DEGALAN - Binders For Heat Sealing Applications Without Films 2008 12 15

DEGALAN -
Binders for Heat Sealing

Applications
Michael Wicke
Jrgen Hartmann
Dr. Bruno Keller
Evonik Rhm GmbH Darmstadt
Platzhalter Bild
Who makes films

and foils pealable?
We do.
Platzhalter Bild
Who makes Aluminuim

stick to blister?
We do.
DEGALAN
Binders for Heat Sealing Applications
The Products The Advantages

DEGALAN P 24 DEGALAN Binders for heat sealing applications provide
a secure sealing for pharmaceutical blister and food
DEGALAN LP AL 23 packaging.
DEGALAN 4792 L These products show excellent seal & peel properties on
DEGALAN 4793 L aluminum foil or film structures like PET.
DEGALAN PM 555 Easy opening to high sealing strength are available.
DEGALAN PM 666 Various substrates like polystyrene or polyvinylchloride

are sealable.
DEGALAN 4150 E
Even non polar substrates like polypropylene are
DEGALAN 4151 E sealable.
DEGALAN VP 4177 E Modern systems with direct adhesion to Aluminum or
PET provide economical and environmental friendly
DEGALAN VP 4174 E packaging solutions.
DEGALAN 4140 D All binders comply with international Food Regulations.
DEGALAN 4032 D
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DEGALAN - Product Range
Product Appearance Solid content Solvent
DEGALAN P 24 Bead Polymer 100 -
DEGALAN LP AL 23 100 -
DEGALAN 4792 L Organic Solution 55 methyl ethyl ketone (MEK)
DEGALAN 4793 L 55 ethyl acetate
DEGALAN PM 555 Organic Dispersion 45 butyl acetate/ MEK 70/30
DEGALAN PM 666 45 butyl acetate/ MEK 70/30
propyl acetate/ ethyl acetate/ iso octane

DEGALAN 4150 E 43
54,0/ 36,5/ 9,5
DEGALAN 4151 E 40
47,8/ 43,8/ 8,4
DEGALAN VP 4177 E 43 tert. butyl acetate/ ethyl acetate 63,5/ 36,5

DEGALAN VP 4174 E 45
54,0/ 36,5/ 9,5
DEGALAN 4140 D Aqueous Dispersion 50 Water
DEGALAN 4032 D 50 Water

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The Product Appearance

The Product Packaging
Bead Polymers
25 Kg Paper Bags 500/750/1000 Kg/Pallet
325 Kg Big Bags
850 Kg Big Bags
Solution Polymers
175 Kg SF 29 Steel Drums 700 Kg/Pallet
850 Kg KOMBI-IBC PE/ME
Minimum Order Size: 2 Pallets

DEGALAN - Properties Summary
Product Adhesion to Sealable versus Remarks

Primering Primering Formulation
Alu necessary?
PET necessary? required?
PVC PS PP PET
yes, or in yes, PVC
yes, with
DEGALAN P 24 + combination with + copolymer to + + - -
Polyester
PVC copolymer achieve adhesion
yes, or in yes, PVC US Drug Master File
yes, with
DEGALAN LP AL 23 + combination with + copolymer to + + - - listed for
Polyester
PVC copolymer achieve adhesion pharmaceutical purpose


Alu necessary?
PVC PS PP PET
yes, or in yes, PVC
yes, with
Polyester
yes, with
Polyester
DEGALAN 4792 L yes, or in yes, PVC

yes, with
+ combination with + Polyester
copolymer to + + - - Easy opening system
DEGALAN 4793 L PVC copolymer achieve adhesion


Alu necessary?
PVC PS PP PET
yes, or in yes, PVC
yes, with
Polyester
yes, with
Polyester

yes, with
DEGALAN PM 555 yes, or in Universally applicable

yes, with
+ combination with + Polyester No + + + +
DEGALAN 4150 E PVC copolymer 4150 E acceptable smell
yes, or in
yes, with PM 555" analogue with
DEGALAN VP 4177 E + combination with + No + + + +
Polyester easy drying properties
PVC copolymer


Alu necessary?
PVC PS PP PET
yes, or in yes, PVC
yes, with
Polyester
yes, with
Polyester

yes, with

yes, with
yes, or in
PVC copolymer
DEGALAN PM 666 no, because of yes, with "PM 555/4150 E" analogue
+ direct adhesion
+ Polyester No + + + + with direct adhesion to Alu
DEGALAN 4151 E


Alu necessary?
PVC PS PP PET
yes, or in yes, PVC
yes, with
Polyester
yes, with
Polyester

yes, with

yes, with
yes, or in
PVC copolymer
+ direct adhesion
DEGALAN 4151 E
no, because of no, because of Universally applicable
DEGALAN VP 4174 E + + No + + + +
direct adhesion direct adhesion direct adhesion to Alu or PET


Alu necessary?
PVC PS PP PET
yes, or in yes, PVC
yes, with
Polyester
yes, with
Polyester

yes, with

yes, with
yes, or in
PVC copolymer
+ direct adhesion
DEGALAN 4151 E
no, because of no, because of Universally applicable
DEGALAN VP 4174 E + + No + + + +
direct adhesion direct adhesion direct adhesion to Alu or PET
no, because of no, because of Primer for 4032 D,
DEGALAN 4140 D + + No + + - (+)
direct adhesion direct adhesion direct adhesion to PLA
DEGALAN 4032 D + Yes - - - + + - -

DEGALAN - Easy to Process
Heat Sealing Lacquer

Preparation
Coating on Aluminium
with the Hand Coater

DEGALAN -
the Classical Acrylic Binders
DEGALAN P 24, DEGALAN LP AL 23

Bead polymer based on n-butyl methacrylate
Structure of coating:
Base Aluminium
Intermediate layer Primering with PVC Copolymer
Heat seal layer DEGALAN P 24, DEGALAN LP AL 23
Sealing substrate PVC, PS
Alternatively:
Base Aluminium
Intermediate layer Primering not necessary
Heat seal layer DEGALAN P 24, DEGALAN LP AL 23
with PVC Copolymer
Use for food packaging and pharmaceutical blister

DEGALAN -
the Easy Opening Acrylic Binders
DEGALAN 4792 L, DEGALAN 4793 L

Organic solution of an acrylic polymer based on ethyl methacrylate
Base Aluminium
Intermediate layer Primering with PVC Copolymer
Heat seal layer DEGALAN 4792 L, DEGALAN 4793 L
Alternatively:
Base Aluminium
Heat seal layer DEGALAN 4792 L, DEGALAN 4793 L
with PVC Copolymer
Use for food packaging and pharmaceutical blister

The Use of DEGALAN P 24
Typical Formulation:
22,5 parts DEGALAN P 24
9,0 parts PVC Copolymer
68,5 parts Methyl ethyl ketone
Technical Requirements:
Layer thickness: 6 8 m as dry film
Drying conditions (lab): 15 sec. at 180 C
Sealing conditions (lab): 0,5 sec, 180 C, 3 bar

Heat Sealing Strength vs. 1 or 2
steps varnishing
N/15 mm
15
DEGALAN P 24
2 steps 1 step
DEGALAN 4792 L 12,0
10,2
10
Aluminium versus PS, PVC
8,0 7,9
2 Steps varnishing
Primer layer PVC copolymer
Heat sealing layer 5
3,7 3,5
2,7 3,0
1 Step varnishing
Combined with PVC copolymer
0
Aluminium Aluminium Aluminium Aluminium
Drying: 15 sec. / 180 C vs. PS vs. PVC vs. PS vs. PVC
Sealing: 0,5 sec., 3 bar, 180 C On primer based Combined 80/20 with
PVC copolymer PVC copolymer

Heat Sealing Strength vs. Sealing
Temperature
N/15 mm
10
DEGALAN P 24
DEGALAN 4792 L 8
6
Aluminium vs. PS
Combined with 20% PVC copolymer
4
Sealing Temperature
Drying: 15 sec. / 180 C 2
Sealing: 0,5 sec., 3 bar
0
180 C 160 C 140 C 120 C 100 C
DEGALAN 4792 L is sealable even at low temperature.

DEGALAN - the Multi Purpose
Olefin-acrylic Binders
DEGALAN PM 555, DEGALAN PM 666

Organic dispersion of copolymers in butyl acetate/ methyl ethyl ketone
General Advantages:
Introducing PP into the packaging industry
HAPS-conform (Non Hazardous Air Pollution Solvents)
DEGALAN 4150 E, DEGALAN 4151 E

Organic dispersion of copolymers in propyl acetate/ ethyl acetate/ iso octane
Additional Advantages:
Free of n-butyl acetate
Acceptable smell
Improved performance

Olefin Acrylic Binders
DEGALAN PM 555
DEGALAN 4150 E
DEGALAN VP 4177 E
Organic dispersion of copolymers of
methacrylic esters and EPDM olefins
Ethylene-propylene-diene monomer
terpolymeric elastomere of the M-group
(saturated polymer back bone, R-group
unsaturated) 2 m
TEM picture:
EPDM-Matrix dark with
thermo plastical domains
1 m
Olefin Acrylic Binders
DEGALAN PM 555, DEGALAN 4150 E, DEGALAN VP 4177 E

Organic dispersion of copolymers of methacrylic esters and olefins
Base Aluminium
Intermediate layer Primering with PVC copolymer
Heat seal layer DEGALAN PM 555, 4150 E, VP 4177 E
with PVC copolymer no primering ness.
Sealing substrate PP, PS, PVC, PET, (PE)
Base PET
Intermediate layer Primering with polyester
Use for food packaging usually.

Heat Sealing Strength vs. Primering
Conditions
N/15 mm
15
DEGALAN PM 555 2 steps 1 step
DEGALAN 4150 E 11,8 11,6
10,9 10,5
9,9
10 9,4
8,9
7,3
Aluminium versus PP
2 Steps varnishing
Primer layer PVC copolymer 5
Heat sealing layer
1 Step varnishing
Combined with various 0
amounts of PVC copolymer 100:0 95:5 92,5:7,5 90:10
Drying: 15 sec. / 180 C Primered with Combined with various
Sealing: 1 sec., 6 bar, 200 C PVC copolymer amounts of PVC copolymer
DEGALAN 4150 E is very tolerant to various formulations.

Heat Sealing Strength vs. Sealing
Temperature
N/15 mm
12
DEGALAN PM 555 10,8
9,7
DEGALAN 4150 E 10
9,6 7,8
8 7,2
Aluminium vs. PP 7
6
Combined with 5% PVC copolymer 4,5
3,7
Sealing Temperature various 4
Drying: 15 sec. / 180 C 1,9

2
Sealing: 1 sec., 6 bar
0
220C 200C 180C 160C
DEGALAN 4150 E seals well at 180C

DEGALAN - the Formulation
DEGALAN PM 555, DEGALAN 4150 E
Typical formulations consist of additional additives.

Matting agents as fillers are often used to improve the workability.
Laboratory tests show the characteristics of the following additives.
Tested were:
1,5 % ACEMATT HK 450
5 % VESTOSINT 2159

Heat Sealing Strength vs. Matting
Agent Formulations
N/15 mm
2 steps 1 step
15
DEGALAN PM 555 13,1
DEGALAN 4150 E 12,0 12,2
11,7
10,2 10,4
10 9,7 9,3
8,6 8,6 8,4
7,6
Aluminium versus PP
2 steps vs. 1 step 95:5
5
amounts of PVC copolymer
5 % VESTOSINT 2159
0
Drying: 15 sec. / 180 C On primer based Combined 95/5 with
Sealing: 1 sec., 6 bar, 200 C PVC copolymer PVC copolymer
HK 450 2159 HK 450 2159
The properties of DEGALAN 4150 E can be improved by formulation.

Bursting Pressure vs. Matting Agent
Formulation
Bursting Pressure / bar
DEGALAN PM 555 2 steps 1,1 1 step

DEGALAN 4150 E 1,0 1,0
0,9
0,8
0,8
0,6 0,6
Aluminium versus PP 0,6 0,6
0,5 0,5 0,5
2 steps vs. 1 step 95:5 0,5
amounts of PVC copolymer
5 % VESTOSINT 2159
0,0
Drying: 15 sec. / 180 C On primer based Combined 95/5 with
Sealing: 1 sec., 6 bar, 200 C PVC copolymer PVC copolymer
HK 450 2159 HK 450 2159
The properties of DEGALAN 4150 E can be improved by formulation.

Acrylic Binders
DEGALAN PM 666, DEGALAN 4151 E, DEGALAN VP 4174 E,

Organic dispersion of copolymers of methacrylic esters and olefins
Base Aluminium
Base PET
Intermediate layer Primering with polyester
Heat seal layer DEGALAN PM 666, DEGALAN 4151 E
Base PET
Heat seal layer DEGALAN VP 4174 E
Use for food packaging usually.

Heat Sealing Strength
without Primering
N/15 mm
10
DEGALAN PM 666 8,8 8,6
8,1 8,4
DEGALAN 4151 E 7,9
8
DEGALAN VP 4174 E 6,9
6
Aluminium versus PP
Not primered! 4
Drying: 15 sec. / 180 C

2
Sealing: 1 sec., 6 bar, 200 C
0
Initial 48h H20
DEGALAN PM 666, DEGALAN 4151 E and DEGALAN 4174 E

have direct adhesion to Aluminium.
Heat Sealing Innovation Focus
Macro Trend Innovation Trend Product Development
Bead Polymer with direct

DEGALAN PM 666
adhesion on aluminum vs. PS to
PVC-free packaging DEGALAN 4151 E
replace PVC copolymers in
Environmentally DEGALAN VP 4174 E
existing formulations
friendly
Replacement of
Packaging Improved water based products
solvent-based HS DEGALAN 4032 D
Products for extrusion-coating
products
Use of bio-renewable
packaging materials
DEGALAN 4140 D -
Replacement of
Process &
aluminum by PET
DEGALAN VP 4174 E -
Material
Optimization
Fast drying lacquers DEGALAN VP 4177 E -
Heat-sealable lids as a
Products for sterilization-
Convenience replacement for DEGALAN VP X
resistant HS lacquers
pull-ring lids

DEGALAN VP 4174 E - the latest
Development
N/15 mm
10
Aluminum 9,1
8,4 8,7
Alu25/PET12 8
PET WDW 50 6,7
6,0 6,0
6
versus PP and PS
4
No Primering!
Layer thickness 6 m
2
Sealing: 1 sec., 6 bar, 200 C 0
vs. PP vs. PS
DEGALAN VP 4174 E - provides an excellent sealing strength with direct

adhesion on various substrates esp. PET.
DEGALAN VP 4174 E - Heat Sealing
Strength vs. Sealing Temperature
N/15 mm
12
Aluminium
PET/WDW 10 9,5
8,9 8,6
Al25/PET12 7,8
8 6,9
Subtrates vs. PP 6,1
5,7
6 5,5 6
6,7
No Primer 4,6
5,6 3,9
Sealing Temperature various 4 2,9
2 1,0
Sealing: 1 sec., 6 bar 0,1
0
220C 210C 200C 190C 180C
DEGALAN VP 4174 E shows a broad application window

DEGALAN - Summary
DEGALAN Binders for Heat Sealing Applications
provide an excellent and secure sealing

strength in combination with smooth peeling
show an universal characteristics
are very tolerant to various formulations

People to contact
Technical Advisors for Heat Sealing Binders

Michael Wicke
T: +49-6151-18-4549 F: +49-6151-18-84 4549
michael.wicke@evonik.com
DE (south), FR, ES, POR, CH, Americas, Africa, Middle East
Jrgen Hartmann
T: +49-6151-18-4960 F: +49-6151-18-84 4960
juergen.jh.hartmann@evonik.com
DE (north), AUT, IT, GB, BENELUX, East Europe, GR, TR, Asia
Business Director for Heat Sealing Binders

Dr. Bruno Keller
T: +49-6151-18-4497 F: +49-6151-18-84 4497
bruno.keller@evonik.com

Thank you for your
Attention
Interest
Questions?

DEGALAN - Binders For Heat Sealing Applications Without Films 2008 12 15

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DEGALAN -

Binders for Heat Sealing

Who makes films

Who makes Aluminuim

The Products The Advantages

DEGALAN PM 666 Various substrates like polystyrene or polyvinylchloride

15.12.2008 | Evonik Roehm GmbH Darmstadt Seite | 4

Product Appearance Solid content Solvent

DEGALAN P 24 Bead Polymer 100 -

DEGALAN 4792 L Organic Solution 55 methyl ethyl ketone (MEK)

DEGALAN 4793 L 55 ethyl acetate

DEGALAN PM 555 Organic Dispersion 45 butyl acetate/ MEK 70/30

DEGALAN PM 666 45 butyl acetate/ MEK 70/30

propyl acetate/ ethyl acetate/ iso octane

DEGALAN VP 4177 E 43 tert. butyl acetate/ ethyl acetate 63,5/ 36,5

propyl acetate/ ethyl acetate/ iso octane

DEGALAN 4140 D Aqueous Dispersion 50 Water

DEGALAN 4032 D 50 Water

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Minimum Order Size: 2 Pallets

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Product Adhesion to Sealable versus Remarks

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Product Adhesion to Sealable versus Remarks

DEGALAN 4792 L yes, or in yes, PVC

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Product Adhesion to Sealable versus Remarks

DEGALAN 4792 L yes, or in yes, PVC

DEGALAN PM 555 yes, or in Universally applicable

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Product Adhesion to Sealable versus Remarks

DEGALAN 4792 L yes, or in yes, PVC

DEGALAN PM 555 yes, or in Universally applicable

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Product Adhesion to Sealable versus Remarks

DEGALAN 4792 L yes, or in yes, PVC

DEGALAN PM 555 yes, or in Universally applicable

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Product Adhesion to Sealable versus Remarks

DEGALAN 4792 L yes, or in yes, PVC

DEGALAN PM 555 yes, or in Universally applicable

DEGALAN 4032 D + Yes - - - + + - -

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Heat Sealing Lacquer

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DEGALAN P 24, DEGALAN LP AL 23

Use for food packaging and pharmaceutical blister

DEGALAN 4792 L, DEGALAN 4793 L

Use for food packaging and pharmaceutical blister

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DEGALAN 4792 L is sealable even at low temperature.

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DEGALAN PM 555, DEGALAN PM 666

DEGALAN 4150 E, DEGALAN 4151 E

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DEGALAN PM 555, DEGALAN 4150 E, DEGALAN VP 4177 E

Use for food packaging usually.

DEGALAN 4150 E is very tolerant to various formulations.

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Drying: 15 sec. / 180 C 1,9

DEGALAN 4150 E seals well at 180C

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