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  • Compressibility Factor

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    ABP
    36 tayangan4 halaman
    This document contains: 1) A table of compressibility factors Z for isobutane at pressures from 0.1 to 15.41 bar and temperatures from 340 to 380 K. 2) Equations for calculating the entropy S of isobutane as a function of temperature T, pressure P, and compressibility factor Z. 3) Details on calculating the residual entropy Sres by plotting (Z-1)/P versus P, calculating the integral of this function, and substituting into the equation for Sres.

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    This document contains: 1) A table of compressibility factors Z for isobutane at pressures from 0.1 to 15.41 bar and temperatures from 340 to 380 K. 2) Equations for calculating the entropy S of isobutane as a function of temperature T, pressure P, and compressibility factor Z. 3) Details on calculating the residual entropy Sres by plotting (Z-1)/P versus P, calculating the integral of this function, and substituting into the equation for Sres.

    Hak Cipta:

    © All Rights Reserved
    Unduh sebagai PDF, TXT atau baca online dari Scribd
    Tandai sebagai konten tidak pantas
    36 tayangan4 halaman

    Compressibility Factor

    Diunggah oleh

    ABP
    This document contains: 1) A table of compressibility factors Z for isobutane at pressures from 0.1 to 15.41 bar and temperatures from 340 to 380 K. 2) Equations for calculating the entropy S of isobutane as a function of temperature T, pressure P, and compressibility factor Z. 3) Details on calculating the residual entropy Sres by plotting (Z-1)/P versus P, calculating the integral of this function, and substituting into the equation for Sres.

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    © All Rights Reserved
    Unduh sebagai PDF, TXT atau baca online dari Scribd
    Tandai sebagai konten tidak pantas
    dari 4

    Table 6.

    1 Compressibility Factors Z for Isobutane


    P (bar) 340 350 360 370 380 T (K)
    0.1 0.997 0.99719 0.99737 0.99753 0.99767
    0.5 0.98745 0.9883 0.98909 0.98977 0.9904
    2 0.95895 0.96206 0.96483 0.9673 0.96953
    4 0.92422 0.93069 0.93635 0.94132 0.94574
    6 0.88742 0.89816 0.90734 0.91529 0.92223
    8 0.84575 0.86218 0.87586 0.88745 0.89743
    10 0.79659 0.82117 0.84077 0.85695 0.87061
    12 0.7731 0.80103 0.82315 0.84134
    14 0.75506 0.78531 0.80923
    15.41 0.71727

    For entropy of isobutane:




    = 0 + +
    0 0


    0 = 295.976



    = 1
    0
    0



    = 295.976 + + 1
    0 0 0
    0
    To calculate for

    a. Plot (Z-1)/P vs P at T=360 K (Z-1)/P vs P


    0
    P Z (Z-1)/P 0 5 10 15 20
    0.1 0.99737 -0.0263 -0.005
    0.5 0.98909 -0.02182
    2 0.96483 -0.017585 -0.01
    4 0.93635 -0.0159125
    -0.015
    6 0.90734 -0.015443333
    8 0.87586 -0.0155175 -0.02
    10 0.84077 -0.015923
    y = -6.83327E-08x6 + 3.53804E-06x5 - 7.16116E-05x4 + 0.00071748x3 -
    12 0.80103 -0.016580833 -0.025 0.003756756x2 + 0.009976341x - 0.02675554
    14 0.75506 -0.017495714 R = 0.988044868
    15.41 0.71727 -0.018347177 -0.03
    b. Calculate value of

    The value of the integral is -0.25934908


    Sres/R -0.67076132
    Sres -5.576709614 J/mol-K
    (J/mol-K)
    So 295.976 To 300
    Rln(P/Po) 22.73892842 T 360
    Sres -5.576709614 A 1.7765
    S 286.8333958 B 0.033037
    tau 1.2
    ICPS 2.306114
    ln(P/Po) 2.735017

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