Plants do not get their nitrogen directly from the air.

Although nitrogen is the most

abundant element in the air, every nitrogen atom in the air is triple-bonded to
another nitrogen atom to form molecular nitrogen, N2. This triple bond is very strong
and very hard to break (it takes energy to break chemical bonds whereas energy is
only released when bonds are formed). As a result, even though nitrogen in the air is
very common, it is energetically unfavorable for a plant to split the nitrogen molecule
in order to get the raw atoms that it can use. The strong triple bond of N 2 also makes
it hard for molecular nitrogen to react with most other chemicals. This is, in fact,
part of the reason there is so much nitrogen in the air to begin with. Also, the
stability and symmetry of the nitrogen molecule makes it hard for different nitrogen
molecules to bind to each other. This property means that molecular nitrogen can be
cooled to very low temperatures before becoming liquid, leading liquid nitrogen to be
a very effective cryogenic liquid.
 Plants get their nitrogen from the soil and not directly from the air. Public Domain Image, source:
Christopher S. Baird.

The act of breaking apart the two atoms in a nitrogen molecule is called "nitrogen
fixation". Plants get the nitrogen that they need from the soil, where it has already
been fixed by bacteria and archaea. Bacteria and archaea in the soil and in the roots
of some plants have the ability to convert molecular nitrogen from the air (N 2) to
ammonia (NH3), thereby breaking the tough triple bond of molecular nitrogen. Such
organisms are called "diazotrophs". From here, various microorganisms convert
ammonia to other nitrogen compounds that are easier for plants to use. In this way,
plants get their nitrogen indirectly from the air via microorganisms in the soil and in
certain plant roots. Note that lightning and high-energy solar radiation can also split
the nitrogen molecule, and therefore also fixes the nitrogen in the air. However, the
amount of nitrogen fixed by lightning and solar radiation is insignificant compared to
the amount fixed by diazotrophs in the soil and in roots. In his book Nitrogen Fixation,
John Postgate states,

The fixation of nitrogen the conversion of atmospheric nitrogen into a form that
plants can use is a process fundamental to world agriculture. It comes about as a
consequence of spontaneous, anthropogenic and biological activities. The existence
and importance of the biological component have been recognized for more than a
century, but scientific advances over the past few decades have radically altered our
understanding of its nature and mechanisms.