Adva PI Sol

1 AITS-CRT-II-(Paper-1)-PCM(S)-JEE(Advanced)/14
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ANSWERS, HINTS & SOLUTIONS
CRT II
(Paper-1)
Q.
PHYSICS CHEMISTRY MATHEMATICS
ALL INDIA TEST SERIES
No.
1. C C B
2. A D A
3. C D B
4. D A C
5. B D A
6. D C D
7. C B D
8. B C C
9. C C A
10. A C A
11. B, D D A, B, D
12. A, B, C A, B, C, D A, B, C, D
13. A, B, C B A, B
14. B, D A, B, C, D A, B, C
15. A, B, D B, C, D A, D
1. 1 2 2
2. 7 6 3
3. 4 1 4
4. 3 2 0
5. 1 4 6
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AITS-CRT-II-(Paper-1)-PCM(S)-JEE(Advanced)/14
2
Physics PART I
dm
3. F ve Av 2
dt
(Av 2 )H

2
mv 2
7. NH qE cos (i)
R
NH 0
( NH horizontal component of normal force) N

1 qE
qER(1cos ) = mv 2
2
F 0.02

A
8. n 10 10 3 kg / ms 10 2 poise
dv 2
1
dx

9. Velocity of bike Vb = 30 m/ s
Let velocity of car be Vc
Vso Vb
f obs = factual
Vso Vc
330 30
120 Hz = 100 Hz
330 Vc
VC = 30 m/s
Distance between initial and final pulse of horn
= Vso t - VC t {t is duration of emission of sound}
= (330 30) 6 = 1800 m
This wave train travels with 330 m/s and cross bike rider moving with velocity of 30 m/s towards
it.
length of wave train 1800 180
time taken = = 5 sec
Vso Vb 330 30 36
11. Kinetic friction acts opposite to relative velocity w.r.t. contact surface.
12. XL = 2XC
XC = 4XC
XL = 2XL
XL XC = 2XL 4XC = 2[XL 2XC] = 0
14. Since vertical Impulse is acting on A

Hence momentum of A & B will constant in horizontal direction only.
and M.E. of A & B will remain constant
SECTION C
1. Angular momentum Conservation
1 MR 2
MR 2 0 mR2 '
2 2
M
M 2m 0 '

M
U = 'R 0R
M 2m
2. M.E. Conservation
k 1
mg(4) x 2 mv 2
2 2
kx = 55
mg + kx = ma
5520 = 2a
a = 17.5 m/sec2
qBR
3. = t = 0.4
mg
dE B2 2C M
5. t= 1000 sec = 1
Bmg
4
Chemistry PART II
SECTION A
1. In (C), the tautomeric form will be

O OH
H 5C 6 C6 H5 H 5C 6 C 6H 5
H5 C6 C 6H 5 H 5C 6 C6 H5
The tautomeric form, contains sp-hybridised carbon in ring, making it unstable.
tautomerism is not shown by (C).
2.

2AgBr 2OH HO OH 2Ag s 2H2O O O 2Br aq
Hydroquinol Hydroquinone

3. PV = constant

105V
P1 Cons tan t
100

P 105
1 1
P 100
7
P 100 5
or 1
P 105
( for N2 or O2 = 7/5)
P1 = 0.93P,
7% decrease in pressure.
4. O2 is replaced by X-8/3, so formula of spinel is MgAl2X3 and deficiency by one anion.
5. W RT

M V
RT
Slope
M
0.082 293
M 3 3
4.65 10 10
6
5.16 10 g
C
6.
PBr5 s PBr4 Br
Cl
Cl Cl

N2 O5 s NO2 NO3 sp2
P
PCl s PCl PCl sp d
5 4

6
3 2
Cl Cl
Cl O s ClO ClO sp
2 6

2

4
3
Cl
7. (I) (II)
(III) (IV)
H
H H
H
(Conjugate base)
(Aromatic)
(Non-aromatic) (anti-aromatic) (anti-aromatic)
(III) and (IV) both are anti-aromatic, but (IV) has more resonating structures than (III).
So, stability of conjugate bases: (I) > (II) > (IV) > (III)
And pka order is: (I) < (II) < (IV) < (III)
8. pH = 9.71, H 1.95 10 10

Pr NH2 HCl
Pr NH3 Cl

Pr NH2 H
Ka
Pr NH3

Ka Pr NH2

H Pr NH3

Pr NH2
0.1
Pr NH3

9. CH2 CH2OH CH2
Cl
dil acidic
H

aq. NaOH
O
Na Cr O

2 2 7
COOH COOH
A
O O
COOH

O Pr oduct(C8H4O3 )
COOH
O
10.
Me Me Me
C CH CH CH2 CH CH3
H / Ni B
2 2
p 2 catalyst

H Ring exp ansion

Me Me

H

CH3
Me
6
11. CH3 CH3

CH3
CH3
Trans - 1, 2 - dimethyl cyclohexane
Trans - 1, 3 - dimethyl cyclohexane
No plane of symmetry in both the above isomers, hence optically active.

12. NO BF4
F
F B F
F
No. of bonds in BF4 4
= B. O. of NO 3.0 , i.e. one sigma bond and two bonds.
It has 5 sigma and two , bonds.
NO+ is diamagnetic and BF4 is also diamagnetic
BF bond energy is lower in BF4 than in BF3, due to presence of back bonding in BF3.
o 0.059 p H2
13. E 2H / H E2H
/H
log10 2
2 2 2 H

14. Ho Hof products Hof reac tan ts
= 166 (51) = 115 KJ mol1
So = 266 243 = 23J = 0.023 KJmol-1K-1
Ho = ve
So = +ve
Go = Ho - TSo
Go will be ve at all temperature and the reaction is favour at temperature.
15. Formula of complex is : [Co(SCN)2(NH3)4]3[Co(ox)3]
Linkage isomerism is due to presence of SCN
Optical isomerism is exhibited due to presence of [Co(ox)3]3 which has asymmetric structure.
Geometrical isomerism is exhibited by [Co(SCN)2(NH3)4]+ part
SECTION C
1. AgNO3 H2S 2O3 Ag2S
Black ppt
2. F
F
F
Sb
F F
F
F F
Sb
F
F
F
Sb-hybridisation is sp3d2 = total 6 hybrid orbitals per sb-atom.
3. O O
O O O
3 RCO H

Pr oduct X
2
The number of sp carbon is X are 10, the sum 1 + 0 = 1
4. nM s nX Mn Xn ne L.H.S
For, Mn Xn ne nM nX R.H.S
0.059 0.01
E log10
n 0.1
n=2
1 1
5. A 2 B2 AB
2 2
1 1
H eA A eB B e A B
2 2
x 0.5x
100 = x
2 2
x = 400 KJmol1
x = 4 102 KJmol1
8
Mathematics PART III

1. u xi 3xj , |u| = 2x, x > 0
2 2
Now u u 2i u i
2 x x 2 3x2 x 1 3x 2
2 2
4 x x 2 x 1 4x 2 2x 1
Squaring, 16x2(x2 x + 1) = 16x4 + 4x2 + 1 16x3 4x + 8x2
2 2
16x = 12x 4x + 1
4 32 1 2
x
8 2
x = 2 1
u 2 1 2 1
a = 2, b = 1
2. 2000x6 + 100x5 + 10x3 + x 2 = 0
2000x 6

x 10x2 1
3
2 0
2
10x 1
x 1000x 1
6
2 1000x6 1
10x2 1
x
1000x6 1= 0 or 2
10x 2 1
x = (10x2 1)
1
x2 which is not possible
10
20x2 + x 2 = 0
1 161
x , m = 1, n = 161, r = 40
40
(m + n + r) = 200
3. Let P(a cos , b sin ) C (0, 0)

b
Slope of cp tan x
a y
2 2
a b
tan sin2 P()
2ab
2ab
sin2 2 tan
a b2
b2
Using sin 2 1 and e2 1
a2
b
2 2
a tan 1 2 1 e tan 1
b2 e2
1 2
a
4 2 2 3
e + 4e tan 4 tan 0
2sin
e2 2 tan sec tan
1 sin
1 k 1 k k 1 k 2
4. Tk cos1
k k 1 k k 1
1 1
Let x , y
k k 1
1 k 12 1 k k 2
1 y2 1 2

k 1 k 1 k 1
1 1 1
Tk cos1 cos , substituting n = 2, 3, 4
k 1 k
1 1 1
S lim cos 1 cos
n n 1 2 2 3 6
120
Sn
6 k
k = 720
5. EAC = A
EAB = +
It is given that tan( ), tan and tan( + ) form a G.P.

tan2 tan2
Thus tan2 tan tan
1 tan2 tan2
tan = 1, = 45, thus B D C E
1
AD = DE = 5 2 , so that area (ABC) = BC AD CD AD 50 tan
2
Now, cot , cot( ), cot form an A.P.
2 cot(45 ) = 1 + cot cot = 3
50
ABC
3
1
6. ABCD is a trapezium and its area = a bh
2
ab
Where EF (mid parallel)
2
Area = 2r(EF)
Now equation of EF is y = x + c .. (1)
From equation (1) passes through (r, r)
c = 2r
x + y = 2r, hence E = (2r, 0) and F(0, 2r)
EF 4r 2 4r 2 2 2r
Area ABCD = 2r 2 2r 4 2r 2
2
4 2 r 2 900 2 , r = 225 r = 15
7. A2 2A + 2I = 0
Divide B by A2 2A + 21
B = (A2 2A + 21)(f(A)) + A I
10
0 1
B A I
1 0
8. FG = p A
DE = q F G
HI = r E
H
P AG AF
In AFG
sin A sinB sinC
bp cp B I D C
AG , AF
a a
Now, incircle of ABC is the excircle opposite to A for AFG the semi perimeter of AFG is
1 bp cp Sp
S AFG p
2 a a a
A Sp A
r S AFG tan tan
2 a 2
A
Since r = (s a) tan
2
sp p a
sa 1
a a s
q b r c
Similarly 1 1
b s c s

9. Since the coefficient of k in both A and B are the same, the only way that A and B can be
parallel is that f(t) = f(t), f(t) = g(t)
The first differential equation, f(t) = f(t)
p
f(t) = p cos t + q sin t. (p, q R) = p2 q2 sin t , tan
q
fmax t M p2 q2

A f 2 t g2 t 1 p2 q2 1

A is constant
10. A upon simplification (a + b + c) (a b) (b c) (c a)

The only way this can be 0 is (a + b + c) = 0
fixed point is (1, 1)
x x
11. t f x t dt f t dt sin x cos x x 1

0 0
x x
x t f t dt =

0
f t dt sin x cos x x 1
0
x x x
f t dt t f t dt f t dt sin x cos x x 1

0 0 0
Again differentiating
x f(x) + f(x) + f(x) xf(x) f(x) > f(x) sin x cos x
f(x) = f(x) sin x cos x
Solving this linear differential equation
We get, f(x) ex = ex cos x + c
If x = 0, f(0) = 0 f(x) = ex cos x
12. Let w be the event that the ball drawn is white

x
Then P(w) =
y
x x 1 y x x x
When, ball is lost P(w) =
y y 1 y y 1 y
x
C2 x 2 x C1 y x C1 x 1 y x C2 x x
When 2 balls is lost P(w) = y
y
y
C2 y 2 C2 y2 C2 y 2 y
x
Similarly for n = 3, P(w) =
y
v uz uz
13. w
uz 1 uz 1
Let, |w| 1
|u z| uz 1
(u z) u z uz 1 uz 1
(|u|2 1)(|z|2 1) 1
|z|2 1 0
14. f(0) = 0, f(0+) = 1, f(0) = 1

discontinuous at x = 0
f(1) = 1, f(1) = 1, f(1+) = 0
discontinuous at x = 1
15. Squaring and adding

sin (x + y) = 1

x + y = 4n 1 , n I
2

x+ y= , y x
2 2
5 sin x = 3
4
cos x =
5
3 4
Also, cos y = and sin y =
5 5
Hence, y > x
SECTION C
1 1 1
1. f x .....
2 2 2
n n 2 n 2n 1
Terms of the sequence are decreasing and number of terms are (2n + 2)
2n 2 2n 2
f x
2
n 2n 1 n2
1
2n 1
2 n 1 n
Now lim = lim
n 2 n 2 1
n 2n 1 n 1 2
n n
12
2 n 1 2 n 1
Similarly lim = lim 2
n
n 2 n n
/ 2 /2
sin x r cos x 3 dx = 3
x r 3 cos3 x 3r sin2 x cos x 3r 2 sin x cos2 x dx
2. I1
0
sin
0
2 2r 3
= r2 r
3 3
/2
/ 2 2
I2 x cos xdx x sin x cos x
0
0
2
4r
I I1 I2 2
2
3 2
2r + 3r 3r + 2 = 6
2r + 3r2 3r 4 = 0
3
3 3 2 21
r1 ,
2
r1r2 ,
2 r 1
4
3. A event that die A was used in first two throws

B event that die B was used in first two throws
C event that next throws gives red face
E event that first two throws give red faces
2
1 4

A 4
2 6
P
E 1 4 2 1 2 2 5

2 6 2 6
B 1 C 3
P P
E 5 E 5
a = 3, b = 5
x2
4. f x 2f f 6 x 2
2
x2
f ' x 2f ' x 2xf ' 6 x 2
2
x2
f ' x 2x f ' f ' 6 x 2
2
x2 2 x2
f ' f ' 6 x (if 6 x2 )
2 2
f(x) is increasing
x2
6 x2 x2 > 4
2
x2
f ' f ' 6 x 2 0 when x < 2 or x > 2
2
f(x) > 0, when x (2, 0) (2, )
a+b+c=0

5. R = 1 + sin ,
8
c 1c 2 = R + r
Rr
sin
Rr
R sin + r sin = R r
R(1 sin ) = r(1 + sin ) (Put R = 1 + sin )
(1 + sin )(1 sin ) = r(1 + sin )
r = 1 sin
Rr = 1 sin2 = cos2
1 1 2 2
cos 2 = 1 cos 1 cos
2 2 4 4
a = 2, b = 4

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1 AITS-CRT-II-(Paper-1)-PCM(S)-JEE(Advanced)/14

14. Since vertical Impulse is acting on A

1. In (C), the tautomeric form will be

11. CH3 CH3

Mathematics PART III

2. 2000x6 + 100x5 + 10x3 + x 2 = 0

3. Let P(a cos , b sin ) C (0, 0)

10. A upon simplification (a + b + c) (a b) (b c) (c a)

12. Let w be the event that the ball drawn is white

14. f(0) = 0, f(0+) = 1, f(0) = 1

15. Squaring and adding

3. A event that die A was used in first two throws

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