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AITS 2 CHEMISTRY (MAIN)

CHEMISTRY (PART B)
SECTION I: (SINGLE CHOICE QUESTIONS)

This section contains 30 Multiple Choice Questions. Each question has four choices (1), (2), (3)
and (4) out of which ONLY ONE is correct.

31. Ba2+ , CN and Co2 ions form an ionic complex. If this complex is 75% ionized in aqueous
solution with Vant Hoff factor(i) equal to four and paramagnetic moment is found to be 1.73
BM(due to spin only) then hybridization state of Co(II) in the complex will be
(1) sp3d (2) d 2 sp3 (3) sp3d 2 (4) dsp3

32. The end product of the following reaction is


OH
Excess
CHCl3/NaOH/

NH2
OH
OH
OHC Cl
OHC
(1) (2)
OHC
NH2 C N
OH
OH
Cl
OHC Cl
(3) (4)

NH2 CHO NC

33. 1 mole of equimolar mixture of ferric oxalate and ferrous oxalate will require x mole of KMnO4 in
acidic medium for complete oxidation, x is
(1) 0.6 mole (2) 0.9 mole (3) 0.3 mole (4) 1.8 mole

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34. The oxidative cleavage of compounds Glucose (A) and Fructose (B) with HIO4 leads to the
formation of acids and aldehydes. The ratios of formic acid to formaldehyde for (A) and (B)
respectively are
(1) 5/1, 3/2 (2) 5/2, 3/1 (3) 3/2, 5/2 (4) 4/2, 5/1

35. The unit cell of hydrated TlAl(SO4)2 is face centered with unit cell length a = 1.19 nm.
If the density of the salt is 2.32 g/cc, then the approximate number of water of hydration units per
TlAl(SO4)2 unit will be (Molar mass of TlAl(SO4)2 is 423.5).
(1) 6 (2) 7 (3) 8 (4) 9

36. Consider the following first order competing reactions:


k k2
X 1
A B and Y C D
If 50% of the reaction of X has been completed when 96% of the reaction of Y was completed,
then the ratio of their rate constants (k2/k1) is
(1) 2.34 (2) 0.215 (3) 1.1 (4) 4.64

37. The kinetic energy, , of a electron is related to the kelvin temperature through the equation,
3 J
kT where k 1.38 10 23 You are given an electron with a deBroglie wavelength
2 particle.K
of 76 .3 nm .
What is the Kelvin temperature of this electron?
(1) 0.50 (2) 1.00 (3) 1.50 (4) 2.00

38. An unknown compound, X, has the molecular formula C 7 H 12 . On catalytic hydrogenation 1


mole of X absorbs 2 moles of H 2 and yields 2-methylhexane. When X is treated with a solution of
Ag ( NH 3 ) 2 OH , a precipitate forms; an analysis of the precipitate shows that it contains silver,
and treatment of the precipitate with dilute HNO3 regenerates B. Which compound represents X?
CH3
|
(1) CH 3CH 2CH 2 CH 2 CH 2 C C H (2) CH3 C C CH 2 CH CH3
CH3 CH3
| |
(3) CH 2 CH CH CH CH CH3 (4) CH3 CH CH 2 CH 2 C C H

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39. Arrange the following in the increasing order of resonance energies

S N O
I III H V
II IV
(1) I > II > III > IV > V (2) II > I > III > V > IV
(3) V > IV > III > II > I (4) IV > V > II > I > III

40. Given the following molar conductivities at infinite dilultion at 25C ; HCl, 426 1cm 2 mol1;
1 2 1
NaCl,126 1cm 2 mol 1 ; NaC (sodium crotonate), 83 cm mol . The conductivity of 0.001
mol/dm3 acid solution is 3.83105 1cm1 . The dissociation constant of crotonic acid is
(1) 4.11105 M (2) 3.11105 M (3) 2.11105 M (4) 1.11105 M

41. When the acids HClO3 , H 3BO3 , H3 PO 4 are arranged in order of increasing strength, which order is
correct ?
(1) H3 BO3 H 3PO 4 HClO3 (2) HClO3 H 3BO3 H 3 PO 4
(3) H3 PO 4 HClO3 H3 BO3 (4) H3 BO3 HClO3 H 3 PO 4

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42.

(1) (2)

(3) (4)

43. Which of the following statements is incorrect


(1) Adsorption always leads to a decrease in enthalpy and entropy of the system.
(2) Adsorption arises due to unsaturation of valence forces of atoms or molecules on the surface.
(3) Adsorption increases with rise in temperature.
(4) Adsorption decreases surface energy.

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44. A nitrogen fluoride on analysis found to contains 42.3% nitrogen and has a vapour density of 33. The
hybridization of N in the molecule is,
(1) sp3 (2) sp3d (3) sp2 (4) both sp2and sp

45. The order of acidity of positions X, Y and Z is


F

z
NO2

HO
x y

F
(1) x > y > z (2) y > x > z (3) z > x > y (4) x > z > y

46. On the basis of the given Ellingham diagram, which of the following statement is correct?
(1) Coke can reduce FeO at a temperature of 873 K.
(2) Coke can reduce FeO at a temperature 983 K.
(3) Coke can reduce FeO in a temperature range of 1073 K > T > 873 K.
(4) Coke can reduce FeO and will itself be oxidized at a temperature > 1073 K.
100

200
G/kJ mol1 of O2

2Fe + O2 2FeO
300

400 2C + O2 2CO

500

500C 600C 710C 800C 900C 1000C

47. XeF5 has the similar geometry with


(1) AsO4 3 (2) IF5 (3) AlH 4 (4) TeCl4

48. The number of identical P-O bonds P2O6 4


(1) Four (2) Six (3) Five (4) three

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49. Which of the following acid is not formed during the step wise hydrolysis of P4O10?
(1) Pyrophosphoric acid (2) Tetra polyphosphoric acid
(3) Tetra metaphosphoric acid (4) Hypophosphoric acid

50. The correct order in which oxygen-oxygen bond length increases is


(1) H2O2 < O2 < O3 (2) H2O2 < O3 < O2
(3) O2 < O3 < H2O2 (4) O2 < H2O2 < O3

CH3

51. + succinic anhydrids AlCl3 C11H12O3


Zn/Hg/HCl
B C11H14O2

SOCl2

H2SO4 NaBH4 C11H12O D AlCl3


F C11H14O E C11H13ClO C

C11H12
NBS NaOEt 2 methyl nepthalene
C11H11Br F is_________
EtOH/

(1) (2) (3) (4)


CH3 CH3 CH3

OH
NaOH(aq)/Br2
52. In the reaction the intermediate (s) is________

O O O
Br
Br
(1) (2) (3) (4) all

Br Br Br Br

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53. One mole of a substance is cooled at rate of 0.4 kJ min1 during freezing. What would be the entropy
of fusion (in JK1 mol1) for this substance using data from the following graph?
800

400
Temp. (K)

1 4
Time (in minute)
(1) 2 (2) 3 (3) 4 (4) 5

54. Which of the following is correct product (A) of the reaction


O
CN3
heat
toulene
A (80% to 90%)
NH
CH3
H O
N N
(1) O (2) N O
N N
CH3 CH3
O O

(3) N CH3 (4)


N
CH3

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55. Which of the following is correct ?


CHFClBr/OH
(1) chlorobenzene

CHCl2Br/OH
(2) chlorobenzene
Ph H
(3) base
C=C Ph C CPhCl
* *
OClPh Cl
O OH
O C CH3 O C CH3
(4) base
H2O CH2
C CH3
C
O
O
56. In which of the following, ring contraction is not involved in the formation of major product?
O
N2 O
H2O/light
(1) (2) Zn(Hg/HCl

Br2 Zn Hg
OH (base) O
(3) A B (4) HCl
CH3COOH H3O+ N CH

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57. Which of the following may be a correct statement.

(1) stabilitry order

(2) Rate of the reaction of BH3 with O(SiH3)2 is faster than the rate of the reaction of BH3 with
O(CH3)2.
NH4Cl
(3) O O Aromatic product
OH /
H H
O
O
COH
CN CN C OH
H 3O +
CN C OH
(4)
O

Pt
58. NH3 + O2 A + H2O

A + O2 B
B + O2 + H2O C
A, B and C are
(1) N2O, NO2 and HNO3 (2) NO, NO2 and HNO3
(3) NO2, NO and HNO3 (4) N2O, NO and HNO3

59. Aluminium chloride exists as dimmer, Al2Cl6 in solid state as well as in solution of nonpolar solvents
such as benzene. When dissolved in water, it gives
(1) Al3+ + 3Cl (2) [Al(H2O)6]3+ + 3Cl
(3) [Al(OH)6]3 + 3HCl (4) Al2O3 + 6HCl

60. The radial wave equation for hydrogen atom is :


3/2
1 1 2 x/2
[(x 1)(x 8x 12)]e
16 4 a 0
2r
Where x ; a 0 radius of first Bohr orbit,
a0
the minimum and maximum position of radial nodes from nucleus are ?
a a a
(1) a 0 ,3a 0 (2) 0 ,3a 0 (3) 0 , a 0 (4) 0 , 4a 0
2 2 2

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