volatile
easy to ignite
produces a large amount of energy when it burns
produces the minimum amount of pollution.
Information about some of the hydrocarbons that are found in petrol is given in the table.
Hexane C6H14 95 69
.............................................................................................................
(1)
.............................................................................................................
.............................................................................................................
.............................................................................................................
(2)
......................................................................................................................
(1)
(c) A fuel scientist recommended increasing the amount of butane and decreasing the
amount of hexane in petrol that is used in the UK in winter.
......................................................................................................................
......................................................................................................................
......................................................................................................................
......................................................................................................................
(2)
Page 1 of 32
(d) Balanced equations for the complete combustion of butane and pentane are given below.
.............................................................................................................
(1)
.............................................................................................................
.............................................................................................................
.............................................................................................................
.............................................................................................................
(2)
......................................................................................................................
......................................................................................................................
(1)
(Total 10 marks)
Q2. Crude oil is a mixture of alkanes from which useful fuel fractions can be obtained.
(a) (i) Suggest the lowest temperature to which crude oil needs to be heated to vaporise all
of these fuel fractions.
Temperature ................................................ C
(1)
(ii) Dodecane boils at +216 C. At what temperature will dodecane gas condense to
liquid?
Temperature ................................................ C
(1)
Page 2 of 32
(iii) Describe what happens in a fractionating column that allows these fractions to be
collected.
..............................................................................................................
..............................................................................................................
..............................................................................................................
..............................................................................................................
..............................................................................................................
..............................................................................................................
(3)
(i) Complete the balancing of the two chemical equations for propane burning in air.
(ii) The products of the two chemical reactions in (b)(i) are different.
Explain why.
..............................................................................................................
..............................................................................................................
..............................................................................................................
..............................................................................................................
..............................................................................................................
(2)
(Total 9 marks)
Page 3 of 32
Q3. Since 2000 there has been a lot more research into alternative, environmentally-friendly fuels
for road transport.
Several pollutants are found in the exhaust emissions produced when fossil fuels are used for
road transport.
Carbon monoxide (CO) interferes with the way that red blood cells carry oxygen. Carbon dioxide
(CO2) increases the level of carbon dioxide in the atmosphere and causes global warming.
Oxides of nitrogen (NOx) are produced at high temperatures when nitrogen and oxygen from the
atmosphere combine.
Sulfur dioxide (SO2) is produced when sulfur impurities in the fuel combine with oxygen in the
atmosphere.
Tiny particles of solids are produced when the fuel does not burn completely.
..........................................................................................................................
(1)
..........................................................................................................................
(1)
(b) Diesel obtained from crude oil is often called fossil diesel. Biodiesel can be made from
many vegetable oils. One research project compared the exhaust emissions when fossil
diesel or biodiesel were used as fuels.
Some of the relative amounts of these exhaust emissions are shown in the bar chart.
Page 4 of 32
(i) Use your knowledge and the information above to explain the environmental benefits
of using biodiesel as a sustainable, low pollution fuel.
...........................................................................................................................
...........................................................................................................................
...........................................................................................................................
...........................................................................................................................
...........................................................................................................................
...........................................................................................................................
(3)
This is because the life-cycle emission of carbon dioxide from biodiesel is less than
that from fossil diesel.
Use your knowledge and the information above to explain why biodiesels contribution
to global warming is considered to be much less than that of fossil diesel.
...........................................................................................................................
...........................................................................................................................
...........................................................................................................................
...........................................................................................................................
...........................................................................................................................
...........................................................................................................................
(3)
(Total 8 marks)
Page 5 of 32
Q4. Crude oil is the source of many useful materials. Crude oil is separated into fractions by
fractional distillation.
(a) Describe how the naphtha fraction separates from the other fractions.
.....................................................................................................................................
.....................................................................................................................................
.....................................................................................................................................
.....................................................................................................................................
(2)
(b) The naphtha fraction is often used to make other useful materials.
For example:
...........................................................................................................................
...........................................................................................................................
...........................................................................................................................
(2)
Page 6 of 32
(iii) Why does ethene have different chemical properties from decane and hexane?
...........................................................................................................................
...........................................................................................................................
...........................................................................................................................
...........................................................................................................................
(2)
(c) Ethene is used as the starting material for many polymers. The most common polymer is
poly(ethene). One hydrocarbon molecule in poly(ethene) will contain thousands of carbon
atoms.
H H
C C
H H
(1)
Page 7 of 32
(d) Read the following information.
Recycling poly(ethene) saves raw materials and energy needed to make new
plastic. When polymers are recycled the plastics must be collected,
transported, sorted into different types by hand and washed. This requires the
use of fossil fuels and is expensive.
You are asked to decide which option for the disposal of poly(ethene) will be put forward in
your area. You decide that recycling is the best option.
Suggest one economic argument and one environmental argument that will be made
against recycling.
Page 8 of 32
For each argument made, how will you persuade those making the argument to accept
your option?
(You must use only one sentence for each argument made against your decision and only
one sentence for your response to it.)
.....................................................................................................................................
.....................................................................................................................................
.....................................................................................................................................
.....................................................................................................................................
.....................................................................................................................................
.....................................................................................................................................
.....................................................................................................................................
.....................................................................................................................................
.....................................................................................................................................
(4)
(Total 12 marks)
Q5. A large reservoir is surrounded by trees. Planners need to protect the environment. The
distance around the reservoir is many kilometres. There will be only one road access to a car
park a few kilometres from the reservoir. From the car park people would be transported to
accommodation, activities or places of interest by steam train.
Page 9 of 32
(a) Coal contains carbon and small amounts of sulfur. The steam train would cause
environmental problems if coal were used as the fuel.
Explain why.
....................................................................................................................................
....................................................................................................................................
....................................................................................................................................
....................................................................................................................................
....................................................................................................................................
....................................................................................................................................
....................................................................................................................................
....................................................................................................................................
(4)
(b) The planners have stated that, as a result of using the steam train, there must be no
overall increase of carbon dioxide added to the atmosphere. The steam train would be
considered as carbon neutral if wood, from the surrounding forest, were used as the fuel.
Suggest why.
....................................................................................................................................
....................................................................................................................................
....................................................................................................................................
....................................................................................................................................
....................................................................................................................................
....................................................................................................................................
(3)
(Total 7 marks)
Page 10 of 32
(i) Describe and explain how the mixture of alkanes is separated by fractional
distillation.
..........................................................................................................................
..........................................................................................................................
..........................................................................................................................
..........................................................................................................................
..........................................................................................................................
..........................................................................................................................
..........................................................................................................................
(3)
(ii) The table gives the name and formula for each of the first three alkanes.
Methane CH4
Ethane C2H6
Propane C3H8
Butane
(1)
H
HCH
H
Page 11 of 32
(c) The relative amounts of and the market demand for some hydrocarbons from the
fractional distillation of crude oil are shown in the graph.
(i) Why is the market demand for the C5 C8 fraction higher than the market demand for
the C21 C24 fraction?
..........................................................................................................................
..........................................................................................................................
(1)
(ii) Cracking is used to break down large hydrocarbon molecules into smaller
hydrocarbon molecules.
Complete the symbol equation by writing in the formula of the other hydrocarbon.
Page 12 of 32
(iii) The C5 C8 fraction has low supply and high market demand.
Suggest three ways in which the oil industry could overcome this problem.
1 .........................................................................................................................
............................................................................................................................
2 .........................................................................................................................
..........................................................................................................................
3 .......................................................................................................................
..........................................................................................................................
(3)
(Total 10 marks)
Q7. Known crude oil reserves are being used up rapidly. Crude oil is used to produce many
useful fuels, such as petrol. One way to conserve crude oil reserves would be to increase the
production of bio-fuels.
(a) Ethanol can be produced for use as a bio-fuel. Cars can be powered by ethanol or
ethanolpetrol mixtures.
Sugar cane can be fermented to give a mixture of water (boiling point 100 C) and ethanol
(boiling point 78 C).
..........................................................................................................................
..........................................................................................................................
(1)
Complete the balanced symbol equation by writing in the formulae of the two
products.
(b) The cost of producing a bio-fuel, such as ethanol, by fermentation, is at least three times
higher than the production cost of petrol. It costs less to produce ethanol from alkanes. In
the production, the vapour of an alkane is passed over a hot catalyst.
..........................................................................................................................
(1)
Page 13 of 32
(ii) Complete the structural formula for ethene, C2H4.
C C
(1)
(iii) Name the compound that is added to ethene to produce ethanol, C2H5OH.
..........................................................................................................................
(1)
(c) As explained in parts (a) and (b), ethanol can be made using either sugar or alkanes as the
starting material.
Evaluate the advantages and disadvantages of using these two starting materials to
produce ethanol.
....................................................................................................................................
....................................................................................................................................
....................................................................................................................................
....................................................................................................................................
....................................................................................................................................
....................................................................................................................................
....................................................................................................................................
....................................................................................................................................
(4)
(Total 10 marks)
Page 14 of 32
Q8. To make crude oil more useful it is separated into different fractions.
(b) Each fraction is a mixture of compounds. Most of these compounds are hydrocarbons,
made up of the elements hydrogen and carbon.
..........................................................................................................................
..........................................................................................................................
..........................................................................................................................
(2)
..........................................................................................................................
..........................................................................................................................
..........................................................................................................................
(2)
(Total 6 marks)
Page 15 of 32
Q9. Crude oil is a complex mixture of hydrocarbons, mainly alkanes. The number of carbon
atoms in the molecules ranges from 1 to over 100.
(a) How does the boiling point change as the number of carbon atoms in the
molecules increases?
.....................................................................................................................................
.....................................................................................................................................
(1)
.....................................................................................................................................
(1)
(c) The simplest hydrocarbon is methane, CH4. Its structure can be represented:
Q10. Crude oil is obtained by drilling into the Earths crust. The diagram shows a section through
the Earths crust to show how this is done.
(a) Crude oil contains many hydrocarbons. Which elements do hydrocarbons contain?
....................................................................................................................................
(1)
Page 16 of 32
(b) The crude oil is separated by fractional distillation. The diagram shows a column used
for this.
............................................................................................................................
............................................................................................................................
............................................................................................................................
............................................................................................................................
............................................................................................................................
(3)
(ii) Naphtha burns more easily than diesel oil. Explain why.
............................................................................................................................
............................................................................................................................
............................................................................................................................
(1)
(2)
(Total 7 marks)
Page 17 of 32
Q11. The diagrams show the percentages of the four main fractions produced from two samples
of crude oil, A and B.
(a) The light fraction contains hydrocarbons used for the manufacture of useful chemicals
such as polymers. Which one of the samples, A or B, would be more useful for the
manufacture of polymers? Explain your answer.
.....................................................................................................................................
.....................................................................................................................................
.....................................................................................................................................
.....................................................................................................................................
.....................................................................................................................................
.....................................................................................................................................
(2)
Page 18 of 32
(b) Heptane (C7H16), is one of the hydrocarbons used for the manufacture of poly(ethene). The
first stage of the process is the production of ethene and another hydrocarbon from
heptane.
C7H16 +
heptane ethene
(i) In the box, draw the structural formula of the other hydrocarbon produced.
(1)
...........................................................................................................................
...........................................................................................................................
...........................................................................................................................
...........................................................................................................................
...........................................................................................................................
...........................................................................................................................
(2)
(Total 5 marks)
Q12. The table shows how much carbon dioxide is produced when you transfer the same
amount of energy by burning coal, gas and oil.
(a) Use the information from the table to complete the bar-chart.
(2)
Page 19 of 32
(b) The second bar-chart shows how much sulphur dioxide is produced by burning the same
three fuels.
Compare the amount of sulphur produced by burning gas with the amount produced by
burning coal.
.....................................................................................................................................
.....................................................................................................................................
(1)
(c) Burning fuels also produces nitrogen oxides, even though the fuels contain no nitrogen.
Explain why this happens.
.....................................................................................................................................
.....................................................................................................................................
(2)
(d) When you release the same amount of energy from coal, gas and oil, different amounts of
carbon dioxide are produced.
Use the information below to explain why.
(3)
.....................................................................................................................................
(1)
(Total 9 marks)
Page 20 of 32
M1. (a) (i) butane
1
(ii) because there are weak forces (of attraction) between molecules
not weak bonds
1
(b) C7H16
1
(ii) 216(C)
1
Page 21 of 32
(b) (i) 10 6+8
1
7 6+8
1
renewable
low pollution:
most emissions are lower or any two named emissions from CO / SO2 / PM10
are lower
Page 22 of 32
(ii) plants / photosynthesis use carbon (dioxide) from the air*
1
ethene has a double (carbon carbon) bond or decane and hexane have only
single (carbon carbon) bonds
accept ethene has a reactive double (carbon carbon) bond for 2
marks
1
Page 23 of 32
(d) economic argument against recycling
counter arguments
poly(ethene) is non-biodegradable
Page 24 of 32
M5. (a) any two environmental problems with linked explanations
Page 25 of 32
M6. (a) (i) heat / evaporate the crude oil / change to gas or vapour
do not accept heat with catalyst
1
(ii) C4H10
1
(b) H H H
H C C C H
H H H
1
(ii) C2H4
do not accept C4H8
1
cracking
Page 26 of 32
M7. (a) (i) by (fractional) distillation
accept a description of the distillation process (heat and how
separation works) eg heat and condense
accept boil / vapourise etc for heat
or
fractionation
1
(ii) CO2
note the order of these products must be correct
1
H2O
wrong way round = 1 mark
1
(b) (i) (hexane) has been broken down (into smaller hydrocarbons / molecules)
1
accept (thermal) decomposition / cracked / split / broken up owtte
(ii) H H
C = C
H H
accept CH2 = CH2
1
Page 27 of 32
(c) candidates must include both sugar cane and crude oil in their evaluation
and both an advantage and a disadvantage to gain full marks.
if they do not then the maximum mark is three
or
enough land to grow sugar cane / land cannot be used to grow food / deforestation
or
continuous process
faster process
4
[10]
Page 28 of 32
(b) (i) mixture: compounds or elements or substances together but not chemically
combined
ignore references to separation
1
(c)
Page 29 of 32
(b) (i) the oil is evaporated / boiled / liquid converted to gas / vaporised
oil is condensed/changed back to liquid/cooled below boiling point (not just cooled)
If the answer is given the opposite way around then diesel must
be specified.
any one for 1 mark
1
(iii)
(b) (i)
Page 30 of 32
(ii) heat
1
catalyst
if neither mark gained allow cracking for 1 mark
1
[5]
M12. (a) both bars correct height_ (to better than half a square)
1 mark for both
(b) a lot less / much less / 18 times less (converse must specify coal)
gains 1 mark
1
coal produces most carbon dioxide / more CO2 than gas / oil
oil and gas also contain hydrogen / contain more hydrogen atoms than carbon
atoms / also produce water
any three for 1 mark each
3
(e) sulphur
for 1 mark
2
[9]
Page 31 of 32
Page 32 of 32