Anda di halaman 1dari 37

Turbo Generator

Note for Hazardous Materials


Assembly

In the event that other hazardous materials are pro


cured or provided on site, the corresponding manufactu
rer's instructions and safety/protection measures shall
be observed.
Siemens AG 2000 - All Rights Reserved
e
Copyright
Distribution: UNRESTRICTED

Siemens AG 2.2-1070-0002
Energy Service MKA &MDB 0908E
Material Safety Data Sheet
BOX 1000, JACKSON, MI 49204-1000
888-4-UNISORB 517-764-6060
FAX 517-764-5607 www.unisorb.com

Section 1 Material Identification

Product Name: Preparation Date: October 20, 2003


Revision Notes: Annual Updating HMIS
H 1
V-1 NON-SHRINK GROUT F0
R 0
Emergency Phone: (800) 255-3924 24 hrs. (Continental U.S.) PPE*
(813) 248-0585 24 hrs. (Outside Continental U.S.) * Section 8

Section II Hazardous Ingredients / Identity Information

Weight % Chemical Name CAS Number


40-60% max Portland Cement 065997-15-1
50-70% max Crystalline Silica 014808-60-7

Section III - Physical/Chemical Characteristics

Boiling Point: Evaporation Rate (Bytl Acetate = 1):


N/A N/A
Vapor Pressure (mmHg): Solubility in Water:
N/A Negligible
Melting Point / Freezing Point (F): Appearance and Odor:
N/A Grey powder, concrete color, cement odor
Vapor Density (Air =1): VOC:
N/A NA

Section IV - Fire and Explosion Hazard Data

Flash Point:
Non - Flammable
Flammable limits
Lower Explosion Limit:
N/A
Upper Explosion Limit:
N/A
Extinguishing Data:
Will not burn except under extreme temperatures (Use water spray, carbon dioxide, or dry chemical foam).
Special Fire Fighting Procedures:
Wear standard fire fighting gear with self-contained breathing apparatus (SBCA) operated in pressure demand or positive pressure
mode.
Unusual Fire and Explosion Hazards:
None
Fire Fighting Disposal Procedures:
Do not dispose into waterways or sewers

V-1 Non-Shrink Grout Page 1 of 3 October 20, 2003


Material Safety Data Sheet
BOX 1000, JACKSON, MI 49204-1000
888-4-UNISORB 517-764-6060
FAX 517-764-5607 www.unisorb.com

Section V - Reactivity Data

Stability:
Stable
Conditions to Avoid:
None known
Chemical Incompatibility:
None known
Hazardous Decomposition:
Carbon monoxide, carbon dioxide, oxides of nitrogen, and other unidentified organic compounds.
Hazardous Polymerization:
Will not occur
Conditions to Avoid:
None known

Section VI - Health Hazard Data

Primary Entry Routes:


Inhalation, skin and ingestion
Target Organs:
Lungs and skin
Acute Effects
Inhalation:
May cause shortness of breath, chest pain, decreased pulmonary functions, and coughing.
Eye:
May cause irritation and inflammation of the cornea.
Skin:
Product becomes alkaline when combined with water. Wet cement product may dry to exposed skin causing irritation and skin burns.
Ingestion:
May cause indigestion, irritation, and gastrointestinal blockage (product will solidify)
Carcinogenicity:
This product contains Crystalline Silica. Crystalline Silica is recognized by IARC as a Group 1 carcinogen, by NTP as a Group 2
carcinogen, and by the state of California (Proposition 65) as carcinogenic to humans. Prolonged exposure to silica dust above
Threshold Limit Values (TLVs) may cause scarring of the lungs with cough and shortness of breath.
Medical Conditions Aggravated by Long-Term Exposure:
Long term exposure to crystalline silica may aggravate existing respiratory conditions such as, but not limited to, asthma and
emphysema.
Chronic Effects:
Prolonged exposure to silica dust above Threshold Limit Values (TLVs) may cause progressive respiratory symptoms (silicosis).

First Aid
Inhalation: Remove to fresh air
Eye Contact: Irrigate eye with water or consult physician if irritation persists.
Skin Contact: Washed exposed skin area with soap and water; consult a physician if irritation persists
Ingestion: Immediately consult a physician

V-1 Non-Shrink Grout Page 2 of 3 October 20, 2003


Material Safety Data Sheet
BOX 1000, JACKSON, MI 49204-1000
888-4-UNISORB 517-764-6060
FAX 517-764-5607 www.unisorb.com

Section VII Precautions For Safe handling and Use

Spill /Leak Procedures:


Follow procedures noted below. DO NOT use water to clean up spills or control dust, always use dry clean up methods. Addition of
water to this product will cause it to solidify and harden. Use appropriate respiratory protection as recommended in Section 8 below. Do
not disperse materials into air.
Small Spills:
Collect using a vacuum cleaner or similar device. Avoid generation of dust caused by sweeping or walking through spill area.
Large Spills:
Collect using mechanical means such as a front end loader. Do NOT use water to control excessive dusting, as this may cause the
product to solidify and harden.
Cleanup:
Equipment used to clean up spills may be rinsed with water. Use large amounts of water to reduce the possibility of product
solidification and cement buildup.
Regulatory Requirements:
This product is not listed as a hazardous waste by US EPA (40 CFR 261).
Disposal:
Consult federal, state and local regulations for any restrictions to disposal of the material. Do NOT dispose of in sewers, drains, or
waterways. Material may solidify and plug/block sewers, drains, or waterways.
Disposal Regulatory Requirements:
None Known
Container Cleaning and Disposal:
Empty containers may be disposed of through normal means. Refer to federal regulation 40 CFR 261.7
Containment:
Do not release into sewers or waterways.

Section VIII Precautions For Safe handling and Use

Ventilation:
Provide general or local exhaust ventilation systems to maintain airborne concentrations below OSHA PELs (Sec. 2). Local exhaust
ventilation is preferred because it prevents contaminant dispersion into the work area by controlling it at its source.
Respiratory Protection:
Seek professional advice prior to respirator selection and use. Follow OSHA respirator regulations (29 CFR 1910.134) and, if necessary,
wear a MSHA/NIOSH-approved respirator. Select respirator based on its suitability to provide adequate worker protection for given
working conditions, level of airborne contamination, and presence of sufficient oxygen. For emergency or non-routine operations
(cleaning spills, reactor vessels, or storage tanks), wear an SCBA.
Warning! Air-purifying respirators do not protect workers in oxygen-deficient atmospheres. If respirators are used, OSHA requires a
written respiratory protection program that includes at least: medical certification, training, fit-testing, periodic environmental
monitoring, maintenance, inspection, cleaning, and convenient, sanitary storage areas.
Protective Clothing/Equipment:
Wear chemically protective gloves, boots, aprons, long sleeves, pants and gauntlets to prevent prolonged or repeated skin contact.
Wear protective eyeglasses or chemical safety goggles, per OSHA eye- and face-protection regulations (29 CFR 1910.133). Contact
lenses are not eye protective devices. Appropriate eye protection must be worn instead of, or in conjunction with contact lenses.
Contaminated Equipment:
Separate contaminated work clothes from street clothes. Launder before reuse. Remove this material from your shoes and clean
personal protective equipment.

To the best of our knowledge, the information contained herein is accurate. However, neither Unisorb Installation Technologies nor any of its
agents assume any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of
any material is the sole responsibility of the user. All materials may present unknown health hazards and should be used with caution. Although
certain hazards are described herein, we cannot guarantee that these are the only hazards which exist.

V-1 Non-Shrink Grout Page 3 of 3 October 20, 2003


Material Safety Data Sheet. (MSDS)
Printing date 10.06.2005 / Reviewed on 10.06.2005 Page : 1/4

1 Identification of substance

Product details

Trade name: V1/50 grout


Application of the substance: grout

Manufacturer / Supplier:
PAGEL Spezial-Beton GmbH & Co KG
Wolfsbankring 9
D-45355 Essen

Informing department: Laboratory


Emergency information:
Tel.: +49 (0)201 / 6 85 04-37
Fax: + 49 (0)201 / 6 85 04-31

2 Composition / Data on components

Chemical characterisation

Description: Cement mortar, fine-grain aggregates and active bonding additives.

Dangerous components:
CAS-No. Designation % Index R-phrases
65997-15-1 Portland cement 25-50 36,37,38,41
EINECS:
266-043-4

3 Hazards identification

Hazard designation: Xi Irritant


Information pertaining to particular dangers for man and environment:
R38 Irritating to skin
R41 Risk of serious damage to eyes
Portland cement reacts with acids by developing heat - danger of spurting
Classification system:
The classification is in line with current EC lists. It is expanded, however, by information from technical literature
and by information furnished by supplier companies.
Observe to no. 11 and 12

4 First aid measures

General information: This product contains cement. Cement produces an alkaline reaction with moisture or
gauging water and therefore splashes of mortar, slurry or gauging water may cause skin irritation and/or caustic
burns to mucous membranes (e.g. eyes). Avoid contact with eyes and prolonged skin contact.
After skin contact:
Immediately wipe off substance and wash with plenty of soap and water.
After eye contact:
Rinse eyes for at least 15 minutes under running water with eyelids held open. Immediately consult a doctor.
After swallowing: Rinse out mouth and then drink plenty of water. Seek immediate medical advice.
After inhalation: Supply fresh air and consult doctor.

5 Fire fighting measures

Suitable extinguishing agents: Not applicable


For safety reasons unsuitable extinguishing agents: Not applicable
Protective equipment: No special measures required
General advice: In connection with fire-fighting water a strong alkaline effect is resulting which may cause caustic
injuries and skin provoking.

(Contd. on page 2)
Material Safety Data Sheet. (MSDS)
Printing date 10.06.2005 / Reviewed on 10.06.2005 Page : 2/4

Trade name: V1/50 grout


(Contd. of page 1)

6 Accidental release measures

Person-related safety precautions: Avoid causing dust


Measures for environmental protection: No special measures required
Measures for cleaning/collecting: Collect mechanically
Additional information: No dangerous materials are released

7 Handling and storage

Handling
Information for safe handling: No special measures required
Information about protection against explosions and fires:
No special measures required

Storage
Requirements to be met by storerooms and containers: No special requirements
Information about storage in one common storage facility: Not required
Further information about storage conditions: Keep containers securely closed and dry and frost-free
Storage class: VCI-Storage class: LGK 13: Non-combustible solids
Class according to regulation on inflammable liquids: Void

8 Exposure controls and personal protection

Additional information about design of technical systems:


No further data; see item 7

Components with critical values that require monitoring at the workplace:


CAS-No. Designation of material % Type Value Unit
65997-15-1 Portland cement 25-50 % MAK 5 mg/m

Additional information:
The list that were valid during the compilation were used as basis

Personal protective equipment:


General protective and hygienic measures:
The usual precautionary measures should be adhered to in handling the chemicals.
Breathing equipment: Not required
Protection of hands: Nitrile impregnated cotton-gloves
Penetration time of glove material:
The exact break trough time has to be found out by the manufacturer of the protective gloves and
has to be observed.
Eye protection: Wear safety goggles when working above eye level of if there is danger of splashing.
Body protection: Protective work clothing

9 Physical and chemical properties:

Form: Solid
Colour: Grey
Smell: Odourless
Value/Range Unit Method
Change in condition
Melting point/Melting range: Not determined
Boiling point/ Boiling range: Not applicable

Flash point: Not applicable

Self-in flammability: Product is not self-igniting

Danger of explosion: Product is not explosive


(Contd. on page 3)
Material Safety Data Sheet. (MSDS)
Printing date 10.06.2005 / Reviewed on 10.06.2005 Page : 3/4

Trade name: V1/50 grout


(Contd. of page 2)

Density at 20 C 2,500 kg/dm DIN 51757

Settled apparent density at 20 C 1,606 kg/dm DIN 52110

Solubility in / Miscibility with water at 20 C < 2 g/l

pH-value: (100 g/l) at 20 C > 12-14

Solids content: 100 %

10 Stability and reactivity

Conditions to be avoided:
No decomposition if used according to specifications
Dangerous reactions: No dangerous reactions know
Dangerous products of composition:
None if handled and stored properly

11 Toxicological information

Acute toxicity: Irritating and sensitising


Primary irritant effect:
On the skin: Irritating in applicable consistence
On the eye: Irritant effect
Sensitisation: No sensitising effect known
Additional toxicological information:
The product is subject to classification according to the calculation method of the General EC Classification
Guidelines for Preparations as issued in the latest version: Irritant
12 Ecological information

General notes:
Water hazard class 1 (Self-assessment): slightly hazardous for water. Do not allow product to reach ground
water, water bodies or sewage system.

13 Disposal considerations

Product:
Recommendation:
Smaller quantities can be disposed of with household waste or commercial waste.
Waste key number (D): 31409 LAGA code Designation: rubble
170101 EWC code Designation: concrete
010410 EAK code dusty and powdery wastes other than those
mentioned in 010407.

Unclean packaging:
Recommendation: Disposal must be made according to official regulations
Carefully emptied packs can be disposed of by REPASACK.
Recommended cleaning agent: Water, if necessary with cleaning agent

14 Transport information

Transport / Additional information:


Not classified as dangerous goods as per above regulations

(Contd. on page 4)
Material Safety Data Sheet. (MSDS)
Printing date 10.06.2005 / Reviewed on 10.06.2005 Page : 4/4

Trade name: V1/50 grout


(Contd. of page 3)

15 Regulatory information

Designation according to EC-guidelines:


The product is subject to classification according to the calculation methods of the General Classification
Guideline for Preparations of the EC as issued in the latest version.
Observe the normal safety regulations when handling chemicals.

Code letter and hazard designation of product: Xi Irritant

Hazard-determining components for labelling: Cement

R-phrases:
R 36 Irritating to eyes
R 37 Irritating to respiratory system
R 38 Irritating to skin
R 41 Risk of serious damage to eyes

S-phrases:
S2 Keep out of the reach of children
S 22 Do not breathe dust
S 24/25 Avoid contact with skin and eyes
S 26 In case of contact with eyes rinse immediately with plenty of water and seek medical advice
S 28 After contact with skin wash immediately with plenty of ... (to be specified by the manufacturer)
S 36 Wear suitable protective clothing
S 37 Wear suitable gloves
S 39 Wear eye/face protection
S 46 If swallowed seek medical advice immediately and show this container or label

National regulations:

GISCODE: ZP1

Classification according to VbF: Void

Water hazard class:


Water hazard class 1 (Self-assessment): slightly hazardous for water

UVV: "Application of coating materials (VBG 23)

TRGS 613

16 Other information

These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific
product features and shall not establish a legally valid contractual relationship.
With new edition this expenditure becomes invalid.

Contact: Mr. D. Schempershofe (QS)


MATERIAL SAFETY 3M
DATA SHEET 3M Center
St. Paul, Minnesota
55144-1000
1-800-364-3577 or (651) 737-6501 (24 hours)

Copyright, 2001, Minnesota Mining and Manufacturing Company.


All rights reserved. Copying and/or downloading of this
information for the purpose of properly utilizing 3M products
is allowed provided that:
1) the information is copied in full with no changes unless
prior agreement is obtained from 3M, and
2) neither the copy nor the original is resold or otherwise
distributed with the intention of earning a profit thereon.

DIVISION: ENGINEERED ADHESIVES


TRADE NAME:
3M(TM) Repositionable Spray Adhesive 75
ID NUMBER/U.P.C.:
62-4669-4830-4 00-21200-30067-7 62-4669-4835-3 - - -
62-4669-4836-1 00-21200-30067-6
ISSUED: May 18, 2001
SUPERSEDES: March 06, 2001
DOCUMENT: 07-7835-7

-----------------------------------------------------------------------------
1. INGREDIENT C.A.S. NO. PERCENT
-----------------------------------------------------------------------------

ACETONE................................. 67-64-1 30 - 40
ISOBUTANE............................... 75-28-5 20 - 30
HEPTANE ISOMERS......................... 64742-49-0 20 - 30
PROPANE................................. 74-98-6 7 - 13
NON-VOLATILE COMPONENTS - N.J. TRADE
SECRET REGISTRY NO. 04499600-6146P++.. TradeSecret 7 - 13

IN CASE OF EMERGENCY: THE NUMBERS AT THE TOP OF THIS PAGE PROVIDE 24


HOUR RESPONSE FROM ANY PHONE FOR ALL EMERGENCIES WITH THIS PRODUCT.
The components of this product are in compliance with the chemical
notification requirements of TSCA. All applicable chemical
ingredients in this material are listed on the European Inventory of
Existing Chemical Substances (EINECS), or are exempt polymers whose
monomers are listed on EINECS.

++Synthetic elastomer, resin and stabilizers. Non-Hazardous per WHMIS


criteria. Non-WHMIS controlled.

-----------------------------------------------------------------------------
2. PHYSICAL DATA
-----------------------------------------------------------------------------

BOILING POINT:................. Compressed gas


VAPOR PRESSURE:................ Compressed gas
VAPOR DENSITY:................. N/D
EVAPORATION RATE:.............. N/D
SOLUBILITY IN WATER:........... nil
SPECIFIC GRAVITY:.............. 0.673 Water=1
-----------------------------------------------------------------------------
Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: 3M(TM) Repositionable Spray Adhesive 75
May 18, 2001 PAGE 2

-----------------------------------------------------------------------------
2. PHYSICAL DATA (continued)
-----------------------------------------------------------------------------

PERCENT VOLATILE:.............. ca. 91 % by wt


pH:............................ N/A
VISCOSITY:..................... N/A
MELTING POINT:................. N/D

APPEARANCE AND ODOR:


Compressed Gas, in aerosol, Mild Solvent Odor/Clear-light yellow

-----------------------------------------------------------------------------
3. FIRE AND EXPLOSION HAZARD DATA
-----------------------------------------------------------------------------

FLASH POINT:................... -50.00 F TCC


Propellant
FLAMMABLE LIMITS - LEL:........ N/D
FLAMMABLE LIMITS - UEL:........ Flamm. Gas
AUTOIGNITION TEMPERATURE:...... N/D

EXTINGUISHING MEDIA:
Carbon dioxide, Dry chemical, Foam

SPECIAL FIRE FIGHTING PROCEDURES:


Wear full protective clothing, including helmet, self-contained,
positive pressure or pressure demand breathing apparatus, bunker coat
and pants, bands around arms, waist and legs, face mask, and
protective covering for exposed areas of the head.

UNUSUAL FIRE AND EXPLOSION HAZARDS:


Closed containers exposed to heat from fire may build pressure and
explode. Vapors may travel long distances along the ground or floor
to an ignition source and flash back.

NFPA HAZARD CODES: HEALTH: 2 FIRE: 4 REACTIVITY: 0 AEROSOL STORAGE: 3


UNUSUAL REACTION HAZARD: none

-----------------------------------------------------------------------------
4. REACTIVITY DATA
-----------------------------------------------------------------------------

STABILITY: Stable

INCOMPATIBILITY - MATERIALS/CONDITIONS TO AVOID:


Heat.

HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur.

-----------------------------------------------------------------------------
Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: 3M(TM) Repositionable Spray Adhesive 75
May 18, 2001 PAGE 3

-----------------------------------------------------------------------------
4. REACTIVITY DATA (continued)
-----------------------------------------------------------------------------

HAZARDOUS DECOMPOSITION PRODUCTS:


Carbon Monoxide and Carbon Dioxide, Toxic Vapors, Gases or
Particulates.

-----------------------------------------------------------------------------
5. ENVIRONMENTAL INFORMATION
-----------------------------------------------------------------------------

SPILL RESPONSE:
Refer to other sections of this MSDS for information regarding
physical and health hazards, respiratory protection, ventilation, and
personal protective equipment. Ventilate area. Extinguish all
ignition sources. Cover with absorbent material. Collect using non-
sparking tools. Place in a U.S. DOT-approved container.

RECOMMENDED DISPOSAL:
Incinerate in a permitted hazardous waste incinerator in the presence
of a combustible material. Facility must be capable of handling
aerosol cans. Dispose of empty cans in a sanitary landfill. Dispose
of waste product in a facility permitted to accept chemical waste.

Recycle aerosol cans where available.

ENVIRONMENTAL DATA:
Not determined.

REGULATORY INFORMATION:
Volatile Organic Compounds: ca. 57 % by wt calculated per SCAQMD rule
443.1 (385 gram/liter).
VOC Less H2O & Exempt Solvents: ca. 537 gms/liter calculated per SCAQMD
rule 443.1.

Since regulations vary, consult applicable regulations or authorities


before disposal. U.S. EPA Hazardous Waste Number = D001 (Ignitable)

EPCRA HAZARD CLASS:


FIRE HAZARD: Yes PRESSURE: Yes REACTIVITY: No ACUTE: Yes CHRONIC: Yes

-----------------------------------------------------------------------------
6. SUGGESTED FIRST AID
-----------------------------------------------------------------------------

EYE CONTACT:
Immediately flush eyes with large amounts of water. Get immediate
medical attention.

SKIN CONTACT:
Flush skin with large amounts of water. If irritation persists, get
medical attention.

-----------------------------------------------------------------------------
Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: 3M(TM) Repositionable Spray Adhesive 75
May 18, 2001 PAGE 4

-----------------------------------------------------------------------------
6. SUGGESTED FIRST AID (continued)
-----------------------------------------------------------------------------

INHALATION:
Remove person to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, get immediate medical
attention.

IF SWALLOWED:
Do not induce vomiting. Drink two glasses of water. Call a physician.

-----------------------------------------------------------------------------
7. PRECAUTIONARY INFORMATION
-----------------------------------------------------------------------------

EYE PROTECTION:
Avoid eye contact with vapor, spray, or mist. Wear safety glasses
with side shields.

SKIN PROTECTION:
Avoid prolonged or repeated skin contact.

RECOMMENDED VENTILATION:
Do not use in a confined area or areas with little or no air
movement. If exhaust ventilation is not adequate, use appropriate
respiratory protection. Provide ventilation adequate to control
vapor concentrations below recommended exposure limits and/or control
spray or mist.

RESPIRATORY PROTECTION:
Avoid breathing of vapors, mists or spray. Select one of the
following NIOSH approved respirators based on airborne concentration
of contaminants and in accordance with OSHA regulations: half-mask
organic vapor respirator.

PREVENTION OF ACCIDENTAL INGESTION:


Do not ingest.

RECOMMENDED STORAGE:
Store at temperatures below 120 degrees F (49 degrees C). Keep out
of the reach of children.

FIRE AND EXPLOSION AVOIDANCE:


Aerosol container contains flammable gas under pressure. Keep away
from heat, sparks, open flame, and other sources of ignition.
Extremely flammable liquid and vapor. Do not pierce or burn
container, even after use. Avoid static discharge.

-----------------------------------------------------------------------------
Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: 3M(TM) Repositionable Spray Adhesive 75
May 18, 2001 PAGE 5

-----------------------------------------------------------------------------
7. PRECAUTIONARY INFORMATION (continued)
-----------------------------------------------------------------------------

EXPOSURE LIMITS

INGREDIENT VALUE UNIT TYPE AUTH SKIN*


-----------------------------------------------------------------------------
ACETONE.............................. 500 PPM TWA ACGIH
ACETONE.............................. 750 PPM STEL ACGIH
ACETONE.............................. 750 PPM TWA OSHAV
OSHA VACATED PEL
ACETONE.............................. 1000 PPM STEL OSHAV
OSHA VACATED PEL
ACETONE.............................. 1000 PPM TWA OSHA
ISOBUTANE............................ NONE NONE NONE NONE
HEPTANE ISOMERS...................... 50 PPM TWA CMRG
PROPANE.............................. 1000 PPM TWA OSHA
PROPANE.............................. 2500 PPM TWA ACGIH
NON-VOLATILE COMPONENTS - N.J.
TRADE SECRET REGISTRY NO. 04499600-
6146P++............................ NONE NONE NONE NONE

* SKIN NOTATION: Listed substances indicated with 'Y' under SKIN refer to
the potential contribution to the overall exposure by the cutaneous route
including mucous membrane and eye, either by airborne or, more particularly,
by direct contact with the substance. Vehicles can alter skin absorption.

SOURCE OF EXPOSURE LIMIT DATA:


- ACGIH: American Conference of Governmental Industrial Hygienists
- CMRG: Chemical Manufacturer Recommended Exposure Guidelines
- OSHA: Occupational Safety and Health Administration
- OSHAV: Occupational Safety and Health Administration Vacated PEL.
Vacated Permissible Exposure Limits (PEL) are enforced as
the OSHA PEL in some states. Check with your local
regulatory authority.

- NONE: None Established

-----------------------------------------------------------------------------
8. HEALTH HAZARD DATA
-----------------------------------------------------------------------------

EYE CONTACT:
Moderate Eye Irritation: signs/symptoms can include redness, swelling,
pain, tearing, and hazy vision.

SKIN CONTACT:
Mild Skin Irritation (after prolonged or repeated contact):
signs/symptoms can include redness, swelling, and itching.

-----------------------------------------------------------------------------
Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: 3M(TM) Repositionable Spray Adhesive 75
May 18, 2001 PAGE 6

-----------------------------------------------------------------------------
8. HEALTH HAZARD DATA (continued)
-----------------------------------------------------------------------------

INHALATION:
Intentional concentration and inhalation may be harmful or fatal.

Central Nervous System Depression: signs/symptoms can include


headache, dizziness, drowsiness, incoordination, slowed reaction time,
slurred speech, giddiness and unconsciousness.

Irritation (upper respiratory): signs/symptoms can include soreness


of the nose and throat, coughing and sneezing.

IF SWALLOWED:
Ingestion is not a likely route of exposure to this product.

WHILE THE FOLLOWING EFFECTS ARE ASSOCIATED WITH ONE OR MORE OF THE
INDIVIDUAL INGREDIENTS IN THIS PRODUCT AND ARE REQUIRED TO BE
INCLUDED ON THE MSDS BY THE U.S. OSHA HAZARD COMMUNICATION STANDARD,
THEY ARE NOT EXPECTED EFFECTS DURING FORESEEABLE USE OF THIS PRODUCT.

Ingestion may cause:

Irritation of Gastrointestinal Tissues: signs/symptoms can


include pain, vomiting, abdominal tenderness, nausea, blood in
vomitus, and blood in feces.

-----------------------------------------------------------------------------
SECTION CHANGE DATES
-----------------------------------------------------------------------------

HEADING SECTION CHANGED SINCE March 06, 2001 ISSUE

-----------------------------------------------------------------------------
Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: 3M(TM) Repositionable Spray Adhesive 75
May 18, 2001 PAGE 7

-----------------------------------------------------------------------------

The information in this Material Safety Data Sheet (MSDS) is believed to


be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR
IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF
MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF
PERFORMANCE OR USAGE OF TRADE. User is responsible for determining
whether the 3M product is fit for a particular purpose and suitable for
user's method of use or application. Given the variety of factors that
can affect the use and application of a 3M product, some of which are
uniquely within the user's knowledge and control, it is essential that
the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.

3M provides information in electronic form as a service to its customers.


Due to the remote possibility that electronic transfer may have resulted
in errors, omissions or alterations in this information, 3M makes no
representations as to its completeness or accuracy. In addition,
information obtained from a database may not be as current as the
information in the MSDS available directly from 3M.
03-G661 Page 1 of 4

NOVAGARD
MATERIAL SAFETY DATA SHEET
SECTION 1- CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME: G 661


GENERIC DESCRIPTION: Silicone Compound
CHEMICAL CLASS: Polysiloxane blend

MANUFACTURED BY: NSCG, Inc.


5109 Hamilton Avenue
Cleveland, OH 44114
216-881-8111

EMERGENCY PHONE NUMBER: CHEMTREC 800-424-9300 (24 hour)

REVISED: 10-03-02 PREPARED BY: Brian Chambers

SECTION 2 - HAZARDOUS COMPONENTS

COMPONENT CAS No. WT % OSHA-PEL ACGIH-TLV


TWA STEL TWA STEL

Amorphous Silica 112945-52-5 5-15 10 mg/m3 NE 10 mg/m3 NE

SECTION 3 - EFFECTS OF OVEREXPOSURE

Potential Health Effects

Eye: May irritate eyes


Skin: May cause mild skin irritation
Inhalation: Not anticipated during industril use
Oral: Not anticipated during industrial use

Special Hazards

Carcinogens: This product does not contain any ingredients listed by IARC, NTP or OSHA
as chemical carcinogens.
Teratogens: None known
Mutagens: None known
Reproductive Toxins: None known

SECTION 4 - FIRST AID MEASURES

Eye: Contact with the eyes may cause temporary irritation. Flush eyes with copious amounts of water
for a minimum of 15 minutes. If chronic irritation develops contact a physician.
Skin: Contact with skin is not expected to cause irritation. Wash contacted areas with soap and water.
Oral: If ingested do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek
medical attention. Never give anything by mounth to an unconscious person.
03-G661 Page 2 of 4

NOVAGARD
MATERIAL SAFETY DATA SHEET

SECTION 5 - FIRE FIGHTING MEASURES

Flash Point: >200 (C) >400 (F) (COC Method)


Flammability Limits in Air: Upper - Not Determined Lower - Not Determined
Extinguishing Media: Water, CO2 ,Dry Chemical, Foam.
Special Fire Fighting Procedures: None
Sensitivity to static discharge: None

This product contains Methylpolysiloxanes which can generate formaldehyde at approximately 300o F and above,
in atmospheres which contain oxygen. Formaldehyde is a skin and respiratory sensitizer, eye and throat irritant,
acute toxicant, and potential cancer hazard.

SECTION 6 - ACCIDENTAL RELEASE MEASURES

Disposal of collected product, residues and cleanup materials may be governmentally regulated. Observe all
applicable local, state and federal waste management regulations. Scrape up and contain for salvage or
disposal. Wash all walking surfaces with detergent and water to reduce slipping hazard. Observe all personal and
protection equipment recommendations described in Section 5 and 8. Local, state and federal reporting
requirements may apply to spills or releases of this matter into the environment. See applicable regulatory
compliance information in Section 15.

SECTION 7 - HANDLING AND STORAGE

Precautions: Keep container closed when not in use. Avoid contact with skin and eyes.

SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls

Local exhaust: None needed General ventilation: None needed Eyewash stations: Recommended

Personal Protective Equipment for Routine Handling

Eyes: Safety glasses


Skin: Wash after any contact. Cloth/rubber gloves
Inhalation: None should be needed

SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical form Paste Odor: Odorless


Specific Gravity @25C: 1.02 Boiling Point (@ 760 mm Hg) Not applicable
Freezing/melting point Not applicable Vapor pressure: Not applicable
Evaporation rate: Not applicable Volatile content: Not applicable
Odor threshold Not applicable Percent Volatile by volume: <1.0%
VOC (EPA method 24): Not applicable Evaporation Rate
Solubility in water: Insoluble (butyl acetate =1): Not applicable
Solubility in organic solvent: Mineral spirits
03-G661 Page 3 of 4

NOVAGARD
MATERIAL SAFETY DATA SHEET

SECTION 10 - STABILITY AND REACTIVITY

Chemical stability: Stable


Hazardous polymerization: Will not occur
Conditions to avoid: None known
Materials to avoid: None known
Conditions to avoid: None known
Hazardous thermal decomposition
and combustion by-products: Carbon monoxide, carbon dioxide, silicon dioxide, and
formaldehyde

SECTION 11 - TOXICOLOGICAL INFORMATION

Ames Test:

Product Information
Acute oral LD 50 (mg/kg) unknown
Acute dermal LD50 (mg/kg) unknown
Acute inhalation LC 50 (mg/L) unknown
Other None

SECTION 12 - ECOLOGICAL INFORMATION

OPTIONAL SECTION - complete information not yet available

SECTION 13 - DISPOSAL CONSIDERATIONS

Disposal method: Disposal should be made in accordance with federal, state and local regulations.

SECTION 14 - TRANSPORTATION INFORMATION

DOT shipping name: Not Regulated DOT hazard class : Not Regulated
DOT labels: None UN/NA number: NA
Placards: None IATA: NA
IMO IMDG -code: NA

European Class:
RID (OCTI): NA
ADR (ECE): NA
RAR(IATA): NA
03-G661 Page 4 of 4

NOVAGARD
MATERIAL SAFETY DATA SHEET

SECTION 15 - REGULATORY INFORMATION

TSCA Status:

All chemical substances found in this product comply with the Toxic Substances Control act Inventory reporting
requirements

EPA SARA Title III Chemical Listings:

Section 302: None found

Section 312, 311 Hazard Class: None

Section 313 chemical: None

WHMIS Hazard class:

Not regulated

Hazard Rating System:

HMIS: Flammability 0, Reactivity 0, Health 1


NFAPA: Flammability 0, Reactivity 0, Health 1

California Proposition 65:

None

The information presented in this Material Safety Data Sheet relates only to the specific product designated herein,
and no warranty, or guarantee, either expressed or implied is made regarding the performance and conditions of
this product. This information is based upon information that Novagard believes to be true and accurate; however,
it is the responsibility of each user to review this information within the specific context of their intended
application.
P120-03-005
Issue: A
MATERIAL SAFETY DATA SHEET Rev Date: Dec-01
Page: 1 of 6

PRODUCT NAME : GREASE - KRYTOX SERIES 240 & LVP


FLUORINATED GREASES

1. Product and Company Identification


Product Name: Krytox 240 Series and LVP fluorinated greases
Synonyms: None
Item Numbers : Krytox 240AD : U30002525; U30002206
Krytox 240AB : U30002536; U30002535
Krytox 240AC : U30002538; U30002537
Krytox LVP : U300-02-075, U300-02-539

European Contact Details US Contact Details

BOC Edwards, Manor Royal, Crawley, BOC Edwards, 301 Ballardvale Street,
West Sussex, RH10 2LW, England Wilmington, MA 01887
General enquiries General enquiries
UK : +44 (0)1293 528844 +(1) 978-658-5410
France : +(33) 1 47 98 24 01 Toll Free: 1-800-848-9800
Germany : +(49) 89-991918-0
Italy : +(39) 0248-4471 24 h Emergency telephone number:
Chemtrec : 1-800-424-9300

2. Composition/Information on Ingredients
Ingredient % Weight CAS No Hazard class* Risk phrase*
Perfluoroalkylether Krytox 240 Series: 68-82 60164-51-4 Not applicable Not applicable
Krytox LVP: 70
Polytetrafluoroethylene (PTFE) Krytox 240 Series: 18-27 9002-84-0 Not applicable Not applicable
Krytox LVP: 30
*Hazard class & Risk phrase. These columns are only completed for ingredients which are classified as hazardous
under EU Directive (67/548/EEC, as amended) and are present in sufficient concentration to make the overall
substance hazardous. In all other situations, the column will be completed as Not applicable.

3. Hazards Identification
EMERGENCY OVERVIEW
This material when properly handled according to good working and hygienic practices is not dangerous to human
health and the environment. Product begins to release irritating and toxic fumes above 290oC/554oF.
For short and long term exposure effects see Section 11 Toxicological data

DCC1 No : 705
BOC Edwards is part of BOC Limited
Ref 2D01-010 form issue 1.2 The stripe symbol is a trade mark of the BOC Group
.
P120-03-005
Issue: A
MATERIAL SAFETY DATA SHEET Rev Date: Dec-01
Page: 2 of 6

PRODUCT NAME : GREASE - KRYTOX SERIES 240 & LVP


FLUORINATED GREASES

Eye Effects: Excessive exposure may cause irritation, discomfort, excessive lacrimation and blurred
vision.
Skin Effects: Excessive exposure may cause irritation, discomfort and rash.
Ingestion/ Oral Relatively non-toxic. (Oral LD50 > 25000 mg/kg).
Effects:
Inhalation Effects: Low volatility makes inhalation an unlikely hazard in normal use. The thermal decomposition
vapours of fluorinated polymers may cause polymer fume fever with flu like symptoms in
humans, especially when smoking contaminated tobacco.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: None known.

NFPA Hazard codes HMIS Hazard codes Rating System


Health 1 Health 1 0 = No Hazard
Flammability 0 Flammability 0 1 = Slight hazard
Instability 0 Reactivity 0 2 = Moderate Hazard
3 = Serious Hazard
4 = Severe hazard

4. First Aid Measures


Eyes: Wash/rinse with plenty of water. If irritation persists consult a specialist.
Skin: Wash off with soap and water. If irritation persists, seek medical attention.
Ingestion/Oral: Rinse mouth. Drink water as a precaution. Do not induce vomiting without medical advice.
Inhalation: Move to fresh air in case of accidental inhalation of vapours of decomposition products. If
breathing problems occur, a qualified individual should administer oxygen or artificial
respiration as indicated. Seek immediate medical attention.
Other Information: Never give anything by mouth to an unconscious person. If substantial quantities are
ingested, seek medical attention.

5. Fire Fighting Measures


Extinguishing Media: The products do not burn. Select extinguishing media to suit other material(s)
involved.
Fire and Explosion Hazard: Possible risk due to irritation and toxic affects of thermal combustion products at
temperatures above 290 oC/554oF. Fire may produce toxic fluorine compounds
including hydrogen fluoride, phosgene, and perfluoroolefins.
Special Protective Equipment Fire fighters should wear a self-contained breathing apparatus (SCBA) which
for Fire Fighters: meets appropriate standards operated in positive pressure mode. Skin protection
should be worn to protect from thermal combustion products.
For Flammability Properties - see Section 9

DCC1 No : 705
BOC Edwards is part of BOC Limited
Ref 2D01-010 form issue 1.2 The stripe symbol is a trade mark of the BOC Group
.
P120-03-005
Issue: A
MATERIAL SAFETY DATA SHEET Rev Date: Dec-01
Page: 3 of 6

PRODUCT NAME : GREASE - KRYTOX SERIES 240 & LVP


FLUORINATED GREASES

6. Accidental Release Measures


In the event of spillage :
Wear personal protective clothing (see Section 8 Exposure Controls and Personal Protection).
Recover released product and collect in a suitable container for reuse or disposal. Wash area to prevent slip
hazard.
Avoid discharge into sewage systems, surface or underground waters and the soil.

7. Handling and Storage


Handling : avoid temperatures above 290oC/554oF without adequate ventilation. Avoid contact with eyes and skin.
Storage : keep containers tightly closed and store in dry, cool well-ventilated areas. No special restrictions on
storage with other products. Store in glass or polythene containers.
Do not carry cigarettes or cigars or smoke in areas where this product is being used or stored. Greasy hands may
contaminate tobacco products. Smoking contaminated products may cause polymer fume fever. Wash thoroughly
after handling and before meals and breaks.

8. Exposure Controls/Personal Protection


Exposure Limits
Ingredient ACGIH - TLV - OSHA - PEL Occupational Exposure
Limits EH40 (UK)
None Not applicable Not applicable Not applicable

Personal Protection:
Engineering Measures: None required under normal conditions of use. Heat only in areas with appropriate
exhaust ventilation.
Respiratory Protection: None required under normal conditions of use. Wear suitable self-contained
breathing apparatus if heating above 290oC/554oF.
Hand/Skin Protection: Wear impervious gloves.
Eye/Face Protection: Use safety glasses.
Hygiene Measures: Wash hands before taking breaks and immediately after handling the product.
Keep away from tobacco products.
Other/General Protection: None.

DCC1 No : 705
BOC Edwards is part of BOC Limited
Ref 2D01-010 form issue 1.2 The stripe symbol is a trade mark of the BOC Group
.
P120-03-005
Issue: A
MATERIAL SAFETY DATA SHEET Rev Date: Dec-01
Page: 4 of 6

PRODUCT NAME : GREASE - KRYTOX SERIES 240 & LVP


FLUORINATED GREASES

9. Physical and Chemical Properties


0
Appearance and Odour Solid white odourless grease Boiling Point No data available C/ 0F
0
pH (as supplied) Neutral Freezing Point 320/608 C/ 0F
0
Solubility in Water Negligible Auto Ignition Not applicable C/0F
0
Volatile Content by Volume No data available Flash Point Does not burn C/ 0F
Specific Gravity 1.89 - 1.93 @ 250C /77 0F
Vapour Pressure (mbar) No data available Vapour Pressure (Torr) No data available

10. Stability and Reactivity


Stability: Stable
Material/Conditions to Avoid: No materials to be specifically avoided. Avoid heating to above 290oC/554oF.
Hazardous Decomposition: Vapours which may irritate the respiratory system may be released above
290oC/554oF. Thermal decomposition will produce toxic fluorine compounds.

11. Toxicological Information


For a comprehensive description for the various toxicological (health) effects which may arise if the user comes
into contact with the substance or preparation refer to Section 3 Hazards Identification.
Animal Data:
ALD value: Dermal : >17000mg/kg (rat)
Oral : >25000mg/kg (rat)
ALC value: Inhalation /4h :>19.54 mg/l (rat)
The figures stated above are for perfluoroalkylether.
Note: ALD/ALC: Average lethal dose/ average lethal concentration.
Carcinogenicity:
No information available.
Toxicity information for PTFE decomposition products:
Inhalation: PTFE decomposition products vary widely in toxicity in experimental animals. Four hour LC50s
(inhalation) for decomposition products range from 0.76 ppm (perfluoroisobutane) to 40,000 ppm
(tetrafluoroethylene monomer). Workers exposed to PTFE fumes produced at 350-380 C (temperatures
associated with liberation of hexafluoroethane, perfluoroisobutylene, and octafluorocyclobutene) exhibited
symptoms consistent with polymer fume fever at workplace air concentrations of 3.5 mg/m3 compounds containing
fluorine.
Chronic: Repeated episodes of polymer fume fever may damage the lungs.

DCC1 No : 705
BOC Edwards is part of BOC Limited
Ref 2D01-010 form issue 1.2 The stripe symbol is a trade mark of the BOC Group
.
P120-03-005
Issue: A
MATERIAL SAFETY DATA SHEET Rev Date: Dec-01
Page: 5 of 6

PRODUCT NAME : GREASE - KRYTOX SERIES 240 & LVP


FLUORINATED GREASES

12. Ecological Information


No information available.
13. Disposal Considerations
Waste from residue/unused products : dispose of as special waste in compliance with the Control of Pollution
(Special Waste) Regulations 1980 (UK), or other relevant national or international regulations.
Contaminated packaging : if recycling is not practicable, dispose of in compliance with the Environmental Protection
(Duty of Care) Regulations 1991 (UK), or other relevant national or international regulations.

14. Transport Information


This product is not regulated as dangerous under transport regulations.

PARAMETER EUROPEAN CANADIAN TDG UNITED STATES DOT


Proper Shipping Name Not applicable Not applicable Not applicable
Hazard Class Not applicable Not applicable Not applicable
Identification Number Not applicable Not applicable Not applicable
Shipping Label Not applicable Not applicable Not applicable

15. Regulatory Information


European Regulatory Information
This product has been classified in accordance with the Dangerous Substances Directive (67/548/EEC, as
amended) and the Preparations Directive (88/379/EEC, as amended), implemented in the UK as the Chemical
(Hazard Information and Packing) Regulations 1994 (CHIP, as amended).
Classified as dangerous to supply : No
Risk Phrases : Not applicable
Safety Phrases : Not applicable
Symbols : None

United States Regulatory Information


All ingredients contained in this product are included on the EPA TSCA Chemical Substance Inventory.
SARA TITLE III - SECTION 313 SUPPLIER NOTIFICATION:
This product does not contain toxic chemicals subject to the reporting requirements of section 313 of the Emergency
Planning and Community Right-To-Know Act (EPCRA of 1986 and 40 CFR Part 372.
California Proposition 65: This product does not contain chemicals known to the State of California to cause cancer,
birth defects, or other reproductive toxicity.

DCC1 No : 705
BOC Edwards is part of BOC Limited
Ref 2D01-010 form issue 1.2 The stripe symbol is a trade mark of the BOC Group
.
P120-03-005
Issue: A
MATERIAL SAFETY DATA SHEET Rev Date: Dec-01
Page: 6 of 6

PRODUCT NAME : GREASE - KRYTOX SERIES 240 & LVP


FLUORINATED GREASES

Canadian Regulatory Information


All ingredients contained in this product are included on the Canadian DSL.
WHMIS Classification: D2B

16. Other Information


This MSDS is compiled in accordance with ANSI Z400.1 and the EU Safety Data Sheet Directive 91/155/EEC.
Sources of information for this data sheet:
DuPont Safety Data Sheet for Krytox Series 240 &250; Krytox GPL202; 203; 205; 206; 207. Reference :
000000485/N/GB. Revision Date : 6 June, 1997.
DuPont Safety Data Sheet for Krytox LVP fluorinated grease. Reference : 000002407/N/GB. Revision Date : 30
March, 1994.
National Library of Medicine (NLM) electronic databases (HSDB, RTECS, CHEMID, Toxline)

Glossary : CAS, Chemical Abstracts Service; NFPA, National Fire Protection Association; HMIS, Hazardous
Material Information Service; LD, Lethal Dose; LC, Lethal Concentration; ACGIH, American Conference of
Governmental Industrial Hygienists; TLV, threshold limit value; OSHA, Occupational Safety and Health
Administration, US department of Labour; PEL, Permissible exposure limit; EH40 (UK), HSE Guidance Note EH40
Occupational exposure limits; PPM, parts per million; TWA, Time-Weighted Average; STEL, Short Term Exposure
Limit; Canadian TDG, Canadian Transportation of Dangerous Goods; US DOT, US Department of Transportation
HSDB
Revisions

___________________________________________________________________________________________
Although the information and recommendations in this data sheet are to the best of our knowledge correct, it is recommended that
you make your own determination of the materials suitability for your purpose before you use it. The information contained in this
data sheet has been reproduced from the manufacturers data, the accuracy of this information is the responsibility of the
manufacturer. BOC Edwards accept no responsibility for damage of any nature resulting from the use of, or the reliance upon this
data sheet.

DCC1 No : 705
BOC Edwards is part of BOC Limited
Ref 2D01-010 form issue 1.2 The stripe symbol is a trade mark of the BOC Group
.