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VOL. 79, NO.


Long-Term Variations of Thermospheric

Temperature and Composition
Centre d'Etude Spattale des Rayonnements
LaboratoireAssociau CentreNational de la RechercheScientifique,ToulouseCedex,France


Centre National d'Etudesde Tdlcommunications,

Issy les Moulineaux, France


Centre d'Etude Spattale des Rayonnements

LaboratoireAssociau CentreNational de la Recherche$cientifique,ToulouseCedex,France

Long-term variations of the thermosphericstructure in the altitude range 100 to 400 km

have been deducedfrom incoherentscatterobservations performedaboveSt Santin (France,
45N) in 1969-1970.This technique provides the following relevant information' the thermal
structure from 100 to 400 km; a parameter proportionalto the molecularnitrogen concentra-
tion around 100 km; a determination of the atomic oxygen concentrationbetween 200 and
400 km; and the ratio of the atomic oxygen concentrationto a weighted sum of the molecular
(N2, 02) speciesaround.200km. The last three parametersare determinedduring daytime.
Combining these data.,we find that (1) a seasonalchangein the compositionat 200 km
results from a seasonal change in the thermal structure between 100 and 200 km and from a
superimposedlower boundary equivalent to seasonalchangesin the atomic oxygen concen-
tration (winter to summerratio of 1.5) and in the molecular oxygen concentration(summer
to winter ratio of about 4); (2) these later variations are linked to the F2 winter anomaly
and support theoretical predictions and previous experimental work; (3) annual and semi-
annual variations of the thermal structure, combined with annual changes in the neutral
composition,result in a semiannual variation of the air density that is already well known
from satellite drag data.

In the past few years, improved observationsof ther- of the ratio of atomic to molecular ion concentrations at
mosphericand ionosphericproperties have made increas- 200 km [Waldteu[el, 1970a], of the molecularnitrogen con-
ingly clear the fact that simple static modelsbasedon fixed centration at 100 km [Waldteu[el, 1969], and of the ther-
lower boundary conditionsare not suited for an accurate mal structure between 100 and 200 km [Fo.ntanari, 1973];
description,of the upper atmosphere;the different diurnal all these data have been collected by incoherent scatter
behavior of the neutral temperature and densities[Bauer observationsat St Santin Nanqa.yin France.
et al., 1970; Swartz and Nisbet, 1971; Alcayd et al., 1971], In the first part of the paper, the methodsused for ob-
variations of the chemical composition in the F region taining the data are briefly discussed;the secondto fourth
[Waldteufel, 1970a; Cox and Evans, 1970], the winter parts describethe observedatmosphericparameter varia-
anomaly of the F2 layer IRishbeth and Setty, 1961], are tions; these observationsare gathered in the conclusion
someexamplesof the inconsistencies existingbetween'static section.
diffusivemodels'and the actual atmosphere.
in fact, many competingfactors,suchas photochemistry, I)ATA
eddy diffusion,tides, and nondiffusiveequilibrium of minor
constituents,are likely to producea departure from static Atomic oxygenco.ncentrationand temperature above 200
diffusive equilibrium. It appears, however, that all these kin. Solvingthe heat balanceequationfor the ions in the
processesare confined below about 200 km; above this F2 region and assumingdiffusiveequilibrium for oxygen
height diffusive equilibrium prevails, and the knowledge in this regionallowsfor a determinationof a set of three
of the thermal structure from 200 km upward, together parameters: the exospherictemperature, a temperature
with the neutral speciesvariations at 200 km, for exam- shapeparameter,and the oxygenconcentrationat an ar-
ple, is thereforesufficientto describethe upper atmosphere, bitrary altitudein the rangeconsidered
[Baueret al., 1970].
excludingthe hydrogen gas. Sincethe purposeof this paper is to identify variations
In view of this statement, the aim of this paper is to of the atmosphericconstituentsthat cannotbe simply in-
presentand discusslong-term variations of the atomic and ducedby thermalexpansion, the oxygendata, evaluatedat
molecular speciesreduced to 200 km altitude. The data 200 km, will be normalizedwith respectto an equivalent
consist of measurementsof the atomic oxygen concentra- Jacchia [1971a] model corresponding to the observed
tion and temperature above 200 km [Bauer et al., 1970], exospherictemperatures.
The main uncertaintyin this comparison
comesfrom the
Copyright @ 1974 by the American Geophysical Union. oxygendensitydetermination(obtainedwith an accuracy

of 15%) and from the exospherictemperature uncertainty Molecularnitrogenconcentration at 100 km. Dougherty
of about 2%. and Farley [1963] and Waldteu/el [19'69']have shownthat
Molecular concentratio,nat 200 kin. Up to 200 km the informationabout the molecularnitrogenconcentrationwas
incoherentscatter spectrum yields a determinationof the containedin the incoherentscatter signal at low altitude:
ratio p of the molecular ion concentrationto the electron the information is given by the narrowingof the scattered
concentration [Evans', 1967; Waldteu/el, 1970a]. In turn, spectrum due to the increasedcollisionrates letweenthe
by a proceduresimilar to the one usedby Evans and Cox ions and neutrals.
[1970], one can use this parameterto obtain the ratio. of The reason fo.r joining this information to the 200-km
the atomic oxygen concentrationto the weightedsum of observationis that, on the onehand,the molecularnitrogen
the molecularnitrogen and oxygenconcentrations. Indeed distribution remains unaffectedby chemistry,and, on the
the continuityequationfor the oxygenions can be written other hand, the molecular nitrogen being the major con-
as follows: stituent in the mixing region, no change in the vertical
distribution is to be expected between the mixing region
T-- o+
o = rr{O}- { }(T{02}
and the diffusive region. It is therefore sufficientto know
the actual thermal structure of the 100- to 200-km region
where {0}, {0+}, {02}, and {N2} denotethe concentrations so as to deduce the molecular nitrogen concentration at
of the different constituents,a is the production rate co- 200 km from the one at 100 km.
efficient, is the atmospheric attenuationof the solarradia- There is some uncertainty about the absolute calibration
tions,. is the solarflux, and y and y are recombination of the nitrogen concentration determined by incoherent
coefficients of 0 + with 0 and Na scatter.However,the relative variations (which are of prime
importancein this study) are determinedwithin an accuracy
o+ + o + + smaller than 10%.


Noting that. 1 -- p = {O+}/N, whereN, is the electron
concentration,and defining the molecular weighted sum Seasonal variations. Figure 1 shows the daytime ob-
{yg} by servationsof the oxygenconcentrationat 200 km obtained
at St Santin during the 1969-1970 period. The data have
{M2 = {02 +2N2 (2) been restrictedto solar zenith a.ngleX such that cosX >
oneobtainsthe {0} to {yM, ratio 0.1; large uncertaintiescorrespondingto sunriseand sunset
periodsare thus avoided.
{o} (1 - P)e Besidesthe scatter affectingeach individual day, a long-
term variation of the median valuesshowsup clearly, char-
At 2 , 1 -- p is not very far from 1, and the typical acterizedby a wide maximumin winter and a minimumin
uncertainty of the p parameter is 0.1, i.e., a 10% uncer- summer.In order to. separatethe thermal expansionef-
tainty in the determinationof 1 - p, and the error on N, fectsfrom thosewhichimply changes in the lowerboundary
is very small (lessthan 1'%); the typicaluncertaintyin the conditions,Figure 2 showsthe variation of the ratio R of
{yM, evaluationis thereforeof the order of 25% when the estimated {0}2ooto the similar quantity provided by
the previousway of determining{0} is usedand the other the Jacchia [1971a] model for the simultaneouslyobserved
parametersare assumedto be known. exospherictemperature.

1.75 -

1.50 -
[O] 200kin

1.25 -

1.0C -

?.5 --

50 --

25 --


1969 1970
Fig. 1. Atomicoxygennumberdensityobserved
at 200km for the 1969-1970
drawn between individual 'median points' for convenience.

- Median values
EXP. Least squar'e [it

[[O]jclxp 200 Km



2.0- I


. . .


. I t * ; , . . '.

I =

: i


I . 1
; . :
=. i
..5 i I t i I I I
.: , : .
' EQU, SOL. E. : SOL;' ' EQU /
I i i i I if' I ' I
1969 1970
Fi. 2. ame a Figure 1 bu for normalized oxygen number densW. The dashed
quare in erm of annual and emiannua]

The seasonaltrend has been sorted out by least square A correlation analysis was performed between the in-
fitting of annual, semiannual,and steady components: stantaneous10.7-cm solar flux and the normalized oxygen
concentration at 200 km. No significant correlation was
- 0./1 + 0.1 co [/(- 4)] found.
The correlationwith geomagneticactivity index Kp was
-]- 0.08 cos[4r/365(d -- 114)]]
found to be marginally significant with an optimal time
where d is the day number. It is remarkable that the ratio delay of 3 to 9 hours.The trend corresponds clearly to a
is closeto 1, on the average, and therefore no basic dis- decreasein the observed oxygen concentrationwith in-
agreementexistsbetween this determination of the oxygen creasingmagneticactivity; a decrease of about 20% is ob-
concentrationand the one proposedby the Jacchia [1971a] servedin Figure 3 for Kp varying between0 and 7, whereas
the Jacchia [1971a] model predicts,in the sameKp range,
The. semiannual and annual componentscorrespond to an increaseby about 20%.
maximumsaround the equino.xes, absoluteminimum at the Preliminaryconclusions.In the abovedescriptionof the
summer solstice, and a relative minimum at the winter oxygendata, two main featureshave been isolated: (1) a
seasonalvariation (if not an annual one), which would be
Comparisonsof these data with the theoretical model
developedby Mayr and Volland [1972a] show a qualitative
agreement for the annual component.However, the am- I I I I I I I I I I ! I I I ! I I I I I I' I IJACCHIA
I I (1971)
plitude of the annual componentis about three times larger
than the one of this work; as for the semiannualcom- Log
[0]200) (T(Kp=O):900
ponent, there is disagreementboth in phase and in ampli-

tude; indeed, the model gives a smaller amplitude at 45
(about 3 times smaller) and indicatesa minimum at equinox
which is the oppositeof the presentobservations.
The inference, then, is that fixed boundary conditions
at somelevel near the base of the thermosphere,a tem-
perature profile of the type proposedby the model in the
100- to 200-km region, and diffusiveequilibrium cannot ex-
plain the observedoxygen concentrationsand that equiva-
lent seasonalchangesin boundary conditionshave to be
Variation o/ geomagneticand solar origin. Figure 2 re-
60 QUA
veals a larger scatter than can be accountedfor by the sta-
tistical errors. The first source of the scattering is the
diurnal variability, describedin an earlier paper by Alcayd

0+-1 +- 2+-3+- 4 +-5+-6+-7+-8+ Kp

et al. [1972]; solar and geomagneticactivities are other Fig. 3. Variation of atomic oxygennumber density with Kp
possiblesourcesof variation. as comparedwith the predictionof the Jacchia[1971a]model.
632 A,c!q)i ET ,,.' TUEaMOSrSRXC
TsMrsR,?ws ,D CorosxTxo

consistentwith the circulationmechanismproposedby John- The observed variation, in qualitative agreement with
to.whichthe light gases earlier studies conductedby Cox and Evans [1970] an(]
sonandGottlieb[i970], according
(oxygen,helium) are carriedfrom the summerto the win- Waldteu[el [1970a, b], exhibits a maximum centered on
ter hemisphere;and (2) a variation of the concentration winter and a minimum in summer,with an annual varia-
with the Kp index, also compatiblewith the circulation tion given by
mechanismof Jhnson and Gottlieb [1970], which would
tend to reversewhen the auroral regionsare heated dur- logo(r) - 3.785 -]- 0.35 cos
this hypothesis
by Reddy [1972], and leading to a maximum to minimum ratio of 5.
by theinterpre,tation
of theog06 neutral
spectrom- As in the caseof the oxygenconcentrationalone,a large
eter data obtainedduringmagneticstorms[Mayr and Vol- scatter of the points is apparent in the hour to hour varia-
land, 1972b; Tach e,t al., 197!]. tion, which cannot be accountedfor by the statisticalerror.
These features will be further discussedwhen the ther- Although the seasonalariation is in phasewith the one
mal structureof the 100-20 km is investigatedbelow. observedon the atomic oxygen concentration,there is a
significant amplitude difference between the two.
Cor0so CAss A 200 In a simple way it has just been shownthat the F' win-
Use of (3) allowsfor a determination
of the ratio ter anomalywas the result of a larger changein the
),M) of the atomicoxygenconcentration to the weighted molecular than in the atomic oxygen concentrationat 200
sum of the molecular oxygen and nitrogen concentrations km. However,it shouldnot be forgottenthat, as Rishbeth
at 200 km. While (1 - p) and Ne are taken from the in- and Setty [1961] pointed out, in order to explain the F
coherentscatterdata, fi (the attenuationof the solarflux) winter anomaly, one should refer to observationat fixed
is obtained through a computerprogram developedby pressurelevels rather than at fixed heights.The next step
G. Lejeune(privatecommunication, 1972)by usingthe pro- in the present study is therefore to get more information
cedure establishedby Dalgarno et al. [1967]; this com- on the thermal structure of the lower F region and on the
of moleculardistribution,in order to separateapparent com-
mentioned earlier. q, is supposedto vary as the 10.7-cm positionchargesdue to thermal expansionfrom changes
flux, and a is kept constant.As opticaldepthsof O and linkedto physical
N are small, comparedto that of O, absorptiondue to
O and N has been computedusing the Jacchia [1971a]
model and the measured exospherictemperatures.
Figure4 showsthe variationof r (the ratio Nitrogen concentrationat 100 km. The analysisof col-
versus time for the years 1969-1970. lisionalspectra initiated by Waldteufel [1969] for 1967-

- -- Median values -
/. - Leas! squar'e fi ! _

,%' , : , * /
1 : . :. . : : '. _
* \\ * __
,:x . ' :
. :
,_. ''
. .' :,/! : --
.' x : -. : :. : -
. \ ' . . . N: . '
o . \' . . . : . . --
- . ! :./ : .: : :z. . _
' ' ' / x:': :i ' '
, , , , ** * , , ,
, ,



103 ! I I I I I ' ! I
1969 1970
Fig. 4. Variation of the {O}/{,M} ratio in 1969and 1970.The dashedline corresponds
to the leastsquaresfit
to an annual component.

-3 Isca

' ,T.,T._L-
'..... ---- 4 TTT
' iT,z'
T ,'T
I I I I I I i I I I I I I I I i I I i i
J F M A M J J A $ 0 N D J F M A M J J A $ 0 N
1969 1970 1971
Molecularnitrogennumberdensityobservedat 100 km for the 1969-1970period.

1968 Waspursuedduring 1969-1970 (Figure 5 showsthe very significantseasonalvariation is thus containedin the
results of such observations).A significantdiurnal varia- thermal structure.

tion, discussedearlier by Waldteuel [1969, 1970b], ap- The effects on the concentrations will therefore be two-
pearson the diagramasscattering of the data on individual fold: on the one hand, irrespectiveof the period consid-
days;the othersignificantfeatureis a slightseasonalvaria- ered, the higher experimentaltemperatures,in the 100-
tion characterizedby a weakmaximumin localwinter and to 200-km region,imply a slower decreaseof the concen-
a maximum to minimum ratio of the order of 1.3. This trations with respectto height; on the other hand, the
variation is consistent with the one observed previously seasonal changein the temperatureprofilebetween100 and
in 1967-1968by Waldteufel[1970b], althoughthe maxi- 200 km is to be reflected in a seasonalchange in the con-
mum of the 1969-1970 winter seemsparticularly weak. centrations,in additionto the one simply due to changes
This smallseasonal variahonis oppositethe oneneeded in the exospherictemperature.
to explainthe variationobservedfor the moleculars
at 200 Vertical distributiono/the atmo.spheric constituents. Fig-
km and in any caseis of a smalleramplitude.Therefore, ure 7 gives the altitude profilesof the differentconstituents
if the behaviorof the weightedsum of the molecularsat normalized to the Jacchia [1971a] model values; the
200 km reflects a similar variation for N2 at that height, molecular nitrogen concentration,in mixing or diffusive
onlyseasonal of the thermalstructurein the 100- equilibrium,has been deducedfrom the 100-km concen-
to 200-kmregionare able to bring a consistency in the tration and the thermal structure; the atomic oxygen con-
Thermal structure. The thermal structure in the 100- to
! [ I I I I
200-km regionappearsto be quite complexand must be Altitude
describedin terms of propagatingtides [Wand, 1969; km

Bernardand Spizzichino, 1971; Amayencand Reddy,1972; 340 --

Salahand Evans, 1972; Wad, 1972]. Fontanariand A1-

cayd [1974], usingthe data yieldedby the 5 parameter PERIQDS Ezospheric
analysisof the incoherent scatterspectrumin the F region 300 --
-- --' [Winter 1060K
(i.e., electronand ion temperatures,Ne, p, and one com- :Summer 1130 K

ponentof the ion drift), have analyzedthe ion tempera- I/ ....... Equinoxes 11,50 K

ture (equalto the neutraltemperature

in thisheightrange)
in terms of steady components and propagatingdiurnal 260 --
and semidiurnaloscillations;for the purposeof seasonal
changes,the resultspresente.d
here deal only with the
diurnallyaveragedtemperatureprofilesaccordingto the 220 --

threewinter,summer,and equinoxperiods.Figure6 shows

the differencebetweenthe averagedexperimentaltempera-
.obtaihed -
for identical exospherictemperatures.
If one looks at temperature gradients,one has to define
180 --

"x,. -
three different regions: from 100 to 140 km the tempera-
ture gradients
are greaterthanJacchia's;
from140to 220 140 --

km the model gradientsare greater than those observed;

and from 220 km to the exospherethe gradients are of the

same order of magnitude. 10C

Otherwiseit is noticeablethat, except for winter, which -60 -20 0 20 60 100 AT(K)

yields a lower exospherictemperature,the global features Fig. 6. Observedtemperaturedeviation from the Jacchia
are mostly differentby the shapeof the profile rather than [1971a] model versus height, with identical exospheric tem-
by changes in the exosphericor turbopausetemperatures. A peratures.
634 ALcA ,T .' T,RMOSrH,RICT,Mr,R^TU, ^D Corosmo

I ! rl I I I '1 I I I I I I I I I I perature variations and that it is mostly due to combined

changesin temperature profile in the 100- to 200-km alti-
(KM) I
tude range and in lower boundary atomic oxygen concen-

Synthesiso/ the observedvariations'at 200 kin. Figure
9 showsthe resultingvariation of {N at 200 km from
300 L- both the observed concentration at 100 km and the tem-
perature profile.
260 - This variation is of the type neededto explainthe
yM seasonaltrend. However, adding the variationsof
{O} and {N (includingthe thermal expansioneffect)
? 'N2.O2102 .0J@
N2 is not enoughto.reproduce the observed{O}./{yM} varia-
1BI - ; .......
tion. Of the 5 to 1 changefrom winter to summer,about
140 -
ji / .." 3 parts are still to be explained.
Changesin {O havethereforeto be identifiedin order
, ,/,,, .:i'i',..,
..... , , ,, ,....
,,,, I , I/'r....I....I,,
to get a consistent picture.Larger {O concentrations in
.6 .lB1. 1.5 2. 3.'./ .6 .8 1. 1.5 2. 3 .4 .6 .8 1. 1.5 2.

TO JACCHIAVALUES summer than in winter are needed; such a trend agrees
with the conclusionsof recent works conductedby Roble
Fig. 7. Ratios of the observednumber and mass densities
to the ones of Jacchia [1971a] models for various exospheric and Norton [1972], Noxon and Johaason [1972], and
temperaturescorrespondingto three typical seasons(T _-- Scialo.m [ 19'73].
1130K in summer' T -- 1060K in winter' T -- 1150K at The amplitudeof the effectcan be estimatedafter the
equinoxes).Solid lines are for ma.ssdensities,dashedlines for followingremarks: in a recent work dealingwith the
{N, for {O, and dotted lines for {O. molecular ions in the F layer Rishbeth et al. [1972] con-
cludedthat a balancebetweenproductionand lossof O ions
centrations,in diffusiveequilibrium,take into. accountthe could be reachedon the basis of a February 1969 rocket
seasonalvariations at 200 km; the {O} behavior will be flightand of the Jacchia[1971a]model.In that casethe
discussedin the next section. The Jacchia [1971] model charge exchangeprocessbetweenO*, O,andN wasequally
has been taken with the relevant exospherictemperature sharedby the twomolecular constituents.
determinedby incoherentscatter (such a procedureis justi- balance could be reached for other rocket flights coveting
fied by the fact that on the averagea good agreementof the springandsummerperiods;in all casesthe production
the model and experimental exospheric temperatures is of O throughchargeexchange
betweenO* and O was a
observed[Alcayd et al., 1972]). factor of 2 to 10 smallerthan the loss.An increaseof
The {N) profiles which are characterizedby essen- in summerwouldhave improvedthe balancein theselater
tially constantlower boundary values exhibit clearly the cases.

effect of the temperatureprofile changes,i.e., a slowerde- On the grounds of the February1969rocketdata,we

creaseof the concentrationwith respectto height than the can deducethat {7M,} is equallysharedbetween7{0,}
one of the model and larger seasonalvariationsthan those and7{N}at thattime.Asa consequence, takingthemodel
resulting from changesin the exospherictemperature. valuefor {0} at 200km for the Februaryperiod(0.25 X
The {O) profilesshowthat an equivalentchangein lower 10 cm-), it is possibleto estimatethe seasonal
boundary values with larger values in winter than in sum- in {O} needed to account for the observed
mer (ratio of 1.5 at 100 km) is needed in order to more {O}/{7M}. The resultsare the ratiosof the proposed
than compensateat 200 km for the seasonalvariation ex- {O} to the modelvalueat 200km and 100km, assuming
pected on the basis of the changingtemperature profile. diffusiveequilibriumand makinguseof the observed tem-
The last feature to be consideredis the total massdensity peratureprofilesat 100 km.
p. It is in generalin better agreementwith the model as
shown in Figure 7. This is an important point, since the Summer: 200 km, 2.5; 100 km, 1.3.
Jacchia [1971a] model relies essentially upon mass den- Winter: 200 km, 0.40; 100 km, 0.30.
sity data. The well-definedsemiannualeffect presentabove Equinox: 200 km, 1.4; 100 km, 0.90.
150 km cannot be simply taken into accountby the semi-
annual exospherictemperature variations. It must be understood that such equivalent boundary
Figure 8 showsthe observedequinoxto solstices(winter changes wouldcorrespond to real changesonlyif diffusive
and summer) massdensity ratios versusaltitude. For com- equilibriumprevailedoverthe altituderangeconsidered.
parison similar quantities obtained through the use of a While these changesin {O} might imply real lower
static diffusive model for the observed solstice and equinox boundarychanges, it is worth mentioninga suggestionre-
exospherictemperatures have also been plotted. centlymade by U. Von Zahn (privatecommunication,1973),
The main feature is that the observed quantities show according to whichlocalchanges near200 km in the O
a trend for a semiannualvariation,sincethe two correspond- concentrationsmight simply be linked to the dissociative
ing equinoxto winter and equinoxto summer ratios tend recombination which representsan important loss process
to have the samemagnitudeover the whole altitude range. for O at this height. Indeed
The model values, which only reflect changes in the
exospherictemperatures,do not exhibit the same trend. 0 + + 0-->0 + + 0
This impliesthat the observedsemiannualvariation is far
from being simply carried by semiannualexospherictem- 02 + --I--e'->O-I'- 0





4,00 +


+ '&

+ A


Corresp. exospheric Corr. Jacchia
model Periods Temp.
+ ' Equi./Summe
AT.. :20 K '1'
- Equi./Winler AT..---90 K A ,.,


1.1 1.2 1.3 1.4 1.5 R
Fig. 8. Equinoxto solstice massdensityratioRmasa functionof altitude.Rmis drawnin continuousdottedlines
for the total observed
for the equinoxto summerandequinoxto winterratios.Symbolsshow
the altitudedependence of R computedby usinga staticdiffusivemodelwith temperaturevariationsof 20K (plus
signscorrespond to an equinoxto summervariation) and of 90K (trianglescorrespond to an equinoxto winter

Replenishingthe Os thus lost necessitatesvertical 0s fluxes actual variationsof {02} at 100 km. In turn, this wouldnot'
correspondingto vertical velocity of the order of 10 cm changesensitivelythe conclusions aboutthe role playedby
sec- at 200 km. O2in the winter anomaly.
Therefore the winter F regionanomaly can be explained Temperatureprofile. The temperatureprofilesdiffer in
by equivalentlower boundarychangesin {0} and {0s} two ways from the one of the model; first, on the average,
between winter and summer of, respectively,3/2 and 1 ,/4
or, more precisely,by suchchangesat constantNs pressure N2]
level in the neighborhoodof 200 km. 109cm-3
If the seasonalchangesof Os} reflect actual boundary 7.

changes at 100km, the conclusionsaboutthe Ns} variations

are slightly affected, since the contributionsof 0s in the
ion-neutral collisionfrequency around 100 km are of the
order of 30% in summerand only 5% in winter, thus en-
ha.ncingthe N2} winter to summer variation at 100 km
from 1.2 to 1.5.


Molecular nitrogen. A model based on an Ns number [] 00kn

density at 100 km fixed at the value given by the Jacchia
[1971a] model is in approximateagreementwith the data Ill] Illill III IllIll !] ill III1
describedhere. A weak annual effect is present, however, 1969 1970

with winter (January) N2 number densitiesabout 20% Fig. 9. Molecular nitrogen number density at 200 km as
higher than the equinoxesand the summer densities.As given by the observeddensitiesof Figure 5 and the observed
pointedout earlier, this annual effectmust be increasedto temperatureprofiles.The continuousline is the annual varia-
50% if the variations of {02} at 200 km correspondto tion averaged over 1969 and 1970.

they correspondto a smaller decreasein the concentrations

with respect to altitude than the one given by the model; The Editor thanks J. V. Evans and R. I-I. Wand for their
second,they show strong semiannualand seasonalvaria- assistancein evaluating this paper.
tions; this pattern suggeststhe existenceof other energy REFERENCES
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N number densities is that the model tends to underesti- variation of the atmosphericdensity at 400 kilometers, J.
Geophys. Res., 76, 7814, 1971.
mate the mean concentrationand the amplitude variation
Alcayd, D., P. Bauer, C. Jaeck, and J. L. Falin, Latitudinal
at the 200-km level.
diurnal variation of some atmospheric parameters deter-
Atomic oxygen. The atomic oxygen concentrationex- mined by a simultaneous analysis of incoherent scatter and
hibits a small winter to summer variation at 200 km with satellite drag data, J. Geophys.Res., 77, 2368, 1972.
winter maximum.In view of the observedthermal structure, Amayenc, P., and C. A. Reddy, Height structure of tidal
winds as inferred from incoherent scatter observations,
which tends to give an oppositeeffect, this implies larger Planet. Space Sci., 20, 1269, 1972.
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to overcompensatethe temperature effect. The observed atomic oxygen concentrationin the lower thermosphere,J.
variation of (0) at 200 km and of the temperatureprofile Geophys. Res., 76, 7797, 1971.
Bauer, P., P. Waldteufel, and D. Alcayd,, Diurnal variations
leads to an atomic oxygen winter to summer ratio of 1.5 of the atomic oxygen density and temperature determined
at 120 km. Such a variation is consistent both with earlier
from incoherent scatter measurementsin the ionosphericF
experimentalresults [Waldteuel, 1970b; Perret, 1971] and region, J. Geophys. Res., 75, 4825, 1970.
with theoretical works such as the circulation models of Bernard, R., and A. Spizzichino, Semidiurnal wind and tem-
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incoherent scatter experiment, J. Atmos. Terr. Phys., 33,
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experimental(0) concentrations agreeon the averagewith Cox,ratio
L. in
V. Evans,
J. Geophys.
75, 6271,
of the
the Jacchia [19'71a] model values.
Molecular oxygen. A large change in the molecular Dalgarno, A., M. B. McElroy, and J. C. G. Walker, The
diurnal variation of ionospherictemperatures, Planet. Space
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The (03) summerto winter ratio at 200 km is about 6. partly ionized gas, J. Geophys. Res., 68, 5473, 1963.
Evans, J. V., Electron temperature and ion composition in the
This ratio of 6 corresponds to a late winter value of (02)
F region, J. Geophys. Res., 72, 3343, 1967.
at 200 km in agreementwith the Jacchia [1971a] model. Evans, J. V., and L. P. Cox, Seasonal variation of the F
It seemsthat the circulationmechanismproposedby John- region ion composition,J. Geophys.Res., 75, 15'9,1970.
son and Gottlieb [1970] might alsobe partly responsible Fontanari, J., Analyse de la temperature neutre observe par
for the relative enrichmentof (0,) in summer. diffusionincoh.rentedans la bassethermosphire,M.S. thesis,
Univ. of Toulouse, Toulouse, 1973.
It must also be recalledthat part of the 200-km variation Fontanari, J., and D. Alcayd.(, Observation of neutral tem-
is due to. the seasonalchangesin the temperatureprofile perature tidal type oscillations in the F region, Radio Sci.,
between 100 and 200 km. 9, to be published, 1974.
Winter F region anomaly. Our resultsconfirm the theo- Jacchia, L. G., Static diffusion models of the upper atmo-
sphere with empirical temperature profiles, Smithson. Con-
retical predictionsof Rishbeth and Setty [1961] that neu-
trib. Astrophys., 8(9), 215-257, 1965.
t'ral compositionchangesat constant pressurelevels are Jacchia, L. G., New static models of the thermosphere and
responsiblefor the winter F region anomaly. However, exosphere with empirical temperature profiles, Smithson.
morethan a simple(0) or (0)/(N2) lowerboundaryvar- Astrophys. Obs. Rep. 313, 1970.
iation of the kind already mentioned by several workers Jacchia,L. G., Revised static modelsof the thermosphereand
exosphere with empirical temperature profiles, Smithson.
[Waldteu[el, 1970a, b; Evans and Cox, 1970; Barlief et Astrophys. Obs. Rep. 332, 1971a.
al., 1971] is needed;indeedthe dominantrole appearsto be Jacchia, L. G., Semiannual variation in the heterosphere: A
played by { reappraisal, J. Geophys. Res., 76, 4602, 1971b.
Global pattern. o. the atmosphere. The long-term be- Johnson, F. S., and B. Gottlieb, Eddy mixing and circulation
at ionospheric levels, Planet. Space. Sci., 18, 1707, 1970.
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by an intermixing of a large semiannualeffect on the alti- the thermosphere, Planet. Space Sci., 21, 1973.
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exospherietemperature, and of large annual effects on tude dependence of the thermospheric annual and semi-
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thermospherietemperature and on compositionchangesat
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constant pressurelevels. neutral composition, Planet. Space Sci., 20, 379, 1972b.
This descriptionlooksmore complexthan simple semi- Noxon, J. F., and A. E. Johanson, Changes in thermospheric
annual effects driven by either temperature variations molecular oxygen abundanceinferred from twilight 6300 A
[Jacchia,1965, 1970] or pure density variations [Jacchia, airglow, Planet. Space Sci., 20, 2125, 1972.
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lower thermosphere during a magnetic storm, paper pre-
Acknowledgments. The authors are indebted to P. Wald- sented at the Fifteenth Meeting of Cospar, Madrid, Spain,
teufel for helpful discussionsand to P. Amayenc for his 1972.
comments. G. Lejeune kindly supplied the authors with his Rishbeth, H., P. Bauer, and W. B. Hanson, Molecular ions in
computer program and is gratefully acknowledged. the F2 layer, Planet. Space Sci., 20, 1287, 1972.

Rishbeth, H., and C. S. G. K. Setty, The F layer at sunrise, J. composition variation above 400 kilometers during a mag-
Atmos. Terr. Phys., 20, 263, 1961. netic storm, J. Geophys. Res., 76, 8318, 1971.
Roble, R. G., and R. B. Norton, Thermospheric molecular Waldteufel, P., Valeur et variation diurne de la densit atmo-
oxygen from solar extreme ultraviole occultation measure- sphrique k 100 km d'altitude, Planet. Space Sci., 17, 725,
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Salah, J. E., and J. V. Evans, Measurements of thermospheric Waldteufel, P., A study of seasonal changes in the lower
temperatures by incoherent scatter radar, paper presented thermosphere and their implications, Planet. Space Sci., 18,
at the Fifteenth Meeting of Cospar, Madrid, Spain, 1972. 741, 1970a.
Scialom, G., Mesure de la composition dans la thermosphre Waldteufel, P., Une tude par diffusion incohrente de la
par spectrometrie de masse en fuse-sonde' Application k haute atmosphere neutre, Ph.D. thesis, Univ. of Paris, Paris,
l'tude des quilibres photochimiques dans la rgion F de 1970b.
l'ionosphre., M.S. thesis, Univ. of Paris, Paris, 1973. Wand, R. H., Evidence for reversible heating in the E region
Shimazaki, T., Effects of vertical mass motions on the com- from radar Thomson scatter observations of ion tempera-
position structure in the thermosphere, Space Res., 12, ture, J. Geophys. Res., 74, 5688, 1969.
1039-1045, 1972. Wand, R. H., Observation of reversible heating by tides in
Swartz, W. E., and J. S. Nisbet, Diurnal variation of the the E region, paper presented at USNC/URSI Spring Meet-
neutral temperature profile at Arecibo from incoherent ing, Washington, D.C., 1972.
scatter measurements and its relevance to the 1400 hour
density maximum, J. Geophys. Res., 76, 185, 1971. (Received April 9, 1973;
Tauesch, D. R., G. R. Carrigan, and C. A. Reber, Neutral accepted October 11, 1973.)