Introduction g l y c e r o l + s o d i u m s t e a r a t e
Fats and oils are used to make a number of prod- H
ucts. One of these is soap, the manufacture of which
H C O H O
is one of the oldest chemical industries. In this topic
you are going to consider the industrial manufacture Þ H C O H 3 C17H35 C O-Na+
of both soap and soapless detergents and learn about
H C O H
their cleansing action.
H
1.Soap Manufacture The soap and the glycerol are separated by adding
The basic chemical reaction by which soap is pro- a concentrated salt solution (brine) to the mixture.
duced is still the same today as that used thousands of The glycerol dissolves in the brine but the soap is in-
years ago. Soap are salts of long chain fatty acids. A soluble and forms a solid on top of the brine. This
common soap is sodium stearate. process is known as salting out.
H H H H H H H H H H H H H H H H H O
H C C C C C C C C C C C C C C C C C C O-Na+
H H H H H H H H H H H H H H H H H
H C O C C17H35
H O
2.Soapless Detergents NaOH
Soaps have been used for washing for thousands C12H25 – – SO2OH
of years but they always had one disadvantage. If neutralization
used in hard water, i.e. water containing dissolved
minerals such as Ca2+ or Mg2+, they produced an
insoluble scum.
Soapless detergents have similar structures to soaps
but are manufactured from aromatic hydrocarbons C12H25 – – SO2O-Na+
obtained from crude oil. They wash just as efficiently
as soap but they do not produce scum with hard wa-
ter.
H H H H H H H H H H H H
H C C C C C C C C C C C C SO2O-Na+
H H H H H H H H H H H H
H H H H H H H H H H H H H H H H H O
H C C C C C C C C C C C C C C C C C C O-Na+
H H H H H H H H H H H H H H H H H
covalent tail ionic head
H H H H H H H H H H H H
H C C C C C C C C C C C C SO2O-Na+
H H H H H H H H H H H H
You should be able to know: Questions:
1. Draw the structural formula of a typical soap F What is a detergent and which properties must
molecule. it possess?
2. Describe briefly the main stages involved in soap F Which part of a detergent molecule dissolves in
manufacture. grease and which paer in water?
3. State the meaning of saponification and explain F Why does it happen?
what advantage it has over ordinary hydrolysis os an F How is the grease loosened from a fabric?
ester. F Why can the tiny droplets of grease not form a
4. Draw the structural formula of a typical soapless larger blob?
detergent molecule. F What name is given to the type of "mixture"
5. Describe briefly the main stages involved in the formed?
manufacture of soapless detergents.
6. Explain why soapless detergents are more useful
than soap in certain areas.
7. Describe similarities and differences in structure
between soap and soapless detergents.
8. Explain what is meant by the term detergent.
9. Describe how detergents remove grease and
act as emulsifying agents.
CHECK TEST
(Soaps and Detergents)
O O
C17H35 C O-Na+ C17H35 C-Na+ 7. A major advantage of soapless detergents is
A. they form an insoluble scum with Ca2+
ions
B. they are manufactured from natural raw
materials
2. The main stages in soap manufacture are C. they do not contain sodium ions
A. heating with sodium hydroxide followed D. they do not form an insoluble scum with
by adding salt solution. Ca2+ ions
B. heating with salt followed by adding
sodium hydroxide solution.
C. adding salt solution followed by adding 8. A detergent is a
sodium hydroxide. A. solid soap
D. heating with sugar solution followed by B. liquid soap
adding salt solution. C. substance which makes hard water soft
D. substance which has a cleansing action
when added to water
3. Which of the following is an example of
saponification?
A. Hydrolysis of a fat with alkali 9. When a detergent is added to a mixture of grease
B. Hydrolysis of a fat with acid and water which part of the molecule is attracted to
C. Hydrolysis of a fatty acid with alkali the grease?
D. Hydrolysis of a fatty acid with acid A. The sodium ion
B. The carbonyl group
C. The hydrocarbon tail
4. Which of the following is a soapless detergent? D. The oxygen atoms