A B C D E F G H I J

1 Example 20.1, p. 594. Fitting data to Langmuir adsorption isotherm using the Solver.
2
3 Model parameters
4 om = 0.1361804 Guessed values were 0.14, 1.
5 K= 25.859883
6
max p
7 p-CO2
mm Hg
omega
g/g
model Residual R^2

Kp
8
9 0 0 0 0 0
10 25 0.0669 0.066939 -3.901E-05 1.521E-09
11 50 0.0924 0.089758 0.00264215 6.981E-06
12 100 0.108 0.1082 -0.0002 4E-08
13 200 0.114 0.120588 -0.0065884 4.341E-05
14 400 0.127 0.127911 -0.000911 8.299E-07
15 760 0.137 0.131699 0.00530082 2.81E-05
16
17 sum R^2 = 7.936E-05
18
19
20
21 Langmuir Isotherm Fit to Data
22
23
24
0.15
25
26 0.125
g CO2/g adsorbent

27
28 0.1
29
30
31 0.075
32
33 0.05
34
35
36
0.025
37
38 -2.08166817117217E-17
39 0 200 400 600 800
40
41
-0.025
42
43 p, CO2, mm Hg
44
45
Example 20.1, p. 594. Fitting data to Langmuir adsorption isotherm using a straight line.

p-CO2 omega p^-1 omega^-1

mm Hg g/g 1 K 1 1

0
25
0
0.0669 0.04 14.94768
max p max
50 0.0924 0.02 10.82251
100 0.108 0.01 9.259259 omega_max = 0.135669 g/g
200 0.114 0.005 8.77193 K= 25.38767 mm Hg
400 0.127 0.0025 7.874016
760 0.137 0.001316 7.29927

Straight Line Plot

16

f(x) = 187.1344231015x + 7.370920257

1/omega, g adsorbent/g adsorbate

14
R = 0.989390163
12

10

0
0 0.005 0.01 0.015 0.02 0.025 0.03 0.035 0.04 0.045

1/p, (mm Hg)^-1

0.04 0.045