CHEMISTRY (PART B)
SECTION I: (SINGLE CHOICE QUESTIONS)
This section contains 30 Multiple Choice Questions. Each question has four choices (1), (2), (3)
and (4) out of which ONLY ONE is correct.
31. Ba2+ , CN and Co2 ions form an ionic complex. If this complex is 75% ionized in aqueous
solution with Vant Hoff factor(i) equal to four and paramagnetic moment is found to be 1.73
BM(due to spin only) then hybridization state of Co(II) in the complex will be
(1) sp3d (2) d 2 sp3 (3) sp3d 2 (4) dsp3
NH2
OH
OH
OHC Cl
OHC
(1) (2)
OHC
NH2 C N
OH
OH
Cl
OHC Cl
(3) (4)
NH2 CHO NC
33. 1 mole of equimolar mixture of ferric oxalate and ferrous oxalate will require x mole of KMnO4 in
acidic medium for complete oxidation, x is
(1) 0.6 mole (2) 0.9 mole (3) 0.3 mole (4) 1.8 mole
34. The oxidative cleavage of compounds Glucose (A) and Fructose (B) with HIO4 leads to the
formation of acids and aldehydes. The ratios of formic acid to formaldehyde for (A) and (B)
respectively are
(1) 5/1, 3/2 (2) 5/2, 3/1 (3) 3/2, 5/2 (4) 4/2, 5/1
35. The unit cell of hydrated TlAl(SO4)2 is face centered with unit cell length a = 1.19 nm.
If the density of the salt is 2.32 g/cc, then the approximate number of water of hydration units per
TlAl(SO4)2 unit will be (Molar mass of TlAl(SO4)2 is 423.5).
(1) 6 (2) 7 (3) 8 (4) 9
37. The kinetic energy, , of a electron is related to the kelvin temperature through the equation,
3 J
kT where k 1.38 10 23 You are given an electron with a deBroglie wavelength
2 particle.K
of 76 .3 nm .
What is the Kelvin temperature of this electron?
(1) 0.50 (2) 1.00 (3) 1.50 (4) 2.00
S N O
I III H V
II IV
(1) I > II > III > IV > V (2) II > I > III > V > IV
(3) V > IV > III > II > I (4) IV > V > II > I > III
40. Given the following molar conductivities at infinite dilultion at 25C ; HCl, 426 1cm 2 mol1;
1 2 1
NaCl,126 1cm 2 mol 1 ; NaC (sodium crotonate), 83 cm mol . The conductivity of 0.001
mol/dm3 acid solution is 3.83105 1cm1 . The dissociation constant of crotonic acid is
(1) 4.11105 M (2) 3.11105 M (3) 2.11105 M (4) 1.11105 M
41. When the acids HClO3 , H 3BO3 , H3 PO 4 are arranged in order of increasing strength, which order is
correct ?
(1) H3 BO3 H 3PO 4 HClO3 (2) HClO3 H 3BO3 H 3 PO 4
(3) H3 PO 4 HClO3 H3 BO3 (4) H3 BO3 HClO3 H 3 PO 4
42.
(1) (2)
(3) (4)
44. A nitrogen fluoride on analysis found to contains 42.3% nitrogen and has a vapour density of 33. The
hybridization of N in the molecule is,
(1) sp3 (2) sp3d (3) sp2 (4) both sp2and sp
z
NO2
HO
x y
F
(1) x > y > z (2) y > x > z (3) z > x > y (4) x > z > y
46. On the basis of the given Ellingham diagram, which of the following statement is correct?
(1) Coke can reduce FeO at a temperature of 873 K.
(2) Coke can reduce FeO at a temperature 983 K.
(3) Coke can reduce FeO in a temperature range of 1073 K > T > 873 K.
(4) Coke can reduce FeO and will itself be oxidized at a temperature > 1073 K.
100
200
G/kJ mol1 of O2
2Fe + O2 2FeO
300
400 2C + O2 2CO
500
49. Which of the following acid is not formed during the step wise hydrolysis of P4O10?
(1) Pyrophosphoric acid (2) Tetra polyphosphoric acid
(3) Tetra metaphosphoric acid (4) Hypophosphoric acid
CH3
SOCl2
OH
NaOH(aq)/Br2
52. In the reaction the intermediate (s) is________
O O O
Br
Br
(1) (2) (3) (4) all
Br Br Br Br
53. One mole of a substance is cooled at rate of 0.4 kJ min1 during freezing. What would be the entropy
of fusion (in JK1 mol1) for this substance using data from the following graph?
800
400
Temp. (K)
1 4
Time (in minute)
(1) 2 (2) 3 (3) 4 (4) 5
CHCl2Br/OH
(2) chlorobenzene
Ph H
(3) base
C=C Ph C CPhCl
* *
OClPh Cl
O OH
O C CH3 O C CH3
(4) base
H2O CH2
C CH3
C
O
O
56. In which of the following, ring contraction is not involved in the formation of major product?
O
N2 O
H2O/light
(1) (2) Zn(Hg/HCl
Br2 Zn Hg
OH (base) O
(3) A B (4) HCl
CH3COOH H3O+ N CH
(2) Rate of the reaction of BH3 with O(SiH3)2 is faster than the rate of the reaction of BH3 with
O(CH3)2.
NH4Cl
(3) O O Aromatic product
OH /
H H
O
O
COH
CN CN C OH
H 3O +
CN C OH
(4)
O
Pt
58. NH3 + O2 A + H2O
A + O2 B
B + O2 + H2O C
A, B and C are
(1) N2O, NO2 and HNO3 (2) NO, NO2 and HNO3
(3) NO2, NO and HNO3 (4) N2O, NO and HNO3
59. Aluminium chloride exists as dimmer, Al2Cl6 in solid state as well as in solution of nonpolar solvents
such as benzene. When dissolved in water, it gives
(1) Al3+ + 3Cl (2) [Al(H2O)6]3+ + 3Cl
(3) [Al(OH)6]3 + 3HCl (4) Al2O3 + 6HCl