Appendix B

THERMODYNAMIC DATA FOR ETHYL ACETATE SYSTEM

B.1 VAPOR PRESSURE (Perry. 7th edition)

B
ln P sat A C ln T DT E
T
Where P sat in Pa and T in K

TABLE B.1: CONSTANTS FOR VAPOR PRESSURE EQUATION

Component A B C D E vi 3
(cm /mol)

Acetic acid (1) 53.27 -6304.5 -4.2985 8.8865e-18 6 57.54

Ethanol (2) 74.475 -7164.3 -7.327 3.134e-6 2 44.44
Ethyl Acetate (3) 66.824 -6227.6 -6.41 1.7914e-17 6 79.84
Water (4) 73.649 -7258.2 -7.3037 4.1653e-6 2 18.07

B.2 WILSON PARAMETERS FOR ETHYL ACETATE SYSTEM

(Barbosa, and Doherty, 1988a)


C C
x
ln i 1 ln x j ij C k ki
j 1 k 1 x
j kj
j 1

vj Aij
Where ij exp
vi RT

Where v j in cm3/mol and Aij in cal/mol, Aij 0 implies ideality.

 TABLE B.2: BINARY INTERACTION PARAMETERS FOR WILSON MODEL

Aij Ai1 Ai 2 Ai 3 Ai 4

A1 j 0.0 -130.6527 1749.9343 2.0311

A2 j 101.6588 0.0 288.2011 198.1757

A3 j -464.1592 28.8790 0.0 26981.1421

A4 j 403.1564 466.1059 1195.67 0.0

B.3 LIQUID HEAT CAPCITIES (Perry. 7th edition)

% Source Perry's Handbook 7th Edition Page:217

C p ( J / kmol K ) C1 C2T C3T 2 C4T 3 C5T 4

TABLE B.3: CONSTANTS FOR LIQUID HEAT CAPCITIES

Component C1*10-5 C2*10-2 C3*100 C4*102 C5*106

Acetic acid (1) 1.3964 -3.2060 0.8985 0.0 0.0
Ethanol (2) 1.0264 -1.3963 -0.030341 0.20386 0.0
Ethyl Acetate (3) 2.2623 -6.2480 1.4720 0.0 0.0
Water (4) 2.763 -20.901 8.1250 -1.4116 9.3701

B.4 HEAT CAPCITIES IN IDEAL GAS STATE

% Source Perry's Handbook 7th Edition Page:225

C p ( J / mol ) R(C1 C2T C3T 2 C4T 3 C5T 4 ), whereR 8.3143J / mol K

 TABLE B.4 CONSTANTS FOR HEAT CAPCITIES IN IDEAL GAS STATE
Component C1 C2*103 C3*105 C4*108 C5*1011
Acetic acid (1) 4.375 -2.397 6.757 -8.764 3.478
Ethanol (2) 4.396 0.628 5.546 -7.024 2.685
Ethyl Acetate (3) 10.228 -14.948 13.033 -15.736 5.999
Water (4) 4.395 -4.186 1.405 -1.564 0.632

B.5 LATENT HEAT OF VAPORIZATION (Perry)

% Source Perry's Handbook 7th Edition Page:203

( J / kmol ) c1 (1 Tr )c c T c T
2
2 3 r 4 r

T
Where Tr is the reduced temperature, Tr and Tc is the critical temperature.
Tc

TABLE B.5 CONSTANTS FOR LATENT HEAT OF VAPORIZATION

Component c1*10-7 c2*101 c3*100 c4*100 Tc
Acetic acid (1) 2.0265 1.1911 -1.3487 1.4227 591.95
Ethanol (2) 5.690 3.359 0.0 0.0 513.92
Ethyl Acetate (3) 4.933 3.847 0.0 0.0 523.3
Water (4) 5.2053 3.199 -0.212 0.25795 647.13