TUGAS KIMIA ANALISIS
Disusun Oleh:
AHMAD DZULFIKAR FAUZI
CAHYA PUJI LESTARI
CHRISTINE INDIRA RP
DEA ALIFTIA FIRDAUSHYA
FARIHA HUNDAGI
HANIFAH ADAMI R M
MAHMUDI
NORMALIA ULFAH K
RAFIDHA HAPSARI
RIZQI UYUN NAFISAH
ROZANA KHOIRUN NISA
SALSALINA SINASA
SITI AGHNIA SALSABILLA
STEPHANUS STEVEN H
DEPARTEMEN TEKNIK KIMIA FAKULTAS TEKNIK
UNIVERSITAS DIPONEGORO
SEMARANG
2017
NIM : 21030114120030
NIM : 21030114120071
NIM : 21030114120049
NIM : 21030114120070
NIM : 21030114120038
NIM : 21030114130195
NIM : 21030114140177
NIM : 21030114120031
NIM : 20130114130155
NIM : 21030114120104
NIM : 21030114130187
NIM : 21030114120017
NIM : 21030114130138
NIM : 21030114140182
11.141. A chemist received different mixts for analysis with the statement that they contained
NaOH, NaHCO3, Na2CO3, or compatible mxts of the substances together with inert
material. From the data given, identify the respective materials and calculate the
percentage of each component. One-gram samples and 0.2500 N HCl were used in all
eases.
Sample 1. With phenolphthalein as an indicator 24.32 ml was used. A duplicate sample
required 48.64 ml with methyl orange as an indicator
Sample 2. The addition of phenolphtalein caused no color change. With methyl
orange, 38.47 ml of the acid was required
Sample 3. To cause a color change in the cold with phenolphtalein 15.29 ml of acid
was necessary, and an additional 33.19 ml was required for complete neutralization.
Sample 4. The sample was titrated with acid until the pink of phenolphtalein
disappeared; this process required 39.96 ml on adding an excess of the acid, boiling, and
titrating back with alkali, it was found that the alkali was exactly equivalent to the excess
acid added.
Answer:
Sampel 1
Karena sampel bisa identifikasi dengan menggunakan indikator phenolphtalein dan methyl orange maka
kemungkinan sampel mengandung Na2CO3

Na2CO3 + PP Na2CO3 + MO

24,32 ml HCl HCl

NaHCO3 PP berubah NaHCO3

48,64 ml
48,64 ml warna

HCl HCl

NaCl NaCl MO berubah

warna

106
48,64 0,25 2000
2 3 = 100 = 64,45 %
1

Sampel 2
Karena dengan menggunakan sampel phenolphtalein sampel tidak berubah warna, dan hanya berubah
warna dengan menggunakan indikator methyl orange maka kemungkinan sampel mengandung NaHCO3
 NaHCO3 + MO

38,47 ml
HCl

NaCl MO berubah
warna

84
38,47 0,25 1000
3 = 100 = 80,79 %
1
Sampel 3
Karena sampel bisa di identifikasi dengan menggunakan phenolpthalein, serta masih membutuhkan
sedikit titran untuk menyempurnakan titrasi maka kemungkinan sampel mengandung Na2CO3 dan
NaHCO3

Na2CO3 + PP

15,29 ml HCl
PP berubah
NaHCO3 warna

33,19 ml
HCl

NaCl NaHCO3

2,61 ml HCl

NaCl
106
30,58 0,25 2000
2 3 = 100
1
2 3 = 40,52 %
84
17,9 0,25 1000
3 = 100 = 37,6 %
1

Sampel 4
Karena identifikasi hanya dengan menggunakan indikator phenolphtalein dan titrasi balik dengan
menggunakan alkali ekivalen dengan kelebihan asam yang ditambahkan maka kemungkinan sampel
mengandung NaOH

NaOH + PP

39,96 ml
HCl

NaCl PP berubah
warna
 40
39,96 0,25 1000
= 100 = 39,96 %
1

11.150. Qualitative analysis of a powder shows the presence of sodium, carbonate, and a
little chloride. With methyl orange indicator, 0.8 gr of the powder in solution gives
a red color when 25.1 ml of 0.5 N is used in the titration. With phenolphthalein
indicator, a cold solution of the same weight of sample requires 18.45 ml of the
acid. What is the percentage composition of the powder?
Answer:

Sampel

11,8 ml
18,45 ml
NaCl Na2CO3
25,1 ml
6,65 ml

NaHCO3

6,65 ml
NaCl

40
11,8 0,5
% = 1
100% = 29,5%
800
106
13,3 0,5
% 2 3 = 2
100% = 44,06%
800

= 100% (44,06 % + 29,5 %) = 26,44%

11.158. A series of solns is known to contain H3PO4, NaH2PO4, Na2HPO4, alone or mixed
in varying compatible combinations. In each case, the titration is made with 1.000
N NaOH to a pink color with phenolphthalein and the soln is then back-titrated
with 1.000 N HCl to a pink color with methyl orange. In each of the dollowing four
cases, determine which components are present and the no. of millimoles of each:
a) Initial titration 48.36 ml, back titration 33.72 ml
b) Initial titration 37.33 ml, back titration 39.42 ml
c) Initial titration 24.36 ml, back titration 24.36 ml
d) Initial titration 36.24 ml, back titration 18.12 ml
Answer:

H3PO4

14,64 ml + NaOH

NaH2PO4

+ NaOH HCl 33,72 ml

Na2HPO4

13.6. A sample of silver coin weighing 0.5000 g and contg. 90% Ag is analyzed by the
Volhard method. What is the least normality that a KCNS soln. may have and not
required more than 50.00 ml in the titration?
Answer :
%

= =

90%0.5
108 / 1000 1
=
50 1 1
= 0.05
Therefore normality KCNS used 0.05 N or above

13.7. A certain soln. of FeCl3.6H2O contains in each ml a wt. of Fe equal to that in 0.300
mg of Fe2O3. How many ml of 0.0500 N AgNO3 would be required to titrate 50.0 ml
of the chloride soln. to a red color with K2CrO4 indicator?
Answer :
255,845
Fe content in each ml of FeCl3.6H2O = 0,3 = 0,21 mg Fe/ ml solution.
159,69

In 50 ml solution, Fe content becomes 0,21 / 50 = 10,49 mg Fe.

10,49
mol equivalent of Cl in respect to Fe = 3 = 0,5635 mol eq.
159,69 /

Reaction of AgNO3 and FeCl3.6H2O is Ag+ + Cl- AgCl.. So, mol eq of Ag needed = mol eq
of Cl = 0,5635 mmol eq.
Volume of AgNO3 titrant needed = 0,5635 mmol eq/0,05 N = 11,27 ml 11,3 ml

13.13. A sample of feldspar weighing 2.000 g yields a mixture of NaCl and KCl weighing
0.2558 g. if 35.00 ml of 0.1000 N AgNO3 is added to the dissolved chlorides and the
 excess Ag+ requires 0.92 ml of 0.02000 N KCNS soln. for titration, what is the
percentage of K in the feldspar?
Answer :
KCl+ NaCl

AgNO3
KCNS
35 ml
0,1 N 0,92 ml
0,02 N

AgCl + Ag+

KCl =x
NaCl +KCl = 0,2558 g = 255,8 mg
NaCl = 255,8 x

x 255,8 x
+ = (35 0,1) (0,92 0,02)
BM KCl BM NaCl
x 255,8 x
+ = 3,4816
74,56 58,45
x = 242,05 mg KCl = 0,24205 gr KCl

1K 39,10
0,24205 0,24205
74,56
%K = KCl
100 = 100 = 6,34%
2 2

11-158. Larutan Series diketahui mengandung H2PO4, NaH2PO4, Na2HPO 4, sendiri atau
terdiri dari campuran yang dapat dikombinasikan. Pada setiap kasus, titrasi
dimulai dengan menggunakan 1 N NaOH hingga warna larutan menjadi pink
dengan menggunakan indicator phenophtalein dan larutan dititrasi balik dengan
1 N HCL hingga warna pink dengan indicator methyl orange. Pada empat kasus
dibawah, tentukan komponen yan tersedia dalam campuran serta milimolnya?
a. Titrasi awal 48,36 ml, titrasi balik 33,72 ml
Jawab

H3PO4

NaH2PO4 PP berubah
33,72 ml

Na2HPO4 NaH2PO4 48,36 ml

Na2HPO4 MO berubah

Maka :
Didalam larutan terdapat campuran H3PO4 dan NaH2PO4

= 48,36 33,72
= 14,64
= 48,36 (2 14,64)
= 19,08

Mol H3PO4 dan NaH2PO4

()
3 4 =


14,64 1
3 4 =
1
3 4 = 14,64
()
2 4 =


19,08 1
2 4 =
1
2 4 = 19,08