Test 2
1. Describe the formation of the line spectrum of the hydrogen atom according to Bohrs Theory. [6m]
2. The diagram below shows a few lines formed in the Balmer series of the hydrogen atom spectrum.
(a) Between the red line and indigo line, which has a higher frequency? [1m]
(b) Explain why the spectrum consists of a set of sharp, distinct lines. [1m]
(c) Draw a labeled energy diagram to show the electron transitions for these lines. [2m]
(d) The frequency for the convergence limit is found to be 8.23 x 1014 Hz.
i) Which electron transition will produce the convergence limit? [1m]
ii) Calculate the energy that is required to promote one electron to produce this line. [2m]
3. (a) The diagram below shows four electron transitions in the hydrogen
atom.
(i) Sketch the line spectrum formed as a result of these four
transitions. [2m]
(ii) In which region of the electromagnetic spectrum are these lines
formed? [1m]
6. (a) Electrons, protons and neutrons are the constituent particles of the atom.
Their masses, in amu, (atomic mass unit) based on the carbon-12 standard are:
proton: 1.007580 neutron: 1.008980 electron: 0.000548
(i) Calculate the mass, (in amu), of a deuterium atom, . [2 m]
(ii) The actual mass of a deuterium atom is 2.014102 amu. Calculate the mass lost, in amu, when the sub-
atomic particles fuse together. [1 m]
(iii) The mass lost is converted into radiant energy according to Einstein's equation E = mc2 (m is
measured in kilograms and c is the speed of light in ms-1). Using this equation, together with E = hv,
calculate the frequency of the radiation emitted. [2 m]
-27 8 -1 -34
(1 amu = 1.66 x 10 kg, c = 3 x 10 ms , h= 6.63x10 Js)
7. (a) The line spectrum of atomic hydrogen in the ultraviolet region of the electromagnetic spectrum is shown
below:
(i) Explain why this spectrum consists of lines which are convergence. [2m]
(ii) Using a labeled energy level diagram, show how the line marked Y on the spectrum is formed. [2m]
(iii) If the frequency of convergence limit in Lyman series is 3.24 x 1015 Hz, Calculate the ionization
energy of hydrogen atom in kJ mol-1. [Planck constant, h = 3.99 x 10-13 kJ s mol-1] [2m]
(iv) Write an equation of ionization hydrogen atom. [1 m]