VIII.

Obaervation Result
Numb Procedure Observation Result Hypothesis/Reaction Conclusion
Before After
1. A. The Reaction of Na2S2O3 and H2SO4 - Na2S2O3 : - Beaker A : 3 Na2S2O3 (aq) + The reaction of

Na2S2O3 Colorless colorless H2SO4 (aq) 3 Na2S2O3 and

Na2S2O3 Na2S2O3
0.1M solution solution Na2SO4 (aq) +4S + H2SO4 has the
0.1M 0.1M
- Aquades : + H2SO4 : H2O (l) reaction order
10 mL 7.5 mL 5 mL
colorless Turbid solution 2
- H2SO4 : (+++)

- Each of those solution is poured into colorless - Beaker B :

different beaker glass (A,B and C) colorless
- Placed on the X sign
solution
- Added H2SO4 5 mL in each beaker glass
- Turn On the stopwatch when H2SO4 start + H2SO4 :
to add Turbid solution
- Turn Off the stopwatch when the solutions
(++)
is constant turbid
- Observed - Beaker C :
- Write the time needed colorless
Time of each solutions
solution
 + H2SO4 :
Turbid solution
(+)
- Time needed :
Beaker A : 100
second
Beaker B : 141
second
Beaker C : 180
second
- Reaction order :
1
 - Beaker A :
H2SO4 0.5 H2SO40.5 M H2SO40.5 M colorless solution
M + Na2S2O3 :
7.5 mL 5 mL
Turbid Solution
10 mL
+ Aquadest + Aquadest (+++)
2.5 mL 5 mL - Beaker B :
colorless solution

- Each of those solution is poured + Na2S2O3 :

into different beaker glass (A,B Turbid Solution
and C)
- Placed on the X sign
(++)
- Added Na2S2O3 0.1 M 5 mL in - Beaker C :
each beaker glass colorless solution
- Turn On the stopwatch when
Na2S2O3 start to add + Na2S2O3 :
- Turn Off the stopwatch when the Turbid Solution
solutions is constant turbid
(+)
- Observed
- Write the time needed - Time needed :
Beaker A : 123
Time of each solutions in
second
beaker glass
Beaker B : 154
second
Beaker C : 181
second
- Reaction order :
1
- Total Reaction
order : 1 + 1 = 2
2. The Reaction of Mg and HCl - Mg ribbon : - Mg ribbon + Mg (s) + 2HCl (aq) The reaction
blackish silver HCl solution : MgCl2 (aq) + H2 between Mg
Mg Ribbon (g)
- HCl : there was and HCl
colorless produce buble solution has
- Cut the Mg ribbon into 16 pieces (@piece=
0.5 cm) solution gas (H2) and it the order
- Put into erlenmeyer that already contain 25 has a sting smell reaction 1
mL HCl 2N
- Time needed :
- Turn On the stopwatch when Mg start to add
- Shaked it once to keep the Mg moved 2N
- Turn Off the stopwatch when when Mg t1 = 09.06 s
completely dissolve
t1 = 09.30 s
- Write the time needed
- Repeat those for 2 times (2x) trata-rata = 09.18 s
- Repeat those step above by using different 1,8 N
concentration of HCl (1.8N; 1.6N; 1.4N;
1.2N; 1.0N; 0.8N; and 0.6N) t1 = 11.13 s
Time of each concentration of the t1 = 11.50 s
trata-rata = 11.315 s
1,6 N
t1 = 20.52 s
t1 = 21.41 s
trata-rata = 20.965 s
 1,4 N
t1 = 30.62 s
t1 = 31.57 s
trata-rata = 31.095 s
1,2 N
t1 = 33.50 s
t1 = 42.34 s
trata-rata = 37.92 s
1,0 N
t1 = 44.13 s
t1 = 48.46 s
trata-rata = 46.295 s
0,8 N
t1 = 82.57 s
t1 =83.23 s
trata-rata = 82.9 s
0,6 N
t1 = 05.00.37
t1 = 05.06.94
trata-rata = 300.03 s
 ATTACHMENT

Non Graphic Method

1. The reaction of Na2S2O3 with H2SO4 solution
3 Na2S2O3 (aq) + H2SO4 (aq) 3 Na2SO4 + 4 S (s) + H2O (l)
Table 1
Determine the concentration of Na2S2O3
- Beaker A
M1 V1 = M2 V2
0,1 . 10 = M2 . 10
M2 = 0,1 M
- Beaker B
M1 V1 = M2 V2
0,1 . 7,5 = M2 . 10
M2 = 0075 M
- Beaker A
M1 V1 = M2 V2
0,1 . 5 = M2 . 5
M2 = 0,05 M
Determine the reaction rate
[2 4 ] [2 2 3 ]
=

0.50.1
=
100

0.4
= 100 = 0,004
0.50.075
= 141

0.425
= = 0,003014
141
 0.50.05
= 180

0.4
= 180 = 0,0025

Determine the reaction order

[2 4 ] [2 2 3 ]
=
[2 4 ] [2 2 3 ]

0,004 (0,5) (0,1)

=
0,003014 (0,5) (0,075)

1,327 = (1,33)
log 1,327
=
log 1,33
= 0,99 = 1

So, the reaction order of H2SO4 = 1

Table 2
Determine the concentration of H2SO4
- Beaker A
M1 V1 = M2 V2
0,5 . 10 = M2 . 10
M2 = 0,1 M
- Beaker B
M1 V1 = M2 V2
0,1 . 7,5 = M2 . 10
M2 = 0075 M
- Beaker A
M1 V1 = M2 V2
0,1 . 5 = M2 . 5
M2 = 0,05 M
 Determine the reaction rate
[2 4 ] [2 2 3 ]
=

0.50.1
= 100

0.4
= = 0,00325
123
0.3750.1
= 154

0.425
= = 0,003014
154

0.2500.1
= 181

0.15
= = 0,000828
181

Determine the reaction order

[2 4 ] [2 2 3 ]
=
[2 4 ] [2 2 3 ]

0,003 (0,5) (0,1)

=
0,002 (0,375) (0,1)

1,5 = (1,33)
log 1,5
=
log 1,33
= 1,42 = 1

So, the reaction order of Na2S2O3 = 1

 Graphic Method
Table 1

Volume Volume (mL)

Time
(mL) Na2S2O3 Total Turbidity
Aquades (second)
H2SO4 0,1M volume
5 10 - 10 100 +++
5 7,5 2,5 10 141 ++
5 5 5 10 180 +

Table 2

Volume (mL)
Volume
Time
(mL) H2SO4 Total Turbidity
Aquades (second)
Na2S2O3 volume
0,5 M
5 10 - 10 123 +++
5 7,5 2,5 10 154 ++
5 5 5 10 181 +

Table 3

mol
log log mol mol
[Na2S2O3] [H2SO4] endapan MS r log r
[Na2S2O3] [H2SO4] [Na2S2O3] H2SO4]]
S
-
0.1 0.5 -1.0000 -0.3010 0.001 0.0025 0.0012 0.08 0.0008 3.09691
-
0.075 0.5 -1.1249 -0.3010 0.00075 0.0025 0.001 0.066666667 0.000472813 3.32531
-
0.05 0.5 -1.3010 -0.3010 0.0005 0.0025 0.0008 0.053333333 0.000296296 3.52827
-
0.1 0.5 -1.0000 -0.3010 0.0005 0.005 0.0012 0.08 0.000650407 3.18682
-
0.1 0.375 -1.0000 -0.4260 0.0005 0.00375 0.0012 0.08 0.000519481 3.28443
-
0.1 0.25 -1.0000 -0.6021 0.0005 0.0025 0.0012 0.08 0.000441989 3.35459
 Graphic of Log [H2SO4] vs Log r

Graphic of Log [H2SO4] vs Log r

-3.16
-0.7000 -0.6000 -0.5000 -0.4000 -0.3000 -0.2000 -0.1000 0.0000
-3.18
-3.2
-3.22
y = 0.5469x - 3.033
-3.24
R = 0.9636
Log r

-3.26
-3.28
-3.3
-3.32
-3.34
-3.36
-3.38
Log [H2SO4]

Graphic of Log [Na2S2O3] vs Log r

Graphic of Log [Na2S2O3] vs Log r

-3.05
-1.4000 -1.2000 -1.0000 -0.8000 -0.6000 -0.4000 -0.2000 0.0000
-3.1
-3.15
-3.2
-3.25
-3.3
Log r

-3.35
y = 1.4146x - 1.7014
R = 0.9827 -3.4
-3.45
-3.5
-3.55
-3.6
Log [Na2S2O3]

Reaction order = 0.5469 + 1.4146

= 1.9615
=2