Lampiran 1

Data Hasil dan Pengamatan

Tabel 1. Hasil Pengamatan Campuran Etanol - Air

Komposisi Etanol Konsentrasi Etanol, OBrix Temperature
XF (%) XW XD YD (OC)
0.1 0.5 0.2 2 98
0.15 1 0.5 6.5 95
0.2 1.8 0.8 8.2 91
0.25 2.5 1.2 9.4 89
Keterangan :
XF : Fraksi Umpan
XW : Konsentrasi Etanol Fasa Cair
XD : Konsentrasi Etanol - Air Fasa Cair

YD : Konsentrasi Etanol Air Fasa Uap

Tabel 2. Hasil Perhitungan Fraksi Volume Etanol

Komposisi Etanol XF Fraksi Volume Etanol
(%) XW XD YD
0.1 0.1051 0.0831 0.2154
0.15 0.1419 0.1051 0.5463
0.2 0.2007 0.1272 0.6713
0.25 0.2522 0.1566 0.7596

Tabel 3. Hasil Perhitungan Psat

XF (%) T (OF) Psat air Psat etanol
0.1 371 703.4583 1573.2295
0.15 368 630.5011 1414.7277
0.2 364 543.1080 1224.1795
0.25 362 503.3510 1137.2156

Tabel 4. Hasil Perhitungan Fraksi Berat Etanol dalam Percobaan

XF Berat Fraksi Berat Etanol
V etanol V air Berat Air
(%) Etanol XD YD
0.1 5.2574 4.1481 44.7426 44.6532 0.0850 0.1760
0.15 7.0956 5.5984 42.9044 42.8186 0.1156 0.2152
 0.2 10.0368 7.9190 39.9632 39.8833 0.1657 0.2668
0.25 12.6103 9.9495 37.3897 37.3149 0.2105 0.3150
Tabel 5. Fraksi Berat Etanol dalam Literatur
Temperature (OC) XD YD
100 0 0
98.1 0.2 0.192
95.2 0.05 0.377
91.8 0.1 0.527
87.3 0.2 0.656
84.7 0.3 0.713
83.2 0.4 0.746
82 0.5 0.771
81 0.6 0.794
80.1 0.7 0.822
79.1 0.8 0.858
78.3 0.9 0.912
78.2 0.94 0.942
78.1 0.96 0.959
Sumber : Geankoplis Appendix A.3.23 Equilibrium Data for Ethanol Water System at
101,325 kPa (1 atm)

Tabel 6. Hasil Interpolasi Fraksi Berat Etanol

Temperature (OC) X Y
98 0.1948 0.1984
95 0.0529 0.3858
91 0.1178 0.5499
89 0.1622 0.6073

Tabel 7. Hasil Perbandingan Nilai K Secara Percobaan dan Literatur

K
Temperature (OC)
Percobaan Literatur
98 10 1.0182
95 13 7.2878
91 10.25 4.6692
89 7.8333 3.7434
 Lampiran 2
Perhitungan

1. Perhitungan untuk Konsentrasi Etanol-Air

V Larutan = 100 ml
Konsentrasi Etanol yang tersedia = 96%
Konsentrasi Etanol yang diinginkan = 10%; 15%; 20%; 25%;
a. 10%
gr akuades 4.9 gr
Nb = mr akuades = 18 gr/mol = 0.27 mol
na
Xa = na+nb
x
46
0.1 = x
+0.27
46

0.1x x
+ 0.027 = 46
46
x 0.1
0.027 = 46 46
0.9x
0.027 =
46

x = 1.38gr
gr 1.38
V= = = 1.725 ml
0.8

b. 15%
gr akuades 4.9 gr
Nb = mr akuades = 18 gr/mol = 0.27 mol
na
Xa = na+nb
x
46
0.15 = x
+0.27
46

0.15x x
+ 0.0405 = 46
46
x 0.15
0.0405 = 46 46
0.85x
0.0405 = 46

x = 2.19gr
 gr 2.19
V= = = 2.74 ml
0.8

c. 20%
gr akuades 4.9 gr
Nb = mr akuades = 18 gr/mol = 0.27 mol
na
Xa = na+nb
x
46
0.2 = x
+0.27
46

0.2x x
+ 0.054 = 46
46
x 0.2
0.054 = 46 46
0.8x
0.054 = 46

x = 3.105 gr
gr 3.105
V= = = 3.88 ml
0.8

d. 25%
gr akuades 4.9 gr
Nb = mr akuades = 18 gr/mol = 0.27 mol
na
Xa = na+nb
x
46
0.25 = x
+0.27
46

0.25x x
+ 0.0675 = 46
46
x 0.25
0.0675 = 46 46
0.75x
0.0675 = 46

x = 4.14 gr
gr 4.14
V= = = 5.175 ml
0.8

2. Perhitungan untuk Konsentrasi Etanol-Air

Diketahui dari grafik kesetimbangan etanol air persamaan garisnya
y = 13.6x 0.93
a. 10%
( +0.93 )
XW = 7.65
(0.5 +0.93 )
XW = = 0.1051
7.65
( +0.93 )
XD = 7.65
(0.2 +0.93 )
XD = = 0.0831
7.65
( +0.93 )
YD = 7.65
(2 +0.93 )
YD = = 0.2154
7.65

b. 15%
( +0.93 )
XW = 7.65
(1 +0.93 )
XW = = 0.1419
7.65
( +0.93 )
XD = 7.65
(0.5 +0.93 )
XD = = 0.1051
7.65
( +0.93 )
YD = 7.65
(6.5 +0.93 )
YD = = 0.5463
7.65

c. 20%
( +0.93 )
XW = 7.65
(1.8 +0.93 )
XW = = 0.2007
7.65
( +0.93 )
XD = 7.65
(0.8 +0.93 )
XD = = 0.1272
7.65
( +0.93 )
YD = 7.65
(8.2 +0.93 )
YD = = 0.6713
7.65

d. 25%
( +0.93 )
XW = 7.65
 (2.5 +0.93 )
XW = = 0.2522
7.65
( +0.93 )
XD = 7.65
(1.2 +0.93 )
XD = = 0.1566
7.65
( +0.93 )
YD = 7.65
(9.4 +0.93 )
YD = = 0.7596
7.65

3. Psat pada Setiap Temperature

Menggunakan Persamaan Antoine untuk mencari Psat air :
a. 10%
3816.44
Psat = exp (18.3036 T46.13)
3816.44
Psat = exp (18.3036 37146.13) = 703.4583

b. 15%
3816.44
Psat = exp (18.3036 T46.13)
3816.44
Psat = exp (18.3036 36846.13) = 630.5011

c. 20%
3816.44
Psat = exp (18.3036 T46.13)
3816.44
Psat = exp (18.3036 36446.13) = 543.1080

d. 25%
3816.44
Psat = exp (18.3036 T46.13)
3816.44
Psat = exp (18.3036 ) = 503.3510
36246.13

Menggunakan Persamaan Antoine untuk mencari Psat etanol :

a. 10%
3803,98
Psat = exp (18.9119 T41.68)
3803,98
Psat = exp (18.9119 37141.68) = 1573.2295
 b. 15%
3803,98
Psat = exp (18.9119 T41.68)
3803,98
Psat = exp (18.9119 36841.68) = 1414.7277

c. 20%
3803,98
Psat = exp (18.9119 T41.68)
3803,98
Psat = exp (18.9119 36441.68) = 1224.1795

d. 25%
3803,98
Psat = exp (18.9119 T41.68)
3803,98
Psat = exp (18.9119 36241.68) = 1137.2156

4. Fraksi Berat Etanol dalam Percobaan

Etanol = 0.789 gr/ml
Air = 0.998 gr/ml
P = 1 atm (760mmHg)
a. 10%
V etanol = Fraksi volume etanol x 50 ml
= 0.1051 x 50 ml = 5.2574 ml
Berat etanol = x V
= 0.789 gr/ml x 5.2574 ml = 4.1481 gr
V air = 50 ml volume etanol
= 50 ml 5.2574 ml = 44.7426 ml
Berat air = x V
= 0.998 gr/ml x 44.7426 ml = 44.6532 gr
berat etanol
Fraksi berat etanol (XD) = berat etanol+berat air
4.1481
= 4.1481+44.6532 = 0.0850
XD x Psat etanol
Fraksi berat Etanol (YD) = P
0.0850 x 1573.2295
= = 0.1760
760
b. 15%
V etanol = Fraksi volume etanol x 50 ml
= 0.1419 x 50 ml = 7.0956 ml
Berat etanol =xV
= 0.789 gr/ml x 7.0956 ml = 5.5984 gr
V air = 50 ml volume etanol
= 50 ml 7.0956 ml = 42.9044 ml
Berat air = x V
= 0.998 gr/ml x 42.9044 ml = 42.8186 gr
berat etanol
Fraksi berat etanol (XD) = berat etanol+berat air
5.5984
= 5.5984+42.8186 = 0.1156
XD x Psat etanol
Fraksi berat Etanol (YD) = P
0.1156 x 1414.7277
= = 0.2152
760

c. 20%
V etanol = Fraksi volume etanol x 50 ml
= 0.2007 x 50 ml = 10.0368 ml
Berat etanol =xV
= 0.789 gr/ml x 10.0368 ml = 7.9190 gr
V air = 50 ml volume etanol
= 50 ml 10.0368 ml = 39.9632 ml
Berat air = x V
= 0.998 gr/ml x 44.7426 ml = 39.8833 gr
berat etanol
Fraksi berat etanol (XD) = berat etanol+berat air
7.9190
= 7.9190 +39.8833 = 0.1657
XD x Psat etanol
Fraksi berat Etanol (YD) = P
0.1657 x 1224.1795
= = 0.2668
760

d. 25%
 V etanol = Fraksi volume etanol x 50 ml
= 0.2522 x 50 ml = 12.6103 ml
Berat etanol =xV
= 0.789 gr/ml x 12.6103 ml = 9.9495 gr
V air = 50 ml volume etanol
= 50 ml 12.6103 ml = 37.3897 ml
Berat air = x V
= 0.998 gr/ml x 44.7426 ml = 37.3149 gr
berat etanol
Fraksi berat etanol (XD) = berat etanol+berat air
9.9495
= 9.9495 +37.3149 = 0.2150
XD x Psat etanol
Fraksi berat Etanol (YD) = P
0.2150 x 1137.2156
= = 0.3150
760

5. Fraksi Berat Etanol dalam Literatur

Untuk mencari fraksi berat etanol dalam cairan (x) dan dalam kondensat (y)
menurut literatur untuk temperatur pada praktikum ini digunakan interpolasi,
a. 98OC
98.198 9895.2
X = (98.195.2) 0.05 + (98.195.2) 0.2 = 0.1948
98.198 9895.2
Y = (98.195.2) 0.377 + (98.195.2) 0.192 = 0.1984

b. 95OC
95.295 9591.8
X = (95.291.8) 0.1 + (95.291.8) 0.05 = 0.0529
95.295 9591.8
Y = (95.291.8) 0.527 + (95.291.8) 0.377 = 0.3858

c. 91OC
91.891 9187.3
X = (91.887.3) 0.2 + (91.887.3) 0.1 = 0.1178
91.891 9187.3
Y = (91.887.3) 0.656 + (91.887.3) 0.527 = 0.5499

d. 89OC
 91.889 8987.3
X = (91.887.3) 0.2 + (91.887.3) 0.1 = 0.1622
91.889 8987.3
Y = (91.887.3) 0.656 + (91.887.3) 0.527 = 0.6037

6. Konstanta Kesetimbangan (K)

a. 10%
2
KPercobaan = = 0.2 = 10
0.1984
KLiteratur = = = 1.0182
0.1948

b. 15%
6.5
KPercobaan = = 0.5 = 13
0.3858
KLiteratur = = 0.0529 = 7.2878

c. 20%
8.2
KPercobaan = = 0.8 = 10.25
0.5499
KLiteratur = = 0.1178 = 4.6692

d. 25%
9.4
KPercobaan = = 1.2 = 7.8333
0.6073
KLiteratur = = 0.1622 = 3.7434
 Lampiran 3
Dokumentasi

Gambar 1. Larutan Etanol-Air Konsentrasi 10%, 15%, 20% dan 25%

Gambar 2. Rangkaian Alat Kesetimbangan Uap Cair

Gambar 3. Etanol 96% dan Hand Refractometer