1.

In adsorption of sucrose on charcoal , the sucrose is called

1)adsorbent 2)adsorbate 3)adsorber 4)absorber

Ans-2

2.In physical adsorption the approximate heat evolved in KJ/mol is

1)20-40 2)40-60 3)60-80 4)40-400

Ans-1

3.For adsorption of gas on solid ,a plot of log x/m vs Log P is linear with slop of
the equation equal to

1)k 2)log k 3)n 4)1/n

Ans-4

4.In physical adsorption , gas molecules are bounded on the solid surface by

1)chemical force 2)electrostatic force 3)gravitational force 4)van der waal force

Ans-4

5.How many layers are involved in chemical adsorption

1)1 2)2 3)many 4)zero

Ans-1

6.Which of the following is not correct regarding the adsorption of a gas on the
surface of solid

1)on increasing temp. ,adsorption increases continuously

2)enthalpy and entropy changes are negative

3)chemisorption is more specific than physisorption

4)it is reversible reaction

Ans-1

7.The Langmuir adsorption isotherm is deduced using assumption

1) the adsorption sites are equivalent in their ability to adsorb the particles

2)the heat of adsorption varies with coverage

3)the adsorbed molecules interact with each other

4)it takes place in multilayer

8.Adsorption is accompanied by

1)decrease in the enthalpy , increase in entropy

2)decrease in the enthalpy , decrease in entropy

3)increase in enthalpy , increase in entropy

4)decrease in enthalpy , decrease in entropy

Ans-3

9.Which of the following is zero during adsorption

1)delta G 2)delta S 3)delta H 4)all the above

Ans-4

10.Which of the following statement is not applicable to chemisorption

1)it is independent of temperature

2)it is highly specific

3)it is slow

4)it is irreversible

Ans-3

11.Adsorption is used in all the cases except

1)for decolourising 2)in homogenous catalysis

3)in separation of inert gases

4)indehumidiser

Ans-2

12.silicate garden is developed by setting of coloured ions in void of silicates .

it is the case of

1)adsorption 2)absorption 3)both 1 &2 4)none

Ans-1

13.Which of the following characteristic is not correct for phyisical adsorption

1)adsorption increases with increase in temp.

2)adsorption is spontaneous

3)both enthalpy & entropy are negative

4)adsorption on solid is of reversible nature

Ans-1

14.In Langmuir model of adsorption of gas on solid surface

1)the rate of dissociation of adsorbed molecules on the solid surface does not
depend on surface covered

2)the adsorption at single site on the surface may involve multiple molecules at
the same time

3)the mass of gas stricking the given area of surface is proportional to pressure
of gas

4)the mass of gas stricking the given area of surface is independent of the
pressure of gas

Ans-3

15.Plot of log x/m vs log P is a straight line included at an angle of 45 . When

pressure is 0.5 atm&Frendlich parameter K is 10 , the amountof solute
adsorbed per gm of adsorbent will be ;

1)1gm 2)2gm 3)3gm 4)5gm

Ans-4

16.which of the following statement is incorrect regarding physiosorption

1)it occurs because of van der waal forces

2)more easily liquefiable gases are adsorbed readily

3)under high pressure , it result in multilayer on adsorbent surface

4)enthalpy of adsorption is low & positive

Ans-4

17.Adsrption power of the adsorbent can be increased

1)by increasing surface area

2)by finely dividing it

3)by making it porous

4)all the above

Ans-4

18.Langmuir adsorption isotherm works particularly well

1)where multilayer adsorption can takes place

2)where only unimolecular adsorption can takes place

3)at initial stage where unimoleculer adsorption takes place & not after that

4)in all above

Ans-2

19.adsorption play no role in

1)in sugar industry to decolourise the crude sugar

2)stoppingbleding from a fresh cut

3)drying of substance by anhydrous CaCL2

4)concentration of ore by froth floatation method

Ans-3

20.Adsorption of gases on the solid surface is generally exothermic because of

1)enthalpy is positive

2)entropy decreases

3)entropy increases

4)free energy increases

Ans-2

21.Rate of physiorption increases with

1)decrease in temp

2)increase in temp

3)decrease in pressure

4)decrease in surface area

Ans-1

22.Which of the following gas molecule will have maximum value of enthalpy
of physiosorption?

1)C2H6

2)Ne

3)H2O

4)H2

Ans- 3

23.Spontaneous adsorption of gas on solid surface is an exothermicprocess

Because

1)dH for the system increases

2)dS for the gas increases

3)dSfor gas decreases

4)dG for gas increases

Ans-3

24.Which of the following gas is adsorbed most by activated charcoal

1)CO2

2)N2

3)CH4

4)Ar

Ans-1

25.During adsorption

1)TdS is positive

2)dH-TdS is negative

3)dH is positive

4)TdS&dG becomes zero

Ans-2

26.The volume of the gas H2, CH4 ,CO2 &NH3 adsorbed by 1g of charcoal at
288 K are in order

1)H2>CH4>CO2> NH3

2)CH4>CO2>NH3>H2

3)CO2>NH3>H2>CH4

4)NH3>CO2>CH4>H2

Ans-4

27.What is equation form of Langmuir isotherm under high pressure?

1)x/m=a/b

2)x/m=aP

3)x/m=1/aP

4)x/m=b/a

Ans-1

28.Rate of physiosorption increases with

1)decrease in temperature

2)increase in temperature

3)decrease in pressure

4)decrease in surface area

Ans-1

29.Which of the following is used to produce smoke screen?

1)calcium phosphide 2)zinc sulphide 3)sodiumcarbonate 4)zinc phosphide

Ans-1

30.What is incorrect for chemisorption ?

1)single layer of molecule is adsorbed

2)enthalpy of adsorption is high

3)activation energy is high

4)noneof these

Ans-4

31.Which of the following process of metallurgy involves adsorption?

1)magnetic separation method

2)electrostatic separation method

3)gravity separation method

4)froath floatation method

Ans-4

32.The phenomenon of accumulation of substance on solid surface is called

1)adsorption

2)sorption

3)absorption

4)desorption

Ans-1

33. Sorption is used to describe

1) adsorption only

2) absorption only

3) both adsorption & absorption taking place simult.

4)none

Ans- 3

34.Chemisorption decreases slightly on

1) increase of pressure on adsorbate

2) decrease of pressure on adsorbate

3) both 1) & 2)4)none

Ans- 1)

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CATALYSIS-

1.Role of catalyst in a chemical reaction is to change

1)enthalpy of reaction

2)nature of product

3)activation energy

4)equilibrium constant

Ans-3

2.potassium meta sulphite used in a food preservation is

1)heterogenous catalyst

2)homogenous catalyst

3)negative catalyst

4)positive catalyst

Ans-3

3.The catalyst used in preparation of Grignard reagent is

1)iodine powder

2)iron powder

3)manganese powder

4)activated charcoal

Ans-1

4.Which of the statement regarding catalyst is not true

1)catalyst are sometimes very specific to reactants

2)a catalyst remains unchanged in composition & mass at end of the reaction

3)a catalyst can initiate a reaction

4)a catalyst does not alter the equillibrium in a reversible reaction

Ans-3
5. Which of the following is characteristic of a catalyst ?

1)it changes equillibrium point

2)it initiates the a reaction

3)it alter the a reaction

4)it increases the average KE of molecules

Ans-3

6.a catalyst increases reaction rate by

1)decreasing enthalpy

2)decreasing internal energy

3)decreasing activation energy

4)increasing activation energy

Ans-3

7.aboilogical catalyst is essentially

1)an enzyme 2)a carbohydrate 3)an aminoacid 4.a nitrogenous base

Ans-1

8.Action of shape selective catalyst depends upon

1)mass 2)solubility 3)particle size 4) none

Ans-3

9.Identify the correct statement regarding enzyme ?

1)enzymes are specific bio catalyst that can normally function at a very low
temperature(about 100K)

2)enzymes are normally heterogenous catalyst that are very specific in action

3)enzymes are specific biological catalyst whichcan not be poisoned

4)enzymes are specific biological catalyst which posses well defined action
sites

Ans-4

10.In a reversible reaction , a catalyst

1)increases rate of forward reaction

2)increases rate of forward reaction to greater extent than that of backward

reaction

3)increases rate of forward reaction and decreases rate of backward reaction

4)increases rate of forward & backward reaction equally

Ans-4

11.which statement about enzyme is not correct?

1)enzymes are in collidal state

2)they are catalyst

3)it can catalyse any reaction

4)urease is an enzyme

Ans-3

12.The rate of biochemical reaction carried by enzyme in human body is 10^3

times faster than when it is carried in the laboratory .The activation energy of
reaction

1)is zero

2)is different in two cases

3)is same in two cases

4)none

Ans-2
13.In petro chemical industry ,alcohols are directly converted into gasoline by
passing over heated

1)Pt 2) ZSM-5 3) Fe 4)Ni

Ans-2

14.Which among the following are enzyme catalyst

1)glucose 2)amylase 3)trypsin 4)nuclease

Ans-2,3,4

15.Reaction of zerolites catalyst depends upon

1)pores 2)aperatures 3)size of cavities 4)pressure

Ans-1,2,3

16.Zeolites are

1)enzyme catalyst

2)liquid catalyst

3)shape selective catalyst

4)non specific catalyst

Ans-3

17.In hydrogenation of oil the catalyst used is

1)Fe 2)Pt 3)Ni 4)Mo

Ans-3

18.The conversion of maltose to glucose is possible by the enzyme

1)zymase 3)maltase

2)lactase 4)diatase

Ans-3
19.According to adsorption theory of catalysis ,the speed of the reraction
increases because

1)adsorption produces heat ,which increases the speed of the reaction

2)adsorption lowers the activationenergy of reaction

3) the conc. Of the reactant molecules at the activation cenetres

Of the catalyst becomes the high due to adsorption

4.in the process of adsorption the activation energy of the molecules become
large

Ans-1

20.pick out the one which does not belong to the family ofenzumes.

a.lipaseb.pepsin

c.ptylind.cellulose

Ans-4

21. which one of the following satement about zeolites is false

A.they are use as cation exchanger

b.they have open structure which enable them to take up small molecules

c.it is alumino silicates having 3D network

d. some of the SiO4^-4 units are replase by AlO4^5- &AlO6^9- ions in zeolites

Ans-4

22.Enzyme are

1)substance made by chemist to activate washing powder

2)very active vegetable catalyst

3)catalyst found in organisms

4)synthesis catalyst
Ans-3

23.A process which is catalyst by one of the product is called

1)acid base catalyst 2)auto catalyst 3)positive catalyst

4)negative catalyst

Ans-2

24.InHabers process for synthesis of ammonia , the catalyst iron gets poisoned
by the following

1)NO , H2S 2)NO , H2S , CO 3) CO, H2S 4)CO2 , H2S

Ans-3

25. In the esterification reaction of the acetic acid with ethyl alcohol , which of
the following acts as autocatalyst?

1)acetic acid 2)ethyl alcohol 3)ester 4)all

Ans-3

26.Stach is converted to make maltase by the following enzyme ?

1)invertase 2)zymase 3)diastase 4)none

Ans-3

27.Which of the following means boiling stones in greek ?

1)catalyst

2)enzyme

3)adsorbent

4)zeolites

Ans-4

28.When oxalic acid is treated with acidified potassium permanganate , which

of the following acts as autocatalyst?
1)CO2 2)SO4^-2 ions 3)Mn+2 4)water

Ans-3

29.Which of the following is example of negative catalyst

1)vanadiumpentaoxide for oxidation of sulphur dioxide

2)Pt for decomposition of H2O2

3)glycerine for decomposition of H2O2

4)all of these

Ans-3

30. Zeolites posses the property of adsorption because of

1) free valencies on the surface of zeolites

2) its structure

3) its surface area

4) all the above

Ans- 1)

31. Zeolites are

1)crystalline

2)amorphous

3)both

4)none

Ans- 1)

32. In Wackersprocess ,_______________ catalyst is used

1) PdCl2 or CuCl2

2) Ni
3)Pt

4) ZnSO4

Ans- 1)

33.In Contact process __________ catalyst is used

1) Ni

2) Al2O3

3) Pt or V2O5

4) Mn

Ans-3)

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