No: 169337320 This booklet contains 24 printed pages. sso 69337 Do not open this Test Béoklet until you are asked to do so. Read carefully the Instructions on the Back Cover of this Test Booklet. Important Instructions + 1. Immediately fill in the particulars on this page of the Test Booklet with omy Blue / Black Ball Poiatt Pen provided by the Board, 2. ‘The Answer Sheet is kept inside this Test Booklet. When you are directed to open the Test Booklet, take out the Answer Sheet and fill in the particulars carefully. 4. The test is of 3 hours duration. 4, The Test Booklet consists of 90 questions, The maxienum marks are 360. 5. There are three parts in the question paper A, B, C consisting of Physics, Mathematics and Chemistry having 30 questions in each part of equal weightage. Each question is allotted 4 (four) marks for each correct response. 6. Candicites will be awarded marks as stated above in instruction No.5 for correct response of each question. Ya (ome fourth) marks will he deducted for indicating incorrect respartse ofeach question. No dechaction fram the total score wall he made if mo response is indicated for an ifeme in the answer sheet. 7. There is only one correct response for each question. Filling up more than one response in each question will be treated as wrong response and marks for wrong response will be deducted Jy as per instruction 6 above 8. For writing partieulars/ marking responses on Side-1 and Side-2 of the Answer Shoet use only Blue/ Black Bat! Point Pen provided by the Board. 9. No candidate is allowed to cary any textual material, printed or written, bits of papers, pager, mobile phone, any electronic device, etc. except the Admit Card inside the examination room hall 10. Rough work is to be done on the space provided for this purpose in the Test Booklet only. This space is given at the bottom of each page and in three pages (Pages 21 - 23) at the end of the booklet 11. On completion of the test, the candidate must hand over the Answer Sheet to the Invigilator on duty in the Room/Hall. However, the candidates ave allowed to take away this Test Booktet ‘with them. 12, The CODE for this Booklet is H. Make sure that the CODE printed on Side-2 of the Answer Sheet and also tally the serial number of the Test Booklet and Answer Sheet are the ‘same as that on this booklet. In case of discrepancy, the candidate should immediately seport the matter to the Invigilator for replacement of both the Test Booklet and the Answer Sheet. 13. Do not fold or make any stray mark on the Answer Sheet. ‘Name of the Candidate (in Capital letters >_- Rell Number infgures (=T TU] tI inwords, Examination Centre suber: [-T [|] Name of Examination Centre (in Capital letters) ;———2 Candidate's Signanure:; 2 = 1 Anvigilator’s Signature: py ag 2 2 Invigilator's SigmanPART A — PHYSICS ALL THE GRAPHS GIVEN ARE SCHEMATIC - AND NOT DRAWN TO SCALE. 1. A particle performs simple harmonic motion with amplitude A. Its speed is trebled at the instant that itis at a distance a from equilibrium position. The new amplitude of the motion is + Q ANS 7A a & A @ 4am (4) 34 2. For a common emitter configuration, if @wand # have their usual meanings, the incorrect relationship between @ and 8 is: 0 oe a corre @) pepe (ay A student measures the time period of 100 oscillations of a simple pendulum four times, The data set is 90s, 91s, 95s and 925. If the minimum division in the measuring clock is 11s, then the reported ‘mean time should be : () 2218s 4H 23s Q) 2=2s (a) 922505 Ifa, b,c, d are inputs to a gate and x is its ‘output, then, as per the following time sgraph, the gate is : 4 FULL ef LL vo FL 2 r— =f ar OR Q) NAND @) NOT 4) AND H/ Page 2 SPACE FOR ROUGH WORKA particle of mass iu is moving along the side of a square of side ‘a’, with a uniform speed v in the a-y plane as shown in the Figure ‘Which of the following statements is false for the angular momentum L abaut the origin ? a) (2) @) () H/Page 3 Vee elit wo [Beri] mw 08 particle is moving from B to €. a moving from D to A T=" 8 k when the particle is i. = v2 moving fom A to B. 4 RX when the particle is aL R_ Je B=mo[s ji when the ppatticle is moving from C to D. is Choose the correct statement a a @) @ In frequency modulation the amplitude of the high frequency carrier wave is made to vary in proportion to the amplitude of the audio signal, In frequency the amplitude of the high frequency carrier wave is made to vary in proportion to the frequency of the audio signal In amplitude modulation the amplitude of the high frequency carrier wave is made to vary in proportion to the amplitude of the audio signal, In amplitude modulation the frequency of the high frequency cartier wave is made to vary in Proportion to the amplitude of the audio signal. modulation Radiation of wavelength A, is incident on a photocell. The fastest emitted electron has speed v. If the wavelength is changed to 2, the speed of the fastest emitted electron will be : a ay SPACE FOR RQUGH WORK EE : a8. Twoidentical wires A and B,each of length ‘carry the same current |. Wire A is bent into a cirele of radius R and wire B is bent to form a square of side ‘a’, IF B, and Bg are the values of magnetic field at the centres of the circle and square respectively, then the ratio BA is : Oo. 16 a o aa 8) = 8 a = : T6v2 9 cACpip® open at both endishas-» fundamiontal froquency fin air, The pipe is dipped vertically in water so that half of it is in water. The fundamental frequency of the air column is now : “ay 2f “@ Ff f e £ a 3 4 Hy/Pagea 10, ‘The region between two concentric spheres of radii ‘a’and ’, respectively (see figure), has volume charge density = A where Ais a constant and ¢ is the distance from the centre, At the centre of the spheres is a point charge Q. The value of A such that the electric field in the region between the spheres will be constant, is : , 0) ae a5 ] a 26 ° 4) An arc lamp requires a‘ direct current of 10.4 at 80 Vito function, If it is connected. to'a 220 V (rms), 50 Hz AC supply, the Series inductor needed for it to work is ~ close to: Q) oo “0.065 H Q) 80H (4) 0.08 H ; CSFACE POR ROUGH WORK12, ‘n’ moles of an ideal gas undergoes a process A~»B os shown in the figure. The maximum temperature of the gas during the process will be : (2) mR 91M ® nk 3 Ve ® 2nR 13. A person trying to lose weight by burning. fat lifts a mass of 10 kg upto a height of 1m 1000 times, Assume that the potential energy lost each time he lowers the mass is dissipated, How much fat will he ase up considering the work done only when the weight is lifted up ? Fat supplies 3.810? | of energy per kg which is converted to mechanical energy with a 20% efficiency rate. Take g=9.8 ms~?: a) "1289109 kg 9.89% 10-3 kg. B) 245¢10-3 kg: ) 645% 10-3 kg H/Page 5 |G A point particle of rhass mi, moves along the uniformly rough track POR as shown in the figure, ‘The coefficient of friction, between the particle and the raugh track equals 2 The patticleis released, from rest from the point P and it comes to rest at a paint R, The energies, lost by the ball, over the parts, PQ and QR, of the track, are ‘equal to each other, and no energy is lost when particle changes direction from PQ to OR, The values of the coefficient of friction and the distance x(=QR), are, respectively close to Horizontal —+ Q Surface (1) 0.29 and 3.5 m (2) 029 and 65 m O2 and 65m @ (4) 02and35._m SPACE FOR ROUGH WORK15. ‘The temperature dependence of resistances of Cu and undoped Si in the temperature range 300-400 K, is best described by : (1) Linear increase for Cu, exponential decrease for Si (2) Linear decrease for Cu, linear decrease for Si 3) Linear increase for Cu, linear increase for Si. (4) Linear increase for Cu, exponential increase for Si, 16. Arrange the following electromagnetic radiations per quantum in the order of increasing energy A: Bluelight B: Yellow light : Ci Xray: D+: Radiowave AS GABD 2) BA D.C “ef D.BAC @ ABDC 17. A galvanometer having a coil resistance 0f 100.0 gives a full scale deflection, when @ current of | mA is passed through it, The value of the resistance, which can convert this galvanometer into ammeter giving a full scale deflection for a current of 10 A, is () 010 @ 30 Ar 0010 @) 20 18. Half-lives of two radioactive elements A and B are 20 minutes and 40 minutes, respectively. Initially, the samples have equal number of nuclei, After 80 minutes, the ratio of decayed numbers of A and F nuctei will be ve 1:4 wey 5:4 G) 1:16 (a) 4:1 19. Identify the semiconductor devices whose characteristics are given below, in the order (a), (b), (c), (d) + 1 1 [intensity Tiluminated of light Ye © (¢) Solar cell, Light dependent resistance, Zener diode, Simple diede . (2) Zener diode, Solar cell, Simple dinde, Light dependent resistance (3) Simplediode, Zener diode, Sélar cell, ‘Light dependent resistance (4) Zener diode, Simple diode, Light dependent resistance, Solar cell H/Page 6 SPACE FOR ROUGH WORK -20. A combination of capacitors is set up as shown in the figure. The magnitude of the electric field, due to a point charge Q (having a charge equal to the sum of the charges on the 4 pf and 9 F capacitors), at a point distant 30 m from it, would equal 3uF aur 1 uF 4 2yF tk sae 8v Q) 420 N/C (2) 480 NYC @) 2oN/C (4) 360. N/C 21. A satelite is revolving in a circular orbitat a height ‘I’ from the earth's surface (radius of earth R:iI< VFL 2 a a=— and byiy= a a2 ze and Pig [W 2 VOL 247 (a) VAE and Bouin = () 26. A uniform string of length 20m is suspended from a rigid support. A short ares «wave pulse is introduced at its lowest end. It starts moving up the string. The time SPACE'FOR ROUGH WORK taken to reach the support is (take g = 10 ms~*) Q) wis @Q Ws @) In2s (4) 2s27, An ideal gas undergoes a quasi static, reversible process in which its molar heat capacity Cremains constant. If during this Process the relation of pressure P and volume Vis given by PV" =constant, then ais given by (Here Cp and Cy, are molar specific heat at constant pressure and constant volume, respectively) | a (2) @ (a) An observer looks at a distant tree of height 10 mwith a telescope of magnifying, power of 20. To the observer the tree appears : (1) 20 times taller. (2) 20 times nearer. G) 10 times taller, (4) 10 times nearer. 30, In an experiment for determination of sefractive index of glass of a prism by i— 6 plot, it was found that a ray incident at angle 35°, suffers a deviation of 40° and that it emerges at angle 79° In that case which of the following is closest to the smaximum possible value of the refractive indox ? () 17 Q 18 @ 15 (4) A pendulum clock loses 12 sa day if the temperature is 40°C and gains 4 5 a day if the temperature is 20°C. The tenperature at which the clock will show correct time, and. the co-efficient of linear expansion (@) of the motal of the pendulum shaft are respectively : (2) 30°C; @= 1.85 x10 (2) 39°C; a=1.83«10-2/9C @) °C; a=1.85x107-5 °C (4) orc ets lOc i H/Page 9 SPACE FOR ROUGH WORKPART B — MATHEMATICS 31, ‘The area (in sq. units) of the region {ecu:yte2vand 24 ye ay, 220, yao} (ay 7-2 mn 5-38 @ 7-4 a) #5 2 (2) hWJ)4 24) 3m #0, and ie S=freRi f(x)=/(-x)); then: (1) contains exactly two elements. (2) contains mote than two elements, (3) is an empty set. , (4) contains exactly one element 12 4 539 LB The integral | —2*— FS is! is equal J Pasay or a @ 8) io ——s+ afte) where C is an arbitrary constant.’ (a) H/Page 10 3B, SPACE FOR ROUGH WORK For x ¢ R, f(s)=llog2—sina| and sl) = fF), then = (2) 3(0)= ~cos(log2) (2) g is differentiable at x=0 and 8'(0) = ~sin(log2) a (ay g is not differentiable at x=0 ')* cos(log2) ‘The centres of those circles which touch the x+y 8x-8y-4=0, externally-and also touch the x-axis, lie on: circle, a) (2) @ parabola, a) a) a hyperbola, a ciscle, an-ellipse which is not a circle. The sum of all real values of x satisfying the equation at say 60 =1is: 4-545] O) 6 @ 3 @ 3 a -437. 3, H/Page 11 If the 24, 5!" and 9M terms of a non-constant AP. are in G.P,, then the common ratio of this G.P. is : aoa 2 a = 8 4 @ F wr 4S is 41. The eccentricity of the hyperbola whose length of the latus rectum is equal to 8 and the length of its conjugate axis ix equal to half of the distance between its foci, is = 2 o % Qs a 4 4 4) 3 ‘Ui the number of terms in the expansion of | 42. (- £ +4) £20, i 28, then the sum ety of the cpefficients of all the terms in this expansion, is (4) 243 QQ 729 B) 64 a 40. SPACE FOR ROUGH WORK ‘The Boolean Expression (pay)qv(-pagh Js equivalent to : a) pa @) py-4 (3) ~paq (4) pag Consider eay= an | 22), {a2} Anormal to y=f(x) at x = a also passes through the point : o (Fe) a (9) (3) (a) # (0%) tn is equal a @ 6)43. If one of the diameters of the circle, given | 46, by the equation, 17+ y*~4x-+6y—12=0, is. a chord of a circle S, whose centre is at (3, 2), then the radius of § is; m5 @ 10 (8) 5v2 ) 5N3 44, Let two fair six-faced dice A and B be thrown simultaneously. If E, is the event that die A shows up four, E, is the event | 47, that die B shows up twoand E, is the event that the stim of numbers on both dice is odd, then which of the following statements is NOT true ? (1) Fy and Ey are independent. (2) Ey, Ep and Ey are independent. "@) Fy and E, are independent. (8) Ey and By are independent 45. A value of @ for which 2+3/sin@ j, 1-2isind purely imaginary, is : (4) ™ ue sin! (%) oF a = H/Page 12 If the sum of the first ten terms of the series Os) ea ela) is = nt, then m is equal to ay 100 2) 99 @) 102 4) 101 ‘The system of linear equations atdy-zed Ax-y-2=0 xty-azeo has a noretrivial solution for : ( Q) (3) infinitely many values of A. exactly two values of A. exactly three values of A. (4) exactly one value of A. Ifthe tine, 53. Y*? er ea the plane, [x+my—2=9, then [+m is equal to: a) 5 (2) 2 (3) 26 (4) 18 274 tesin 3 SPACE FOR ROUGH WORK49, [fall the words (with or without meaning) having five letters, formed using theletters of the word SMALL and arranged as ina dictionary: then the position of the word SMALL is (ay 528d 2) 58th (3) seth (4) 59" 50, If the standard deviation of the numbers 2, 3, @and IT is 3.5, then which of the following is true? (1) 32340491 2) se 23044. @) 32-260 +55: (4) 3a? 32a + 84: 51. A wire of length 2 units is cut into two parts which are bent respectively to form a square of side=x units and a circle of radius=r units. If the sum of the areas of the square and the circle so formed is minimum, then : (ly x=2r (2) 2r=r Q) 2e=(w+a)r a d-a= or x 52, Let p= lim, (14tan?Je)** then log p is equal to: @ @) @ Delis 53. 34, 55. Let P be the point on the parabola, y?=8x ‘which is at a mininyum distance from the centre C of the circle, x7+(y+6)2=1. ‘Then the equation of the circle, passing through C and having its centre at P is a Pry Fay M0 (2) x2 +y?-454+9y4+18=0 (3) et +yt=ax+8y412=0 (4) x2 +y?-144y-12=0 Ifa curve y= f(x) passes through the paint (1, =1) and satisfies the differential ‘equation, y(l-+2y) dx=a dy, then 1 3) is equal ta - 2 qa) a 4 @ § 2 @ -= 4 ® -= Let @, 8 and ¢ bethree unit vectors such + fa — tat ¢x(Bxe] Bee u 2 + b is not parallel to c, 2 then the angle ‘between a and 6 is: a & @ = @ = @ = () \ _ "age 13 [= = UWSPACE FOR ROUGH WORK ‘ .87. 58. EA= [> 4 and A adj A=A AT, then Sa+h is equal to: a) 4 Q) 13 @) 1 @ 5 A man is walking towards a vertical pillar ina straight path, at @ uniform speed. At a certain point 4 on the path, he observes that the angle of elevation of the top of the pillar is 30°, After walking for 10 minutes from. A in the same direction, at a point B, he observes that the angle of elevation of the top of the pillar is 60°, Then the time taken (in minutes) by him, from B to reach the pillar, is: a) 20 @ 5 @) 6 () 10 ‘The distance of the paint (1, —5, 9) from the plane —y+z=5 measured aldng the Line x= y= is! ay (2) () © Wi0 (4) 10v3 5%. 60, Twosides ofa rhombus are along thelines, yoy+1=0 and 7x-y-5=0. If its diagonals intersect at (—1, —2), then which one of the following is a vertex of this rhombus ? @ 10 7 @ (as) @) (-3,-9 ) (3, -8) HOsx<2q, then the number of real values of x, which satisly the equation cost +cos2x+cos3x+ cose =0, is + a) 7 ey 9 eB 3 @ 5 H/Page 14 SPACE FOR ROUGH WORKPART C — CHEMISTRY 61. Two closed bulbs of equal volume (V) containing an ideal gas initially at pressure pand temperature T, are connected through 9 narrow tube of negligible volume as shown in the figure below. The temperature of one of the bulbs is then raised to T,, The final pressure pis : [eHtSHe 0 (8) ge) | (es) 3 a jot 62. Which one of the following statements about water is FALSE ? (1) There is extensive intramolecular hydrogen bonding in the condensed phase. (2) Tee formed by heavy water sinks in normal water. BY Water is oxidized to oxygen during photosynthesis, Water can act both as an acid and. as.a base. 63. 64. 65. In the Hofmann bromamide degradation reaction, the number of moles of NaOH and Br, used per mole of amine produced are (1) Two motes of NaOH and two moles of Br, (2) Four moles of NaOH and one mole of Br, . (3) One mole of NaOH and one mole of Br. (4) Four moles of NaOH and two moles of Br, Which of the following atoms has the highest first ionization energy ? ty) K Q) Sc B) Rb (8) Na ‘The concentration of fluoride, lead, nitrate and iron in a water sample from an underground lake was found to be 1000 ppb, 40 ppb, 100 ppm and 0.2 ppm, respectively. This water is unsuitable for drinking due to-high concentration of : (1) Nitrate (2) Iron (3) Fluoride AT Lead H/Page 15 SPACE FOR ROUGH WORK66. carbon monoxide are -393.5 and —283.5 kJ mol~', respectively. The heat ‘of formation (in kJ) of carbon monoxide per moleis: @ 6765 @ -105 @) 05 (a) 6765 70, 67. The equilibrium constant at 298 K for a reaction A+B=C+D is 100. If the initial concentration of all the four species were 1M each, then equilibrium concentration of D (in mol L~!) will be : ay 1.818 @ 1.182 6) (a) 0.818 0.182 71. 68. The absolute configuration of HH HOH H-—-al CH, is: @) 5,38) (2) PR, 3R) @) @R.35) (4) (25, 3R) H/Page 16 ‘The heats of combustion of carbon and | 69. For a linear plot of log (x/m) versus log p in a Freundlich adsorption isotherm, which of the following statements is correct? (k and m are constants) (1) Only 1/# appears as the slope (2) log (1/n) appears as the intercept, (3) Both k and 1/m appear in the slope term, (4) 1/n appeors as the intercept. ‘The distillation technique most suited for separating glycerol from spent-lye in the soap industry is : (i) Steam distillation (2) Distillation under reduced pressure (3) Simple distillation (4) Fractional distillation Which of the following is an anionic detergent ? (1) Cetyltrimethyl ammonium bromide 2) Glyceryl oleate (3) Sodium stearate (4) Sodium lauryl sulphate The species in which the N atom is ina state of sp hybridization is : @) Noy @ 8) : (4) -NO3 SPACE FOR ROUGH WORK73. Thiol 0) @ 8) @) 74, Whicl conee! a) (2) @) @ group is present in Cysteine Methionine Cytosine Cystine ‘h one of the following ores is best nitrated by froth floatation method ? Galena Malachite Magnetite Siderite 75. Which of the following statements about low di Q (2) @) @ 76. Whie metall Oy Q) (3) (4) H/Page 17 iensity polythene is FALSE 7 ts synthesis requires dioxygen or a peroxide initiator as a catalyst. It is weed in the manufacture of buckets, dust-bins etc Its synthesis requires high pressure, | Itis a poor conductor of electricity. h of the following compounds is lic ane! ferromagnetic ? vo, MnO, THO, cro, 77. The product of the reaction given below 1.NBS/ hw parte Aa 2. HyO/KxCO; 78, The hottest region of Bunsen flame shown in the figure below is region 4 region 3 — region 2 —— region 1 (1) region 3 (2) region 4 (3) region 1 (4) region 2 SPACE FOR ROUGH WORKG29, Av300 K and 1 atm, 15 ml of a gaseous | #1. The reaction of propene with HOC! hnydrocarbon requires 375 mL air (Cl,+H,0) proceeds through the containing 20% ©, by volume for complete intermediate = combustion. After combustion the gases ‘occupy 330 mL, Assuming that the water (1) CH 3-CH(OH)-CH3 formed is in liquid form and the volumes ‘were measured at the same temperature: (@) CHj-CHCI-CH} and pressure, the formula of the ‘hydrocarbon is )- CH,-CH*=CH,-OH (4) CH,-CH*-CH,-cI ay cy (2) CyHyp 82. 2-chloro-2-methylpentane on reaction Q) Cal : with sodium methoxide in methanol yields : @) C3Hg CH, 1 fa) C)HyCHyC-OCH3 CHy 80. The pair in which phosphorous atoms have a formal oxidation state of +3 is (©) GqHsCHC~ CH, CH (Q) Orthophosphorous and hypophosphoric acids da) G)HsCH=C-CHy (2) Pyrophosphorous and. CH, pyraphosphoric acids (1) only (3) Orthophespherous and pytaphosphorous acids (@) (a) and (b) (3) All of these (4) Pyrophosphorous and hypophospharric acids | (4) (a) and (¢) H/Page 18 SPACE FOR ROUGH WORK83. a5. Which one of the following complexes shows optical isomerism ? (1) frans|Co(en),ClJC1 (2) [CocNit,),c1,IC (8) (CofNH),Cl] (4) cis{Cofen},CL,ICi (en=ethylenediamine) The main oxides formed on combustion of Li, Na and K in excess of air are, respectively : (1) Lij0,, NajO, and KO, Q) Lig, NazO, and KO, (@) Li,0, Na,O and KO, (4) LiO,, NaO, and K,0 18 g glucose (C,H,,0,) is added to 178.2 g water. The vapor pressure of ‘water (in torr) for this aqueous solution is: (1) 7524 2) 759.0 6) 76 76.0 86. 87. 88. The reaction of zinc with dilute and concentrated nitric acid, respectively, produces : (1) NO and N,G (@) NO, and NO (3) N,O and NO, (4) NO, and NO Decomposition of H,O, follows a first order seaction. concentration of HO, decreases {rom 01.5 to 0.125 M in one such decomposition. When the concentration af HyO, reaches 0.05 M, the rate of formation of Q, will be: In fifty minutes the (Q) 2.66 L min~! at STP (2) 134x107? mol min7! (3) 693%10-? mel min~1 (4) 6.93x10-4 mol min=? The pair having the same magnetic moment is [AL.No,:Cr= 24, Mn =25, Fe =26, Co =27] Q) IMn@j0),°* and (Cr(H,0),P * (2) [CoC P~ and [Fe(H,0),/* (3) [CrH,0),)** and (CoC), )?~ (4) [Cr(4,0)_|?* and {Fe(H,0),)° * ‘H/Page 19 SPACE FOR ROUGH WORK89, Galvanization is applying a coating of: | 90. A stream of electrons from a heated ay @ (3) (a) Ca Zn cr filament was passed between two charged plates kept at a potential difference Vesu. Ife and m are charge and mass of an electron, respectively, then the value of hi/A (where A is wavelength associated with electron wave) is given by: GQ) dime a B) meV 4) Qmev -000- HyPage 20 ‘SPACE FOR ROUGH WORK