LAPORAN KERJA PRAKTEK

PLANT LINEAR LOW DENSITY POLYETHYLENE

PT. CHANDRA ASRI PETROCHEMICAL
Periode : 04/09/2017 29/09/2017

DisusunOleh :
Atik Kurnia 21030114120077
Muhammad Airlangga 21030114130163

JURUSAN TEKNIK KIMIA FAKULTAS TEKNIK

UNIVERSITAS DIPONEGORO
SEMARANG
2017
Laporan Kerja Praktek
Jurusan Teknik Kimia Fakultas Teknik Universitas Diponegoro

LEMBAR PENGESAHAN
PRAKTEK KERJA
PT. CHANDRA ASRI PETROCHEMICAL TBK.

Nama : Atik Kurnia/ Muhammad Airlangga

NIM : 21030114120077 / 21030114130163
Jurusan / Fakultas : Teknik Kimia / Teknik
Tanggal : 4 29 September 2017

Cilegon, 30 Agustus 2016

Pembimbing,

Mengetahui,
Section Manager, L & D Mnager,

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Laporan Kerja Praktek
Jurusan Teknik Kimia Fakultas Teknik Universitas Diponegoro

Halaman Pengesahan
LAPORAN TUGAS UMUM

UNIVERSITAS DIPONEGORO
FAKULTAS TEKNIK
JURUSAN TEKNIK KIMIA

Nama : Atik Kurnia/ Muhammad Airlangga

NIM : 21030114120077 / 21030114130163
Pabrik : PT. Chandra Asri Petrochemical Tbk., (Cilegon)
Dosen Pembimbing : Dr. Istadi, S.T., M.T.

Semarang, September 2017

Dosen Pembimbing,

Dr. Istadi, S.T,M.T.

NIP. 197103011997021001

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Laporan Kerja Praktek
Jurusan Teknik Kimia Fakultas Teknik Universitas Diponegoro

KATA PENGANTAR

Puji syukur kehadirat Allah SWT yang melimpahkan rahmat dan karunia-
Nya sehingga penulis dapat menyelesaikan laporan kerja praktek di PT. Chandra
Asri Petrochemical Tbk. dengan lancar. Laporan kerja praktek ini disusun sebagai
salah satu syarat unutk menyelesaikan studi program Strata-1 di Jurusan Teknik
Kimia, Fakultas Teknik, Universitas Diponegoro, Semarang.
Penulis menyadari laporan ini tidak akan selesai tanpa bantuan dari
berbagai pihak. Oleh karena itu pada kesempatan ini penulis mengucapkan terima
kasih kepada:
1. Bapak Dr. Siswo Sumardiono, ST, MT. sebagai Ketua Jurusan Teknik
Kimia, Fakultas Teknik, Universitas Diponegoro, Semarang.
2. Bapak Dr. Istadi, S.T., M.T sebagai dosen pembimbing atas bimbingannya
3. Bapak Priyo Utomo atas segala ilmu beserta shock therapy yang diberikan
kepada penulis sehingga mampu memahami proses produksi di LLDPE
Section
4. Mas ervid selaku pembimbing dan Mas Bangkit selaku pembimbing
lapangan yang telah memberikan waktu dan ilmu kepada penulis sehingga
penulis mampu menyelesaikan kerja praktek di LLDPE Section.
5. Bapak Sugianto, Bapak Joko, Bapak Mulyanto, Mas Aldi dan Mas Habibi
atas kerja sama yang telah memberikan ilmu dan support-nya sehingga
penulis dapat melaksanakan kerja praktek di LLDPE Section.
6. Ibu Fera dan Teh Ochi dari HRD Section yang telah memberikan berbagai
bantuan dan fasilitas dalam On the Job Training.
7. Teman-teman seperjuangan On the Job Training LLDPE Section yang
seru dan bersahabat.
8. Semua pihak yang telah membantu proses terselesaikannya laporan kerja
praktek ini.
Semoga laporan ini dapat memberikan manfaat bagi penyusun dan
pembaca.

Semarang, September 2017

Penyusun

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 Laporan Kerja Praktek
Jurusan Teknik Kimia Fakultas Teknik Universitas Diponegoro

DAFTAR ISI
LEMBAR PENGESAHAN .................................................................................... ii
KATA PENGANTAR ........................................................................................... iv
DAFTAR ISI ........................................................................................................... v
DAFTAR TABEL ............................................................................................... viii
DAFTAR GAMBAR ............................................................................................. ix
BAB I ...................................................................................................................... 1
1.1 Latar Belakang dan Sejarah PT. Chandra Asri Petrochemical ..................... 1
1.2 Lokasi Pabrik ................................................................................................ 5
1.3 Bahan Baku dan Produk ............................................................................... 6
1.3.1 Bahan Baku Utama (Ethylene) ............................................................... 7
1.3.2 Bahan Penunjang .................................................................................... 8
1.3.2.1 Co-monomer (Butene-1 / Hexene-1) ................................................... 8
1.3.2.2 Hidrogen (H2)..................................................................................... 10
1.3.2.3 Nitrogen (N2) ..................................................................................... 11
1.3.2.4 Catalyst .............................................................................................. 13
1.3.2.5 Co-catalyst ......................................................................................... 13
1.3.2.6 Additive.............................................................................................. 14
1.3.3 Produk ................................................................................................... 15
1.4 Struktur Organisasi ..................................................................................... 16
BAB II ................................................................................................................... 17
2.1 Konsep Proses ............................................................................................ 17
2.2 Design Struktur Proses ............................................................................... 20
2.2.1 Baterry limit .......................................................................................... 22
2.2.2 Flare Stack ............................................................................................ 23
2.3 Deskripsi Proses ......................................................................................... 25
2.3.1 Unit Purifikasi ....................................................................................... 25
2.3.1.1 Purifikasi Ethylene ........................................................................... 25
2.3.1.2 Purifikasi Nitrogen........................................................................... 28
2.3.1.3 Purifikasi Co-monomer .................................................................... 30
2.3.1.4 Persiapan Hidrogen .......................................................................... 31
2.3.1.5 Persiapan Co-catalyst ...................................................................... 32

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Jurusan Teknik Kimia Fakultas Teknik Universitas Diponegoro

2.3.2 Unit Reaksi............................................................................................ 33

2.3.2.1 Catalyst System................................................................................ 33
2.3.2.2 Reaktor ............................................................................................. 35
2.3.2.3 Product Discharge System ............................................................... 40
2.3.2.4 Reactor Static Control (RSC) .......................................................... 41
2.3.2.5 Killing System ................................................................................. 42
2.3.3 Unit Finishing ....................................................................................... 45
2.3.3.1 Proses Degassing ............................................................................. 45
2.3.3.2 Proses Additive Handling ................................................................ 48
2.3.3.3 Proses Pelleting................................................................................ 49
2.3.4 Unit Recovery........................................................................................ 51
2.3.4.1 Sistem Refigerasi ............................................................................. 54
BAB III ................................................................................................................. 56
3.1 Peralatan Utama .......................................................................................... 56
3.1.1 Spesifikasi Fluidized Bed Reactor (C-4001)......................................... 56
3.1.2 Dasar Reaksi Reaktor LLDPE Plant ..................................................... 57
3.1.3 Dasar Operasi Fluidisasi ....................................................................... 57
3.1.4 Cara Kerja Fluidized Bed Reactor (C-4001) ........................................ 59
3.1.5 Keuntungan dan Kerugian Fluidized Bed Reactor (C-4001) ................ 60
3.2 Spesifikasi Alat Pendukung ........................................................................ 61
3.2.1 Unit purifikasi ....................................................................................... 62
3.2.2 Unit Reaksi ............................................................................................ 70
3.2.3 Unit Finishing........................................................................................ 72
3.2.4 Unit Recovery ....................................................................................... 75
BAB IV ................................................................................................................. 81
4.1. Penyediaan Air .......................................................................................... 81
4.1.1 Sistem pengolahan Air Laut (Sea Water Treatment System) ............... 82
4.1.2 Water Treatment System ....................................................................... 84
4.1.3 Cooling Water System .......................................................................... 89
4.1.4 Sistem Pemadam Kebakaran (Fire Fighting System) ........................... 90
4.2 Penyediaan Uap .......................................................................................... 91
4.3 Penyediaan Tenaga Listrik ......................................................................... 96

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Jurusan Teknik Kimia Fakultas Teknik Universitas Diponegoro

4.4 Penyediaan Udara Tekan ............................................................................ 98

4.5 Pengolahan Limbah .................................................................................... 99
4.5.1 Pengolahan Limbah Cair..................................................................... 100
4.5.2 Unit Pengolahan Limbah Padat........................................................... 103
4.5.3 Unit Pengolahan Limbah Gas ............................................................. 105
BAB V................................................................................................................. 107
5.1 Kesimpulan ............................................................................................... 107
5.2 Saran ......................................................................................................... 108
DAFTAR PUSTAKA ......................................................................................... 109

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 Laporan Kerja Praktek
Jurusan Teknik Kimia Fakultas Teknik Universitas Diponegoro

DAFTAR TABEL

Tabel 1. 1 Perkembangan PT. Chaandra Asri Petrochemical, Tbk ......................... 3

Tabel 1. 2 Komposisi bahan baku ethylene ............................................................. 7
Tabel 1. 3 Sifat-sifat fisik dari ethylene .................................................................. 7
Tabel 1. 4 Sifat fisik n-hexane ................................................................................ 9
Tabel 1. 5 Sifat fisik hexene-1................................................................................. 9
Tabel 1. 6 Kandungan butene-1 ............................................................................ 10
Tabel 1. 7 Kandungan hexene-1 ............................................................................ 10
Tabel 1. 8 Sifat fisik Hidrogen .............................................................................. 11
Tabel 1. 9 Kandungan Nitrogen ............................................................................ 12
Tabel 1. 10 Sifat Fisik Nitrogen ............................................................................ 12
Tabel 1. 11 Spesifikasi Grade Produk LLDPE PT. Chandra Asri Petrochemical 15
Tabel 2. 1 Proses open-close valve pada PDS.......................................................41
Tabel 4. 1 Karakteristik Air Olahan .................................................................... 102
Tabel 4. 2 Karakteristik Gas Keluaran dari Incinerator Parameter ................... 103
Tabel 4. 3 Gas Hasil Pembakaran Sludge dari Limbah Cair ............................... 103

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 Laporan Kerja Praktek
Jurusan Teknik Kimia Fakultas Teknik Universitas Diponegoro

DAFTAR GAMBAR

Gambar 1. 1 Lokasi PT. Chandra Asri .................................................................... 5

Gambar 1. 2 Struktur Organisasi PT. Chandra Asri Petrochemical Tbk. ............. 16
Gambar 2. 1 Katalis Ziegler-Natta ....................................................................... 17
Gambar 2. 2 Aktivasi TiCl4 dengan TEAL ........................................................... 18
Gambar 2. 3 Reaksi Adisi Molekul Radikal Bebas dari Ethylene ........................ 18
Gambar 2. 4 Rearrangement Struktur LLDPE ..................................................... 19
Gambar 2. 5 Propagasi LLDPE ............................................................................. 19
Gambar 2. 6 Terminasi LLDPE ............................................................................ 20
Gambar 2. 7 Pembagian 4 unit LLDPE ................................................................ 21
Gambar 3.1 Grafik Penurunan Tekanan dan Tinggi Hamparan ........................... 59
Gambar 3. 2 Fluidized Bed Reactor LLDPE Plant PT. Chandra Asri .................. 61
Gambar 4. 1 Sistem Pengambilan Air Laut (Sea Water Intake System) ............... 82
Gambar 4. 2 Standar baku mutu kualitas air PT. Chandra Asri ............................ 85
Gambar 4. 3 Skema Water Treatment System ....................................................... 86
Gambar 4. 4 Skema Cooling Water System .......................................................... 89
Gambar 4. 5 Fire Fighting System ........................................................................ 90
Gambar 4. 6 Skema Unit Penyedia Steam di PT. Chandra Asri Petrochemical ... 92
Gambar 4. 7 Skema Proses Pada Sistem Boiler .................................................... 93
Gambar 4. 8 Skema penyediaan Instrument and Plant Air System....................... 99
Gambar 4. 9 Skema Sistem Pengolahan Air Limbah .......................................... 100

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