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Safety Data Sheet

according to Regulation (EU) No. 1907/2006

FINO Die hardener premium


Print date : 02.06.2008 19913 / 19914 Page 1 of 7

1. Identification of the substance/preparation and of the company/undertaking

Identification of the substance or preparation


FINO Die hardener premium
Article number 19913 / 19914
Further product name
ETHYL ACETATE
TOLUENE
Company/undertaking identification
Company name : FINO GmbH
Street : Mangelsfeld 18
Place : D-97708 Bad Bocklet
Telephone : +49-97 08-90 94 20 Telefax : +49-97 08-90 94 21
Contact person : Alexander Wahler Telephone : +49 9708 909 420
e-mail : info@fino.de
Internet : www.fino.com

2. Hazards identification

Classification
Indications of danger : Highly flammable, Harmful
R-phrases :
Highly flammable.
Harmful by inhalation.
Explication of special hazards for human health and environment
Harmful by inhalation.

3. Composition/information on ingredients

Chemical characterization ( substance )


Preparation from the below listed substances with harmless additives.

Hazardous components
EC-No. CAS-No. Chemical name Quantity Classification

205-500-4 141-78-6 ethyl acetate 20-80 % F, Xi R11-36-66-67


203-625-9 108-88-3 toluene 15-40 % F, Repr. Cat. 3, Xn, Xi
R11-63-48/20-65-38-67

Full text of each relevant R phrase can be found in heading 16.


Index No. : 607-022-00-5
Further Information
None

4. First aid measures

General information
No specific information.
After inhalation
Provide fresh air.
Immediately get medical attention.

GB - EN Revision date : 18.04.2008


Safety Data Sheet

according to Regulation (EU) No. 1907/2006

FINO Die hardener premium


Print date : 02.06.2008 19913 / 19914 Page 2 of 7

After contact with skin


After contact with skin, wash immediately with plenty of Water and soap.
Change contaminated clothing.
After contact with eyes
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
After ingestion
Have victim drink large quantities of water, with active charcoal if possible.
Do not induce vomiting.
Consult physician.
Advice to doctor
No specific information.

5. Fire-fighting measures

Suitable extinguishing media


Foam. Water spray. Carbon dioxide. Dry extinguishing powder.
Extinguishing media which must not be used for safety reasons
High power water jet.
Special exposure hazards arising from substance or preparation itself, combustion products, resulting
gases
In case of fire and/or explosion do not breathe fumes.
Do not breathe vapour.
Special protective equipment for fire-fighters
Not known.
Additional information
None

6. Accidental release measures

Personal precautions
Provide adequate ventilation.
The following must be prevented: inhalation.
Environmental precautions
Do not empty into drains or the aquatic environment.
Methods for cleaning up/taking up
Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents).
Collect in closed containers for disposal.
Additional information
None

7. Handling and storage

Handling
Advice on safe handling
If suction of the immediate vicinity is impossible or insufficient, adequate airing of the working place
must be ensured.
Advice on protection against fire and explosion
Keep away from sources of ignition.
Take precautionary measures against static discharges.
Further information on handling

GB - EN Revision date : 18.04.2008


Safety Data Sheet

according to Regulation (EU) No. 1907/2006

FINO Die hardener premium


Print date : 02.06.2008 19913 / 19914 Page 3 of 7

Vapours are heavier than air and will spread at floor level.
Product can form vapour/gas mixtures that are able to explode.
Storage
Requirements for storage rooms and vessels
Store only in original container.
Keep container tightly closed in a cool, well-ventilated place.
Advice on storage compatibility
Keep away from food, drink and animal feeding stuffs.
Further information on storage conditions
No special precautionary measures.

8. Exposure controls/personal protection

Exposure limit values

Exposure limits (EH40)


CAS-No. Chemical name ml/m mg/m F/ml Category Origin

141-78-6 Ethyl acetate 200 - TWA (8 h) WEL


400 - STEL (15 min) WEL
108-88-3 Toluene 50 191 TWA (8 h) WEL
150 574 STEL (15 min) WEL

Exposure controls

Occupational exposure controls


See chapter 7. No further action is necessary.
Protective and hygiene measures
The usual precautionary measures are to be adhered to when handling chemicals.
Keep away from food, drink and animal feeding stuffs.
"Wash hands when done working with material; at breaks, lunch, shift changes, etc."
When using do not eat, drink or smoke.
Take off immediately all contaminated clothing
Protect skin by using skin protective cream.
Respiratory protection
Do not breathe vapour.
If suction of the immediate vicinity is impossible or insufficient, adequate airing of the working place
must be ensured.
"Filter types: A, B, E, K. Class 1: Maximum permitted concentration of pollutant in breathing air = 1000
ml/m (0,1 Vol.-%); class 2 = 5000 ml/m (0,1 Vol.-%); class 3 = 10000 ml/m (0,1 Vol.-%);"
Hand protection
Wear suitable protective gloves.
Eye protection
Tightly sealed safety glasses.
Skin protection
Lab apron.

GB - EN Revision date : 18.04.2008


Safety Data Sheet

according to Regulation (EU) No. 1907/2006

FINO Die hardener premium


Print date : 02.06.2008 19913 / 19914 Page 4 of 7

9. Physical and chemical properties

General information
Physical state : liquid
Colour : transparent
Odour : characteristic
Important health, safety and environmental information
Test method
pH-Value : not applicable
Changes in the physical state
Melting point : not applicable
Boiling point : 77,1 C
Flash point : - 83 C
Flammability
Solid : not determined
Explosive properties
not determined
Lower explosion limits : 2,1 vol. %
Upper explosion limits : 11,5 vol. %
Vapour pressure : 50 hPa
(at 20 C)
Density (at 20 C) : 0,93 g/cm
Water solubility : partially soluble
Viscosity / dynamic : viscous
Other information
Auto-ignition temperature
Solid : 434
Ignition temperature : 430 C

10. Stability and reactivity

Conditions to avoid
No specific if used according to specifications.
Materials to avoid
Not known.
Hazardous decomposition products
None if used according to specifications.
Additional information
None

11. Toxicological information

Acute toxicity
Toxicological analyses are not available.
Corrosive and irritant effects
After skin contact: Prolonged/repetitive skin contact may cause skin defattening or dermatitis.
Irritant effect on the eye: irritant.
Following inhalation: In high concentrations, irritations of mucous membranes and narcotic effects.
After ingestion: Nausea. Caution if victim vomits: Risk of aspiration!

GB - EN Revision date : 18.04.2008


Safety Data Sheet

according to Regulation (EU) No. 1907/2006

FINO Die hardener premium


Print date : 02.06.2008 19913 / 19914 Page 5 of 7

Sensitising effects
No sensitizing effect known.
Severe effects after repeated or prolonged exposure
Up to now, damaging effects to humans are not known when handling that product.
Additional information on tests
No further data.
Empirical data on effects on humans
No special references.

12. Ecological information

Ecotoxicity
Do not empty into drains or the aquatic environment.
Effects on fishes cannot be excluded.
Mobility
No information available.
Persistence and degradability
No classification known.
Bioaccumulative potential
Respective data are not available.
Other adverse effects
No further data.
Further information
None

13. Disposal considerations

Advice on disposal
Remove according to the regulations.
Hand over to officially registered waste disposal company.
Contaminated packaging
Waste disposal according to official state regulations.

14. Transport information

Land transport (ADR/RID)


UN number : 1173
ADR/RID class : 3
Classification code : F1
Warning plate
Hazard-no. : 33
Hazard label : 3
ADR/RID packing group : II
Limited quantity : LQ4
Description of the goods
ETHYL ACETATE
Remarks (land transport)
Transport Category: 2
Tunnel Restriction Code: D1E
Inland waterways transport
UN number : 1173
GB - EN Revision date : 18.04.2008
Safety Data Sheet

according to Regulation (EU) No. 1907/2006

FINO Die hardener premium


Print date : 02.06.2008 19913 / 19914 Page 6 of 7

ADNR class : 3
Classification code : F1
Hazard label : 3
Packing group : II
Limited quantity : LQ4
Description of the goods
ETHYL ACETATE
Marine transport
UN number : 1173
IMDG code : 3
Hazard label : 3
IMDG packing group : II
EmS : F-E, S-D
Limited quantity : 1L
Description of the goods
ETHYL ACETATE
Remarks (marine transport)
Special regulations: -
Air transport
UN/ID number : 1173
ICAO/IATA-DGR : 3
Hazard label : 3
ICAO packing group : II
Limited quantity Passenger : 1L
IATA-packing instructions - Passenger : 305
IATA-max. quantity - Passenger : 5L
IATA-packing instructions - Cargo : 307
IATA-max. quantity - Cargo : 60 L
Description of the goods
ETHYL ACETATE
Remarks (air transport)
Passenger-LQ: Y305

15. Regulatory information

Labelling
Danger symbols :

F - Highly flammable Xn - Harmful


Hazardous component(s) to be indicated on label
ethyl acetate
toluene
R phrases
11 Highly flammable.
20 Harmful by inhalation.
Additional advice on labelling

GB - EN Revision date : 18.04.2008


Safety Data Sheet

according to Regulation (EU) No. 1907/2006

FINO Die hardener premium


Print date : 02.06.2008 19913 / 19914 Page 7 of 7

Product is classified and labelled according to EC regulations or according to the corresponding


national laws.
EU regulatory information
Additional information
No further data.
National regulatory information
Water contaminating class : 2 - water contaminating

16. Other information

Full text of R-phrases referred to under sections 2 and 3


11 Highly flammable.
20 Harmful by inhalation.
36 Irritating to eyes.
38 Irritating to skin.
48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation.
63 Possible risk of harm to the unborn child.
65 Harmful: may cause lung damage if swallowed.
66 Repeated exposure may cause skin dryness or cracking.
67 Vapours may cause drowsiness and dizziness.
Further Information
The information is based on present level of our knowledge. It does not, however, give assurances of
product properties and establishes no contract legal rights.

GB - EN Revision date : 18.04.2008