Thermophysical Properties of Fluids. Il. Methane, Ethane, Propane, Isobutane, and Normal Butane B.A. Younglove and J.F. Ely ‘Thermophyses Dison, National Engineering Laboratory, National Bure of Standaris, Boulder, Colorado 80303, Reosved October, 1986; evied mans ecied Joe 1, 1887 ‘Tables of methane, ethane, propane, isobutane, and normal butane thermodynamic and transport properties are presented. The mathematical relations from which these thermo- plysital propesticn atc Ubtaiued ate Ueouited The tables ist pressure, density, temps ‘ure, internal energy, enthalpy, entropy, specific heat at constant pressure and at constant volume, sound speed, viscosity, thermal conductivity, and dielectric constant. Key words: density; equation of tate; ethane; isobutane; methane: normal butane; propane; thermo dynamic properties; thermophrical properties; transport properties. Contents 3. Introavetion 27) Appendix ©. Triple Point, Creal Font, Manik 2, Thermodynamic and Related Propet. 578 mum Pressures and Temperatures 2.3. The Equation of State. 578 Appendix D. Critical Point Enhancement to 2.9. Two-Phase Roundaries 578 Thermal Conductivity. 2.2.1. Vapor Pressure. 578 Append. ThemopiialProperi of Mati 22.2. Vapor Density at Coexistence 578 223. Liquid Density at Coexistence 378 _“Appendia F. Theemophybical Properce of tie 224. ‘Ine Melting Line by ane 23, Derived Thermodynamic Properties 579 Appendix G. ‘Thermophys Properties of Pro- 231. Entropy 5 pas 329) Veal Fe Specite Heat 510 Arrendiy 23.3, Reference Stat. 579 butane... 234, Enthalpy 579 Appendix I. Thermophysical Properties of Nor- 23,5, Internal Energy 579 mal Butane.. 23.6. Speciic Heat. 379 Appendix J. Coefiients for Equations for Com- 23.7. Sound Speed 579 puting Thermophysical Properties... 3, Transport Properties. = 519 41. Viscosity 570 32. Thermal Conductivity... 581 4, Dielectric Constant enn 381 5, Summary of Uncertainties... 581 etch rae 6. Acknowledgments... 31 _Keterence values tor entropy ana entaaipy. 7. References: 581 Coefficients for the collision integral. 1 2. : 581 3. Typical uncertainties in calculated properties “Appendix A. List of Symbols and Units. 1. Introduction 582 se sea on m2 158 14 380 380 ae ‘The thermophysical properties of methane, ethene, (©1987 by the U5. Secretary of Commerc on bef the Unie Site, “This copyrights ined fo the Ameran Instat of Phys and the propane, isobutane, and normal butane are presented in this, report ia tabular form in SI units. The properties are com- ‘Ansan Chania Soe, puted from a set of equations which are the same foreach of Repos evan rom ACS; see Reprint List at back of sue the fluid, such that only the coelliients need be changed. (0047-2600/87/040877-222/818.00 7 4 Phys. Chem, Ret Dats, Vol 16, No 4, 1987578 ‘rom one fluid to another. A previous publication"? for ar~ gon, ethylene, parahydrogen, nitrogen nitrogen trifluoride, land oxygen followed the same guidelines, ‘A 22-term modified Benedict-Webb-Rubin (MBWR) ‘equation of state was used to represent the pressure-vol- ume-temperature (PVT) surface ofthese fuids. This equa- tion has been widely used for this purpose, since it possesses the advantage ofhigh computational speed, as wellas that of, high accuracy, This equation is particularly useful when ‘minimiring the deviatous in Siting We eapstineutal date, especially in multiproperty regression optimization which includes specifc heat oF sound speed data as input. ‘The MBWR form allows the computation of pressure ‘asa function of density and temperature and is also used to compute internal energy, enthalpy, entropy, heat capacity, and sound speed. Other relations used in conjunction with fi: MDWR aie those fr vajes paeouie, eting presut densities ofthe saturated liquid and vapor, viscosity thermal conductivity, and dielectric constant. These equations have te same form for each ofthe fluids and only the coeficients need to be changed when going from one fuid to another. ‘The equations are described in the text below and in NBS ‘Technical Note 1079 by R. D. McCarty,’ which describes ec comuptes stan syscu setF RED, HneraeAlve B.A. YOUNGLOVE AND J. F.ELY {gram for the computation of thermophysical properties for ‘these fuids. The tables presented here contain properties for the liquid-vapor boundary, the propeitics of the quid on the melting line, and the thermophysical properties on iso- bars at temperatures that span the pressure-temperature density surface. The temperature spacing along each isobar as chosen s0 a8 to allow accurate linear interpolation for these properties. 2. Thermodynamic and Related Properties 2.1, The Equation of State ‘The modified Benedict-Webt-Rubin equation for computing presre sa function of density and temperate has a well-cstablished reputation for versatility, Ii a fe- Suen choise when Sting date ct bigaeeaey mhih vores ‘Wide ranges of temperature and pressure and when corelat- ing several sets of data from diferent sours. Ils advantage of adaptability to ficient computer propramming is even ‘ore appreciated in mulipropert fitting in which eiferent ‘pes of data such as PVT and heat capacity ae ft simulla- neous "Pn uated fu dhe MBWR eyuaion P= pRT + p'{G(1)T + G(2)T"? + (3) + G(A)/T + G(S)/T*] + p'1G(O)T + G7) + O(8)/T + G(9)/T7} + PTGOOT + G11) + G/T] + p'LGL13)] + p*{GC14)/T + G(15)/T"] + p'[G(16)/T} + pGUT/T + G18)/T?) + p"[G(19)/T*] + p'1G(20)/T? + G(21)/T exp typ") Fp UGUL2)/1? + GU28)/T* expt yp") + p"1GOA)/T? + G25)/T Jexp yp) + p°(G(26)/T? + G2T)/T expt yp") + p"[G(28)/T? + G(29)/T Jexp(9p*) 4p GOO)/T2 + 6AD/T? 4 G32)/Texptae?) ‘The nonlinear parameter, gnmma, is defined as — 1/p2 ‘end is not an adjustable parameter ofthe ft. The voriables are defined in Appendix A. ‘The PVT surfaces for methane, ethane, propane, isobu- ‘ane, end normal butane, are from the work of J. F. Ely:* Coefficients for each of the fuids are given in Appendix J ‘The maximum temperatures and pressures for which these surfaces are valid are given in Appendix C. Extrapolation ‘beyond these Hisits wil saul in large uaccrtaatina ad is not advised 2.2. Two-Phase Boundaries 221. Vapor pressure ‘The vapor pressures given in the tables forthe liquid vapor coexistence boundary and the temperature of the liq ‘uld-vapor boundary or each isobar are computed from the ‘vapor pressure equation, InP=InP, + ¥,(Dx+V,2)2 + ¥,3)" FVM + HV, Q) where x= (I=T,/T/U-T/T) a “4 Phys. Cher. Rt Data, Vol. 16, No.4, 1967 @ —_—_—_———_—_- ‘As in the case with the MBWR equation, the coef cients for this equetion and all those following are found in ‘Appendix J. 222. Vapor Density at Coenstence Values of the vapor density for the liquid-vapor coexis- vrs entra fon Wane =tno,—Innlni Ds whee Penson Scsorees S40 6 = naen-nnn—n. « 223 untae The id enya he gra conn boty nec Pim Pe + (Pa —pedexplace)], a” mee‘THERMOPHYSICAL PROPERTIES OF FLUIDS 579 (inx+ ¥ Aen =x! + ¥ ama and x is defined in Ea (6) 224, TheMetingLine ‘The pressures atthe solid-liquid coexistence boundary are given by. PaA+BTe. 0 wo fan aaa, () 2.3. Derived Thermodynamic Properties ‘The properties derived form the equation of state and ‘deal gas heat capacity are entropy, enthalpy, internal ener- 8y, specific heat at constant volume and at constant pres- sure, and sound speed. 23:1. Entropy “The euwopy bs eomputed ut sonst s [Sarai LE-@,p ale. 20) where P°, 7°, C2, and $® are the reference state values, de- Tied below. 2.2. Ideal Gas Speci Heat ‘he ideal gas specitic heat, C3, is computed from the following: SS memreno 5 GUsriter 1 - Eso soe any where, u= G/T. «ay 2:3, Retoronce State Values of $° and H® are at the reference state of T° = 298.15 K,and P* = 0.101 325MPa (25°Cand 1 atm) (see Table 1). The value for methane is from McDowell and Kruse.‘ The values for ethane and propane are from Chao et al,® and the values for isobutane and normal butane are from Chen et al.” 234.Enthapy ‘The enthalpy is computed from H(Tp) = HT") + (P—pRTV/p + Lie CGe) Jet ere aay 2.35.Interna Energy ‘The internal energy is E(Tp) = H(Tp) —P/p as “Tame Values of etrpy and enthalpy the reference sat The fet encestateenpeature abd pre are 96.15 apd0101 325 MPaforall fds. = a Yeo sys Ethane maate m2 Propane 702 4702 Taobotane 295350 in9326 Normal butane 509.908 192787 12:36. Specie Heat at Constant Volume and at Constant Pressure The geht tnt con=c-a[ [Z(22) Jo. an sod constant preset cunacanst (2) ow 237. $ound Speed ‘From die relations fr specie neat and the PYT equa tions, the sound speed is computed from, Sa) 3. Transport Properties 3.4. Viscosity Representation for the viscosity of methane, ethane, isobutane, and normal butane have been generated by ‘Younglove! The eoproostation forthe vceclty of propane was developed by Ely.? “The functional form fr the viscosity is HW 4D AD on ‘The frst term of the expansion isthe dilute eas term whieh is to (5/16)( 000RN,)"(M,7)"°/(Qe") « 19) ‘The distance at which the potential energy function is zero as been interpreted as 0; however it isused asan adjus- table parameter for fitting experimental data asi ¢, the po- ‘ential energy minimum. The value of the colision integral, ‘0, hasbeen evaluated by Ely? as wu =[5 ema)? Valea penal Tesco (1) ‘oration ofthe oc de mT) =F, (1) + F,(2)€F, (3) — Inf T/F, (4) ]P > an ‘emt mercy quot eco ont ne ps mae.T) = explFe.D1 — explG(D] , G(T) =E,(1) + B,2)/T, an ww) (22) ay 4. Phys. Chem. Ret. Data, Vol 16,No. 4, 1987500 B.A. YOUNGLOVE ANUJ. F. ELY ‘Taute 2, Coticent forthe colin integral ciy= —somaneat Giay= tole moose Ca)= a1 s6917 y= “au zak gst ae C= eIss2118 6) 158 63 056, c= “Larson so42 = = a2 661014 9)= — —onmesroee ‘TaMUe 3. Typical uncer in cae propetios Proper Tila Gx Fd Cael twiow 7, telow 7, above 7, ‘etn Methane rroswere 2 os ry os Density % 02 a3 ol 50 ‘Temperature ar a a1 1 Entaipy ct 2 1 1 0 Specie hea, 5 5 5 2 0 Specie hea C5 3 5 2 0 Speed ofound 2 os as 2 ‘Thermal conducty 5 4 : i cont Se i 3 2 5 Dinette constant % os os dos os ihane Prete % 2 oa ‘7 2 Dom Fa a 2 3 ‘Temperate $ a ar ar a Ent Qed) 3 t s 1 Entropy mal) is 1 1 5 Sous bn % ; 3 2 fo Spee ent, 56 1 i i 0 Speed of wound as 06 a6 0 ‘Thermal condetiy % 2 2 2 0 Visa % a a a 5 Diets conan os os os 2 Propane Pressre 9 2 as as 2 Density a oo 1s is Entity Gyo) 3 r 2 3 Entropy /ma) 2 t 1 3 Specie at 96 2 2 2 5 Specie at 3 3 5 te Speed of scund fe as i i 0 ‘Themalconsucivity $ 2 2 2 0 Viet 2 2 2 5 Dinette constant 0s 0s ns a2 Trobatane Presre 9 2 04 1 02 easy oon om aL 2 “Temperate ar ar al a2 Enthaly (met) an rey on a Entropy @/ma) 2 t t 5 Sprite heat 2 2 2 ry Specie baat, C5 2 2 a 0 Sen of und as i i “ ermal conduc f 2 2 to Viscosity % 2 2 2 10 Dinette constant fos os es ao ‘Normal butane Pramas 2 2 1 was os Desi 36 des on 0.06 3 “Temperate 5 ar an or a2 Entlpy (mol) 1 3 3 3 Entropy /nel) 2 t i 5 Spats het Gy % 2 2 2 io Speci heat, C2 2 2 a % Syed of sound 96 i 2 2 5 ‘Thermal conduct 2 2 2 0 Vicoaty a a a 5 Diasec conan % 00s 005 0s as 4 Phys. Chem, Ret. Data, Vol. 16, No.4, 1987‘THERMOPHYSICAL PROPERTIES OF FLUIDS FieT) = O(N) + [E3) +E ATOPY +(ns), 04 (2s) 3.2. Thermal Conductivity Representations for the thermal conductivity, 2, of ethane, sobutane, and normal butane were generated by “Younglove. The ethane ft was developed by Ingham’ and ‘that for propane by Ely.” “The fanctionel form ofthe thermal condtivity sepom sentation is Am ig Bot Pipe Fip) +205 witee the dilute gas thermal conductivity i given by Aq = 1000n(C2 — SR /2)[G,(1) + G,(2E/KT ] an Here, is defined in Eq, (20) and C? is defined sbove. The terms Fy F,, and Fare 28) oo) Rey mmo", (29) AS Bimre-? (30) ‘The 2. term is the critical enhancement term and is de- scribed in Appendix D. 4, Dielectric Constant ‘The equations used to represent the diclectric constant, Ai Dp) Gt Din RIT BPO) e-td rae an Equation (32) is the Clausius-Mossotti relation. Source documentation for methane is Straty and Good- ‘win, and for ethane ic Weber. * Haynes and Goodwin were the sources of dielectric constant for propane, isobutane,"® ‘and normal butane." In certain cases the forms reported by the authors were modified to conform to Eq. (31) 5. Summary of Uncertainties ‘The uncertainties fr the thermophysical quantities de- sorbed in this work, Table 3, are based on an evaluation of | deviation plots of the various data sources from the fitting functions, Consideration is also given forthe claimed acour acies of the underlying dats used in fitting, and on the ‘weighting ofthe data. Uncertainties inthe derived quantities are estimated from the accaracies of the properties from ‘which they are computed. 581 6. Acknowledgments We are indebted to the office of Standard Reference ‘Daraof the National Bureau of Sumndards for their generous ‘support ofthis work, and in particular toDr. H.J. White, Jr, ‘who originally conceived the idea for this volume. 7. References "R.A. Yomlove, "Thermophys proper of id I. Argon, ey ‘ne prahyorogen, sivoper, nitrogen tui and oxy," J. Ps {Goes et Data ti, Sopp 98. BLA. Youngioe“interstiveprogram tales thermophsica prop eres fi ids” Nat. Br. tnd. (US) Tech Noe 1048 198). erase Foran program for microcomputers oa Toor ist. Sind. (US) Te “LF Bly, "A rditve model forthe therophy cl poprtie ofarton loxdesich tres" Nat Br, Stand (U.) Tech. Not (tobe pub- listed) 25 NeDowel and FH. Kris. Chem. Eng. Dat 8, 47 (1963) 5. Chao, RC Wit, 1 B..Zroln, "del gs termodyeamic Properties of thine snd propane,” IPs. Chem. Ret Date 2 (1973) °S.S:Chen RC. Wilt, andD..Zwoisi "el ps thermodynamic et Data § (1975) 'A.Younglove (toe paises) Fly (private communication). "Ingham {peat communication). "2, By and HL tag (ete communication) 8G. €.Staty and RD. Goedvin, “Dida contuxt and polarizability fstuated and compeesed ld methane,” Cryogenics 12,712 (1973), Set funtion forcompeese gaseous and Iiqu ethane,"J. Chom. Phys 6, 4451976), "°R-D. Goodwin and W. M. Haynes, "Thermophys properties of peo- pene roms 85 f 0D Kat prnrento 7 MPa" Ra Mor Stand. (US) ‘Monogr. 170 (1982). "SRD. Gondwin and W.M. Haynes, “Thermophys properties ofsobu- ‘une fom 1146700 K at presuesto 7 MPa," Natl Bur Stand US.) “ech Note Cs (1982). WSK Hayne snd RB. Goodwi,“Thermoptys Sf 000. ‘mal butane om 138 to 700K a presturesto 70 MPa” Nall Bat. Stand (0.8) Monogr. 18 (1982). “D.D, Waguaa,W.H, Evan V.E, Parker, RH. Sebume, 1 Halow,S. ‘heemedynamic proper” J. Phys Chem. Ret Dats 1, Supe. 2 198, Appendix A. List of Symbols and Units Primary Thermophysical Quantities Phat, presse, Pat catcal pint, Pat tiple point, MPa poe density, pat exitical point, mol/ém* pen 2 ofa t trol point. of vapoe atte le point TTT texaperatue, Pteiical point, Pat triple point, K “

“o°s3n6 “ocoses: “asiz'o “aisolo vse.3' s.an alse “ie 8.0109 ins.0. Glens ltsesa sao Gaaio Isase as.ae se 19 ooo Mie.0G.a93solnss90 Gensco asneco Isha as.ar ata 2h cone 130-0 0.7505 Gubaepe Gago 4398.0 ted sty aba 545 b!oe 1400914983 oinaste Jase" Aaa.0 tesla 35193393 Sisa 0.0180 150.0 Olg4r9Glowo3eFi-o 4548.0 M687 2810 34s 592. o-ote2 70.0 0.5704 0.03886 4215.0 $621.0 172.9 28.10 33.38, 6.68 0.0186 ols 815983 Oceasse —aasrlo. $957.0 1789 351230138 $05. oce200 4 Phys. chem. Ret Data Vol. 16. No.4 1967‘THERMOPHYSICAL PROPERTIES OF FLUIDS 589 “Toeomophysel propertie of metane = Corioued SS ee ee ee re eg hee heey ia Ge eed ites [ea 4: Phys. Chem, Ret. Data, Vol. 16, No 4, 1967B.A. VOUMALOVE AND J. F.ELY “Thermophys properties of mechane - Canned p/m? _ovlam?__avmel_t/nal_Mimabk) imal Klee W/o) _ Cae 390.0 0.5518 0.03440 9006.0 11910.0 192.2 29.66 38.03 ABI-B 12-8 0.0812 1.068, 260.0 9.8364 0.02244 9305.0 12700.0 199.3 30.18 38.52 487. 13.1 0.0028 1.00066 foo-0 —O'te26 lovoos j0ss0:0 H3ago.0 199.5 32.39 Soces Syo’s Ha Boas Toons {0:0 014896 OLonmes 11210.0 ta700.0 199°5 Sod A1-7R SRIe 4B 0.0524 1 ose io:0 —Glaane DloaTa4 {1490.0 3090.0 dors Macs? 299 gold ised 910859 Tlonosd coo G.ei95 avoagis 2600-0 6120.0 202.2 35.75 Gaon azla tact olespe T9002 500.0 013459 OlonwoE {4070-0 14230.0 207.2 34.05 MSI S20 1950 O.046S ToooAT 520.0 0.5711 0.02813 14450.0 19170.0 209.0 99.15 47.49 $11.7 17-8 0.0701 1.00046, Stoo S33 Soba BSG Fitioo 8 3) BSS BES GCE Sen Stoo 013326 D020 9290-0 adHH0.0 diaa arty Soret Go0.3 19.0 0.087 YLomN soo: 013258 Oloa0o4 1N140.0 at30.0 Hes] 2.93 S126 onl Ble OL0RKTTandd (401225 Mo tae 50.70 asi§ 2816 $921.0 69.99 34.03 $3.43 1516.0 206.0 0.24 1.67789 woo) G91 Suri Wie Gat S412 Masih i969 1208 T6sses iiiemt 2's e's asa. 79.33 32.94 0 isle Ltn enesr fies? 7 pli “grod.e “sera. act 38.75, 6 tte Sloue yeas Net Dito dota pte.0 sale 25.68 {se oloas ons me Bios 39210 eonso 38.1 su 2498 olon39 tooans Hoo 135 Blows? 3 5500 ood 3838 S $155 olois toon 150.0 1333 Olona 0 demo ten? 353 © S194 OLoas ooter 6:0 ER B:0hRE 8 éec8 18 IEF 3693 88 Laie 1w0.0 1.095 0.08800, 0 $038.0 168.9 25.17 7 Yer Seam oon 190.0 1031 0.06462 3 78.0 170.7 5.21 3 yaa Oleaes toma? 200.0 0.9839 0.08153, sein. tas 28.36 9 Hat oloaas toon30 hio.0 —9'9362._0"0sbie geste inet sas 1 O£E gem Coons io:0 9.8950 0.0388 Siro.o 118i) 38 8 813 Ooze Home) hio0 818836 Dlosnar Jen. 1772 35.60 $189 010255 0010s Jeo Olsi76 Olosovr Jenin 183 38.79 3 9134 o!oae7 tooo 350.0 tbe OLanno1 BIS! ol) 38.58 3 915m O02 190086 240.0 0.7545 9.04701 181.4 26.22 34.64 20.8 9.92 0.0290 1.00072 Hoo 017258 0"04s25 17 26183 M419) Qe} 013 O.os03 ooo nwo:0 0.6998 9.08362 0 26.79 35119 45:7 108 o-08Is n90.0 016355 D"0u011 M52 312 S's Male 4019 Olome hoo OleateO\03937 ire ds) Ye2s Hels tne Oloass iro.o Glee oc03ei4 1988 3828 Seles gs.0 119 0.0869, Bao'0 0159329103687 W999 ds.72 io9 Meola 212 O-0sBS woo 0° s3s6 Oloasee 10 3918 iss 5.7 2.0398 35:0 OSS Bates fat deus Sen ate oan 360.0 0.5838 0.0338 195.2 90.16 36.52 487.8 13.1 0.0028, 370-00 s2a8 0.03286 ies joe? feos fee tae O.ous 300.0 O.s0i6 0.03127 10230.0, W962 31.73 10.10 508.0 tho 0.0875, 400-0 14890 0103048 40550: ire i ales S105 a3 O.0e 0:0 aleesTleages | 11210°0 Woe Mee Sak Ta @°osa4 tonosT as aedsQloamI@ 1690.0 gore 3asy noe S519 1S.4o-0ss9 10005 ‘itolo ean 02839 13320°0 dos’) Gest sae En} 1815 0-02 otos0 s00:0 013910. 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Mnes.0 Hsele 2806 Mins Met nasa W010 DATS ONAL 3916.0 S2IaL0 T9941 25.38 MAE 7.5 0302 170.0 2.218 0.1445 4173.0 $558.0 161.2 25.29 wast 1.00283 Wo.0 3pm fuiaes —Measlo Gaan-0 e509 35.29 isso $o03s2 ahora toes naate duno Gse0 Tes? 38-35 sows 100239 2:0 Yass 011s i960 6925-0 tesa 28.40, S018 Olnaas 100227 do'o Fam pioe sasro Taea-0 170-0 35.20, 4085S Ooms tCo02i7 HIME 81088 SH:8 SO UES Be B39 ES 0S INN? 3H0[0—1g209'1010 $968.0 7549.0 172.9 a5.8h does 9°38 Dloz6e 300198 Gsolo—USs4 Oconee gan8.0 29CD 3783 26-08 412.3960 010279 1.00180 260-0145 009308 64910 BoAD-O 178.7 26.24, fod 9.94 5.00183 270.0 1.436 0.08953 6755.0 $989.0 177.0 26.51 ars 10, 00178 260.0 13840108629 Torso B5ar-0 178.3 26:80, 5210) 00170 dso.o "3860108527 7295.0 9495.0 179.8 7-13, aaa to, ‘0164 Sooo Laat Oconee 15670. r0ns0-0 Yg0ck 37-48 ale 003s8 as.0 a0 olarasy Saeco tongo. tek 38.39 ash oi Sao Mima Blonser earzo ttisoco taala 873 433 oie Hoo 1137 Gloves fruplo Tsa0c0 asia 29.19, ss 013° Hoe its bcunen foro His0o.0 Ihe sea an? ‘01 380.0 1.017 0.06558 9911.0 t3070.0 189.6 31.21 39.61 499.3 as fo0.0 019457 0.05019 0880.0 T3870.0 I91-7 32:31 40.70 S10. ae @o-0 —acgnns G.oseTo 11490:0I35e0-0 195-7 Meo 297 S319 20108 co.9 0185920105251 125900 Tear0.0 197-6 35.76 44.13 SED‘ 20103 40.0 G1HoxtOoso12 135200 17310.9 1991s A692 45.38 $80°3 ‘0098 ‘00:0 «G12N19 OouRtT 140700 14920-0 20L"4 AROS Helah S62" 00095 540.0 0.7146 0.04434 15630.0 201200 208.1 40.21 48.35 0008 Sooo O.4890Biuea9s Le4s0l0 QHHH0L0 dose 420 49.38 00s $80.0 0.6652 9.08146 17280.0 22110. 208.6 2.1) 50.46 10.0808 1.00082 Sooo eleaae Blocdod Ueisaco Zatzoco aes 29a Sd + Slonat 1o009 030 MPa tae 90.75) ast.8 “579.0 67.92 a 3.42 206.0 gras wo.0 43853 Sm20 93013 341 S10 ise Ves530 13000 41003 Salo 43122 2's Sect nk Vs0000 Taelenr® 39919 yu30 ea S79 Be Viste 130.0 4793 4omd.0 1480 26.30 37.36 suas 00886 tase 4516 46919 94 deo? 3679 sa 100858 140.0 3s 4isa0 150.9 asi2 Gee Sst ose Hoo 408 Bie 82 Bak ie 599 Veoaoe 591 ‘7 Chom, Ret Data, Vo. 16, Ho. 4, 1987592 B.A. YOUNGLOVE AND J. F. ELY Thermophys propels of metlone ~ Gotnues rr Kain! olin? moist’) “Minot” vee WK) Co 1.0 3.518 9.2181 4445.9 $814.0 57.8 25-83 ED 336. TH 0.0191 F040 Ha0-0 a3 pans Od SH6I- 158g 28-38 Ma's MTT 912 ovnans Lonae Woo ENG BARR eek RES ASR BE aces 2o0:0 2195) tks? 4919.0 Gssnlo tena 25403036 Mera 28S Lome 1.00N8 nio-0 2180) DIN Sel ROH oa. asu#s MAE ane BN Oloate 1.008 20066 idee Sagan Saayo feels 25.88 SHY MMe. 837 oneT 20.0 2.488 0.1829 Sosz.0 T926!0 169.5 25.84 eS Mada 927 O10Ree aso.) 2S LtasT © GaISO 2720 170.8 36.03, MLM) aang et OvoaetLLooate 360.0 22a 1400 «GaTTIO R6a0L0 172.3 de.38 Salon 4l9.6 9195 10RD 27S © Fest o.t297—Towo-0 9523.0 749 36.82 Asal e's fol6 Loa ouass © 2.005 0.1281 Tae1-0 9679.0 75-1 27'15 35-7 aaP'a 18.3. OLOaSD LLoOaKe 9 11938 0.1209 7556-0 rondo. 179-3 27151 3g.0S 449] 1113 OunaHs Longa 0 1g BlNleg—Tanecn towo.9 173 nim Mao aeele THe minus t eman 8 Ete SS Neo T8Hee He: TN AS ERS Solas Tens 0 tito octost gana 1tia0-0 tO 28/34 iad Head 12.2 Ov0Re4 1 Lo0ate 9 1108 0.1065 4698.0 11510.0 182-0 2929 376R arsA 12.5 OLDE 100309 D tess Oltoae —Soseco HHamoco tact 39.68 Jest @:o4rd 100205, 31.0 1.565 0.08773 9893.0 12660.0 185.2 30.69 39.14 0.0448 1.00192 Sano 42. B.ops13 $505.0 1309000 186.3 S1a2 9.80 S\oa60 1oo387 200.0 4G G.er0a) s05u0'9 wn.0 8:3 Aha io.ae oat T0078 to:e M7 logos tago.0 Issanca toa'a Galen ioseo tootst 60.0 35) Olareds t2se0.0 teaioca 94a 35.6 9.0393 100184 0.0 306 0.078i9 13310.0 1730-9 196:1 36.99 9.0530 oores 00.0 138 0.07217 4060.0 16220°0 198-0 38-06 Siosee 1 00n42 520:0 113 Ocoubse Masoco Toiaoce tosis 33.46 oot E003 540.0 Sona logget 436300. 301300 201.7 40.21, olen 10083 $60.0 0.06441 6440.0 21100.0 202.5 44.28 e073 1.00121 0.) B.0s0tT | 18350.0 3390.9 300.9 2.54 6.0802 1.0118 so.78* 451.9 2847 -$729.0 $115.0 67.93 34.04 206.0 0.5 1.67753 woo) ae'a nae “gua “guue.9 Ts sca is7:0 1208 gssa2 130.0, Sieg 35.38 20 Bis? 9B.0 017s 160488 Tatcaoge 301.9 34.43 sae 99 M19 0.187 so” 8.383 bane Weg 36183 5.a5 olmse S90 olga uso 36.27 Sse “ose Sign Oak 1506 25194 36152 jap. loz 0.0190, Sos o!a? ise 257) isa) dane 99 O.ose foe Ss HST 3537 35k BAT 899 8.0088 Wo.0 4.tas 0.2770 157.1 25.49 38.03 845.2. 7.34 0.0207 0.0 Ak oon 39.0 2546 Mom 55-8 sh OOM noe Sash 838 ead a5.g1 deen 5.7.23 o.0aas noo Xs) 0.39 tele 3589 is) aso B13 ones hoo aa ana 166 38.71 Mies doe B94 OLoasy boro 326302034 tro se) Min imag 9139 Olea hoo = Nom Baath 169.8 3629 Sloe 49.19/97 lone amo aT ROD 112 26:85 35.28 5.9 10.3 0.0805 20-0 «2.781 9.1703 GmME.G 9305.0 172.4 36. 35.52 4nd 10.6 @.0RIE 1 Gana 300-0 21590 0.1615 7546.0 10020.0 174.9 27.52 36.14 448-8 11.30.0344 1.00317 sios0 sng rts6) 7525.0 1m390:0 176.1 37°91 S630 458-7 1/8 0°05? T0007 0.0 2a st slog. ovs0.0 177-3 dear dela? MaDe 1119 01081 Loner B00 25350 taes 5382.0 11120-01744 28.75 STM 46e_9 122 9103 T0088 Bo:0 3389 aT Seance 5000 479:8 ded) 99s 52 HES 020k Looe “Phys Chom. at. Data, Vol. 16,No. 1967‘THERMOPHYSICAL PROPERTIES OF FLUIDS 593 ‘Teermaphical properses of methane - Canine 7 beiy Deny EOS Gyan Wie Kym? maid? Ymat__met_tnckk) Mn) ais Pes ons 350.0 2.213 0.1887 4979.0 11660.0 160.6 29.69 38.21 ABA 12.8 1.09271 iao'0 Oca $279! 1220-0 Her docts EO BT's 13. Hanae 30:0 651308 956810 2480.0 U82' 30130 9120 Ea Sa vnn3ss 300.0 0.1269 9895.0 130$0.0 183-8 31.29 9.71 499.2 13.7 1.00250 200° 0205 0530°0 F3480-0 385.9 32 4O.79 SLOSS Yoon? 0:9 0.1094 1870.0 138300 19919 30e lon Sa Sa Vooais 60:0 Olin? 12580"0 Yea00-0 BITE 3597 MID SIDE 15.9 100208 {30.0 Bito03 1g310.0 Wvann-0 TR 362 ASS SDS TSS 1.00199 000 8.03623 14060"0 14210-0 195°6 $805 46-46 SEE 17.9 -066@ 1.0019 53.0 BOSE THNSD-D ASHEN BES NG SE SRT 17S osama 18a 510.0 (0.08907 15620-0 20120-0 199.3 40.22 45.61 $81.7 18.0 0.0738 1.00175, 560.0 0.08587 164400. 28900-0 201°3 4-21 48159 S812 IBS LOTTA TGoI69 00. .o80r3 | 16130.0 25120.0 206.5 42.98 51.31 610.0 19.4 O.08a21.oo1S8 050 Ma star so.s* 2.17 5729.0 67.93 $4.08 $3.40 1538.0 206.0 0.028 1.57787 100.8 args “Saas. Ghar Gna Seloe Lasela Isto 0/2081 essss 120.0 25'58 0 “At3I-0 S319 Sn'st 56.75 taste 981 O17 160507 199 3s yess" S740 0) SRG Tayo gO 1g sr762 HSS feat EES Shed 3b Secs tba CHS ISH ns Ouse 3126-0 816 26.96 39189 “28ST S180 LOTS? 100966 40:0 Sars 3259:0 5.8 26.68 3.03 292.3 $167 O.0162 1.00038, 148.0 outst 02.0 M1 36.42 38.20 299° 5186 Lote? 1.00895 10:0 Story 3816.8 150.8 35.81 36.58 9.78.43 0.883 1.00089 1. 0.3738 4085.0 183.0 25.2. 6.19 0.0198 1.00734 10. oie sto Iss 35.00 he elon09 Looser 200. 0.3107 158.8 25.53 1.89 0.0232 1.00611 bi3oad 15916 5.54 010285 100598 g 20. 294s eos 25°57 80n39 00878 to, 2e01 tet 38.64 B29 onssh 20) 3889 test 38:90 0251 1 e0302 a 1665 26.09 oozes cooast 2346 167.9 26.91 5.18 4in.s 0.0294 1.00461 iss 1993 2est 35:38 ee Sloaoe Tones a M0.5 26.86 3510 0 Sloe eon 2094 ma Pa asia dane loss enui 2022 M30 st deze fags O.o348 100398 iorao:0 17s: 36:33 3897 42-2 oles 00372 tnnte:o 176! 28:76 3738 68-7 9.0386 10036 3490-0 1779 39 Ml St Ma7e:9 178.¢ 29.70 SHIT aS o.04rs — ¥on340 122$0.0 179.8 39.19 ast (0.0430 1.00330 2640.0 160-9. 30.71 ri olo4es 10032 Hi0a0:0 142.9 31°24 92 lous 100312 Waei0:9 Hb: 48 a3 8.0837 100382 13820.0 188.0. 34.61 52:1 6.0561 100259 16390:0 190.0 35.79 5's 172900 1919 36.93 Asa $52.6 9is0.0 19816 381749158 S23 00586 “002s? 068100247 Slonea 100038 4: Phys. Chem. Rf. Data, Vol 16, No.4 1987504 B.A. VOUNCLOVE AND J. F. BLY “Taemophsen propertin of methane - Canines K___ bay? ato _IAeoX)_—_“Iimtk)” ls sn Wie) Cam MOQ LTR OANTE 5600.0 2uLI0.0 197.4 40.22 48.63 SEL. 18.0 9.0139 1.00219 seco EH SHO oben (8 TR SBE TS Sea saa Soc) 166201086 aoe: 2010 2.18 $0182 600. 19.0 O10409 Yo0a08 sole 607100) Boiv0lo 2029 aioe $133 S102 19.8 Lome oI oot 451.9 5118.0 5707.0 67.94 34.04 $3.40 1598.0 206.0 0.228 1.67762 woo 91s Ssayr'o “sans'o 93.10 Galas S406 ass"0 15910 01209 asse? tno, ee? 3ss8l0 “Gea 9b loa Gels) Utes tela Olle snaee tie.60 9.2 3os4.0 “aao9.0 S168 atlea@o.94 leer. 7.9 lias 85149 138.699 "5.399 si7aio “algo walle 37.38 40.98 “ae6.1 “5.66 O.01e4 1.011 woo 51398 Suos'o @asz.o 43!) 311s 40°73 ars 5°71 Longs ons? iso b9 Sisco Galo 14s:3 26.78 9.58 esis $190 cond otoRs 130.0 81833 Ssoolo Wg2s-0 t4e'e G6.si 38.6) Mos? Go OLONS otoNe 100 Tike 3781-0 SooR0 149t 2412 aa Hed 64s OOIRG Loose iwo.0 3.396 Saco Spa0.0 1834 $0003 iw0.0 6.38 4390/0 6098-0. 135.3 Yoon 20.0 om. tesco G4s2.0 187") S00 fosn Se $545.0 6628-0 158.0 veons ane Slaw Su’ Tiss.0. 140.5 10066 ao.0 S18) Seaiso 7500.0. 142.0 1.00633 joie 952 So0uio 7as6.0. 143.5 100608 soo ata S168'0 g207"0168°0 20059 roo 4519 6424.0 $560.9 166.4 4.00555 mo 38 S102! $9140. 16.7 Hoose ioc ies S72! 93700 18.0 Taosis 00.0 3.898 382.0 S981.0 171.8 ooer fico 368 Js0il0 v03600 172.9 3.00462 hoo er soes'o 107200 173.8 Yoo Sioo 3500 fio 111000. 178.0 100433 joo 36 56019 148800 17753 00408 yoo.0 3.281 9261.0 2240.0. 178.3 1.00396 joo Sia 9$67'0 126300 173.4 003s Goce 088 bare) 130300 140% ieoars foo 90a 10520°9.43830°0. 62's, 00356 mo0 ta 1180: 14660:0 1845, 1.00339 fon has Hs60°0 15510.0. 186.5 1.00393 aie RAD 1390.9 7200.0. 190.3 102s soo Me {os0'9 2200.0. 192.2 Tomee smo a6 His20.0 1910.0. 198.4 Vo0373 S0;0 ose lta8st6aa0.0 1090.0. 197.7, Veoas So0:0 pou 14243 19260°0 2090.0. 199.4 Eons (080 MP ose soa 452.0 28.17 -s727.0 5609.0 67.95 4 Lem 19.0 9g arp “gaaglo “sni0.9 93.08 38 ress ioe He's ANE AeS:3 EB 180562 Holo S9u"@ alee “asealo “asaelo 7038. 32 is7es2 400, 37's 28's) “aoee-0 “a9ma.0 92.17 154865 1ae'390 Sone Gao “anv “t6s2.0 gate 153i 0" ist bie 58.0 Gate tad 27.58 1.01835 15010 118s Olden Sato 42.0 ane 276 Touass ‘Phys. Cham. Ret, Dat, Vol. 18, No.4, 1887‘THERMOPHYSICAL PROPERTIES OF FLUIDS 595, Thermophys! propertis of mane ~ Continued 7 Dassy Deaty WS Gy Gp Sound Vie. Therm ‘Deh K kim? ld? vol Weak Simch) 3K) vs has Wen) _ Com 155.0 41.29 0.7099 3860.0 4696.0 144,926.85 oor 1.01386 330-0 "9.517 .5201 3991.0 3281.0 148-8 6:20 boogea9 180.0 9248 ST64 268.0 5655.0 150.7 25.96 Bloate tanta 190.0 8655 sams 454010 RN-D 52.75.80 Bioxga 01082 thn Puan on'ante dane’ euaen tags ets oan 100908 tos.0 1.912 Cavan H9a2.0 608.0 188.8 8.74 Sioned oogze Rov) 69S 014796 5076.0 674I-D 156.3 25.78 0244 1 “on9aa 280 749k 014669 $08.0 6922.0 187-1 28.76, Bina 100099 hol) F298 bases Stato 7100.0 tT. 5.78 onset eames 20.0 6.625 0.4130 $472.0 7809.0 161.0 26.00 0.0375 1.00813 3s0:0 6337 OLg806ISR-O Ge. T62.5 26.17 leans 100777 geo) LoS Olde Gag-0 SIG. 168.9 26.3 fumast eons H:0 Sak 6.368 GaSe ane Mes.2 ele bower t auos0 Sell 0.303) 6947-0 985.0 166.5 26.92 ole 1 dose $ia0g orga Faana 9506.0 167.8 27.25 10M Son.) 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YOUNGLOVE AND J.F.ELY Thermophoset propane of methane - Canine Kbps? dns oth Mont) inate WANK) Cone 20.0 2.6% 0.758 $8.0 619 1.8 35.90 448.7 0.0991 00831 20.0 7.ay 9.48 9199.0 Fes 6.98 6 OLS 8.0803 bones too ote cane $5020 W658 7D) eae NG a3 fon Gaia ae 992k.o tert Bel 36. a8 O08 fon NANG ae D sosoo.o 168.3 bri99 9m A542 ose Hon Slate Blase D tiow.o 190.6 dee? 3795 Mer oio3s0 100736 ison Skea D Umino i723 a9. Gass dance 2.0419 1 o0ee3 seo Sat) 03368 8 tn0n.o 140 3m Wes MeN d Soe 1 otees Moo S38 haan D iiseoo ts. MIs Mes) Bh ioe 1o0ees fon Slop baatae D 12990-0 aU olen 90 Oost Tope ae oognataneen.0 1800.9 he ioe stn“e 2006 100895 EHS G3 tein. 5800.0 fet ae Sh 8.0364 Sisal Azo1 baggie aod tase isso 4395's 2.0596 1 onst6 hae 913808 13a7e.p 13260 foes 45152 Ssh Olas Tones Soon Noo baN2—Ldnon’n tena. wisn Sve oinmos tones Sinn EI ine See. 8 dot. Woe iene sit Gon 10043 580.0 Rm o.2o7y 17280-02208, 2214 50.61 601 o.ns1yt9oans 120 MPs i ssn 28.38 5683.0 34.05 52.35 1541.0 207.0 os 1.69790 ‘ane ana 9 “si00-0 B45 $4100 U459°0 58-0 01209 asue2 Bz 38.68 8 aoe.0 Sas) S688 taselo "981 Olam tenes es ules 8 “asa2.0, Sain $838 isso a2 octet T'sr9a3 387 2.6 9 "2300.0 31.09 64.86 919.3 55.8 9.130 1.5169 Bog rar 8 “ame.9 Bos Gis Moe St Oras Tsner Mee 116 8 “aas.0 Bs file basis “Ea loi Loney qa hast 0 ines fey ities ele Sis alone Tone 18.10 o.9at4 0 5176.0 26.11 aoa? 237.19 0.0219 eke S00 363) GaN 46k olnoe t iiss ope 3 eMs0 Selo nist ges 807 Lone Wax arms, 9 6618.0 25.99 36.99 346.2. 8.42 0.0252 1.01484 Hos 85te5 a3 Boe e383 EB ORS east ie oleee@ a) S598 Rela 7609816 Lomo otana 240.0 10.09 0.6291 $806.0 7713.9 26.12 36.2 7 3.i¢ 0.0260 4 Geo’) "Seas agape Sone so B29 Melt? 40s’ 5°78 eas0 1 doo 9.216 stash TO Beas 3620 7 wo. oat poe | Naw nsup gaat.n Bano tem deae any tbe ona Solo Hina bisa M7y'8 Sanco teala Gn dees aa Tons imo Tae olasia—Hus2-0 Speco tess Figs Geld) Mea 14 Ons 1 So! Tensncdray 7435/0 0200-5 t66-9 decor AT20. 458-77 Ose Bic) 31leolkes—Aata.o THogolo taio ans Hraa e013 12.3 laa Molo Sins olta98—fen6.9 iao.0 trh.z 29.39 dead aed 12.6 Lous §s00Slesk lates Bons. an.9 Hvis 29.76 get able 12.9 Lond Mod 64h elaaee Sone Havo.a tie as MIT aa 122 Rows Moo SHO BIW SSteco Tastee a's Mote Belge fala 13'S BlousD Phy. Chem. Ret Data, Vol 18, No. 1967