N de prctica 1
Ttulo COMPLEXOMETRC PARTE II: Determinacin de la Dureza
Total, Clcica y Magnsica en una muestra de agua.
RESUMEN
Abstract
The determination of the hardness of water is very important in various scientific and industrial areas
as it is responsable for the formation of scale or crusts in pipes which leads to failures and loss of
efficiency in different processes of water treatment or heat transfer.
With the objective of determining by Complexometry with EDTA the Total Hardness, Calcic and
Magnesium of a Water sample of natural origin, by means of valuation procedures using as a primary
standard a cationic solution of carbonate and the use of NET for the total hardness and the indicator
Murexin for the calculation of the volume used in the determination of the calcium hardness and by
the difference of volumes with the two indicators for the calculation of the magnetic hardness, It was
possible to determine these values giving as results: total hardness 52.5556 6.4137 ppm CaCO3,
calcium hardness 35.4307 6.8567 ppm CaCO3, magnesium hardness MgCO3. Based on the
obtained values, it was possible to conclude according to the classification of water hardness given by
OMS that the analyzed water sample is of moderately hard type since it is in a range between 51-150
mg / l CaCO3.
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Tratamiento estadstico
REACCIONES QUIMICAS
Dureza total
Ca 2+
+ Y 4-
CaY 2- Q exp = Vdudoso Vcercano
Vmax. vmin.
Mg2+ + Y4- Mg Y2
Q exp = 56,6892 54,3271
Calculo de la dureza total del agua 56,6892 47,2410
mol EDTA = mol Ca2+
(V EDTA) x (M EDTA) = mmol Ca2+ Q exp = 0,2500
(V EDTA) x (M EDTA) = mg CaCO3
PM CaCO3 Qexp < Qcrit
mg CaCO3 = (V EDTA) x (M EDTA) x (PM 0,2500< 0,829 (se acepta)
CaCO3)
Dureza clcica
ppm CaCO3= mg CaCO3
L muestra Q exp = 40,1548 37,7928
40,1548 30,7066
ppm CaCO3= (V EDTA NET ) x (M EDTA) x (PM
CaCO3) Q exp = 0,2499
L muestra
Qexp < Qcrit
ppmCaCO3=2,4(ml) x0,0118(mmol/ml) x100,0869(mg/mmol)
0,05 L 0,2499< 0,829 (se acepta)
ppm CaCO3= 56.6892 mg/L
Calculo de la dureza Clcica Dureza magnsica
mol Ca2+ = mol EDTA
mmol Ca2+ = (V EDTA) x (M EDTA) Q exp = 19,8980 15,9184
mg CaCO3 = (V EDTA) x (M EDTA) 19,8980 9,9490
PM CaCO3
mg CaCO3 = (V EDTA) x (M EDTA) x (PM Q exp = 0,4
CaCO3)
Qexp < Qcrit
ppm CaCO3= (V EDTA murx ) x (M EDTA) x (PM
CaCO3) 0,4< 0,829 (se acepta)
L muestra
ppm CaCO3=1,6(ml) x0,0118(mmol/ml) x
100,0869(mg/mmol) RESULTADOS Y DISCUSIONES
0,05 L Tabla N4. Resultados obtenidos en la
determinacin de la Dureza Total, Clcica y
ppm CaCO3= 37,7928 mg/L Magnsica en una muestra de agua.
Durz.Total Dureza Clcica Durz
mg mgCaCO3/V Magnsica
Calculo de la dureza Magnsica CaCO3/ sol(L) mgMgCO3/Vsol
Vsol(L) (L)
mmol Mg2+ = mmol EDTA mmol Ca2+ 56,6892 37,7928 15,9184
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