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NAME: ________________________________ June 2005

St. Charles College


Final Exam SCH 12U
Teacher: Mrs. D. Johnston Time: 2 hours
Marks: 90

Instructions: 1: Please answer Part A on the answer sheet, Parts B & C in the space provided,
Part D on foolscap and graph paper.
2: Use the proper problem solving format when completing problems that involve
calculations, including significant digits.
4: The only resources allowed are a calculator and the resource booklet provided.
5: At the end of the exam, detach Parts B and C from the exam booklet, and arrange
the pages in the following order: Answer sheet, Part B, Part C, foolscap, Part A,
Part D, reference booklet. DO NOT STAPLE PAGES.
WRITE YOUR NAME ON EVERY PAGE TO BE EVALUATED.

PART A MULTIPLE CHOICE (30)


1. Which molecule is polar?
a. carbon dioxide
b. carbon tetrachloride
c. propane
d. methyl chloride
e. butane
2. Infrared spectroscopy allows researchers to determine the kinds of bonds and the functional groups that are
present in a molecule. What does infrared spectroscopy measure?
a. the absorption of white light
b. bond stretching, bending, and vibrating
c. the degree of absorption of infrared light
d. the emission of infrared light from the organic molecule
e. the emission of full-spectrum light from a sample
3. Which compound is formed by the oxidation of a secondary alcohol?
a. tertiary alcohol
b. aldehyde
c. carboxylic acid
d. primary alcohol
e. ketone
4. Which statement describes condensation polymers?
a. They are made of monomers that have two functional groups.
b. They may form between an organic acid and an amine.
c. Two examples are nylon and polyester.
d. When they are produced, a small molecule (such as water, ammonia, or ethanol) is also
produced.
e. all of the above
5. Which statement is correct?
a. Aldehydes strongly resist oxidation.
b. Ketones are easily oxidized.
c. Carboxyl groups are easily oxidized.
d. An ester may be hydrolyzed to give a carboxylic acid and an alcohol.
e. Amides will not react with water.
6. Amino acids are the monomers that are found in proteins. What feature do all amino acids share?
a. the same side chains attached to the amino group
b. alcohol and amino groups attached to the central carbon
c. different side chains attached to the central carbon
d. carboxylic acid groups attached to an amino group
e. carboxylic acid and amide groups
7. Which scientist postulated that electrons can only move between certain energy levels?
a. Rutherford
b. Dalton
c. Einstein
d. Schodinger
e. Bohr

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NAME: ________________________________ June 2005

8. Which element has the ground state electron configuration [Ne] 3s 23p x13p y1 for its valence electrons?
a. Mg
b. Al
c. Si
d. P
e. S
9. Which sublevel, when full, corresponds to the lanthanide series of elements?
a. 3d
b. 3f
c. 4d
d. 4f
e. 5f
10. How does atomic radius change from left to right across a period in the periodic table?
a. It increases.
b. It decreases.
c. It stays the same.
d. It increases and then decreases.
e. It decreases and then increases.
11. A solid compound consists of ions bound in a crystal lattice. Which property would you not expect this solid
to have?
a. high melting point
b. good conductivity in the solid state
c. hard
d. soluble in a polar solvent
e. brittle
12. Which process produces the most energy?
a. cooking
b. chemical reaction
c. physical change
d. dissolution
e. nuclear reaction
13. Which substance has a standard enthalpy of formation, DH 0f , equal to zero?
a. gold, Au (s)
b. water, H 2O (l)
c. carbon monoxide, CO (s)
d. zinc, Zn (g)
e. water, H 2O (g)
14. 150.0 mL of water absorbs 7.84 kJ of energy. The specific heat capacity of water is 4.184 J/gC. What is the
temperature change?
a. 0.0125C
b. 12.5C
c. 353 K
d. 80C
e. 80 K
15. When a sample of potassium nitrate is dissolved in water, the temperature of the water changes from 23.5C
to 20.3C. Which statement describes this process?
a. This process is exothermic, so the surroundings get cooler.
b. This process is exothermic, so the surroundings get warmer.
c. This process is endothermic, so the surroundings get cooler.
d. This process is endothermic, so the surroundings get warmer.
e. None of the above options can be known for sure.
16. Which statement does not represent a rate?
a. The speed of a car is 45 km/h.
b. The half-life of an element is 12.4 h.
c. A family consumes 4 L of milk every three days.
d. It takes 15 min to walk to the store.
e. A cat eats three cans of wet food per week.
17. Which statement about the factors that affect reaction rates is false?
a. Decreasing the concentrations of the reacting particles decreases the chance of collision.
b. A collision with poor orientation requires a higher activation energy than a collision with
optimum orientation.
c. Increasing the pressure in a gaseous reaction increases the chance of collision.
d. A reaction occurs every time particles of the reactants collide.
e. Increasing the temperature increases the reaction rate.

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NAME: ________________________________ June 2005

Potential Energy Diagram

18. Use the Potential Energy Diagram. What is shown by the letter B?
a. the activation energy of the forward reaction
b. the activation energy of the reverse reaction
c. the transition state
d. the heat of reaction
e. the entropy of the reaction
19. Use the Potential Energy Diagram. What is shown by the letter C?
a. the activation energy of the forward reaction
b. the activation energy of the reverse reaction
c. the transition state
d. the heat of reaction
e. the entropy of the reaction

20. The isotope has a half-life of 165 days. The isotope has a half-life of 330 days.
Which statement about these two isotopes is false?
a. One year represents slightly more than two half-lives of a sample of the calcium isotope.
b. Almost all of 100 g of the calcium isotope will decay in one years time.
c. 100 g of the vanadium isotope will decay to somewhat less than 50 g in a year.
d. The calcium isotope decays at twice the rate of the vanadium isotope.
e. All of these statements are true.

Redox Equation:
KMnO 4 + HCl KCl + MnCl2 + Cl2 + H 2O

21. Use the Redox Equation. Which reactant is the oxidizing agent?
a. K +
b. KMnO 4
c. HCl
d. Cl-
e. Cl2
22. Which substance is the reducing agent in the following equation?
PbO 2 + Pb + 4H + 2Pb 2+ + 2H 2 O
a. Pb
b. PbO 2
c. H +
d. Pb 2+
e. H 2O
23. In which redox equation is the substance on the left reduced? (The equations are not balanced.)
a. Fe 2+ Fe 3+
b. NO 2 N 2 O 2 -
c. NH 3 NH 4
d. H 2O O 2 + 4H +
e. H 2SO 4 + NaOH H 2O + Na + + SO 42-
24. Which substance is the strongest oxidizing agent?
a. Fe
b. Br2
c. Cu 2+
d. Zn 2+
e. H 2

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NAME: ________________________________ June 2005
25. A galvanic cell has a solid lead electrode in a solution of 1.0 mol/L Pb(NO 3)2 and a solid zinc electrode in a
solution of 1.0 mol/L Zn(NO 3)2. What reactant will be reduced?
a. Zn 2+
b. Pb 2+
c. Pb
d. Zn
e. NO 3-
26. A galvanic cell involves the following reaction. If the silver-copper cell is run long enough for a change of
1.08 g at the silver electrode, what will the change in mass at the copper electrode be?
2Ag + (aq) + Cu (s) 2Ag (s) + Cu 2+ (aq)
a. 1.08 g loss
b. 1.08 g gain
c. 0.32 gain
d. 0.63 g gain
e. 0.32 g loss
27. Which redox reaction is not spontaneous under standard conditions?
a. 2Fe + 3Br2 2Fe 3+ + 6Br-
b. 2Fe 3+ + 3Ni 2Fe + 3Ni2+
c. Fe 2+ + Ni Fe + Ni2+
d. 2Fe 3+ + Ni 2Fe 2+ + Ni2+
e. All of these reactions are spontaneous.
28. Which statement about electrolytic cells is not correct?
a. Electrons always flow from the anode.
b. The standard cell potential of an electrolytic cell is negative.
c. In an electrolytic cell, electroplating occurs at the cathode.
d. Reduction occurs at the cathode.
e. Oxidation occurs at the cathode.
29. Which situation represents an equilibrium system?
a. Water is running out of a tap into a bathtub at the same rate as water is draining out of the
bathtub.
b. CFCs are catalyzing the breakdown of ozone into oxygen gas at the same time as lightning
is creating ozone from oxygen gas.
c. Water is evaporating from a lake, and water vapour is condensing at the surface of the
lake.
d. Sugar in tea is dissolving into solution at the same rate as sugar is crystallizing out of
solution.
e. Rain falling on the ground makes mud puddles.
30. What is the correct equilibrium constant expression for the following reaction?
2NCl3(g) N 2(g) + 3Cl2(g)
a.

b.

c.

d.

e.

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NAME: ________________________________ June 2005

PART B SHORT ANSWER (25)


For the following questions, write the most appropriate answer in the space provided.

1. Why are amides polar? (3)

2. What are the three different molecular shapes that can occur with a tetrahedral geometric arrangement of
electron groups? (3)

3. Write the line structural formula of each compound. (3)


a) an alcohol derived from butane

b) an aldehyde derived from butane

c) an acid derived from butane

4. Polyester is made from the following monomers.

a) What is the structure of the repeating unit in polyester? (2)

b) What type of polymerization reaction is this? (1)

5. The neutralization of nitric acid with potassium hydroxide has an enthalpy change of -53.4 kJ/mol. Write a
thermochemical equation for this reaction. (3)

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NAME: ________________________________ June 2005
6. The reactant concentration of a first-order reaction is 0.05 mol/L, and the rate constant is 0.25 s- 1. What is the
rate of this reaction? (3)

7. What is the equilibrium constant expression for the following equilibrium reaction?
H 2O (g) + Cl2O (g) 2HOCl(g) (1)

8. If an acid dissolves a metal, has a redox reaction occurred? If so, what has been reduced and what has been
oxidized? Use Mg and HCl as reactants. (3)

9. Describe how cathodic protection prevents the corrosion of iron. Provide an example of a metal that is used in
cathodic protection. (3)

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NAME: ________________________________ June 2005

PART C ORGANIC NOMENCLATURE & REACTIONS (10)


1. Complete the following table. (5)

Reaction Type of reaction Class of organic product

2. Complete the following table. (5)

Name Structural diagram Class

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NAME: ________________________________ June 2005
2-fluoro-3,3-dimethylbutanal

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NAME: ________________________________ June 2005
4-methylpentanamide

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NAME: ________________________________ June 2005
meta-dimethylbenzene

CH 3 CH 2 )O)CH 2 CH 2 CH 3

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NAME: ________________________________ June 2005

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NAME: ________________________________ June 2005

PART D MAKING CONNECTIONS (25)


For the following questions, write the answer on foolscap. Use complete sentences in your answer. If the question
requires mathematical calculations, show all of your work. Write a final statement that gives your solution.

1. Balance the following redox reaction using the half-reaction method under acidic conditions.
FeAsS + NO 3- Fe 3+ + SO 42- + H 3AsO 4 + NO (5)

2. How long does it take to deposit 1.35 g of nickel from a solution of Ni(NO 3)2 onto the cathode of an
electrolytic cell, using a current of 1.50 A? Express your answer in minutes.
(Faraday Constant = 96 000 C/mol) (5)
3. Plants produce glucose from carbon dioxide, water, and sunlight. (5)
6CO 2(g) + 6H 2O (l) C 6 H 12O 6(s) + 6O 2(g)
a) The heat of formation of glucose is -1274.5 kJ/mol. Use this heat of formation, and standard enthalpies of
formation, to determine how much energy is needed from the Sun to make one mole of glucose.
b) Plants produce about 7.0 10 14 kg of glucose a year, using solar radiation. How much solar radiation is
used?

4. The two substances in the following table have similar molecular masses but very different boiling points.
Explain how this is possible. (5)

Name Formula Molecular mass Boiling point


ethanol CH 3 CH 2 OH 46.0 u 78.5/C
carbon dioxide CO 2 44.0 u -78.5/C

5. The data in the table below were collected for the following reaction.
2HI(g) H 2(g) + I2(g) (5)

Concentration of HI (mol/L) Time (s)


0.1000 0
0.0715 50
0.0558 100
0.0457 150
0.0387 200
0.0336 250
0.0296 300

a) Plot the data on the graph paper provided.


b) What is the rate of the reaction at 100 s? Do the calculation on the graph paper.
c) On your graph, sketch the change in concentration H 2(g) over time.

At the end of the exam, detach Parts B and C from the exam booklet, and arrange
the pages in the following order:
Answer sheet, Part B, Part C, foolscap, Part A, reference booklet.
DO NOT STAPLE PAGES.
WRITE YOUR NAME ON EVERY PAGE TO BE EVALUATED

Its been a pleasure working with you.


Have a good holiday.
Good luck next year.
Come back and visit.
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NAME: ________________________________ June 2005

St. Charles College


Final Exam 12U Chemistry

ANSWER SHEET

PART A MULTIPLE CHOICE

1. _______ 2. ______ 3. ______ 4. _____ 5. _____ 6. ______

7. ______ 8. ______ 9. _____ 10. _____ 11. ______ 12. ______

13. ______ 14. _____ 15. _____ 16. ______ 17. ______ 18. ______

19. _____ 20. _____ 21. ______ 22. ______ 23. ______ 24. ______

25. _____ 26. ______ 27. ______ 28. ______ 29. ______ 30. _____

PART A __________/30
MARKS

PART B ___________/10

PART C ___________/25

PART D ___________/25

TOTAL __________/90

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NAME: ________________________________ June 2005

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