COMPOUND CONTAINING

13 NITROGEN
LESSON PLAN

Lect Description H.W.

No.
1 i) Introduction of Theory Question : Q.1, 2, 3, 4, 5,
nitrocompounds 6, 7, 8, 14.
ii) Classification (1 time each)
iii) Preparation
a) Nitration of alkane
b) From alkyl halide
c) From salts of D-halogen
carboxylic acid
d) From Amines
e) From D-nitro alkene
f) From oxime

2 iv) Chemical reaction Theory Questions : Q.9, 10, 11, 12, 13,
a) Condensation with 14
aldehyde and ketone (1 time each)
b) Reduction
c) Hydrolysis
d) Halogenation
e) Reaction with nitrous
acid (Victor-Mayer test)
f) Nef carbonyl synthesis

3 i) Introduction to amines Theory Questions : 17, 18, 19, 20, 21,

ii) Classfication of amines 22, 23, 25, 26, 29 (1 time each)
iii) Nomenclature of amines
iv) Preparation of amines
a) Ammonolysis of RX Levl I : 1, 2,3, 4, 6, 8, 10, 14, 15,
Levl I : 5, 7, 9, 11, 13, 49, 50, 52 53.
Levl II : 3 Levl II : 9, 10 , 13, 14, 15
Levl III : 9 Levl III : 1, 2, 4, 6, 14
PCQS : PCQS : 2
Compound Containing Nitrogen
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Lect Description H.W.

No.
4 b) Gabriel phthalimide Theory Questions : Q.27, 28, 30, 31,
synthesis 35, 36, 37, 38, 39, 40
c) Hoffmann Bromamide
reaction
d) Reduction of
1) Nitro compound
2) Amide compound
3) Oxime compound
4) Nitrile compound
5) Isocynide compound

v) Physical properties
vi) Chemical properties
a) Basicity of amine
Levl I : 16, 19, 44 Levl I : 17, 21, 46, 48
Levl II : 3, 17, 232, 23, 33 Levl II : 1, 2, 12, 16, 18, 19, 21,
Levl III : 7 32, 34
PCQS : 29 Levl III : 8, 11, 19
PCQS : 12, 14, 16, 20, 21, 23, 31

5 b) Reaction with HCl/ Theory Questions : 42, 43, 44, 45,

H2SO 4/H2O 46, 47, 48, 49, 50, 51, 52
c) Reaction with HNO2
acid
d) Carbylamine test
e) Hoffmanns exhaustive
alkylation Diazotization
f) Hoffmanns elimination Levl I : 14, 15, 16, 18, 19, 22
g) Hinsbergs test Levl I : 22, 25, 26, 27, 31, 32, 33,
Diazotization o level o 13. 35, 36, 37, 40, 41, 42, 47
Levl I : 23, 24, 28, 29, 30, 34, 39, Levl II : 7, 25, 26, 27, 29
43, 45 Levl III : 5, 10, 17, 18, 20, 21, 22,
Levl II : 5, 24, 81 24
Levl III : 13 PCQS : 1, 3, 6, 7, 8, 9, 13, 17, 19,
PCQS : 22 25, 28
Compound Containing Nitrogen
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Lect Description H.W.

No.
6 h) Electrophilic aromatic
substitution
1) Bromination
2) Nitration
3) Sulphonation
i) Acylation of amine
i) Hoffmanns Musturd oil
reaction
j) Oxidation of aniline
Levl I : 38 Levl II : 16, 23
Levl II : 28 PCQS : 24
Levl III : 15
PCQS : 11, 15, 5, 18

7 vii) Diazonium salt Theory Questions : Q.53, 55, 56, 58,

a) Preparation 60, 63, 65, 66, 67, 68, 69, 70,
b) Chemical properties 71, 74
1) Sandmeyer reaction Levl II : 1, 2, 5, 6, 7, 8, 9, 11, 12
2) Gattermann reaction Levl II : 1, 2, 3, 4, 5, 6, 8, 10
3) Replacement by I Levl III : 2, 3, 4, 5, 8, 11
4) Replacement by F PCQS : 2
5) Replacement by H
6) Replacement by
NO 2 C.W.
7) Replacement by Levl I : 3, 4, 10, 13
OH Levl II : 7
8) Diazocoupling Levl III : 1, 6, 7, 10
reaction PCQS :

Compound Containing Nitrogen