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1) State (a)Law of conservation of mass (b)Law of definite proportion (c)Law of multiple

proportions (d) Gay Lussacs law of gaseous volume (e) Avogadros law
2) A metal forms two oxides. The higher oxide contains 80% metal. 0.72g of the lower oxide
gave 0.8g of higher oxide when oxidised. Show that the data illustrates the law of multiple proportions.
3) Equal masses of oxygen, hydrogen and methane are taken in a container in identical
conditions. Find the ratio of the volumes of the gases.
4) The atomic masses of two elements (A and B) are 20 and 40 respectively. If x g of A contains
y atoms, how many atoms are present in 2x g of B.
5) How many atoms are present in 100amu of He?
6) How many g atoms are there in atom?
7) Insulin contains 3.4% sulphur. Calculate minimum molecular weight of insulin.
8) Calculate the total number of atoms in 0.5 mole of potassium dichromate.
9) What is the maximum number of moles of CO2 that could be obtained from the carbon in 4
moles of Ru2(CO3)3 ?
10) 4 g H2 reacts with 20g O2 to form water. How much water is formed?
11) It was found that 380ml of a gas at 270C and 800mm of Hg weighed 0.455g. Find the

molecular weight of the gas.


12) How many grams of MgSO4vwould contain the same mass of sulphur that is present in 200g

of FeSO4? (Mg=24, Fe=56, S=32, O=16)


13) How many moles of Al2O3 will be formed when a mixture of 5.4g of Al and 3.2 g of O 2 is

heated? [Al=27, O=16]


14) The vapour density of a mixture containing NO 2 and N2O4 is 38.3 at 270C. Calculate the mole

of NO2 in 100g mixture.


15) What is the simplest formula of a compound containing 50% of element A(atomic mass 10)

and 50% of element B(atomic mass 20)?


16) Calculate the amount of KClO3 needed to supply sufficient oxygen for burning 112L of CO gas

at S.T.P.(Atomic weight of K=39, Cl=35.5, O=16)


17) When 15g of a mixture of NaCl and Na 2CO3 is heated with dil HCl, 2.5g of CO 2 is evolved at

STP. Calculate % composition of the original mixture.


18) Brass is an alloy of Cu-Zn. A sample of brass weighing 6g when treated with excess of dil

H2SO4 gives 328ml of dry hydrogen gas at 270C and 760mm Hg pressure. Hat is the % of copper by

weight in the alloy?(Atomic mass of zinc is 65.4g, R=0.082L atm K -1mol-1)


19) Calculate the weight of CaO required to remove hardness of 16 6L of water containing 1.62g

of Ca(HCO3)2 in 1L.
20) A closed vessel is found to contain 1g of Mg and 0.5g of oxygen. The mixture is burnt.
(a) Which is the limiting reagent?
(b) Find the weight of the excess reagent.
(c) How many mL of M/4 solution of H2SO4 will dissolve the residue in the vessel?
21) Define (a)molarity (b) molality (c) mole fraction (d) limiting reagent
22) Calculate the number of sulphate ions in 100ml of 0.001M H 2SO4 solution.
23) Concentration of glucose in blood is approximately 90mg/100ml. find the molarity of the

glucose solution in blood.


24) A solution of glucose in water is labelled as 10%(w/w). The density of the solution is

1.20g/ml. Calculate the molality, molarity and mole fraction of each component in solution.
25) Calculate the molality of solution of ethanol in water in which the mole fraction of ethanol is

0.04.(density of water = 1g/cc)


26) If the density of methanol is 0.8kgL-1, what is the volume needed for making 2.5L of its 0.25M

solution?
27) A commercial sample of oxalic acid is labelled as 22.5% by w/w (density 1.5g/cc). Calculate

(a) molarity (b) volume of acid required to prepare 1L of 0.2M oxalic acid, H 2C2O4.
28) The density of 3M solution of NaCl is 1.25g/ml. Calculate the molality of the solution.
29) What volume of 10M HCl and 3M HCl should be mixed to obtain 1L of 6M HCl solution?
30) How are 0.5mol Na2CO3 and 0.50M Na2CO3 different?

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