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Roll No, Candidates must write the Code on tat the title page of the answer-book. want as o aryfa & FETS wR sraee fered | XU- 1 Series OSS Gone Net 56/3 Please check that this question paper contains 12 printed pages. Code number given on the right hand side of the question paper should be written on the title page of the answer-book by the candidate. Please check that this question paper contains 80° questions. Please write down the Serial Number of the question before attempting it. 15 minutes time has been allotted to read this question paper. The question “paper will be distributed at 10.15 am. From 10.15 a.m. to 10.30 a.m,, the student will read the question paper only and will not write any answer on the answer script during this period. gra ota at ot fe sa we A aha ye ee 1 Seer Foie ae at ok fee me ais eR a on oR & yee oH fre | pur sia a a fe ee ee F390 we BU we aT aR fret YR STS wee, we aT mate saya fe | we omer at wet & foe 16 Bre ar waa fern tea ar fan ig 7 10.15 48 fear SPT | 10.15 WS 10.30. we oe daa HE a WA ot we orf S chr 2 omgica wae am wet fara CHEMISTRY (Theory) Tae faa ctgirs) Time allowed : 3 hours Da CT Maximum Marks : 70 Crt Prater wre : 3 90d LN Ly afer 3i5 : 70 56/3 P.T.O. General Instructions : Ute (i) All questions are compulsory. ols (ii) Marks for each question are indicated against it. (iii) Questions number 1 to 8 are very short-answer questions and carry 1 mark each. (iv) Questions number 9 to 18 are short-answer questions and carry 2 marks each. (v). Questions number 19 to 27 are also short-answer questions and carry 3 marks each. (vi) Questions number 28 to 30 are long-answer questions and carry 5 marks each. (vii) Use Log Tables, if necessary. Use of calculators is not allowed. arr FSET : @ > wei wer otra F 1 (i) ee wer & ae? ates eae eb (iii) were 18 8 om arf cy sade wet BI ache Ter & fee 1 aie 2 1 (iv) TEAM 9 G18 TH asa were | we TH fie 2 aie 1 (o) were 19 3.27 aH of ay-sate 9eT E 1 ade IETS ae 3 sie F 1 (vi) Ter-dom 28 & 30.c-sada sea & 1 neds wer & fore 6 ais & 1 (vii) Sen Wen Se AT BE | aepeed % svalt at arpa wet t ’ 1. Write a distinguishing feature of metallic’ solids. 1 orcia ata at wear & fee um cam fefae 1 2. Fluorine does not exhibit any positive oxidation state. Why ? 1 gaa AY sere sister orrer efit agi att 1 del? 8. _ Differentiate between molarity and molality of a solution. 1 fae a ate Sik Fiera HF siee we AT | 56/3 2 4. Write the structure of the molecule of a compound whose IUPAC name is 1-phenylpropan-2-ol 1 fret afin at omy. icra fear freer anézsi.cat. (TUPAC) waft sigan a wae . 1 bhrenitta- 2-3 5. What is Tollen’s réagent ? Write one usefulness of this reagent. 1 Het (Tollen) sities eat eat ¢ 7 ee safiemie a us sect fee 1 6.' Give the IUPAC name of the following compound : 1 HC\ CH i” ZN pr CH, ery fra aif at ong qiea. (TUPAC) walt agen am afm : Rey ee lol lg BON 7 ww SO . ON cH, 7) What does the designation ‘6, 6’ mean in the name nylon:6,6 ? 1 agctia-6, 6 # 6,6 an tha aun 2? 8. What are the products of hydrolysis of sucrose ? 1 We & ae-somed } sere wT E 7 9. Given that the standard electrode potentials (E*) of metals are : K*/K =~ 293 V, Agt/Ag = 0:80.V, Cu /Cu = 0:34 V, Mg” /Mg = - 2:37 V, Cr*/Cr =- 0-74 V, Fe /Fe = - 0-44 V. Arrange these metals in an increasing order of their reducing power. 2 OR 66/3 3 P.T.O. Two half-reactions of an electrochemical cell are given below : MnO; (aq) + 8 Ht {aqg)+5e > Mn?* (aq) +4 H,O , Eo=+151V Sn°* (aq) > Sn“* (aq) +20, EB = + 0-15 V, Construct the redox reaction equation from the two half-reactions and calculate the cell potential from the standard potentials and predict if the reaction is reactant or product favoured. ¥e agi & one weds frm (BY) Re ee: K*/K =-293V, Agt/Ag =0-80-V, Cu2*/ Cu = 0-34 V, Mg” /Mg =-237V, Cr*/Cr =-0-74V, Fe’ /¥e = - 0-44 V, OB apt & eS agi soard wrel } ar Fer ate she +10. il. 56/3 aaa we fgets tet at St antoifefeand AY at age: MnO; (aq) + 8 H* (aq) + 56° > Mn” (aq) +4 HO), EP =4151V Sn” (aq) > Sn** (aq) + 2, EP = +045 V, a ¢ etafitersit 3 stan tise (orebvaa) after ar miter fefae sit ars fivdl 2 de fora vieefere aafie sik srs afte fe aia safes at oer sere saga et Express the relation among the cell constant, the resistance of the solution in ‘the cell and the conductivity of the solution. How is the conductivity ofa solution related to its molar conductivity ? ta feris, fa 8 fare a wfae sik fare at aera & de ot de der @, 38 ae aie | fee wan fae at aes seat cee are a wafer Bat 2 ? Define the terms, ‘osmosis’ and ‘osmotic pressure’. What is the advantage of using osmotic pressure as compared to other colligative properties for the determination of molar’ masses of solutes in solutions ? ‘error ak Rime aa wet at oferta are | ser awpher eat at GT A camot ga & sadn at frees Pada vet & stat gonna gt wo fae wr a aa e 2 Rr 4 metic) Lat 12. Complete the following chemical reaction equations : zB @ = 1,+ HNO, > (cone.) Gi) HgCly + PH; > frafetad warts attic etter at ye aif : @) 1, + HNO, > FR) (ii) HgCly + PH; > 13. What is meant by coagulation of a colloidal solution ? Name any method by which coagulation of lyophobic sols can be carried out. 2 wicigch frat % weet Saar THE TT 2? feet cw fat ara aaee fae wa-fatet sit a cheat fea a aac BI 14, Describe the following : 2 (i) Tyndall effect (ii) Shape-selective catalysis frafetad a avi afar: @ fea wea G) aaght-aune sek 15. Identify A and B in each of the following processes : 2 . NaCN _ .. reduction @) CH ,CH,Cl ———>A N/E, B i NaNO,/HCL © C,H;NH, a A (i) C,H,NH, oo frafefan sete set 7 A ak Bat ugar aif : Ny : @ cacao: “SX, Soe we Ce Ce relia) NaN NH, Gi) C,H,NH, NaNO, /HOI, A aa B eg 56/3 5 P.T.O. 16. Draw the structural formulae of the following compounds : @) -HyP,05 Gi) XeF, frefafed afte oat a ae : @ HyP,0; Gi) XeFy 17. Give the chemical tests to. distinguish between the following pairs of compounds : (i) Ethylamine and Aniline (ii) Aniline and Benzylamine frfafad afer a sie aS fae warts ster fafa : @) frei atk faci F Gi) freia ott Otaretie F 18. Draw the molecular structures of the monomers of @ Pvc Gi) Teflon 10Y Fe wad @ ates deat aed gi: Emer ts . Paper @ PVC Gi) tai 19. Silver crystallises in fcc lattice. If the edge length of the unit cell is 407 x 10° em and the density of the erystal is 105 g em’, calculate the atomic mass of silver.(Ny = 6-02 x 10” atoms mol) fren wee-Bfaa why (foc) are HF Greta aa 21 ae ah ws ta S aN a wae 4.07 x 10% om a ak fea HAT 105 gem a, Tt fae a AM] mera ofeafers STE | (Ny = 6-02 x 10% aA fe Te) 56/3 6 20. 15 g of an unknown molecular substance was dissolved in 450 g of water. The resulting solution freezes at - 0-34°C. What is the molar mass of the substance ? (K, for water = 186 K kg mol) 3 Fe 450 gH we sere ones vend st 15 g ar a ster eT 2 1 ora fee - 034° CR fetes der 21 sa ved a atee xem aT am? (K, 5a % faq = 1-86 K kg mol) 21. Describe the role of the following : 3 G) NaCN in the extraction of silver from a silver ore Gi) Todine in the refining of titanium Gii) Cryolite in the metallurgy of aluminium OR Describe the principle involved in each of the following processes of metallurgy : 3 (i) Froth floatation method Gi) Electrolytic refining of metals (iii) Zone refining of metals frafetad a after ar aot afi : RCT G) > Fre ores 2 feat & frenit F NaCN at brite Gi) aFrm afer H ani A Ps (ii) Caffe & eget a arte at aaa arget & Prafefaa acts yam 4 afater fred ar ahr site = @ 8 war fafa i) age a aga-atogedt oper Gi) orgsit a SA oReROT 22. How would you account for the following : : 3 (@ The electron gain enthalpy with negative sign is less for oxygen than that for sulphur, (ii) Phosphorus shows greater tendency for catenation than nitrogen. (iii)) Fluorine never. acts as- the central. atom in polyatomic interhalogen compounds. 56/3 é 7 P.T.O. 23, 25. 26. 56/3 frrafefiad a ar aied wee : @ Peete ate pre hr pet er se A 1 Gi) ARERR St ater Geter Jace at yeh ates exfer F Gi) TETAS since Afi A VI wh A Seta vey at yf F ad aa 21 How would you convert the following: : (i) Phenol to benzoquinone (i) Propanone to 2-methylpropan-2-0l (iii) Propene to propan-2-ol 10 Years Forfeited a wale 3 att: bred @ Oia a asters F Gi) SRR ar 2-Afrenth-2-sie Gi) TH a T-2218 7 Elel—g How would you differentiate between Syl and Sy2 mechanisms. of substitution reactions ? Give one example of each. Siren afiiai Bt Sy1 ak Sy2 traf’ & te om Sa sie at 2 FAS Ta EH SaeTT Gf | Write the name, the state of hybridization, the shape and the magnetic behaviour of the following complexes : [CoGl,P, [Ni(CN),F*, [Cr(H,0),(C,0,),1" (At. No. : Co = 27, Ni = 28, Or = 24) Frafefad sixcaat & am, dau aaen, angfi sik quate aaen fafa - [CoCl,*, [N(CN)P*, [Cr(H,0),(C,0,).1” (Wem wis : Co = 27, Ni = 28, Cr = 24) Differentiate between fibrous proteins and globular proteins. What is meant by the denaturation of a protein’? en si sik nen ada Aske ee ae 1 ide} fete (denaturation) % amy Faq wed F 7 "97... Explain the following terms with an example for each : 3 @. ' Antibiotics Gi) Antiseptics (iii) Analgesics a ley Frafetan eh at ee sere BY gE areT Are : “Tear @ relies sitar (Bfeartizes) Gi) feet werd (Rfeafere) Gi) tered sitwr (Heres) 28. (a) Complete the following chemical equations : @ — Cr,OF- (aq) + H,S (g) + H* (aq) > Gi) Cu”* (aq) + I (aq) > (b) - How would you account for the following : i) ‘The oxidising power of oxoanions are in the order VO} < C107" < Mn0j. (i) The third ionization enthalpy of manganese (Z = 25) is exceptionally. high. (ii) Cr’* is a stronger reducing agent than Fe™*, 5 OR (a) Complete the following chemical equations : @ — MnO; (aq) + 8,07" (aq) + H,0 @ > Gi) Cx,0? (aq) + Fe (aq) + H* (aq) > (b) Explain the following observations : (@) — La** @ = 57) and Lu* (Z = 71) do not show any colour in solutions. (ii) Among the divalent’ cations in the first series of transition elements, manganese exhibits. the = maximum paramagnetism. ii) Cut ion is not known in aqueous solutions. Bi 56/3 9 P.T.O. 56/3 (a) (b) (a) (b) fetafas veets wie a gr sfie : @ — Cy,0% (aq) + HS (g) + HY (aq) > eee! ate Cr Ty (i) Cu?* (aq) + I (aq) > frafefad st arr feraat ee afar : @ siedtzorrt at sietaor wat VO} < Cr,02"< MnO; % 7H Hates Gi) rts (2 = 25) a aaa are led sriaitiee ser ah 2 (ii) Cr sidega Fe & atte yar ara g 1 aaa frefaton carafe aire a a aie : @ — MnO; (aq) + 8,07" (ag) + H,0 @) > Gi) Cx,07" (aq) + Fe” (aq) + H* (aq) > frafafad. sachet at caren aifie : @ Lae (Z = 67) sR Lu® (2 = 71) ferro ae tr et fear Gi) wm dt S Gem ae 3 fede eri Farts waits aagaae elf aa 21 (ii) Sete freer Cut ar a after aa SAT ST | Explain the following terms : * (i) - Rate of a reaction Gi). Activation energy of a reaction The decomposition of phosphine, PH, proceeds according to the following equation : 4 PH, (g) > P, (g) + 6 H, () It is found that the reaction follows the following rate equation : Rate = k (PH, The half-life of PH, is 37-9 s at 120° C. (i) How much time is required for 3/4" of PH, to decompose ? Gi) | What fraction of the original sample of PH, remains behind after 1 minute ? OR, 10 30. 56/3 (a) (b) (a) (b) (a) (b) (a) (b) Carl Cra) Explain the following terms ; () Order of a reaction eos (ii) Molecularity of a reaction The rate of a reaction increases four times when the temperature changes from 300 K to 320 K. Calculate the energy of activation of the reaction, assuming that it does not change’ with temperature. (R = 8:314 JK mol) 5 Frafafad vet st ee aif : @ > afhfrear st ae: Gi) aime st afer Sat GiaiH, PH, 1 add ffefar weet & ayer dete: 4 PH, (g) > P, (g) + 6 Hy (@) ae Ta stat @ f& aafiteer Frafetad a aiaer 3 agan ad 2 : & =k(PH. 120°C % PH, a srf-ary 37-932 | @) PH; & 3/4 amt & srmfea oF & fem fact ara wT 2 i) 1 fire & wear PH, & ya stead ar Stee eT Be] oT ? aaa fre vel at we aif @ after at aife Gi) We after a stttarar WH 300 KS agar 320K a a Rw after at a aR Pt a ont 21 afifea at airat sat at oftrer aif, ag ane ge fe aA agen arr gwar wr offs wal de 21 (R= 8314 TK™ mol) Illustrate the following name reactions giving a chemical equation in each case : @ — Clemmensen reaction (ii) Cannizzaro’s reaction’ Describe how the following conversions can be brought: about : (i) Cyclohexanol to cyclohexan-1-one (ii) | Ethylbenzene to benzoic acid Gii) Bromobenzene to benzoic acid 5 OR 1 P.T.O. (a) (b) (ay (b) (a) (b) 56/3 Illustrate. the following name reactions : @® Hell -Volhard - Zelinsky reaction Gi). - Wolff Kishner reduction reaction How are the following conversions carried out : (i) . Ethyleyanide to ethanoic acid . Gi) Butan-1-ol to butanoic acid (iii) Methylbenzene to benzoic acid Write chemical equations for the involved reactions. fafatad am at sfiiensit st ree & tae carats wile tax feafag : i) setter aififipar (i) Sart a afhina ants aifae f frefefcd wainer $8. fae ara @ : @ ascites a aacitede-13ie G) eaetata a dats ore F Gi) ARASH a asigs are F awa frefetian amt at afiteareit at serecr 3 ar fafa ; @ ta- deed - Sire athe G) aee- fae STH after fra wai $8 fire oT aad g @) Uaerarrigs aT Weise ort F @ aea1aia w apts ara t Gi) Yartsia a asigs ara 7 aiater afttaasit % fae carats ote fefae 1 ate Ty ireeicny elo 9 12

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