KMnO4 + H2SO4 + FeSO4 K2SO4 + MnSO4 + Fe2(SO4)3 + H2O

Redox reactions 2-
Cr(OH)3 + IO-3 I- + CrO4 [ in basic medium]
1. Fill in the blank :
(i) Oxidation number of free elements or atoms is . AsO33 MnO 4 AsO34 MnO 2 [alkaline medium]
(ii) Oxidation number of allotropes is .. 10. In the following redox reaction find x,y,z
(iii) Oxidation number of atoms in homo-nuclear molecules is
. x CrCl3 + y H2O2 + z NaOH Na2CrO4 + NaCl + H2O
(iv) Oxidation number of mono-atomic ions is equal to 11. Explain, why?
..on them . (a) H2S acts as reductant whereas, SO2 acts as
(v) Oxidation number of .. in compounds is - 1
reductant and oxidant both.
(vi) Oxidation number of H in its compounds is .. ,
except in metalhydrides where it is .. . (b) H2O2 acts as reductant and oxidant both.
(vii) Oxidation number of O is .in its compounds , but in 12. Find which one is disproportionation and why?
F2O it is and in peroxides it is and .in KO2 .
(viii) Oxidation number of alkali metals in their compounds
(ix) The oxidation states of iodine in HIO4 ,H3IO5
andH5IO6 respectively, are : .. 13. Write complete balanced equation for the following in
1. Calculate the oxidation number of acidic medium by(a) ion-electron and (b)oxidation
(a) Cr in (chromyl chloride) CrO2Cl2 number method
(b)iron in Fe(CO)5., FeSO4 (NH4)2SO4 . 6H2O (a) HCl + KMnO4
Cl2 + KCl + MnCl2 + H2O

(c) Co in [Co(NH3)6]Br3., (e) of Cr in CrO5 , (b) Br + Br O 3 + H+
Br2 + H2O
(f)sulphur in peroxo mono sulphuric acid (H 2SO5) 14. Write complete balanced equation for the
(g)chlorine in bleaching powder CaOCl2. following in basic medium by ion-electron metho

(h) P in Ba (H2PO2)2 is (i) N in (a) C2H5OH + Mn O 4
C2H3O + MnO2(s) + H2O
(i) sulphur in H2S2O7 and H2S2O8 Cr O 24 + I O 4 + H2O
(b) CrI3 + H2O2 + OH
(j) H in NaBH4 and LiAlH4 15.
(k) P in KH2PO2
2. Which can act as a reducing agent
(i)HNO3(ii)H2SO4(iii) H2S (iv) K2MnO4 v) HClO4 (6) H2O2
3. Which can act as a oxidising agent in above 16. by1mole of KMnO4 . ions in acidic medium(5/2)
and which can show proportionation ?
17. Is this a redox reaction,justify your answer
4. Find oxidation and reduction in the given reeaction
18.

5. The value of n in the equation

19.
MnO4- + 8H+ + ne -- Mn2+ + 4H2O is
6. Oxidation numbers ofA, B and C are +6, -2 and-1,
respectively. What will be the formula of the
molecule whenA,BandC associate with each other ? 20. Using Stock notation, represent the following compounds
7. Which of the following, do not show disproportionation :HAuCl4, Tl2O, SnO, Fe2O3, CuI, CuO, MnO and MnO2
and why ? ClO, ClO2, ClO3 and ClO4- 21. Justify that the 2Cu2O(s) + Cu2S(s) 6Cu(s) + SO2(g) is
8. Select the species acting as reductant and a redox reaction
oxidant in the reaction given below : 22. Write the net ionic equation for the reaction of potassium
dichromate(VI), K2Cr2O7 with sodium sulphite, Na2SO3, in
i)SO2 + 2H2S
3S + H2O an acid solution to give chromium(III) ion and the sulphate
ii)BaCl2 + Na2SO4
BaSO4 + 2NaCl ion
ii)3I2 + 6NaOH
NalO3 + 5Nal + 3H2O 23. Permanganate ion reacts with bromide ion in basic
medium to give manganese dioxide and bromate ion.
9. Balance the reactions by oxidation number method: Write the balanced ionic equation for the reaction.
Zn + N O 3
Zn2+ +N2O + H2O (Acidic Medium)
MnO4-+ C2O4-2 + H+ CO2 + Mn+2 + H2O CHEMISTRY BY MUKESH SHARMA