Recovery
Efficiency
60%+ MAXIMIZING OIL RECOVERY
EFFICIENCY AND SEQUESTRATION
OF CO2 WITH NEXT GENERATION
CO2-EOR TECHNOLOGY
Todays Oil
Recovery
Efficiency
33% Presented by:
Vello A. Kuuskraa, President
Advanced Resources International
vkuuskraa@adv-res.com
May 2008
SPE FOUNDATION
The Society gratefully acknowledges
those companies that support the program
by allowing their professionals
to participate as Lecturers.
Future Challenge
390 Billion Barrels
Cumulative Production
175 Billion Barrels
Proved Reserves
21 Billion Barrels
Antrim Gas
LaBarge Plant
Gas Plant
10 8
2
1 Currently
Currently,105
105 CO2-EOR
1 Enid Fertilizer projects provide 250,000
McElmo Dome Plant
Sheep Mountain B/D
Bravo
JA Dome 7
F 0 19
94 Jackson Affordable natural CO2
.C D
R
Dome launched CO2-EOR
61 1 activity in the 1980s
Val Verde
Gas Plants 14 Federal tax credits
(Sec.43) and state
severance tax relief still
Source: Oil and Gas Journal, 2008. encourage CO2-EOR
JAF02742..PPT 5 May 9, 2008
Growth of CO2-EOR Production in the U.S.
JAF2008008.XLS
300,000
GULF COAST/OTHER
ced Oil Recovery
MID-CONTINENT
250,000
ROCKY MOUNTAINS
PERMIAN BASIN
y)
200 000
200,000
(barrels/day
150,000
Enhanc
100,000
50,000
0
1986 1988 1990 1992 1994 1996 1998 2000 2002 2004 2006 2008
Y
Year
Source: Oil and Gas Journal, 2008.
CO2
Pure CO2 Vaporizing
p g Original
g
C d i
Condensing
CO2 Oil Components Oil
Into Oil
Direction of Displacement
100
88.1
80
n Barrels
60
47.4
Billion
40
20
23
2.3
0
Technically Economically Already
Recoverable Recoverable* Produced/
Proven
*Assuming oil price of $70/B (real); CO2 costs (delivered to field at pressure) of $45/metric ton
($2.38/Mcf); investment hurdle rate (15%, real).
14,000
12,500
12,000
9,700
,
ns
10 000
10,000
n Metric Ton
8,000 7,500
6,000
,
Million
4,000 2,800*
2,200**
2,000
0
Total U.S. New Net Lower-48
CO2 Demand Lower-48 From Captured
CO2 Demand CO2 Emissions
TOTAL 2 400
2,400 645
* Source: 12th Annual CO2 Flooding Conference, Dec. 2006
** MMcfd of CO2 can be converted to million metric tons per year by first multiplying by 365 (days per year) and then dividing by 18.9 * 103 (Mcf per metric ton).
80% Jay
S lt Creek
Salt C k
y Factor
Means
Recovery
2003 Recovery
Time
Background
Th
The Means
M oilil fifield
ld iis llocated
t d iin th
the
West Texas portion of the Permian
Basin, near Midland (Andrews
County)
Cou ty) Texas.
e as
The field is located along the eastern
edge of the Central Basin Platform.
Th
The field
fi ld was discovered
di d iin 1934
and developed on 40-acres well
spacing in the 1950s. Water
injection
j began
g in 1963,, using g an 80-
acre inverted nine-spot pattern.
A full-scale CO2 miscible flood was initiated in 1983 in the upper zones of
the Means San Andres Unit,
Unit encompassing 8 8,500
500 acres and holding 230
MMB of OOIP.
Reservoir Properties
Reservoir Depth, ft* 4,400 The Grayburg/San Andres
Area acres
Area, formations are at depths ranging
- Field 14,300 from 4,200 to 4,800 feet.
- Unit 8,500
Significantly, the reservoirs oil is
Net Pay, Ft 29o API with a viscosity of 6 cp
cp.
- Upper San Andres 54 The minimum miscibility pressure
- Total 120(e) (MMP) is 2,000 psi.
Average Porosity, % 9%
The reservoir has a net pay of 54
Average Permeability, md 1
feet in the Upper San Andres Flow
Initial Water Saturation 0.29 Unit (within a 300 foot gross
Initial Formation Volume Factor 1.04 interval), a porosity of 9% and a
Initial Reservoir Pressure, psig 1,850 permeability
bilit off 1 tto 20 md.
d
Current Reservoir Pressure, psig 2,000
Reservoir Temperature, oF 105
Oil Gravity,
G it oAPI 29
Oil Viscosity, cp 6
CO2-EOR Development
p
Summary
The Means case study is an example of effectively
applying
l i CO2-EOREOR to
t a high
hi h viscosity,
i it low
l API gravity
it oilil
reservoir with an underlying weak aquifer.
An integrated infill drilling and CO2 WAG flood has raised
oil recovery efficiency from about 25% to an expected
50%.
Of the 25% of OOIP increase in recovery efficiency, 15%
OOIP is due to CO2-EOR and 10% OOIP is due to infill
development associated with CO2-EOR.
Background
g
The Salt Creek Field is located in the
Permian Basin of West Texas (Kent
(
Salt Creek
County, Texas). With 700 million barrels Field
of OOIP, it is one of the major oil fields
located on the northeast end of the
Horseshoe Atoll oil play
play.
The field produces from a
Pennsylvanian-age Canyon Reef
carbonate at a depth of 6
6,300
300 feet
feet.
The 12,100-acre field contains two
limestone build-ups, not in pressure
communication.
Oil production at Salt Creek began in 1950. A centerline waterflood was
started in 1953.
Tertiary
T ti oilil recovery (CO2 WAG) began
b in
i 1993 iin th
the main
i pay zone
(MPZ) and later expanded to the residual oil zone (ROZ) in 2000.
Reservoir Properties
Current Reservoir Pressure, psig 3,150 The field averages 100 feet of
net pay, 11% porosity and 20
Reservoir Temperature, oF 129
md permeability (with 1 to
Oil Gravity, oAPI 39 2,000 md of permeability in
Oil Viscosity, cp 0.53 individual flow units).
*Includes ROZ interval from 6,500 to 6,700.
Primary/
y Salt Creek Field Oil Recovery
Total Secondary CO2-EOR F t by
Factor, b Process
P
OOIP 700
35 70
Cum. Recovery (2003) 370 328 42
recover an additional 120 million barrels, Source: Wilkinson, J.R., ExxonMobil Production Company; et. al., SPE paper 88770,Lessons Learned
from Mature Carbonates for Application to Middle East Fields
Fields, presented at the SPE 11th Abu Dhabi
18% of OOIP. International Petroleum Exhibition & Conference, Abu Dhabi, 10-13 October 2004.
The EOR project plans to inject about 1,200 Bcf of CO2, equal to 0.8 HCPV for a gross
CO2/oil ratio of 13 Mcf/B.
Summary
Net production numbers are in thousands of barrels of oil equivalent per day.
Source: Whiting Petroleum, 2008
pth
Dep
478 Days
(Breakthrough)
1839 Days
(Channeling in 6,900 0 20 40 60 80 100 0 20 40 60 80 100
Layer 2)
% Injected Before % Injected After
0 100 200 300
Distance,, ft
Source: Adapted by Advanced Resources Intl from Enhanced Oil Recovery, D.W. Green and G. P. Source: SACROC Unit CO2 Flood: Multidisciplinary Team Improves Reservoir Management and
Willhite, SPE, 1998. Decreases Operating Costs, J.T. Hawkins, et al., SPE Reservoir Engineering, August 1996.
Water
covery - % OOIP
0.8
Efficiency, EA
20 0.8 HCPV
0.7
0.6 HCPV
0.6
15
Sweep E
5.0
pD
at
0.4
B
3.0
10
.T.
0.3
.M
1.5
1.0
0.2 0.6 5
0.2
0.1
0.1
0 0
0 0.2 0.5 1 2 5 10 20 50 100 200 500 1000
0 10 20 30 40 50
Mobility Ratio, M
Years
Note: VpD is displaceable fluid pore volumes of CO2 injected.
Source: Claridge, E.L., Prediction of Recovery in Unstable Miscible Source: SPE 24928 (1992)
Displacement, SPE (April 1972).
IInnovative
ti Flood
Fl d Design
D i and d Well
W ll Placement.
Pl t Adding
Addi h horizontal
i t l
production wells and vertical CO2 injection wells, enabling CO2 to contact
residual oil from poorly swept portions of the reservoir.
Viscosity and Miscibility Enhancement. Adding mobility control with
viscosity enhancers and lowering MMP with miscibility enhancers.
Increased Volume of CO2 Injection. Injecting up to 1.5 HCPV of CO2.
Flood Performance Diagnostics
g and Control. Fullyy staffed technical
team. Uses instrumented observation wells and downhole sensors to
monitor progress. Conducts periodic 4-D seismic and pressure plus zone-
by-zone flow tests (among others) to manage and control the CO2 flood.
R i
Reviews performance
f off pastt CO2-EOR
EOR floods.
fl d
Sets forth theoretically and scientifically possible
advances in technology for CO2-EOR.
Examines how much game changer CO2-EOR
technology would increase oil recovery and CO2
storage capacity.
Next
e t Ge
Generation
e at o CO2-EOR O would
ou d significantly
s g ca t y
improve domestic oil recovery efficiency.
Technically Recoverable
Favorable
Basin OOIP Reservoirs State-of-the-Art Next Generation
Studies (BBbls) (#) (BBbls) (BBbls)
Eleven Basins
Basins** 596 1 111
1,111 88 1
88.1 ?
*Evaluating the Potential for Game Changer Improvements in Oil Recovery Efficiency from CO2 Enhanced Oil Recovery, Advanced
Resources International, report prepared for the U.S. DOE, Office of Oil and Natural Gas, Office of Fossil Energy, August 2005.
http://www.fe.doe.gov/programs/oilgas/eor/Game_Changer_Oil_Recovery_Efficiency.html.
**Storing CO2 with Enhanced Oil Recovery Advanced Resources International, report prepared for U.S. DOE/NETL, Office of Systems,
Analyses and Planning, DOE/NETL-402/1312/02-07-08, February 7, 2008. http://www.netl.doe.gov/energy-
analyses/pubs/Storing%20CO2%20w%20EOR_FINAL.pdf.
CO2 Source
Oil to Production Well
Market
CO2
Injection
CO2
Recycled
Swept Area
USA
Beulah
CO2
Source: EnCana, 2005