Cermica 54 (2008) 345-350 345

Estabilidade trmica da zelita A sintetizada a partir de

um rejeito de caulim da Amaznia

(Thermal stability of the zeolite A synthesized after kaolin

waste from Amazon region)

A. A. B. Maia1, R. S. Anglica2, R. F. Neves1

1
Programa de Ps-Graduao em Engenharia Qumica, Universidade Federal do Par
2
Instituto de Geocincias, Universidade Federal do Par
anabmaia@yahoo.com.br

Resumo

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Abstract

Zeolite A was calcined at 200, 400, 600, 800 and 1000 C for 2h to evaluate its thermal stability. The zeolite A was synthesized
using kaolin waste from kaolin processing industries for paper coating located in the Amazon region. Both zeolite A and further
calcined products were characterized by X-ray diffraction analysis and scanning electron microscopy. The zeolite A structure
remained stable up to 600 C, where only small variations in peak intensities were observed. At 800 C the diffraction pattern still
exhibited zeolite A but with the absence of some peaks. At 1000 C nepheline, mullite and probably sodalite were formed. The zeolite
A was also heated at 900 and 950 C to check the two exothermic peaks observed in the DTA curve. The X-ray diffraction analysis
indicated the presence of nepheline, sodalite and mullite.
Keywords: kaolin waste, zeolite A, thermal stability.

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 348 A. A. B. Maia et al. / Cermica 54 (2008) 345-350

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)LJXUD  'LIUDWRJUDPDV GH UDLRV ; GD ]HyOLWD $ H GD PHVPD UHFULVWDOL]DomR > @ $ PXOLWD IRUPDGD SURYDYHOPHQWH
FDOFLQDGDDH& FRUUHVSRQGH j WUDQVIRUPDomR GH IDVH GD PHWDFDXOLQLWD
[Figure 3: XRD patterns of the zeolite A and of the same calcined
XWLOL]DGDFRPRPDWHULDOSUHFXUVRUMiTXHVHJXQGRGDGRVGH
at 200, 400, 600 and 800 C.]
 A. A. B. Maia et al. / Cermica 54 (2008) 345-350 349

GRV SLFRV SULQFLSDLV GD VRGDOLWD 3URYDYHOPHQWH KRXYH

FRQYHUVmRJUDGXDOGDVRGDOLWDSDUDQHIHOLQDMiTXHHVVDIDVH
pDPDLVHVWiYHO>@$ FDUQHJLHLWDF~ELFDpIRUPDGDSHOR
DTXHFLPHQWR GD QHIHOLQD D WHPSHUDWXUDV VXSHULRUHV D 
& >@ 'D PHVPD IRUPD HVVH DXPHQWR QD WHPSHUDWXUD
WDPEpPIDYRUHFHXDIRUPDomRGHXPDPDLRUTXDQWLGDGHGH
PXOLWD$VVLP HP WRGDV HVVDV WHPSHUDWXUDV GH FDOFLQDomR
 D  & WDPEpP IRL REVHUYDGD XPD TXDQWLGDGH
VLJQLFDWLYD GH PDWHULDO QmR FULVWDOLQR YHULFDGR SHOD
VLJQLFDWLYDHOHYDomRQRbackgroundQRVGLIUDWRJUDPDVGH
)LJXUD0RUIRORJLDVGD]HyOLWD$FDOFLQDGDQDVWHPSHUDWXUDVGH
UDLRV;)LJ
CONCLUSES
$ ]HyOLWD$ QmR VRIUHX WUDQVIRUPDomR GH IDVH QD IDL[D
GH  D  & 1HVVDV WHPSHUDWXUDV RFRUUHX VRPHQWH
YDULDomR QDV LQWHQVLGDGHV GRV SLFRV FDUDFWHUtVWLFRV VHQGR
TXHD&DOpPGHVVDREVHUYDomRYHULFRXVHWDPEpP
GHVDSDUHFLPHQWR GH DOJXQV SLFRV SURYDYHOPHQWH GHYLGR j
GHVRUGHPGHVXDHVWUXWXUDFULVWDOLQD$&REVHUYRX
VHDIRUPDomRGHQHIHOLQDHSURYDYHOPHQWHVRGDOLWDDSDUWLU
GD ]HyOLWD $ DVVLP FRPR D SRVVtYHO IRUPDomR GH PXOLWD
D SDUWLU GD PHWDFDXOLQLWD SUpH[LVWHQWH$  H  & R
SURGXWR GH VtQWHVH FRQVWLWXtGR SULQFLSDOPHQWH SRU ]HyOLWD
$SDVVDSRUWUDQVIRUPDomRGHIDVHVWHQGRFRPRUHVXOWDGR
DSHQDVDSUHVHQoDGDQHIHOLQDVRGDOLWDHPXOLWD'HIRUPD
TXHDWUDQVIRUPDomRGHIDVHLQLFLRXD&HD&
R SURGXWR GH FDOFLQDomR DSUHVHQWRX D PHVPD FRQVWLWXLomR
SRUpPIRLREVHUYDGRXPDXPHQWRQDRUGHPHVWUXWXUDOSDUD
QHIHOLQDHPXOOLWD
2UHMHLWRGHEHQHFLDPHQWRGHFDXOLPSDUDSDSHOPRVWURX
VH FRPR XPD H[FHOHQWH PDWpULDSULPD SDUD SURGXomR GH
]HyOLWD$SXUD>@VHQGRGHVVDIRUPDPDLVXPDDOWHUQDWLYD
&DH&E QD WHQWDWLYD GH PLQLPL]DU LPSDFWRV DPELHQWDLV 2XWURV
[Figure 5: Morphologies of the zeolite A samples calcined at 800 C HVWXGRVMiYrPFRQUPDQGRHVVDVHRXWUDVSRVVLELOLGDGHVGH
(a) and 1000 C (b).]
DSURYHLWDPHQWRGHVVHVUHMHLWRV>@

'5;)LJRSURGXWRGHVtQWHVHpFRQVWLWXtGRSRU]HyOLWD
$HPDWHULDOQmRFULVWDOLQRSRVVLYHOPHQWHDPHWDFDXOLQLWD
2 JUDX GD RUGHP HVWUXWXUDO GD FDXOLQLWD p XPD GDV
YDULiYHLVTXHFRQWURODPDWHPSHUDWXUDGHPXOLWL]DomRVHQGR
TXHHPWRUQRGH&SDUDHOHYDGDRUGHPHHPWRUQRGH
&SDUDEDL[D>@
$DQiOLVHPRUIROyJLFDGRSURGXWRFDOFLQDGRD&
AGRADECIMENTOS
$R &RQVHOKR 1DFLRQDO GH 'HVHQYROYLPHQWR &LHQWtFR
H 7HFQROyJLFR  &13T SHOR DSRLR QDQFHLUR DR SURMHWR
$SOLFDomR GH UHVtGXRV GH FDXOLP GD UHJLmR $PD]{QLFD
SDUD D SURGXomR GH UHIUDWiULRV H XWLOL]DomR HP IRUQRV QD
LQG~VWULDGHFHUkPLFDYHUPHOKD(GLWDO8QLYHUVDO
)LJEPRVWURXTXHHVVHSURFHVVRSURYRFRXXPDPXGDQoD 3URF  DOpP GD EROVD GH SURGXWLYLGDGH HP
QDPRUIRORJLDTXHSDVVRXDVHUQDIRUPDGHFULVWDLVF~ELFRV SHVTXLVD56$QJpOLFDSURFHVVR
FRPDUHVWDVDUUHGRQGDGDVGRPLQDQWHVDVVRFLDGRVjVPDVVDV
LUUHJXODUHVSRUYH]HVQDIRUPDGHJOyEXORVRXVHPIRUPDV REFERNCIAS
GHQLGDV
$H&)LJDQHIHOLQDVHHQFRQWUDFRPRIDVH >@ $%17  $VVRFLDomR %UDVLOHLUD GH 1RUPDV 7pFQLFDV
GRPLQDQWHFRPSLFRVPDLVLQWHQVRVHQTXDQWRDVRGDOLWDH $PRVWUDJHP GH 5HVtGXRV 1%5 5LR GH -DQHLUR
DPXOOLWDPRVWUDUDPVHSUHVHQWHVHPSHTXHQDVTXDQWLGDGHV 
DSUHVHQWDQGR SLFRV GH PHQRUHV LQWHQVLGDGHV 2 DFUpVFLPR >@0&0DUWHOOL7UDQVIRUPDo}HVWpUPLFDVHSURSULHGDGHV
GD WHPSHUDWXUD GH  SDUD  & FRQWULEXLX SDUD XP FHUkPLFDVGHUHVtGXRVGHFDXOLQVGDVUHJL}HVGR5LR&DSLP
DXPHQWRGDRUGHPHVWUXWXUDOGDQHIHOLQDFRPQtWLGDUHGXomR HGR5LR-DUt%UDVLO7HVHGH'RXWRUDGRHP*HRTXtPLFD
GD ODUJXUD D PHLDDOWXUD ):+0 GRV SLFRV  HP  H 3HWURORJLD 8QLYHUVLGDGH )HGHUDO GR 3DUi %HOpP 3$
D  & H  HP  D  & DOpP GD GLPLQXLomR 
350 A. A. B. Maia et al. / Cermica 54 (2008) 345-350

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7DPXUD6FL7HFKQ$GY0DWHU6 SUHFXUVRU XP UHMHLWR GH EHQHFLDPHQWR GH FDXOLP GD
>@$*XDOWLHUH31RUE\*$UWLROL-+DQVRQ3K\V&KHP $PD]{QLD DSOLFDomR FRPR DGVRUYHQWH 'LVV 0HVWUDGR
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114 >@603)ORUHV$SURYHLWDPHQWRGRUHMHLWRGHFDXOLP
>@6+.LP03DUN<-6RQ+-/HH*&-HRQJ QD SURGXomR GH DOXPLQD SDUD FHUkPLFD H VtOLFD GH EDL[D
01%DH:7/LPF%XOO.RUHDQ&KHP6RF28 JUDQXORPHWULD7HVH'RXWRUDGRHP*HRORJLDH*HRTXtPLFD
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>@0*XLVQHW)55LEHLUR=HyOLWRV8P1DQRPXQGR >@ 06%DUDWD'&&'DO0ROLQ$PELHQWH&RQVWUXtGR
DR 6HUYLoR GD &DWiOLVH )XQGDomR &DORXVWH *XOEHQNLDQ 2
 >@ ( 6DOGDQKD 6tQWHVH H FDUDFWHUL]DomR GD DQDOFLPD D
>@&.RVDQRYLF%6XERWLF,6PLW7KHUPRFKLP$FWD SDUWLU GH UHMHLWR GH FDXOLP H DSOLFDomR FRPR DGVRUYHQWH
317 'LVV0HVWUDGR(QJ4XtP8QLYHUVLGDGH)HGHUDOGR3DUi
>@-$5DER=HROLWH&KHPLVWU\DQG&DWDO\VLV$P&KHP %HOpP3$
(Rec. 21/12/2007, Rev. 14/03/2008, Ac. 04/04/2008)