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CHEM 212 (DE) Final Exam

Make sure your bring


your UW ID card
a calculator
molecular model kit (optional)

Format
The exam consists of 10 questions, and you must do any 7 of the 10 questions. Each question is worth
15 marks. The exam will be marked out of 105. The front page of the exam, including instructions is
given on the last page of this booklet.) The exam is cumulative. Here is a more detailed breakdown.
Module 2: Symmetry two questions
Module 3: Quantum theory and atomic structure two questions
Module 4: Ionic compounds and ionic bonding one question

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Module 5: Valence bond theory one questions

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Module 6: Molecular orbital theory four questions

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There are no true/false questions and no multiple-choice questions. All of the questions are short-answer

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or long-answer. I strongly advise you to review all of the examples done in the modules, and to review all

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of the assignments problems. There is no sample exam! The exam questions are similar to questions
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you have done on your assignments.

Solutions to all of assignments, including answers to the extra problems, have been posted on UW-
ACE.
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**** The next three pages show you what information you will be provided with on the exam. ****
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After the exam has been marked, you will be able to view a complete summary of your marks in CHEM
212 (i.e. one minute summary marks, assignment marks, exam mark and final grade) at the web-site
below.
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http://scienide.uwaterloo.ca/~cbissonn/chem212de/
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Make sure you check your marks summary to ensure that your assignment grades have been recorded
correctly.
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https://www.coursehero.com/file/6348538/Final-Exam-Information/
S
CHEM 212 DATA BOOKLET
1 18
1A 8A
1 2
H 2 13 14 15 16 17 He
1.008 2A 3A 4A 5A 6A 7A 4.003
3 4 5 6 7 8 9 10

A
Li Be B C N O F Ne
6.941 9.012 10.81 12.01 14.01 16.00 19.00 20.18
11 12 13 14 15 16 17 18
Na Mg 3 4 5 6 7 8 9 10 11 12 Al Si P S Cl Ar
22.99 24.31 3B 4B 5B 6B 7B 8B 1B 2B 26.98 28.09 30.97 32.07 35.45 39.95
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
39.10 40.08 44.96 47.88 50.94 52.00 54.94 55.85 58.93 58.69 63.55 65.38 69.72 72.59 74.92 78.96 79..90 83.80
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54

M
Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
85.47 87.62 88.91 91.22 92.91 95.94 (98) 101.1 102.9 106.4 107.9 112.4 114.8 118.7 121.8 127.6 126.9 131.3
55 56 (57-71) 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86

m
Cs Ba La-Lu Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn

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132.9 137.3 178.5 180.9 183.9 186.2 190.2 192.2 195.1 197.0 200.6 204.4 207.2 209.0 (209) (210) (222)
87 88 (89-103) 104 105 106 107 108 109 110 111 112 113

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Fr Ra Ac-Lr Rf Db Sg Bh Hs Mt Uun Uuu Uub Uut

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(223) 226

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Constants
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Conversion factors
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(in SI units) 1 a.m.u. = 1.66056 1024 g
ao 0.529177 1010 m = 1.66056 1027 kg
me 9.109534 1031 kg
1.60211 1019 C = 1.60219 1012 erg
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e 1 eV
1.11265 1010 C2 J1 m1 = 1.60219 1019 J

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o 8.85419 1012 C2 J1 m1 = 8065.48 cm1
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h 6.626176 1034 J s
RH 2.179 1018 J 1 pm = 1012 m
c 2.997925 108 m s1 1 nm = 109 m
6.022045 1023 mol1
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NA
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Equations

me e 4
( )
nx h2 n2 ( 2no )! EA N Z + Z e2 1
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RH = n = 2
sin En = N= Uo = 1
8 o2 h 2 L L 8mL2 ne !( 2no ne ) ! 4 o (r+ + r ) n
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Do not bring to exam


Values of the Born Exponent Madelung Constants

Ion Born exponent Structure A


configuration (n) NaCl 1.74756
He 5 CsCl 1.76267
Ne 7 ZnS 1.63806
Ar 9 CaF2 2.51939
Kr 10
Xe 12

https://www.coursehero.com/file/6348538/Final-Exam-Information/
START

S Is the molecule
linear?
yes Does the
molecule
possess a
yes
Dh

no

A
no

Is the molecule a perfect


tetrahedron, octahedron
or icosahedron?
yes
Cv

Td or Oh or Ih

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no

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Does the molecule yes Are there n C2 yes yes
Is there a h Dnh
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possess a Cn axis, with
plane?
n 2? Cn axis?
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no no
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no
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yes yes

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Is there an S2n Are there n v Dnd


axis? planes?
yes
Is there a mirror plane?
no
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no
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S2n Dn

no Cs
Is there a h
yes
Cnh
E
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plane?
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Is there a centre of yes


inversion? no

no Are there n v
yes
Cnv
planes?
C1 Ci
no

Cn

Do not bring to exam


https://www.coursehero.com/file/6348538/Final-Exam-Information/
S Selected Character Tables

C2h
Ag
Bg
E
1
1
C2
1
1
i
1
1
h
1
1
C2v
A1
A2
E
1
1
C2
1
1
v(xz)
1
1
v(yz)
1
1
Au 1 1 1 1 B1 1 1 1 1
Bu

D2h
Ag
B1g
1

E
1
1
A 1

C2(z)
1
1
1

C2(y)
1
1
C2(x)
1

1
1
i
1
1
B2

(xy)
1
1
1

(xz)
1
1
1

(yz)
1
1
1 1

B2g
B3g
1
1
1
1
1
1
M 1
1
1
1
1
1
1
1
1
1

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Au 1 1 1 1 1 1 1 1

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B1u 1 1 1 1 1 1 1 1

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B2u 1 1 1 1 1 1 1 1

P
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B3u 1 1 1 1 1 1 1 1
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Valence Orbital Ionization Energies (in eV)
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Atom 1s 2s 2p

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3s 3p
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H 13.6
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He 24.6
Li 5.4
Be 9.3
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B 14.0 8.3

E
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C 19.4 10.6
N 25.6 13.2
O 32.3 15.8

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F 40.2 18.6
Ne 48.5 21.6
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Na 5.1
Mg 7.6
Al 11.3 5.9
Si 14.9 7.7
P 18.8 10.1
S 20.7 11.6
Cl 25.3 13.7
Ar 29.2 15.8

Do not bring to exam


https://www.coursehero.com/file/6348538/Final-Exam-Information/
University of Waterloo
Final Examination
Fall Term 2008

Course Number CHEM 212 (DE)

Course Title Inorganic Structure and Bonding 1

Section 081

Instructor C. Bissonnette

Duration of Exam 2 hours

Number of Exam Pages 11

Exam Type Closed book

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Additional Materials Allowed Calculator, Molecular Models, Data Booklet (supplied)

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Student Name

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Given name(s) Surname

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Student ID Number

Signature
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INSTRUCTIONS
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Non-programmable, non-graphing calculators are permitted. Laptop and notebook computers are not.
This Exam Booklet and the Data Booklet must be returned. The Exam Booklet has 11 pages. The
Data Booklet has 3 pages.

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The Data Booklet has a periodic table, fundamental constants, conversion factors and key formulas,
the Point Group Decision Tree, a table of VOIEs, a few character tables, Born exponents and
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Madelung constants.
Do all work on this Exam Booklet. Scrap paper is not allowed. You must provide neat and
organized solutions.
Do any seven (7) of the ten (10) questions. All questions are worth 15 marks each. If you do more
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than seven questions, only the first seven questions attempted will be marked.
Indicate which questions you did by circling six of the numbers below.
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1 2 3 4 5 6 7 8 9 10
(circle only seven numbers)

Do not write in this box.

1. / 15 5. / 15 9. / 15

2. / 15 6. / 15 10. / 15

3. / 15 7. / 15

4. / 15 8. / 15 Total: / 90

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