ANNISA ALVI RAMADHANI

5900470521
CHEM ENG THERMODYNAMICS

PROBLEM 2
975
Using equation A =
18.4 + 3 ln . Guessing T and input to equation until we get A=2

T A
215 2,247
225 2,182
235 2,128
245 2,083 Using interpolation
255 2,047
265 2,018
273 2,000 UCST, A = 2
275 1,996
285 1,979
295 1,966
305 1,958
315 1,953
325 1,951
335 1,953
345 1,957
355 1,963
365 1,971 Using interpolation
375 1,981
385 1,992
391,15 2,000 LCST, A = 2
395 2,005
405 2,019
415 2,034
425 2,050
435 2,067
445 2,085
For UCST
T A1 X1 A2 X2
200 2,370 0,820 2,370 0,180
203 2,343 0,811 2,343 0,189
206 2,317 0,802 2,317 0,198
209 2,292 0,793 2,292 0,207
212 2,269 0,784 2,269 0,216
215 2,247 0,774 2,247 0,226
218 2,226 0,765 2,226 0,235
221 2,206 0,755 2,206 0,245
224 2,188 0,745 2,188 0,255
227 2,170 0,735 2,170 0,265
230 2,153 0,724 2,153 0,276
233 2,138 0,714 2,138 0,286
236 2,123 0,704 2,123 0,296
239 2,109 0,693 2,109 0,307
242 2,096 0,682 2,096 0,318
245 2,083 0,670 2,083 0,330
248 2,072 0,659 2,072 0,341
251 2,061 0,647 2,061 0,353
254 2,051 0,635 2,051 0,365
257 2,041 0,622 2,041 0,378
260 2,032 0,608 2,032 0,392
263 2,024 0,594 2,024 0,406
266 2,016 0,577 2,016 0,423
269 2,009 0,558 2,009 0,442
272 2,002 0,527 2,002 0,473
273 2,000 0,500 2,000 0,500

For LCST
T A1 X1 A2 X2
391,150 2,000 0,500 2,000 0,500
392 2,001 0,519 2,001 0,481
395 2,005 0,543 2,005 0,457
398 2,009 0,558 2,009 0,442
401 2,013 0,569 2,013 0,431
404 2,018 0,581 2,018 0,419
407 2,022 0,590 2,022 0,410
410 2,027 0,599 2,027 0,401
413 2,031 0,606 2,031 0,394
416 2,036 0,614 2,036 0,386
419 2,041 0,622 2,041 0,378
422 2,045 0,627 2,045 0,373
425 2,050 0,634 2,050 0,366
428 2,055 0,640 2,055 0,360
431 2,061 0,647 2,061 0,353
434 2,066 0,653 2,066 0,347
437 2,071 0,658 2,071 0,342
440 2,076 0,663 2,076 0,337
443 2,082 0,669 2,082 0,331
446 2,087 0,674 2,087 0,326
449 2,093 0,679 2,093 0,321
452 2,098 0,684 2,098 0,316
455 2,104 0,689 2,104 0,311
458 2,109 0,693 2,109 0,307
461 2,115 0,698 2,115 0,302
So, the graph will be

UCST
290

270

250

230

210

190

170

150
0.000 0.100 0.200 0.300 0.400 0.500 0.600 0.700 0.800 0.900

LCST
470.000

460.000

450.000

440.000

430.000

420.000

410.000

400.000

390.000

380.000
0.200 0.300 0.400 0.500 0.600 0.700
 UCST AND LCST
500

450

400

350

300

250

200

150

100

50

0
0.000 0.100 0.200 0.300 0.400 0.500 0.600 0.700 0.800 0.900
Problem 4
Guess T => Until we get P=1600

5363.7
P1sat exp 19.1478
T

2048.97
P 2 sat exp 14.6511
T

T P1sat P2sat P y*
273 0,606863 1268,659 1269,265 0,000478
274 0,651976 1303,89 1304,542 0,0005
275 0,700078 1339,833 1340,533 0,000522
276 0,751341 1376,495 1377,246 0,000546
277 0,805947 1413,885 1414,691 0,00057
278 0,864084 1452,01 1452,874 0,000595
279 0,925954 1490,88 1491,805 0,000621
280 0,991763 1530,5 1531,492 0,000648
281 1,06173 1570,881 1571,943 0,000675
281,5 1,098344 1591,359 1592,457 0,00069
281,6 1,105801 1595,477 1596,583 0,000693
281,65 1,109546 1597,539 1598,649 0,000694
281,68 1,111799 1598,778 1599,889 0,000695
281,685 1,112175 1598,984 1600,10 0,000695
281,683 1,112025 1598,901 1600,014 0,000695
 P1sat
y1
P

P 2sat
y2 1
P

T P1sat y1 y1x10^5 P2sat y2 y2x10^5

281,683 1,112025 0,000695015 69,5015 1598,90 0,000686569 68,6569
281,684 1,112100 0,000695062 69,5062 1598,943 0,000660763 66,0763
281,685 1,112175 0,000695109 69,5109 1598,984 0,000634957 63,4957
281,686 1,112250 0,000695156 69,5156 1599,025 0,000609150 60,9150
281,687 1,112325 0,000695203 69,5203 1599,067 0,000583342 58,3342
281,688 1,112400 0,000695250 69,5250 1599,108 0,000557534 55,7534
281,689 1,112476 0,000695297 69,5297 1599,149 0,000531726 53,1726
281,690 1,112551 0,000695344 69,5344 1599,191 0,000505917 50,5917
281,691 1,112626 0,000695391 69,5391 1599,232 0,000480108 48,0108
281,692 1,112701 0,000695438 69,5438 1599,273 0,000454298 45,4298
281,693 1,112777 0,000695485 69,5485 1599,314 0,000428488 42,8488
281,694 1,112852 0,000695532 69,5532 1599,356 0,000402677 40,2677
281,695 1,112927 0,000695579 69,5579 1599,40 0,000376866 37,6866
281,696 1,113002 0,000695626 69,5626 1599,438 0,000351054 35,1054
281,697 1,113077 0,000695673 69,5673 1599,48 0,000325242 32,5242
281,698 1,113153 0,000695720 69,5720 1599,521 0,000299429 29,9429
281,699 1,113228 0,000695767 69,5767 1599,562 0,000273616 27,3616
281,700 1,113303 0,000695814 69,5814 1599,604 0,000247802 24,7802
281,701 1,113378 0,000695862 69,5862 1599,645 0,000221988 22,1988
281,702 1,113454 0,000695909 69,5909 1599,686 0,000196173 19,6173
281,703 1,113529 0,000695956 69,5956 1599,727 0,000170358 17,0358
281,704 1,113604 0,000696003 69,6003 1599,769 0,000144542 14,4542
281,705 1,113679 0,000696050 69,6050 1599,81 0,000118726 11,8726
281,706 1,113755 0,000696097 69,6097 1599,851 0,000092910 9,2910
281,707 1,113830 0,000696144 69,6144 1599,893 0,000067092 6,7092
281,708 1,113905 0,000696191 69,6191 1599,934 0,000041275 4,1275
281,709 1,113981 0,000696238 69,6238 1599,975 0,000015457 1,5457
281,710 1,114056 0,000696285 69,6285 1600,017 -0,000010362 -1,0362
So, the phase diagram :

281.71

281.705
Temperature
281.7

281.695

281.69

281.685

281.68
69.4800 69.5000 69.5200 69.5400 69.5600 69.5800 69.6000 69.6200 69.6400
y1 x 10^5

281.71

281.705
Temperature

281.7

281.695

281.69

281.685

281.68
0.0000 10.0000 20.0000 30.0000 40.0000 50.0000 60.0000 70.0000 80.0000
y2 x 10^5

281.71

281.705
Temperature

281.7

281.695

281.69

281.685

281.68
0.0000 10.0000 20.0000 30.0000 40.0000 50.0000 60.0000 70.0000 80.0000
y1 x 10^5
y2 x 10^5