18.27 All these runs were made at the same W/Fao.

We are also told that the recycle rate is

high enough to have mixed flow throughout. Thus changing the recycle rate from rum 1 to 2,
or from run 3 to 4 with no change in rate shows that film resistance does not influence the
rate.

Next, if the particles were no-porous then the smaller size (runs 1 e 2) should have double the
rate of the larger size ( runs 3 e 4)This is not what is measured hence the results are not
consisten with the guess of non-porous particles.

Alright, let us see if the results are consistent with the assumption of porous particles.

- if in the regime of no pore diffusion resistance the rates should be the same for large e small
pellets

- if in the regime of strong pore diffusion the rate should halve from 4 to 2 in going to the large
particles

Our results are 1/2 way. between these two extremes, hence we must be operating under
conditions where pore diffusion is just beginning to influence the rate.

Thus we conclude:

Porous particles, no film resistence, pore

resistance just beginning to intrude e affed the rate

traduo:

Todas estas corridas foram feitas no mesmo W / Fao. Tambm nos dito que a taxa de
reciclagem alta o suficiente para ter fluxo misturado em toda. Assim, mudar a taxa de
reciclagem do rum 1 para 2, ou da corrida 3 para 4 sem alterao na taxa mostra que a
resistncia do filme no influencia a taxa.

Em seguida, se as partculas no eram porosas, ento o tamanho menor (corridas 1 e 2) deve

ter o dobro da taxa do tamanho maior (corridas 3 e 4). Isto no o que medido, portanto, os
resultados no so consistentes com a suposio de Partculas no porosas.

Certo, vamos ver se os resultados so consistentes com a suposio de partculas porosas.

- se no regime de ausncia de resistncia difuso dos poros as taxas deveriam ser as mesmas
para as grandes e pequenas pastilhas
- se no regime de difuso de poros forte a taxa deve reduzir para metade de 4 para 2 em ir
para as partculas grandes

Nossos resultados so meio caminho. Entre esses dois extremos, portanto, devemos estar
operando em condies onde a difuso de poros est apenas comeando a influenciar a taxa.

Assim, conclumos:

Partculas porosas, sem resistncia ao filme, poros

Resistncia apenas comeando a se intrometer e afetou a taxa