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KRM_Chemistry PART-TEST 1(Solutions & Solids) 30.04.

2017

1. What happens to the freezing point of an aqueous solution of AgNO3 when NaCl is added to it
such that all silver gets deposited in the form of AgCl?
a. It is raised
b. it is lowered
c. it remains unchanged
d. it is lowered by twice the original value

2. Total vapour pressure of a mixture of 1 mol of X and 2 mol of Y is 200 torr. if PO of X an Y are
145 torr and 245 torr respectively, it is a case of:
a. positive deviation from Raults Law
b. negative deviation from Raults Law
c. No deviation
d. Cannot be decided

3. The vapour pressure of a solvent is 0.8 atm. When a non-volatile substance B is added to it, its
vapour pressure decreases to 0.6 atm. The mole fraction of B in the solution is :
a. 0.5
b. 0.25
c. 0.75
d. 0.95

4. The depression in freezing point for 1M urea, 1M glucose and 1M NaCl is


a. 1:1:1
b. 1:1:2
c. 1:2:3
d. 2:2:1

5. The molecular weight of benzoic acid in benzene as determined by depression in freezing point
method corresponds to :
a. ionisation of benzene
b. dimerisation of benzene
c. trimerization of benzene
d. salvation of benzoic acid

6. In a 0.2 molal aqueous solution of a weak acid HA, the degree of ionisation is 0.3. Taking Kf of
water as 1.86, the freezing point of the solution will be nearest to (in oC):
a. -0.48
b. -0.36
c. -0.26
d. +0.48

7. If x is the degree of dissociation of Na2SO4, the vant Hoff factor is


a. 1 + x
b. 1 - x
c. 1 - 2x
d. 1 + 2x

8. An azeotropic solution of two liquids has a boiling point lower than either liquid when
a. positive deviation from Raults Law
b. negative deviation from Raults Law
c. No deviation
d. Cannot be decided
KRM_Chemistry PART-TEST 1(Solutions & Solids) 30.04.2017

9. FeCl3 reacts with K4[Fe(CN)6] to form a blue complex. If the two are separated by an SPM as
shown below then:

a. blue colour will form towards A


b. blue colour will form towards B
c. blue colour will form on both sides
d. No blue colour will form

10. Commercial cold packs often contain solid NH4NO3 and a


pouch of water separated by a seal. On breaking the
seal NH4NO3 comes in contact with water and the temperature drops. Which of the following
statements is true:
a. H +ve ; S -ve
b. H -ve ; S +ve
c. H +ve ; S +ve
d. H -ve ; S -ve

11. Mole fraction of a solute in benzene is 0.2, then the molality of the solution is:
a. 2
b. 4
c. 3.2
d. 3.8

12. A 1.03% solution of glycerine is isotonic with 2% solution of glucose. The molar mass of
glycerine is:
a. 92.7
b. 98.0
c. 90.2
d. 96.4

13. The osmotic pressure of urea is 500mm at 10. If the solution is diluted and temperature
raised to 25, the pressure decreases to 105.33 mm. What is the extent of dilution:
a. 2.5 times
b. 3.25 times
c. 5 times
d. 7.5 times

14. A solution of liquids A and B has POA : POB = 1:2 and mole fraction in solution 1:2 also.
The mole fraction of A in vapours is:
a. 0.2
b. 0.25
c. 0.36
d. 0.52

15. Which of the following azeotropic solutions has the boiling point less than boiling point of the
constituents A and B?
a. CHCl3 and CH3COCH3
b. CS2 and CH3COCH3
c. CH3CH2OH and CHCl3
d. CH3CHO and CS2
KRM_Chemistry PART-TEST 1(Solutions & Solids) 30.04.2017

16. Which of the following arrangements shows schematic alignment of magnetic moments of
antiferromagnetic substances?

17. Which of the following is not a characteristic of a crystalline solid?


a. Definite and characteristic heat of fusion.
b. Isotropic nature.
c. A regular periodically repeated pattern of arrangement of constituent particles in the entire
crystal.
d. a true solid

18. Iodine molecules are held in the crystals lattice by ________________.


a. london forces
b. dipole-dipole interactions
c. covalent bonds
d. coulombic forces

19. Which of the following point defects are shown by AgBr(s) crystals?
(A) Schottky defect
(B) Frenkel defect
(C) Metal excess defect
(D) Metal deficiency defect
a. (A) and (B)
b. (C) and (D)
c. (A) and (C)
d. (B) and (D)

20. A compound formed by elements A and B forms a cubic lattice where A atoms occupies the
corners of a cube while B atoms occupies the face centres. The formula of the compound can be
a. AB3
b. AB
c. A2B
d. A3B

21. The density of solid argon is 1.65g/ml. If Argon is assumed to be a sphere of radius 1.54 x 10-8
cm, what % of solid argon is apparently empty space?
a. 32
b. 52
c. 72
d. 62

22. The number of unit cells in 58.5g of NaCl is approximately:


a. 0.5 x 1023
b. 1.5 x 1023
c. 3 x 1022
d. 6 x 1021
KRM_Chemistry PART-TEST 1(Solutions & Solids) 30.04.2017

23. The crystal system of a compound with none the edges or the angles equal to each other is
called
a. Cubic
b. hexagonal
c. trigonal
d. monoclinic

24. In the CsCl structure the ratio of the radius of the anion to the cation is 1.37. The edge length of
the unit cell is
a. Twice the radius of the anion
b. equal to the radius of the anion
c. four times the radius of the anion
d. 1.414 times the radius of the anion

25. In a compound PQ2O4 oxide ions are arranged in CCP while cations P are present in
octahedral voids. The cations Q on the other hand are equally distributed between the octahedral
and tetrahedral voids. The fraction of octahedral voids occupied is
a. 1/4
b. 1/2
c. 1/3
d. 2/3

26. If Z is the number of atoms in the unit cell lattice that represents ABCABC.. type of close
packing, the total number of tetrahedral voids is:
a. Z
b. 2 Z
c. 1/2 Z
d. 1/4 Z

27. The number of nearest neighbours and next nearest neighbours of a Na+ in a crystal of NaCl is
a. 12 Cl-, 6 Na+
b. 6 Cl-, 12 Na+
c. 6 Cl-, 6 Na+
d. 6 Na+ 12 Cl-

28. For HCP the coordination number of each atom is


a. 6
b. 4
c. 12
d. 18

29. NaCl is doped with 10-4 mol % of SrCl2, the number of cationic vacancies is:
a. 6.02 x 10 15
b. 6.02 x 10 16
c. 6.02 x 10 17
d. 6.02 x 10 14

30. KCl crystallises in the same type of lattice as does NaCl . Given rNa+/rCl- = 0.55 and rk+/rCl- =
0.74 , calculate the ratio of the edge length of KCl to NaCl:
a. 1.123
b. 0.432
c. 1.876
d. 1.564