, and lungs, and causes breathing
difficulties, violent coughing, acute tracheobronchitis, and chemical
pneumonia.
Exposure to relatively low levels of chlorine can be fatal. Similarly, chlorine
dioxide causes shortness of breath, bronchitis, and emphysema.
Acute exposure can cause potentially fatal pulmonary edema.
Despite the safety and environmental benefits associated with chlorine-free
bleaching, most pulp and paper mills have not switched to these safer and more
secure technologies.
In order to adequately address the recognized safety and security threats created
by facilities using and storing dangerous chemicals, the United States needs a
comprehensive policy dedicated to making its pulp and paper millsand all
chemical plantssafer. This policy should:
Cement
Cement is manufactured through a closely controlled chemical
combination of calcium, silicon, aluminum, iron and other
ingredients.
Cement can harm your health in a number of ways.
Cement is one of the most widely used construction
materials. Unless used safely, it can cause:
irritant dermatitis
allergic dermatitis
difficulty in breathing
musculoskeletal problems
Health effects
Dermatitis Skin affected by dermatitis feels itchy and sore,
and looks red, scaly and cracked. Cement is capable of
causing dermatitis by two mechanisms - irritancy and allergy.
Irritant dermatitis is caused by the physical properties of
cement that irritate the skin mechanically. The fine particles
of cement, often mixed with sand or other aggregates to
make mortar or concrete, can abrade the skin and cause
irritation resulting in dermatitis. With treatment, irritant
dermatitis will usually clear up. But if exposure continues
over a longer period the condition will get worse and the
individual is then more susceptible to allergic dermatitis.
Allergic dermatitis is caused by sensitisation to the
hexavalent chromium (chromate) present in cement. The
way this works is quite distinct from that of irritancy.
Sensitisers penetrate the barrier layer of the skin and cause
an allergic reaction. Hexavalent chromium is known to be the
most common cause of allergic dermatitis in men. Research
has shown that between 5% and 10% of construction
workers may be sensitised to cement and that plasterers,
concreters and bricklayers are particularly at risk. Once
someone has become sensitised to hexavalent chromium,
any future exposure may trigger dermatitis. Some skilled
tradesmen have been forced to change their trade because
of this. The longer the duration of skin contact with a
sensitiser, the more it will penetrate the skin, and the
greater the risk of sensitisation will become. Therefore, if
cement is left on the skin throughout the working day, rather
than being washed off at intervals, the risk of contact
sensitisation to hexavalent chromium will be increased. Both
irritant and allergic dermatitis can affect a person at the
same time. Cement burns Wet cement can cause burns. The
principal cause is thought to be the alkalinity of the wet
cement. If wet cement becomes trapped against the skin, for
example by kneeling in it or if cement falls into a boot or
glove, a serious burn or ulcer can rapidly develop. These
often take months to heal, and in extreme cases will need
skin grafts or can even lead to amputation. Serious chemical
burns to the eyes can also be caused following a splash of
cement. Inhalation of dust High levels of dust can be
produced when cement is handled, for example when
emptying or disposing of bags. In the short term, exposure to
high levels of cement dust irritates the nose and throat.
Scabbling or concrete cutting can also produce high levels of
dust which may contain silica.
*The pan mill (DKW) is one of the most effective preparation machines for
plastic ceramic bodies.
*Combined with the high weight of edge rolls, different relative movements
under the edge rolls and due to the slow operating mode the body is
effectively crushed, sheared and mixed.
* Moreover water can be added and the body can be plasticized further.
They usually consist of a trough or tube containing either a spiral blade coiled
around a shaft, driven at one end and held at the other, or a "shaftless spiral",
driven at one end and free at the other. The rate of volume transfer is
proportional to the rotation rate of the shaft. In industrial control applications the
device is often used as a variable rate feeder by varying the rotation rate of the
shaft to deliver a measured rate or quantity of material into a process.
Screw conveyors can be operated with the flow of material inclined upward.
When space allows, this is a very economical method of elevating and
conveying. As the angle of inclination increases, the capacity of a given unit
rapidly decreases.