SALT ANYALSIS

ACID RADICAL

1.salt + dil. H2SO4 ------------- brisk efference of CO3-2

(Carbonate)

If no response heat it.

salt +dil.H2SO4 ------------ smell of acteate (CH3COO-) OR SMELL OF

ROTTEN EGG (SULPHITE)

2. REACTION WITH CONC.H2SO4

SALT + CONC.H2SO4 -------------- PUGENT SMELL + COLOURLESS FUME

*GIVES WHITE FUME AMMONIUM HYDROXIDE

OR

*PUGENT SMELL WITH REDDISH BROWN (DOESNOT CHANGE FESO4)

FUME (BROMIDE)

OR

*PUNGENT SMELL WITH VIOLET VAPOUR (IODIDE)

OR

*PUNGENT SMELL WITH REDDISH BROWN GAS WHICH TURNS FESO4

SOL.BLACK. (NITRATE)

CONFIRMATIVE ---------------- AG. SALT + AGNO3 WHITE PPT

(CHLORIDE)

OR

YELLOW PPT SLIGHTLY SOLUBLE IN AMMONIUM HYDROOXIDE

(BROMIDE)

OR

YELLOW PPT IN-SOLUBLE IN AMMONIUM HYDROOXIDE (IODIDE)

OR

ag.SOL + FESO4 [FRESHLY PREPARED] + CONC. H2SO4 ----------------

[BY THE SIDE OF TESTUBE] BROWN RING AT THE FUNCTION OF TWO
LIQUID (NITRATE)

3.TEST OF SULPHATE SO4-2

ag.SOL. + BACL2 ------------ WHITE PPT (SULPHATE)

4. TEST OF PHOSPHATE PO4-3

SALT + CONC.HNO3 + AMMONIUM MOLYBDATE -------------- YELLOW

PPT [PO4-3]

BASIC RADICAL

ZERO GROUP

SALY + NAOH -------------- SMELL OF AMMONIUM GAS [NH3]

BROWN PPT ------------------ NH3 CONFIRMED

FIRST GROUP

O.S + DIL. HCL -------- WHITE PPT -------- KI OR K2Cr2O4 ------YELLOW

PPT ------- PB2+ CONFIRM

SECOND GROUP

CU2+ DISSOLVE BLACK PPT IN HNO3---HEAT----- 1. ADD ACETIC ACID

& PPT SEROCYNIDE

[BROWN PPT]

2. ACETIC
ACID + KI -------- WHITE PPT

AS3+ BROWN PPT DISSOLVE IN HNO3 AMMONIUM

MOLYIDAL [YELLOW PPT]

CA2+ YELLOW PPT DISSOLVE IN HNO3 AMMONIUM

MOLYIDAL [YELLOW PPT]

THIRD GROUP

O.S + NH4CL(S) + NH4OH----------------- 1. WHITE PPT [AL3+] 2.

BROWN PPT [FE3+]

CONFIRMATIVE

AL3+ ------------- WHITE PPT -----DIL.HCL---- DISSOLVE 2-3 DROPS

BLUE LITMUS SOLUTION -----

-------------
NH4OH DROPWISE BLUE COLOUR
FE3+ -----BROWN PPT ----DIL.HCL----- DISSOLVE POT FERROYOND ------
PARRISAN BLUE COLOR

FORTH GROUP

O.S + NH4CL + NH4OH +H2S --------- 1. WHITE PPT [AL3+] 2. BLACK

[NI2+, CO2+]

3. FLESH COLOUR +
LIGHT BROWN [ MN2+]

NI2+----- O.S + NH4OH + FEW DROPS OF DIMETHYLGLYOIME --------

BRIGHT RED PPT [NI2+]

ZN2+ ------ O.S + NAOH -------- WHITE PPT ZN2+ CONFIRMED

CO2+ -------- O.S + NH4OH + DIL. ACETIC ACID + KNO3 ---------

YELLOW PPT CO2+

Mn2+ + O.S + NAOH ---------- WHITE PPT ---BR2 / WATER ---- BALCK
OR BROWN PPT

FIFTH GROUP

O.S + NH4CL + NH4OH + (NH4)2CO3 SOL. --------- WHITE PPT Ba2+,

Sr2+ , Ca2+

1. 2-3 DROPS POTASSIUM CROMATE---------- YELLOW PPT [Ba2+]

2. 1-2 ml AMMOUNATE SOL. + 1 ML NH4OH SOL. ------- WHITE PPT BY

THE SIDE OF TEST TUBE

3. 1 ML OF AMM. SULPHATE SOL. --------- WHITE PPT [Sr2+]

SIXTH GROUP

O.S + NH4CL +NH4OH +AMM. PHOSPHATE ------- SCRATCH THE SIDE

OF TEST TUBE BY GLASS ROD [Mg2+]