1
Diketahui :
Table B.1.3 Major Equipment Summary for unit 200 (continued)
Reaktor
R-201
Carbon steel
Packed-bed section 7.2 m high filled catalyst
Diameter = 0.72 m
Height= 10 m
Maximum pressure rating of 14.7 bar
Stream Number 5 6
Temp (C) 250 364
Tekanan (bar) 14.7 13.9
Fraksi Uap 1.0 1.0
Laju Alir Massa (ton/jam) 10.49 10.49
Laju Alir Mol (kmol/jam) 328.3 328.3
Komponen (kmol/jam)
Dimetil-eter 1.5 130.5
Methanol 323.0 64.9
Air 3.8 132.9
Reaksi :
Laju reaksi :
= ( )
2
Fraksi massa :
1.5
XDimetil-eter : = 0.00457 kmol/jam
328.3
323
Xmetanol : = 0.98385 kmol/jam
328.3
3.8
Xair : = 0.0115747 kmol/jam
328.3
Massa komponen :
F = N x BM
FDimetil-eter ( ) : 1.5 x 46.07 = 69.105 kg/jam
Fmethanol ( ) : 323 x 32.043 = 10349.889 kg/jam
Fair ( ) : 3.8 x 18.02 = 68.476 kg/jam
Reaksi :
A = Methanol
B = Dimethil-eter
C = Air
2A B+C
Methanol = A
3
2. Sehingga reaksi menjadi
A B+C
3. = + - 1 = 0
4. = CaO . = 0
0.98385 0 0.004568
5. = = = 1 , = = = 0.00478 9.
0.98385 0.98385
0 0.0115747
= = = 0.0163
0 0.98385
1470
6. 0 = 0 . 0 = 0 . [0 ] = 0.98385 . [8.314 ] = 0.3325 /
523.15
7. = 0 (1 )
0
= 0 (0.00478 + 12 )
0
= 0 (0.0163 + 12 )
0
8. = 0 . exp[ ]
9. 1 = 0 . exp[ ]
80480
6
1 = 1.2110 . exp[ ] 3
(8.3144 . ) . . .
9679.59
1 = 1.21106 . exp[ ]
9679.59
1 = 1.21106 . exp[ ]
523
1 = 0.01108 kmol/3 . . .
4
Maka persamaannya menjadi :
9679.59
= 1.21106 exp [ ]
KESETIMBANGAN
= exp[ ]
Dengan nilai -G
[ ]=[ ]+
= exp[( ) + ]
= exp [ + ]
Dimana
= = , S=perubahan entropi reaksi
T
T (C) Kp 1/t ln kp
(K)
200 473 92,6 0,002114165 4,528289142
300 573 52 0,001745201 3,951243719
400 673 34,7 0,001485884 3,546739687
5
5
4.5 y = 1562.4x + 1.225
R = 1
4
3.5
3
2.5 Series1
2 Linear (Series1)
1.5
1
0.5
0
0 0.0005 0.001 0.0015 0.002 0.0025
Linearisasi menjadi :
Persamaan :
= exp[ + ]
ln = +
1
ln = +
= +
Diperoleh persamaan :
= 1562.4 1.225
Maka :
1562.4
= exp [ 1.225]
1562.4
= exp [ 1.225]
523
= 5.82629
6
Persamaan laju reaksi menjadi :
= 1 2 0.5 0.5
1 1
= 2 =
2
= 1 1 0.5 0.5
= 1 1 0.5 0.5
= (1 1 0.5 0.5 )
1
= 1 ( 0.5 0.5 )
[0 (0.00478 + 12 ) ]0.5
1
= 0.01108 . 8.314 . 523 ([0 (1 ) ]
0 5.82629 0
[0 (0.0163 + 12 ) ]0.5 )
0
=
0
[0 (0.00478 + 12 ) ]0.5
1
= 0.01108 . 8.314 . 523 ([0 (1 )]
5.82629
[0 (0.0163 + 12 ) ]0.5 )
0 =
Persamaan menjadi :
1
0 = 0.01108 . 8.314 . 523 ([0 (1 )] 5.82629 [0 (0.00478 + 12 )]0.5
[0 (0.0163 + 12 ) ]0.5 )
7
[0 (0.0163 + 12 ) ]0.5 )
1
= 0.01108 . 8.314 . 523 ([0 (1 )] 5.82629 [0 (0.00478 + 12 )]0.5
[0 (0.0163 + 12 ) ]0.5 )
10349.889
memasukan nilai 0
1
= 0.01108 . 8.314 . 523 ([0.3325(1 )] 5.82629 [0.3325(0.00478 + 12 )]0.5
10349.889