Data analysis
The captured images were downloaded to a personal computer
and sized using Optimas imaging software (Media Cyberbetics
Inc, Silver Spring, MD, USA). The software was calibrated by
placing an object of known size in the field of view of the
camera. For the purposes of cluster analysis, two parameters
were calculated and reported: the mean arithmetic equivalent
diameter and the cluster shape factor.
FIG 1 - Diagrammatic sketch of the apparatus. To calculate the mean arithmetic equivalent diameter, Optimas
first counts the number of pixels within a tracing. Then knowing
the dimensions of a single pixel, Optimas calculates the area
within the tracing. Optimas finally calculates the diameter Deq of
stator
a circle with the same area as the traced image:
rotor
location
4np 2s
255 mm
lip
ps is the width of a square pixel
The mean arithmetic circularity is defined as the square of the
10 mm launder perimeter of a traced area, divided by the area, according to
255 mm
Equation 2:
p2
C = (2)
FIG 2 - Sketch showing the location of the bubble sampling probe A
in the flotation cell.
where:
to each other at the time the image was recorded. Only by C is the mean arithmetic circularity
inspecting a series of frames, could it truly be concluded that a
group of bubbles are in fact rising as a cluster. P is the perimeter
A is the area
Experimental procedure
The circularity thus defined is a dimensionless number lying
Experiments were carried out in batch mode. A known amount of between 4 for a perfect circle and infinity for a line. The
silica was added in the cell to produce slurry at ten per cent circularity is related to the shape factor Sf described in Equation
solids by mass. Dodecylamine (DDA) and frother were then 3, which ranges from zero for a line to one for a perfect circle:
added and conditioned for 15 min. The collector concentration
and the frother concentration were 200 g/t of silica and 25 ppm 4A 4
in all tests, respectively. The impeller speed was varied from 700 Sf = = (3)
P2 C
P = PO N 3 D5 (4)
where:
is the density of the pulp
N is the rotational speed
D is the impeller diameter
Po is the dimensionless power number
The impeller design used in this study was similar to that of a
Chile-X impeller, for which the dimensionless power number is
0.67 (Jameson, 1989).
Values of the power input at various impeller speeds, as
calculated using Equation 4, are shown in Table 1, together with
measured cluster equivalent diameters, which are also shown in
Figure 3. The cluster size increases continuously with increasing
impeller speed, to reach a maximum at approximately 1400 rpm
(after which it decreases with further impeller speed. The initial FIG 3 - The equivalent diameter of bubble clusters, bubbles in
increase in the clusters size indicates that initially the turbulence clusters and freely rising individual bubbles, as a function of
created in the cell promotes cluster formation probably due to impeller speed.
increasing collision rates between individual bubbles or bubble
aggregates. It seems that at higher impeller speeds, the bubble towards smaller bubbles due to bubble break-up. However, the
aggregates undergo break-up because of high shear rates, as is shear rate does not have a pronounced effect on the bubble size for
evident from the decrease in cluster size above 1400 rpm the impeller speed range used in the present work (see Figure 5).
approximately. Figure 4 shows the average shape factor Sf of the clusters, as a
The rates of bubble-particle collision and bubble-particle function of impeller speed. The average shape factor, which has a
aggregate break-up are largely determined by the local energy value of zero for bubbles arranged along a straight line, and one
dissipation rate. For a given system, the local dissipation rate in for a perfectly spherical cluster, is not strongly affected by the
an agitated vessel decreases rapidly with the distance from the impeller speed, assuming values between 0.4 and 0.5 which is
impeller. In a flotation cell, the energy dissipation around the midway between the two extremes. Thus it appears that the
impeller zone is usually five to 30 times higher than the average clusters do not adapt a particular shape as the energy intensity
value which means that successful cluster formation is unlikely and hence the shear in the cell is increased.
to be achieved there. It has been shown that the spatial An increase in shear rate affects not only the collision rate
distribution of local energy dissipation is practically independent between bubbles and particles but also the breakup of the bubbles
of impeller speed, but is strongly influenced by impeller type and themselves in the cell. To investigate the effect of the agitation
cell geometry (Hui, 2000). Therefore, it is likely that different rate on the bubble break-up, the bubble size was measured as a
impellers and flotation cells will result in different bubble function of impeller speed ranging from 450 to 1000 rpm, in the
aggregate behaviour. absence of particles. The results are given in Figure 5 where the
The effect of the agitation rate on the average size of the average and Sauter-mean diameters of the bubbles are shown as a
bubbles in the clusters is shown in Figure 3. It is seen that the function of the impeller speed in the cell. The difference between
bubble size shows a very small continuous increase with impeller the Sauter-mean diameter, which is the volume-to-surface mean
speed, suggesting that the clustering phenomenon has a minimal bubble diameter, and the average diameter, is an indication of the
influence on the bubble size within the clusters. Also shown in spread of bubble sizes. For a mono-size distribution, the average
Figure 3 is the average size of the individual free bubbles in the and the Sauter-mean bubble sizes are the same while for a scatter
cell, ie those not involved in clusters, as a function of impeller of sizes, the Sauter mean is larger then the arithmetic mean,
speed. The average sizes of the independent bubbles do not show because the former is strongly influenced by the larger bubbles
much change with changes in impeller speed. As the shear (Parthasarathy et al, 1992). As can be seen from Figure 5, as the
increases, the bubble distribution is expected to shift more impeller speed is increased, both the Sauter-mean diameter and
CONCLUSIONS
The effect of impeller speed on cluster formation in a flotation
cell was investigated. A device was used in which bubbles were
allowed to rise from the cell into a viewing cell containing clean
water and frother where clusters could be recorded and analysed.
The sizes of the bubbles in the clusters, the effective diameters of
the clusters, and the diameters of the individual bubbles not
involved with clusters, were all measured as a function of
impeller speed. It was found that there was an intermediate
impeller speed where the equivalent diameter of the clusters was
a maximum, and beyond this speed, the cluster size decreased
due to breakage of clusters in the cell.
FIG 4 - The effect of impeller speed on the shape factors Sf of The sizes of the bubbles in the clusters were measured, as were
clusters.
the averages of the independent bubbles present in the cell, for
comparison. It was found that the equivalent diameter of the
bubbles included in clusters was not strongly dependent on the
impeller speed but was slightly larger than the size of the
independent bubbles, indicating that lager bubbles are more
effective in forming bubble clustering. The average cluster shape
factor Sf was about 0.4, showing that the clusters were rather
irregular in shape, intermediate between a linear and a spherical
shape. The shape factor was not sensitive to the impeller speed.
ACKNOWLEDGEMENTS
The authors would like to acknowledge the Australian Research
Council for its support the Special Research Centre for
Multiphase Processes.
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