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Fontbot, L., and Bendez, R.

, 2009, Cordilleran or Butte-type veins and replacement bodies as a deposit class in porphyry systems. In: Williams et al., P.J. (ed)
Proceedings of the 10th Biennial Society of Geology Applied to Ore Deposits Meeting, Townsville, Australia, p. 521-523.

Cordilleran or Butte-type Veins and Replacement


Bodies as a Deposit Class in Porphyry Systems
Llus Fontbot
Earth and Environmental Sciences, University of Geneva, rue des Marachers 13, CH-1205 Geneva, Switzerland

Ronner Bendez
Bilbao 295, Lima, Peru

Abstract: Cordilleran or Butte type polymetallic abundant cross-cutting relationships and sparse
mineralization in a porphyry-related setting is known geochronological data; later than porphyry Cu, skarn,
in numerous districts. Most of it is largely and high sulfidation Au (-Ag) deposits). Polymetallic
epithermal, is found in the upper part of the systems, mineralization frequently postdates an early quartz
cuts earlier veins with potassic and phyllic alteration sericite stage that may deposit important pyrite
assemblages, and occurs as veins, massive volumes. (3) Deposition mostly under epithermal
replacement bodies, and sulfide-cemented breccias. conditions at shallow levels beneath the paleo-
surface. (4) Cu-Zn-Pb-W-Sn-(Ag-Au-Bi) metal
Keywords: porphyry, epithermal, polymetallic suites, very rich in sulfides (up to more than 50 wt.%
total sulfides). (5) Frequently, but not always, well-
developed zoning of ore and alteration minerals (see
1 Introduction below). (6) The main occurrence as open-space
fillings (veins, breccia bodies) in silicate host rocks
In magmato-hydrothermal porphyry systems one or and as replacement in carbonate rocks. (7)
more of the the following main deposit types may Cordilleran ores display notably higher Ag/Au ratios
occur: 1) porphyry copper deposits, 2) intermediate than high-sulfidation epithermal Au-(Ag)
and high sulfidation epithermal Au and Ag deposits, mineralization. (8) Fluid inclusion data consistently
3) Cu, Cu-Fe, Au, and Zn-Pb skarn deposits, 4) point to moderate to aqueous fluids of (moderate) to
Cordilleran or Butte-type polymetallic veins and low salinity and trapping temperatures below 375C
replacement bodies, 5) "distal" Au deposits. (e.g., Baumgartner et al., 2008, Bendez et al., 2008,
Cordilleran or Butte type polymetallic Beuchat et al., 2004, Catchpole et al. 2008, Deen et
mineralization in a porphyry-related setting is known al. 1994; Friehauf, 1998; MacFarlane et al., 1994,
in numerous districts. Most of it is largely Prendergast et al., 2005, Rusk et al., 2008).
epithermal, is found in the upper part of the systems,
cuts earlier veins with potassic and phyllic alteration
assemblages, and occurs as veins, massive 3 "Late" character
replacement bodies, and as sulfide-cemented breccia
bodies. This kind of mineralization is known among As already pointed out by Einaudi (1982), those
others in Butte ("Main Stage veins"), Magma, Cordilleran polymetallic deposits studied in detail
Superior, Bisbee and Tintic, USA; Yauricocha, appear to be systematically "late" in the life of the
Morococha, Julcani, Quiruvilca, Huarn, Hualgayoc, spatially associated magmato-hydrothermal systems.
Colquijirca and Cerro de Pasco, Peru; Bor, Serbia; For instance, in Butte "the Main Stage veins always
Erstberg, Indonesia. Specially in carbonate host rock, cut the porphyry Cu-Mo veins" and the pyrite-quartz-
as it is the case of several Miocene Peruvian deposits, sericite veins (Rusk et al., 2008). In Morococha,
the mineralized volumes may be very important. similar observations are made (Kouzmanov et al.,
2008). In Colquijirca, in addition to cross-cutting
evidences (Bendez and Fontbot, in press), absolute
2 Main characteristics age determinations suggest that the Cordilleran
polymetallic mineralization postdates by 0.3 My and
The main characteristics of Cordilleran ore deposits as long as 0.8 My the high-sulfidation epithermal
can be summarized as follows (largely after Sawkins Au-(Ag) disseminated ores. Also in porphyry
1972 and Einaudi, 1982; Bendez et al. 2008): (1) systems in which no economic polymetallic
close association in time and space with calc-alkaline mineralization is known, late polymetallic veins are
igneous activity, i.e., same geological environment as recognized (e.g., "third hydrothermal event" at La
Escondida, Padilla et al., 2001).
most porphyry Cu and high-sulfidation epithermal
AuAg deposits. Several Cordilleran base metal
4 Zoning
deposits (e.g., Butte, Morococha) are superimposed
on porphyry deposits, where others have no obvious
The zoned character of these deposits is a frequent,
link to a porphyry. (2) Deposition late in the
but not compulsory characteristic of the class. Two
evolution of the porphyry system (as seen from
Fontbot, L., and Bendez, R., 2009, Cordilleran or Butte-type veins and replacement bodies as a deposit class in porphyry systems. In: Williams et al., P.J. (ed)
Proceedings of the 10th Biennial Society of Geology Applied to Ore Deposits Meeting, Townsville, Australia, p. 521-523.

end members can be distinguished. Strongly zoned indicating that mineralizing fluids strongly fluctuated
deposits have cores dominated by enargite, pyrite, in terms of pH and sulfidation states from highly
quartz(tennantite, wolframite, chalcopyrite, acidic and very high sulfidation states, to mildly
covellite, chalcocite, alunite, dickite, kaolinite) and acidic and low sulfidation states. It appears that the
external parts by Fe-poor sphalerite, galena(sericite, sulfidation state in Cordilleran ore deposits depends
kaolinite, dickite, hematite, siderite). Weakly zoned on several factors, including the temperature and
deposits consisting of internal parts bearing spatial path followed by the ore forming fluids and
pyrrhotite, pyrite, quartz(chalcopyrite, arsenopyrite, their interaction with the host rock (e.g.,
tetrahedrite, carbonates, sericite, chlorite, quartz) and Baumgartner et al., 2008). Therefore, the same type
external parts of Fe-rich sphalerite, galena, of fluids originated by similar magmato-
pyrrhotite(rhodocrosite, siderite, and other hydrothermal systems may develop or not metal
carbonates, sericite, chlorite, quartz). Both end- zoning.
member styles are present in the same deposit,

Figure 1. Schematic position of Cordilleran polymetallic deposits and other porphyry-related ore deposit types.

Similarly, the existence of very acidic host Cordilleran polymetallic deposits remains to be
rock alteration zoning depends to an important evaluated.
degree of the proportion of vapors which are
degassed coetaneously with the aqueous low saline
fluids thought to be responsible of the polymetallic 5 Nomenclature issues and conclusion
mineralization. If the proportion of acidic oxidized
vapor-derived fluids is high, up to adavanced This class of ore deposits have been traditionally
argillic alteration can develop and hence a zoned named Cordilleran or Butte-type base metal veins
alteration pattern may occur. However, if the low or lodes (e.g., Meyer et al. 1968; Sawkins, 1972;
saline, less acidic aqueous fluids dominate, i.e., the Einaudi, 1982; Guilbert and Park, 1985; Bartos,
fluids thaught to be responsible for the Cordilleran 1987; Macfarlane and Petersen, 1990; Hemley and
mineralization (e.g., Baumgartner et al., 2008; Hunt, 1992; Bendez et al., 2003 and 2008; Dilles
Bendez and Fontbot, in press; Catchpole et al., et al., 2004, and Baumgartner et al., 2008).
2009), no acidic alteration is developed. This may "Epithermal polymetallic veins", "intermediate"
explain that several deposits that share the main or "high sulfidation polymetallic veins" (e.g.
characteristics of Cordilleran ore deposits, Hedenquist et al., 1998) are other terms that have
including their "late character" in the life of a been used recently. We prefer to keep the classical
magmato-hydrothermal system, show only weak terms of "Cordilleran" or "Butte-type" for these
zoning (e.g., San Cristobal vein in Central Peru, polymetallic veins and replacement bodies. In our
Campbell 1984, Beuchat et al., 2004, large parts of view, the main distinctive features of the class are
the Morococha veins, Catchpole et al., 2008). If the "late" character within the evolution of a
carbonate-hosted high-temperature, carbonate- porphyry system, specifically post-dating quartz-
hosted Ag-Pb-Zn(Cu) deposits in Northern Mexico sericite-pyrite veins, a well as the sulfide rich
(Megaw et al., 1988) also to weakly or non-zoned polymetallic, i.e., Zn-Pb-Cu-W-Sn-(Au-Ag-Bi),
mineral assemblages. As discussed above, the terms
Fontbot, L., and Bendez, R., 2009, Cordilleran or Butte-type veins and replacement bodies as a deposit class in porphyry systems. In: Williams et al., P.J. (ed)
Proceedings of the 10th Biennial Society of Geology Applied to Ore Deposits Meeting, Townsville, Australia, p. 521-523.

"epithermal" and "intermediate" or "high FI microthermometry and LA-ICP-MS case study:


sulfidation" can be applied to many Cordilleran ECOFRI, Granada, September 2009
Deen JA, Rye RO, Munoz JL, Drexler JW (1994) The
deposits. However they are not sufficiently precise magmatic hydrothermal system at Julcani, Peru; evidence
and, in the porphyry context, these terms bear the from fluid inclusions and hydrogen and oxygen isotopes.
danger of favoring an abusive assimilation with the Economic Geology: 89:1924-1938.
acid-sulfate or high-sulfidation epithermal Au-(Ag) Dilles JA, Kent AJ, Rusk B (2004) Magmatic sources of
disseminated ores, that in several deposits appear to metals in the Butte, Montana, porphyry Cu-Mo and
form coetaneously with the quartz-sericite-vein Cordilleran base metal lode deposit [abs.]: International
Association of Volcanology and Chemistry of the Earths
stage (e.g. Muntean and Einaudi, 2001). These Interior, 2004 General Assembly, Volcanism and its
veins when present, are systematically cut by Impact on Society, Abstract with Programs, CD-ROM
Cordilleran base metals veins. The term "zoned Einaudi MT (1982) Description of skarns associated with
base metal veins" (Einaudi et al., 2003), again, can porphyry copper plutons, southwestern North America, in:
be applied to a number of Cordilleran polymetallic Titley SR, ed., Advances in the geology of porphyry
copper deposits, southwestern North America: Tucson,
deposits, including to some of the most
Univ. Arizona Press: 139-184
representative, but a well-developed zoning is not Friehauf K (1998). Geology and geochemistry of porphyry-
an intrinsic feature of the class. related, carbonate-hosted, massive replacement Cu-Au
It is important, also for exploration purposes, deposits - A case study of the Superior District, Arizona.
to recognize Cordilleran or Butte-type polymetallic PhD. thesis, Stanford University, CD-ROM
mineralization as an specific class, which may Guilbert JM, Park Jr. CF (1985) The Geology of ore deposits.
Freeman and Company, New York, 985pp
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Colquijirca, Butte) in the late stages of the life of intrusion-centered hydrothermal systems: Far Southeast-
porphyry systems. Ongoing research (e.g., Lepanto porphyry and epithermal Cu-Au deposits,
Catchpole et. al. submitted) examines the question Philippines: Economic Geology 93: 373-404
if the low saline aqueous fluids responsible for the Heinrich CA (2007) Fluid-fluid interactions in magmatic-
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with meteoric water and, by acquiring a lower II. Some general geologic applications: Economic
density, are able to ascend to upper parts of the Geology 87: 2343
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JA, Fontbot L (2008) The Miocene Morococha district,
central Peru: large-scale epithermal polymetallic overprint
Acknowledgements on multiple intrusion-centered porphyry systems.
PACRIM Congress 2008, Gold Coast, Queensland, 117-
This work is financed by the Swiss National 121
Macfarlane AW Petersen U (1990) Pb isotopes of the
Science Foundation project 200020-116614. Hualgayoc area, northern Peru: implications for metal
provenance and genesis of a Cordilleran polymetallic
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