The underwater casting of relatively thin lifts of concrete in water decreases with the shear rate that facilitates pumping and
requires the proportioning of highly flowable concrete that can placement. The shear-thinning behavior is affected by the
resist water dilution and segregation and spread readily into place. water content and the type and dosage rate of the AWA.
An investigation was carried out to determine the effects of anti- Anti-washout concrete can be highly thixotropic, whereby a
washout admixture concentration, water-cementitious materials relatively fast buildup of viscosity can be observed at a given
ratio, and binder composition on the washout resistance of highly
flowable concrete. shear rate. Such thixotropy can contribute to stability of
Two main types of antiwashout admixtures were used: 1) a pow-
freshly cast concrete, including the resistance to water erosion
dered welan gum at concentrations of 0.07 and 0.15% (by mass of of exposed surfaces.
binder); and 2) a liquid-based cellulosic admixture with dosages Several of the relevant mixture properties necessary for
up to 1.65 L /100 kg of binder. The water-cementitious materials successful underwater placement contradict one another.
ratios were set at 0.41 and 0.47, corresponding to high-quality Such concrete should therefore be tailored to achieve good
underwater concrete. Four binder compositions were used: a stan- balance between mixture parameters that have direct bearing
dard Canadian Type 10 cement, the same cement with 10% silica on rheological properties and performance of the hardened
fume replacement, the cement with 50% granulated blast-furnace
concrete. With sound mixture proportioning and proper
slag replacement, and a ternary cement containing 6% silica fume
and 20% Class F fly ash. The concentrations of anti-washout combinations of HRWR and AWA, it is possible to secure
admixture have direct impact on washout resistance. For a given high-performance concrete for underwater applications.8-9
washout loss, greater slump flow consistency can be achieved with Slump flow consistency is often used to assess deformability
the increases in anti-washout admixture concentration and of highly flowable concrete. For underwater concrete, the slump
decreases in water-binder ratio. The washout mass loss can be flow is influenced, in order of importance, by the AWA
reduced, for a given consistency, when the ternary binder or 10% concentration and binder content, by the water-cementitious
silica fume replacement is used. materials ratio (w/cm), and by HRWR dosage.10 The washout
mass loss is affected by, in order of importance, the AWA
Keywords: admixture; fly ash; granulated blast-furnace slag; silica fume; dosage, binder content, w/cm, and HRWR concentration.
slump; water-reducing admixture (high-range).
The w/cm has direct bearing on stability of fresh concrete
and mechanical properties. For underwater AWA concrete,
INTRODUCTION the Standards of the Japan Society of Civil Engineers (JSCE)
Anti-washout admixtures (AWAs) are used to enhance the recommend limiting the w/cm to 0.50 and 0.55 when casting
stability of fresh cement-based systems, including underwa- reinforced concrete in seawater and in fresh water, respectively;
ter concrete. Several researchers have reported improvement these values can be 0.60 and 0.65, respectively, for non-
in washout resistance and in-place properties of underwater- reinforced concrete.11
cast concrete when the concrete incorporates AWAs.1-3
The use of supplementary cementitious materials has direct
Such admixtures are also used in self-consolidating concrete
bearing on workability and stability of fresh concrete. For
to enhance resistance to bleeding, segregation, and surface
example, the substitution of cement mass by 8% silica fume
settlement.
or by 20% Class F fly ash can enhance washout resistance,
Commonly used AWAs include cellulose derivatives and compared with concrete made without any supplementary
polysaccharides of microbial sources.4-6 The mode of action cementitious materials. For concrete with 0.41 w/cm and a
of AWA depends on the type and concentration of the poly- slump of 230 mm, the incorporation of 8% of silica fume is
mer. For example, welan gum is believed to increase the vis- reported to reduce washout loss, segregation coefficient, and
cosity of mixing water as long-chain polymer molecules
surface settlement by as much as 6, 65, and 50%, respectively,
adhere to the periphery of water molecules, thus imbibing
compared with concrete with 100% cement.12 In the case of
and fixing part of the mixing water and enhancing the paste
concrete with 20% fly ash replacement, the washout loss,
viscosity.7 This can improve the capacity of the paste to sus-
segregation coefficient, and surface settlement were found
pend solid particles and retain free water. Concrete modified
to decrease by as much as 6, 40, and 65%, respectively,
with AWA exhibits higher yield value and plastic viscosity
compared with concrete without supplementary cementitious
compared with non-AWA concrete. 6 High-range water-
materials.12
reducing admixture (HRWR) is added to reduce the yield
value of AWA concrete. The increase in HRWR and AWA
dosages could secure flowable concrete of relatively low ACI Materials Journal, V. 98, No. 4, July-August 2001.
MS No. 00-124 received June 5, 2000, and reviewed under Institute publication pol-
yield value and moderate-to-high plastic viscosity of high icies. Copyright 2001, American Concrete Institute. All rights reserved, including
washout resistance. Mixtures containing AWA can exhibit the making of copies unless permission is obtained from the copyright proprietors.
Pertinent discussion will be published in the May-June 2002 ACI Materials Journal if
shear-thinning behavior, whereby the apparent viscosity received by February 1, 2002.
Naphthalene-based
1.6 to 8.2 4.2 to 9.8 5.9 to 9.4 2.1 to 5.9 0.0 to 3.1 3.2 to 5.6 4.0 to 7.0 0.7 to 2.8
HRWR, L/m3
Welan gum AWA, 0.07* 0.07 0.07 0.07 0.07 0.07 0.07 0.07
% mass of CM 0.15 0.15 0.15 0.15 0.15
0.15
Melamine-based HRWR,
1.4 to 2.0 2.5 to 4.1 1.9 to 3.9 0.0 to 2.6 0.0 to 1.5 3.1 to 4.5 1.0 to 3.0 0.0 to 1.7
L/m3
Cellulose AWA,
L/100 kg of CM 1.0 1.0 1.0 1.0 1.0 to 1.65 1.0 1.0 1.65
*0.07% binder = 0.17% of water for w/cm = 0.41 and 0.15% of water for w/cm = 0.47.
0.15% binder = 0.37% of water for w/cm = 0.41 and 0.32% of water for w/cm = 0.47.
Fig. 1Relationship between slump and slump flow. Fig. 2Effect of cementitious materials combination and
w/cm on HRWR demand of mixtures made with welan gum
and fixed slump flow of 450 mm.
Table 4Results of mixtures with 0.41 w/cm and
cellulosic AWA
HRWR,* Slump, Slump Washout
Type of CM L/m3 AWA type dosage mm flow, mm loss, %
1.4 Cellulosic AWA 255 465 5.9
100% C (1.0 L/100 kg
2.0 CM) 265 555 8.5
2.5 240 400 3.6
Cellulosic AWA
10% SF 3.5 (1.0 L/100 kg 255 510 5.9
CM)
4.1 265 535 6.4
1.9 Cellulosic AWA 240 400 3.6
6% SF +
3.2 (1.0 L/100 kg 270 490 4.1
20% FA CM)
3.9 275 555 4.8
0.0 Cellulosic AWA
240 380 3.7
50% SL 1.9 (1.0 L/100 kg 260 525 6.4 Fig. 3Effect of cementitious materials combination and w/
CM)
2.6 275 610 8.6 cm on HRWR demand of mixtures made with cellulosic AWA
*
High-range water-reducing admixture. and fixed slump flow of 450 mm (1 L = 1 L/100 kg CM).
50% SL
the 450 mm slump flow level, the concrete with the silica
Increasing
20 HRWR fume and fly ash again exhibited the lowest washout losses
of approximately 3 and 4% in mixtures containing 0.15%
6% SF + 20% FA
welan gum and 1 L/100 kg cellulosic AWA, respectively.
10 10% SF
CONCLUSIONS
0 Based on the results of this study, the following conclu-
300 350 400 450 500 550 600 650 700 sions appear to be warranted:
Slump flow (mm) 1. The measurement of slump flow is more sensitive in re-
Fig. 7Effect of w/cm and binder composition on varia- flecting changes in consistency of highly flowable AWA
tions of washout loss with slump flow.
30 (41%) Welan gum AWA (53%)
12 450 mm 550 mm
W/CM = 0.41 25 W/CM = 0.47
Washout loss (%)
20
10% SF
Increasing
8 15
HRWR 100% C
6 10
6% SF + 20% FA 5
4
0
2
%
S L 5%
S L 7%
%
SF 5%
7%
SF 5%
SF %S 07%
5%
%
SL 7%
7%
7
0% .07
15
0% .07
0% C-0
0% .15
0% 0.0
.1
.0
.1
.0
.1
0% .1
.0
.0
6% +20 -0.
.
5 0 A-0
5 0 A-0
-0
-0
-0
-0
-0
-0
+2 F-0
-0
-0
-0
0
0%
+2 A-
C
C
F
F
SF %S
10
%
%
10
10
6% 10
50
10
10
10
6% 10
SF
Fig. 8Variations of washout loss with slump flow for mix- Fig. 10Comparison of washout losses of various mixtures with
tures made with different binder types (w/cm = 0.41 and slump flow of 450 and 550 mm containing welan gum AWA.
0.15% welan gum).
30 (41%) Cellulosic AWA
10
W/CM = 0.41
25 450 mm 550 mm
Washout loss (%)
8 20
100% C
Increasing
15
HRWR W/CM = 0.41 W/CM = 0.47
6 10% SF 10
5
4 0
6% SF + 20% FA
%
L
L
L
L
L
L
-0
-1
-1
-1
5
-1
-1
-1
-1
-1
.6
C
SF
SF
SL
SL
FA
FA
C
-1
0%
0%
0%
2
C
0%
0%
0%
10
10
50
10
10
50
10
+2
+2
10
SF
6%
6%
Fig. 9Variations of washout loss with slump flow for mixtures Fig. 11Comparison of washout mass losses of various
made with different binder types (w/cm = 0.41; 1.0 L/100 kg of mixtures with slump flow of 450 and 550 mm containing
cementitious materials of cellulosic AWA). cellulosic AWA.